Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Mikrofilm Buch |
| Sprache: | German |
| Veröffentlicht: |
1997
|
| Ausgabe: | [Mikrofiche-Ausg.] |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Bonn, Univ., Diss., 1997. - Mikrofiche-Ausg.: 3 Mikrofiches : 24x |
| Beschreibung: | [10], 153, XVIII S. graph. Darst. |
Internformat
MARC
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| 049 | |a DE-29T |a DE-355 |a DE-11 | ||
| 100 | 1 | |a Vogel, Christian |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen |c von Christian Vogel |
| 250 | |a [Mikrofiche-Ausg.] | ||
| 264 | 1 | |c 1997 | |
| 300 | |a [10], 153, XVIII S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b h |2 rdamedia | ||
| 338 | |b he |2 rdacarrier | ||
| 500 | |a Bonn, Univ., Diss., 1997. - Mikrofiche-Ausg.: 3 Mikrofiches : 24x | ||
| 650 | 0 | 7 | |a Glycosyltransferasen |0 (DE-588)4157751-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Chemische Synthese |0 (DE-588)4133806-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Enzymsubstrat |0 (DE-588)4311292-4 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Glykosidasen |0 (DE-588)4299582-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Glykoside |0 (DE-588)4021359-6 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Glykoside |0 (DE-588)4021359-6 |D s |
| 689 | 0 | 1 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
| 689 | 0 | 2 | |a Enzymsubstrat |0 (DE-588)4311292-4 |D s |
| 689 | 0 | 3 | |a Glykosidasen |0 (DE-588)4299582-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Glykoside |0 (DE-588)4021359-6 |D s |
| 689 | 1 | 1 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
| 689 | 1 | 2 | |a Enzymsubstrat |0 (DE-588)4311292-4 |D s |
| 689 | 1 | 3 | |a Glycosyltransferasen |0 (DE-588)4157751-6 |D s |
| 689 | 1 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007889716&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-007889716 | |
Datensatz im Suchindex
| _version_ | 1812453241027297280 |
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INH AI,T
SEITE
1. EINLEITUNG 1
11 BEDEUTUNG DER KOHLENHYDRATE 1
12. BIOSYNTHESE DER KOHLENHYDRATE 1
13. ENZYME 2
2 THEORIE 4
2 1. CHEMISCHE SYNTHESE VON OLIGOSACCHARIDEN 4
2.2. SCHUTZGRUPPENSTRATEGIE 4
2.2 1. THERMODYNAMISCH KONTROLLIERTE REAKTIONEN 5
2.2.1.1. KETON-SCHUTZGRUPPEN 5
2.2.12. ALDEHYD-SCHUTZGRUPPEN - 7
2.2.13. SCHUTZ DER ANOMEREN 1 -HYDROXYGRUPPE 8
2.2.2. KINETISCH KONTROLLIERTE REAKTIONEN 10
2.2.21. DIE METHYLGRUPPE 10
2.2 2.2. DIE BENZYLGRUPPE 10
2.2.23. DIE ACETYLGRUPPE 11
2.2 2.4. DIE BENZOYLGRUPPE 11
2.2.25. DIE TRIPHENYLMETHYLGRUPPE 11
2.2.26. DIE TRIMETHYLSILYLGRUPPE 12
2.3. METHODEN ZUR KNUEPFUNG GLYCOSIDISCHER BINDUNGEN 12
2.31. SYNTHESEN VON SS -D-PYRANOSIDEN DER GIUCO-REIHE 12
2.3.11. DIE OXAZOLIN-METHODE 13
2.3.12. DIE KOENIGS-KNORR-METHODE 14
2.3 1.3. DIE ORTHOESTER-METHODE 16
2.3.14. DIE ANHYDRID-METHODE 17
2.3.2. SYNTHESE VON A-D-PYRANOSIDEN DER GIUCO-REIHE 18
2.3 2.1. DIE TRICHLORACETIMIDATMETHODE 19
2.3.2 2. A-GLYCOSYLIERUNGEN UEBER FLUORIDE 20
2.3.2 3. A-GLYCOSYLIERUNGEN UEBER BROMIDE 22
2.3 2.4. A-GLYCOSYLIERUNGEN UEBER THIOGLYCOSIDE 23
2.3.3. DIRIGIERENDE FUNKTIONELLE GRUPPEN BEI 2-AMINOZUCKEM 25
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/950689831
2 3 3 1
2.33.2.
2.3.33.
2.4.
2.4.1.
2.4.2.
2.4.3.
3.
3.1.
3.2.
4.
4.1.
4.2.
4.2.1.
4.2.1.1.
4.2.1.2.
4.2.1.3.
4.2.1.4.
4.2.1.5.
4.2.1
.6
4.2.1.7.
4.2.1.
8.
4.2.1.9.
4.2.2.
4.2.2.1.
4.2.2.2.
4.22.3.
4.22.4.
SEITE
DIE PHTHALIMID-METHODE 25
DAS AZID-VERFAHREN 25
DAS NITROSOHALOGENID-VERFAHREN 26
STRUKTURAUFKLAERUNG VON KOHLENHYDRATEN 28
FAB-MASSENSPEKTROMETRIE 28
'H-NMR-SPEKTROSKOPIE 28
N
C-NMR-SPEKTROSKOPIE 29
PROBLEMSTELLUNG UND SYNTHESESTRATEGIE 30
PROBLEMSTELLUNG
30
SYNTHESESTRATEGIE
31
ERGEBNISSE UND DISKUSSION
43
ERGEBNISSE
43
SYNTHESE VON A-D-GLUCOPYRANOSYL-(L-3)-A-D-MANNOPYRANOSYL-
(L-7)-4-METHYLUMBELLIFERON
44
L,2:4,6-DI-0-ISOPROPYLIDEN-SS-D-MANNOPYRANOSE (9)
44
1.2.3.4.6- PENTA-O-ACETYL-A/SS-D-MANNOPYRANOSE (
1
)
44
2.3.4.6- TETRA-O-ACETYL-A-D-MANNOPYRANOSYL-BROMID (
2
)
45
3.4.6- T RI-0-ACETYL-(R/S)-1,2-0-( 1 -METHOXYETHYLIDEN)-
SS-D-MANNOPYRANOSE (3)
46
(R/S)
1,2-0-( 1 -METHOXYETHYLIDEN)- SS -D-MANNOPYRANOSE (4) 47
3.4.6- TRI-0-BENZYL-(R/S)
1,2-0( 1 -METHOXYETHYLIDEN)-
SS-D-MANNOPYRANOSE (5)
4G
I ,2,4,6-T ETRA-O-ACETYL-3-O-BENZYL-A -D-MANNOPYRANOSE (
6) 50
3-O-BENZYL-A-D-MANNOPYRANOSE (7)
52
3 -O-BENZYL
1,2:4,6-DI-O-ISOPROPYLIDEN- SS -D-MANNOPYRANOSE (8) 52
L,2:4,6-DI-0-ISOPROPYLIDEN-SS-D-MANNO-PYRANOSE (
9) 54
ETHYL-2,3,4,6-TETRA-0-BENZYL-L-THIO-SS-D-GLUCOPYRANOSID (13)
57
1.2.3.4.6- PENTA-O-ACETYL-SS-D-GLUCOPYRANOSE (10) 57
ETHYL-2,3,4,6-TETRA-0-ACETYL-L-THIO-SS-D-GLUCOPYRANOSID (
11
)
58
ETHYL
-1
-THIO- SS -D-GLUCOPYRANOSID (
12
)
60
ETHYL-2,3,4,6-TETRA-0-BENZYL-L-THIO-SS-D-GLUCOPYRANOSID
(13) 61
SEITE
4.2.3
A
-D-GLUCOPYRANOSYL-( 1 -3)- A -D-MANNOPYRANOSYL-
(1 -7)-4-METHYLUMBELLIFERON (20) 63
4.2.3.1. 2,3,4,6-TETRA-0-BENZYL-A-D-GLUCOPYRANOSYL-(L-3)-L,2:4,6-DI-0-
ISOPROPYLIDEN- SS -D-MANNOPYRANOSE (14) 63
4.2.32. 2,3,4,6-T ETRA-O-BENZYL- A -D-GLUCOPYRANOSYL-
(1 -3)- A -D-MANNOPYRANOSE (15) 64
4.2.33. 2,3,4,6-TETRA-O-BENZYL-
A
-D-GLUCOPYRANOSYL-( 1 -3)-1,2:4,6-
TETRA-O-ACETYL-A-D-MANNOPYRANOSE (16) 65
4.2.34. A-D-GLUCOPYRANOSYL-( 1 -3)-1,2,4,6-TETRA-O-ACETYL-
A -D-MANNOPYRANOSE (17) 67
4.23.5. 2,3,4,6-TETRA-O-ACETYL- A -D-GLUCOPYRANOSYL-( 1 -3)-1,2,4,6-
TETRA-O-ACETYL-A-D-MANNOPYRANOSE (18) 68
4.2.3.6.
2,3,4,6-TETRA-0-ACETYL-A-D-GLUCOPYRANOSYL-(L-3)-2,4,6-TRI-0-ACETYL
-A-D-MANNOPYRANOSYL-(L-7)-4-METHYLUMBELLIFERON (19) 70
4.2.37.
A
-D-GLUCOPYRANOSYL-( 1 -3)- A -D-MANNOPYRANOSYL-
(L-7)-4-METHYLUMBELLIFERON(20) 72
4.2.4. SS -D-GALACTOPYRANOSYL-( 1 -4)- SS -D-GLUCOPYR ANOSYL-
(L-7)-4-METHYLUMBELLIFERON (23) 73
4.2.41. 2,3,4,6-T ETRA-0-ACETYL-GALACTOPYRANOSYL-( 1
-4)-1,2,3,6-TETRA-O-
ACETYL- SS -D-GLUCOPYRANOSE (21) 73
4.2.42. 2,3,4,6-TETRA-0-ACETYL-SS-D-GALACTOPYRANOSYL-(L-4)-2,3,6-TRI-0-
ACETYL- SS -D-GLUCOPYRANOSYL-( 1 -7)-4-METHYLUMBELLIFERON (22) 74
4.2.43. SS-D-GALACTOPYRANOSYL-(L-4)-SS-D-GLUCOPYRANOSYL-
(1 -7)-4-METHYLUMBELLIFERON (23) 77
4.3. 2-ACETAMIDO-2-DEOXY- SS-D-GLUCOPYRANOSYLNEOGLYCOLIPIDE
UND SEPHAROSE-GELE 78
4.3.1. BENZYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID (26) 78
4.3.1.1.
2-ACETAMIDO-L,3,4,6-TETRA-0-ACETYL-2-DEOXY-SS-D-GLUCOPYRANOSE(24) 78
4.3.1.2. BENZYL-2-ACETAMINO-1,3,4,6-TETRA-0-ACETYL-2-DEOXY-SS-D-
GLUCOPYRANOSID (25) 80
4.3.13. BENZYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID(26) 82
4.3 2. N-PENTYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID(28) 83
4.3.2.1
4.32.2
4.3.3.
4.3.3.1.
4.3.3.2.
4.3.33.
4.3.4.
4.3.41.
4.3.42.
4.3.5.
4.3.5.1.
4.3.5.2.
4.3.5.3.
4.3.54.
4.35.5.
4.3 6.
N-PENTYL-2-ACETAMIDO-1,3,4,6-TETRA-0-ACETYL-2-DEOXY- SS -D-
GLUCOPYRANOSID (27)
N-PENTYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID (
28)
BIS-[2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL]-N-HEXAN-
(L-OE)-DIOL (31)
2- ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSYL-
CHLORID (29)
BIS-[2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSYL]-
N-HEXAN-(L-6)-DIOL (30)
BIS-[2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL]-N-HEXAN-
(1 -6)-DIOL (31)
BIS-[2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL]-N-DECAN-
(L-LO)-DIOL (33)
BIS-[2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSYL]-
N-DECAN-(L-10)-DIOL (32)
BIS-[2-ACETAMIDO-2-DEOXY- SS-D-GLUCOPYRANOSYL]-N-DECAN-
(L-LO)-DIOL (33)
P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-N-BUTYLAMID (38)
P-(2- ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSYL)-
HYDROXYMETHYLBENZOESAEURE-METHYLESTER (34)
P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEUREMETHYLESTER (35)
P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE (36)
P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-O-N-SUCCINIMIDYLESTER (3 7)
P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-N-BUTYLAMID (38)
P-(2-ACETANUDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-AMINOHEXYL SEPHAROSE-GEL (39)
SEITE
83
85
85
85
86
89
89
89
92
93
93
95
95
96
97
98
SEITE
4.3.7, BENZYL- SS-D-GALACTOPYRANOSYL-(
1 -4)-2-ACETAMIDO-2-DEOXY-
SS-D-GLUCOPYRANOSID (42)
99
4.3.7
.1 2,3,4,6-TETRA-0-ACETYL-SS-D-GALACOPYRANOSYL-(L-4)-2-ACETAMIDO-
L,3,6-TRI-0-ACETYL-2-DEOXY-SS-D-GLUCOPYRANOSE (40) 99
4.3.72. BENZYL-2,3,4,6-TETRA-O-ACETYL- SS -D-GALACTOPYRANOSYL-( 1 -4)-2-
ACETAMIDO-3,6-DI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSID (41)
100
4.3.73. BENZYL- SS-D-GALACTOPYRANOSYL-(
1 -4)-2-ACETAMIDO-2-DEOXY-
SS -D-GLUCOPYRANOSID (42) 103
4.4. DIALKYLGLYCERYLPHOSPHOETHANOLAMINE 104
4.4.1. L-(2'-AMINOETHYL)-PHOSPHO-2,3-DI-0-OCTYL-GLYCERIN (46) 104
4.4.11. 2-PHTHALIMIDOETHYLPHOSPHORYL-DICHLORID (43) 104
4.4.12.
1 -O-BENZYL-2,3 -DI-O-OCTYL-GLYCERIN (44) 105
4.4.13. L,2-DI-0-OCTYL-GLYCERIN(45) 105
4.4.14. L-(2'-AMINOETYL)-PHOSPHO-2,3-DI-0-OCTYL-GLYCERIN (46) 106
4.4.2. L-(2'-AMINOETHYL)-PHOSPHO-3-0-OCTYL-2-0-HEXADECYL-GLYCERIN (52)
108
4.4.21. L,2-0-ISOPROPYLIDEN-3-0-OCTYL-GLYCERIN (47) 108
4.4.22. L-0-0CTYL-GLYCERIN(48)
109
4.4.23. L-O-OCTYL-3-O-TRIPHENYLMETHYL-GLYCERIN (49) 109
4.4.2 4. L-0-0CTYL-2-0-HEXADECYL-3-0-TRIPHENYLMETHYL-GLYCERIN (50)
110
4.4.25. L-O-OCTYL-2-O-HEXADECYL-GLYCERIN (51)
111
\
4.4.2.
6. L-(2'-AMINOETHYL)-PHOSPHO-3-0-OCTYL-2-0-HEXADECYL-GLYCERIN (52) 111
4.5. A-D-GLUCOPYRANOSYL-(
1 -3)-A-D-MANNOPYRANOSYL-( 1 -7)-4-METHYL-
UMBELLIFERON (20) ALS SUBSTRAT FUER A-ENDOMANNOSIDASE 114
4.5.1. ENZYM
114
4.5.2. CC-ENDOMANNOSIDASE-ANSAETZE
114
4.5.3 ZEITABHAENGIGKEIT DER SPALTUNG VON A-D-GLUCOPYRANOSYL-
(1 -3)-0-A-D-MANNOPYRANOSYL-(
1 -7)-4-METHYLUMBELLIFERON (20) 114
4.5.4. SUBSTRAT-KONZENTRATIONSABHAENGIGKEIT DER SPALTUNG VON
A-D-GLUCOPYRANOSYL-(
1 -3)-A -D-MANNOPYRANOSYL-
(1 -7)-4-METHYLUMBELLIFERON (20)
115
4.6. DISKUSSION DER ERGEBNISSE 117
SEITE
4.6.1 SYNTHESE VON A-D-GLUCOPYRANOSYL-( 1 -3)-A-D-MANNOPYRANOSYL-
(1-7)-4-METHYLUMBELLIFERON (20) UND SEINE VERWENDUNG ALS
SUBSTRAT FUER EINE A-ENDO-MANNOSIDASE 117
4.6 1.1. SYNTHESE VON A-D-GLUCOPYRANOSYL-(L-3)-A-D-MANNOPYRANOSYL-
(1 -7)-4-METHYLUMBELLIFERON (20) 117
4.6 1 2. DIE VERWENDUNG VON (20) ALS SUBSTRAT EINER A-ENDOMANNOSIDASE
118
4.6.2. SYNTHESE DER 2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL-
GLYCOSIDE (26), (28), (31), (33), (38), DES AFFINITAETSGELS (39) UND
DES BENZYL- SS -D-GALACTOPYRANOSL-( 1 -4)-2-ACETAMIDO-2-DEOXY-
SS-D-GLUCOPYRANOSIDS (42) 118
4.6.3. SYNTHESE DER DIALKYLGLYCEROPHOSPHOETHANOLAMINE (46) UND (52) 119
5 EXPERIMENTELLER TEIL 121
5.1. ALLGEMEINES 121
5.11. ANALYTISCHE GERAETE
121
5.12. REINIGUNG DER DARGESTELLTEN PRODUKTE 121
5.1.3. CHEMIKALIEN
122
5.2. A -D-GLUCOPYRANOSYL-( 1 -3)- A -D-MANNOPYRANOSYL-( 1 -7)-4-METHYL-
UMBELLIFERON (20) UND SS-D-GALACTOPYRANOSYL-(L-4)-0-SS-
GLUCOPYRANOSYL-( 1 -7)-4-METHYLUMBELLIFERON (23) 122
5.2.1 1,2:4,6-DI-O-ISOPROPYLIDEN-SS-D-MANNOPYRANOSE (9) 122
5 2.1.1. 1,2,3,4,6-PENTA-O-ACETYL-A-D-MANNOPYRANOSE (1) 122
5 2 12. 2,3,4,6-TETRA-O-ACETYL-A-D-MANNOPYRANOSYL-BROMID (2) 123
5.2.13. 3,4,6-T RI-O-ACETYL-1,2-0-( 1 -METHOXYETHYLIDEN)-
SS-D-MANNOPYRANOSE (3) 123
5.2.14. (R/S)-L,2,-0-(L-METHOXYETHYLIDEN)-SS-D-MANNOPYRANOSE (4) 123
5.2.1.5. 3,4,6-TRI-0-BENZYL-(R/S)-L,2-0-(L-METHOXYSTHYLIDEN)-
SS -D-MANNOPYRANOSE (5)
124
5.2.16.
1,2,4,6-TETRA-0-ACETYL-3-0-BENZYL-A-D-MANNOPYRANOSE (6) 124
5 2 1.7. 3-O-BENZYLMANNOPYRANOSE (7) 124
5 2.1.8. 3-O-BENZYL-L ,2:4,6-DI-0-ISOPROPYLIDEN-SS-D-MANNOPYRANOSE (8)
125
5.2.19. 1,2 4,6-DI-O-ISOPROPYLIDEN-SS-D-MANNOPYRANOSE (9) 125
5.2 2. ETHYL-2,3,4,6-TETRA-0-BENZYL-L-THIO-SS-D-GLUCOPYRANOSID (13) 125
SEITE
5.
2.2.1 1,2,3,4,6-PENTA-O-ACETYL- SS -D-GLUCOPYRANOSE (10) 125
5
2.2.2. ETHYL-2,3,4,6-TETRA-0-ACETYL-L-THIO-SS-D-GLUCOPYRANOSID (11) 126
5.2.23. ETHYL-L-THIO-SS-D-GLUCOPYRANOSID(
12) 126
5.
2.2.4 ETHYL-2,3,4,6-TETRA-0-BENZYL-L-THIO-SS-D-GLUCOPYRANOSID (13) 126
5.2.3. A -D-GLUCOPYRANOSYL-(
1 -4)- A-D-MANNOPYRANOSYL-( 1 -7)-4-METHYL-
UMBELLIFERON (
20) 127
5
2.3.1 2,3,4,6-TETRA-0-BENZYL-A-D-GLUCOPYRANOSYL-(L-3)-L,2:4,6-DI-0-
ISOPROPYLIDEN-SS-D-MANNOPYRANOSE (14)
127
5 2.3.2. 2,3,4,6-T ETRA-O-BENZYL-A -D-GLUCOPYRANOSYL-( 1 -3)- A-D-
MANNOPYRANOSE (15)
127
5.2.33. 2,3,4,6-T ETRA-O-BENZYL-A-D-GLUCOPYRANOSYL-(
1 -3)-1,2,4,6-
TETRA-O-ACETYL-
A
-D-MANNOPYRANOSE (16) 128
5.2.3.4. A-D-GLUCOPYRANOSYL-( 1-3)-1,2,4,
6-TETRA-O-ACETYL-A-D-
MANNOPYRANOSE (17) 128
5 2.3.5. 2,3,4,6-T ETRA-0-ACETYL-A-D-GLUCOPYRANOSYL-( 1 -3)
1,2,4,6-
TETRA-O-ACETYL- A-D-MANNOPYRANOSE (18) 128
5.2.3.
6. 2,3,4,6-TETRA-0-ACETYL-A-D-GLUCOPYRANOSYL-( 1 -3)-2,4,6-TRI-0-
ACETYL-A-D-MANNOPYRANOSYL-(
1 -7)-4-METHYLUMBELLIFERON (19) 129
5.2.37. A -D-GLUCOPYRANOSYL-( 1 -3)- A -D-MANNOPYRANOSYL-(
1 -7)-4-METHYL-
UMBELLIFERON (
20) 129
5.2.4. SS -D-GALACTOPYRANOSYL-(
1 -4)- SS -D-GLUCOPYRANOSYL-( 1 -7)-4-METHYL-
UMBELLIFERON (23)
129
5
.2.4.1 2,3,4,6-TETRA-0-ACETYL-SS-D-GALACTOPYRANOSYL-(L-4)-L,2,3,6-
TETRA-O-ACETYLGLUCOPYRANOSE
129
5.2.42. 2,3,4,6-TETRA-0-ACETYL-GALACTOPYRANOSYL-(L-4)-2,3,6-TRI-0-
ACETYL- SS -D-GLUCOPYRANOSYL-(
1 -7)-4-METHYLUMBELLIFERON (22) 130
5.2.43. SS -D-GALACTOPYRANOSYL-(
1 -4)- SS -D-GLUCOPYRANOSYL-( 1 -7)-4-
METHYLUMBELLIFERON (23)
130
5.3.
2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYLNEOGLYCOLIPIDE UND
-SEPHAROSEGELE
131
5.3.1. BENZYL-2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSID (26) 131
5.311.
2-ACETAMIDO-1,2,4,6-TETRA-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRANOSE (24) 131
SEITE
5 3 12 BENZYL-2-ACETAMIDO-1,3,4,6-TETRA-0-ACETYL-2-DEOXY- SS -D-
GLUCOPYRANOSID (25) 131
5 3 13. BENZYL-2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSID (26) 131
5 3.2. N-PENTYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID(28) 132
5.3.2.1. N-PENTYL-2-ACETAMIDO-L,3,4,6-TETRA-0-ACETYL-2-DEOXY-SS-D-
GLUCOPYRANOSID (27) 132
5.3.22 N-PENTYL-2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSID (28) 132
5.3 3 BIS-[2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSYL]-N-HEXAN-
(L
6)-DIOL (31) 132
5.3.31. 2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCOPYRA-
NOSYL-( 1 )-CHLORID (29) 132
5.3.3 2. BIS-[2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY-SS-D-
GLUCOPYRANOSYL]-N-HEXAN-(L
6)-DIOL (30) 133
5.3 3 3 BIS-[2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSYL]-N-HEXAN-
(L
6)-OL (31) 133
5.3.4. BIS-[2-ACETAMIDO-2-DEOXY-SS-D-GLUCOPYRANOSYL]-N-DECAN-
(L-LO)-DIOL (33) 134
5 3 4 1 BIS-[2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY-SS-D-GLUCOPYRA-
NOSYL]-N-DECAN-( 1 -10)-DIOL (32) 134
5 3 4 2 BIS-[2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL]-N-DECAN-
(L-LO)-DIOL (33) 134
5.3.5. P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-N-BUTYLAMID (38) 134
5 3 5
1 P-(2-ACETAMIDO-3,4,6-TRI-0-ACETYL-2-DEOXY- SS -D-GLUCO-
PYRANOSYL)-HYDROXYMETHYLBENZOESAEURE-METHYLESTER (34) 134
5 3 5 2 P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEUREMETHYLESTER (35) 135
5.3.53. P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE (36) 135
5.3 5 4 P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-O-N-SUCCINIMIDYLESTER (37) 135
SEITE
5 3 5.5. P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-N-BUTYLAMID (38) 136
5.36 P-(2-ACETAMIDO-2-DEOXY- SS -D-GLUCOPYRANOSYL)-HYDROXYMETHYL-
BENZOESAEURE-AMINOHEXYLSEPHAROSE-GEL (39) 136
5.3.7. BENZYL- SS -D-GALACTOPYRANOSYL-( 1 -4)-2-ACETAMIDO-2-DEOXY-
SS-D-GLUCOPYRANOSID (42) 137
5 3.7.1 2,3,4,6-T ETRA-O-ACETYL- SS -D-GALACTOPYRANOSYL-( 1
-4)-2-ACETAMIDO-
L,3,6-TRI-0-ACETYL-2-DEOXY-SS-D-GLUCOPYRANOSE (40) 137
5.3.72. BENZYL-2,3,4,6-TETRA-O-ACETYL- SS -D-GALACTOPYRANOSYL-( 1 -4)-2-
ACETAMIDO-3,6-DI-0-ACETYL-2-DEOXY-SS-D-GLUCOPYRANOSID (41) 137
5.3.73. BENZYL- SS -D-GALACTOPYRANOSYL-( 1 -4)-2-ACETAMIDO-2-DEOXY-
SS -D-GLUCOPYRANOSID (42) 137
5.4. DIALKYLGLYCERYLPHOSPHOETHANOLAMINE 138
5.4.1. L-(2'-AMINOETHYL)-PHOSPHO-2,3-DI-0-OCTYL-GLYCERIN(46) 138
5 4.1.1. 2-PHTHALIMIDOETHYLPHOSPHORYL-DICHLORID (43) 138
5.4.12. L-0-BENZYL-2,3-DI-0-OCTYL-GLYCERIN (44) 138
5.4.13. L,2-DI-0-OCTYL-GLYCERIN(45) 139
5.4.1.4 L-(2'-AMINOETHYL)-PHOSPHO-2,3-DI-0-OCTYL-GLYCERIN(46) 139
5.4.2. L-(2'-AMINOETHYL)-PHOSPHO-3-0-OCTYL-2-0-HEXADECYL-GLYCERIN (52)
140
5.4.21. L,2-0-ISOPROPYLIDEN-3-0-OCTYL-GLYCERIN (47) 140
5.4.22. L-0-0CTYL-GLYCERIN(48) 140
5.4.23. 1 -O-OCTYL-3 -O-TRIPHENYLMETHYL-GLYCERIN (49) 140
5.4.2.4. L-0-0CTYL-2-0-HEXADECYL-3-O-TRIPHENYLMETHYL-GLYCERIN (50) 141
5.4.25 L-O-OCTYL-2-O-HEXADECYL-GLYCERIN (51) 141
5 4.2.6. L-(2'-AMINOETHYL)-PHOSPHO-3-0-OCTYL-2-0-HEXADECYL-GLYCERIN (52)
141
5.5. ENZYMKINETIK DER A-ENDOMANNOSIDASE AM SUBSTRAT
A-D-GLUCOPYRANOSYL-(L-3)-A-D-MANNOPYRANOSYL-
(1 -7)-4-METHYLUMBELLIFERON (20) 142
5.5.1. A-ENDOMANNOSIDASE - ANSAETZE 142
5.6 SPEKTROSKOPISCHE METHODEN 143
5.6.1 'H-NMR-SPEKTREN 143
5.6.2. FAB-MASSENSPEKTREN 143
6
.
6
.
1
.
6
.
2
.
6.3.
64.
7.
7.1.
7.2.
8
.
SEITE
ZUSAMMENFASSUNG
144
SYNTHESE VON A-D-GLUCOPYRANOSYL-(L-3)- X-D-MANNOPYRANOSYL-
(L-7)-4-METHYLUMBELLIFERON (20)
(20) ALS SUBSTRAT VON A-ENDOMANNOSIDASE
SYNTHESE DER ACETYLGLUCOSAMIN- UND ACETYL-LACTOSAMIN-SS-D-GLYCOSIDE
SYNTHESE DER PHOSPHOETHERLIPIDE
VERZEICHNIS DER ABBILDUNGEN
FAB-MASSENSPEKTREN
'H-NMR-SPEKTREN
ABKUERZUNGSVERZEICHNIS
LITERATURVERZEICHNIS
144
145
145
145
146
146
147
148
149 |
| any_adam_object | 1 |
| author | Vogel, Christian |
| author_facet | Vogel, Christian |
| author_role | aut |
| author_sort | Vogel, Christian |
| author_variant | c v cv |
| building | Verbundindex |
| bvnumber | BV011699676 |
| ctrlnum | (OCoLC)633412961 (DE-599)BVBBV011699676 |
| edition | [Mikrofiche-Ausg.] |
| format | Microfilm Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV011699676 |
| illustrated | Illustrated |
| indexdate | 2024-10-09T16:08:24Z |
| institution | BVB |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007889716 |
| oclc_num | 633412961 |
| open_access_boolean | |
| owner | DE-29T DE-355 DE-BY-UBR DE-11 |
| owner_facet | DE-29T DE-355 DE-BY-UBR DE-11 |
| physical | [10], 153, XVIII S. graph. Darst. |
| publishDate | 1997 |
| publishDateSearch | 1997 |
| publishDateSort | 1997 |
| record_format | marc |
| spelling | Vogel, Christian Verfasser aut Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen von Christian Vogel [Mikrofiche-Ausg.] 1997 [10], 153, XVIII S. graph. Darst. txt rdacontent h rdamedia he rdacarrier Bonn, Univ., Diss., 1997. - Mikrofiche-Ausg.: 3 Mikrofiches : 24x Glycosyltransferasen (DE-588)4157751-6 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Enzymsubstrat (DE-588)4311292-4 gnd rswk-swf Glykosidasen (DE-588)4299582-6 gnd rswk-swf Glykoside (DE-588)4021359-6 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Glykoside (DE-588)4021359-6 s Chemische Synthese (DE-588)4133806-6 s Enzymsubstrat (DE-588)4311292-4 s Glykosidasen (DE-588)4299582-6 s DE-604 Glycosyltransferasen (DE-588)4157751-6 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007889716&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Vogel, Christian Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen Glycosyltransferasen (DE-588)4157751-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Enzymsubstrat (DE-588)4311292-4 gnd Glykosidasen (DE-588)4299582-6 gnd Glykoside (DE-588)4021359-6 gnd |
| subject_GND | (DE-588)4157751-6 (DE-588)4133806-6 (DE-588)4311292-4 (DE-588)4299582-6 (DE-588)4021359-6 (DE-588)4113937-9 |
| title | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen |
| title_auth | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen |
| title_exact_search | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen |
| title_full | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen von Christian Vogel |
| title_fullStr | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen von Christian Vogel |
| title_full_unstemmed | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen von Christian Vogel |
| title_short | Synthese von Glycosiden als Substrate für Glycosidasen und Glycosyltransferasen |
| title_sort | synthese von glycosiden als substrate fur glycosidasen und glycosyltransferasen |
| topic | Glycosyltransferasen (DE-588)4157751-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Enzymsubstrat (DE-588)4311292-4 gnd Glykosidasen (DE-588)4299582-6 gnd Glykoside (DE-588)4021359-6 gnd |
| topic_facet | Glycosyltransferasen Chemische Synthese Enzymsubstrat Glykosidasen Glykoside Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007889716&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT vogelchristian synthesevonglycosidenalssubstratefurglycosidasenundglycosyltransferasen |