Physical chemistry of surfaces:
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| Main Authors: | , |
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| Format: | Book |
| Language: | English |
| Published: |
New York [u.a.]
Wiley
1997
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| Edition: | 6. ed. |
| Series: | A Wiley-Interscience publication
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXI, 784 S. Ill., graph. Darst. |
| ISBN: | 9780471148739 |
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| 245 | 1 | 0 | |a Physical chemistry of surfaces |c Arthur W. Adamson and Alice P. Gast |
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| _version_ | 1804126226901630976 |
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| adam_text | PHYSICAL CHEMISTRY OF SURFACES SIXTH EDITION ARTHUR W. ADAMSON
DEPARTMENT OF CHEMISTRY, UNIVERSITY OF SOUTHERN CALIFORNIA LOS ANGELES,
CALIFORNIA AND ALICE P. GAST DEPARTMENT OF CHEMICAL ENGINEERING,
STANFORD UNIVERSITY STANFORD, CALIFORNIA A WILEY-INTERSCIENCE
PUBLICATION JOHN WILEY & SONS, INC. NEW YORK / CHICHESTER / WEINHEIM /
BRISBANE / SINGAPORE / TORONTO CONTENTS PREFACE XIX I. GENERAL
INTRODUCTION 1 IL CAPILLARITY 4 1. SURFACE TENSION AND SURFACE FREE
ENERGY 4 2. THE YOUNG-LAPLACE EQUATION 6 3. SOME EXPERIMENTS WITH SOAP
FILMS 8 4. THE TREATMENT OF CAPILLARY RISE 10 A. INTRODUCTORY DISCUSSION
10 B. EXACT SOLUTIONS TO THE CAPILLARY RISE PROBLEM 12 C. EXPERIMENTAL
ASPECTS OF THE CAPILLARY RISE METHOD 16 5. THE MAXIMUM BUBBLE PRESSURE
METHOD 17 6. DETACHMENT METHODS 19 A. THE DROP WEIGHT METHOD 19 B. THE
RING METHOD 21 C. WILHELMY SLIDE METHOD 23 7. METHODS BASED ON THE SHAPE
OF STATIC DROPS OR BUBBLES 26 A. PENDANT DROP METHOD 27 B. SESSILE DROP
OR BUBBLE METHOD 27 C. SOURCES OF OTHER DEFORMED SHAPES 30 8. DYNAMIC
METHODS OF MEASURING SURFACE TENSION 33 A. FLOW METHODS 33 B. CAPILLARY
WAVES 34 C. MAXIMUM BUBBLE PRESSURE METHOD 35 9. SURFACE TENSION VALUES
AS OBTAINED BY DIFFERENT METHODS 35 10. PROBLEMS 40 GENERAL REFERENCES
43 TEXTUAL REFERENCES 43 VII VLLL CONTENTS III. THE NATURE AND
THERMODYNAMICS OF LIQUID INTERFACES 48 1. ONE-COMPONENT SYSTEMS 48 A.
SURFACE THERMODYNAMIC QUANTITIES FOR A PURE SUBSTANCE 48 B. THE TOTAL
SURFACE ENERGY, E S 51 C. THE EFFECT OF CURVATURE ON VAPOR PRESSURE AND
SURFACE TENSION 53 D. THE EFFECT OF PRESSURE ON SURFACE TENSION 55 2.
STRUCTURAL AND THEORETICAL TREATMENTS OF LIQUID INTERFACES 56 A. FURTHER
DEVELOPMENT OF THE THERMODYNAMIC TREATMENT OF THE SURFACE REGION 58 B.
CALCULATION OF THE SURFACE ENERGY AND STRUCTURE OF INTERFACES 61 3.
ORIENTATION AT INTERFACES 63 4. THE SURFACE TENSION OF SOLUTIONS 65 A.
BINARY SOLUTIONS 65 B. THE SURFACE TENSION OF POLYMERIE SYSTEMS 69 5.
THERMODYNAMICS OF BINARY SYSTEMS: THE GIBBS EQUATION 71 A. DEFINITION OF
SURFACE EXCESS 71 B. THE GIBBS EQUATION 73 C. THE DIVIDING SURFACE 74 D.
OTHER SURFACE THERMODYNAMIC RELATIONSHIPS 76 6. DETERMINATION OF SURFACE
EXCESS QUANTITIES 77 A. EXPERIMENTAL METHODS 77 B. HISTORICAL FOOTNOTE
AND COMMENTARY 79 C. THEORETICAL CALCULATION OF SURFACE EXCESS
QUANTITIES 79 7. GIBBS MONOLAYERS 80 A. THE TWO-DIMENSIONAL IDEAL-GAS
LAW 82 B. NONIDEAL TWO-DIMENSIONAL GASES 83 C. THE OSMOTIC PRESSURE
POINT OF VIEW 86 D. SURFACE ELASTICITY 89 E. TRAUBE S RULE 90 F. SOME
FURTHER COMMENTS ON GIBBS MONOLAYERS 91 8. PROBLEMS 92 GENERAL
REFERENCES 96 TEXTUAL REFERENCES 96 IV. SURFACE FILMS ON LIQUID
SUBSTRATES 101 1. INTRODUCTION 101 2. THE SPREADING OF ONE LIQUID ON
ANOTHER 104 A. CRITERIA FOR SPREADING 104 B. EMPIRICAL AND THEORETICAL
TREATMENTS 107 C. KINETICS OF SPREADING PROCESSES 110 D. THE MARANGONI
EFFECT 111 E. LENSES-LINE TENSION 112 3. EXPERIMENTAL TECHNIQUES FOR THE
STUDY OF MONOMOLECULAR FILMS 113 A. MEASUREMENT OF T T 114 B. SURFACE
POTENTIALS 116 CONTENTS IX C. MEASUREMENT OF SURFACE VISCOSITY 118 D.
OPTICAL PROPERTIES OF MONOLAYERS 126 E. MICROSCOPIC EVALUATION OF
MONOLAYERS 128 F. DIFFRACTION STUDIES 130 4. STATES OF MONOMOLECULAR
FILMS 131 A. GASEOUS FILMS 131 B. GAS-LIQUID TRANSITIONS 132 C.
CONDENSED PHASES 133 D. THE SOLID STATE 135 E. MONOLAYER COLLAPSE 136 F.
DOMAIN SHAPES AND INTERACTIONS 136 5. MIXED FILMS 140 6. EVAPORATION
RATES THROUGH MONOMOLECULAR FILMS 146 7. DISSOLUTION OF MONOLAYERS 148
8. REACTIONS IN MONOMOLECULAR FILMS 151 A. KINETICS OF REACTIONS IN
FILMS 151 B. KINETICS OF FORMATION AND HYDROLYSIS OF ESTERS 152 C. OTHER
CHEMICAL REACTIONS 155 9. PROBLEMS 156 GENERAL REFERENCES 158 TEXTUAL
REFERENCES 158 V. ELECTRICA! ASPECTS OF SURFACE CHEMISTRY 169 1.
INTRODUCTION 169 2. THE ELECTRICAL DOUBLE LAYER 169 3. THE STERN LAYER
175 4. THE FREE ENERGY OF A DIFFUSE DOUBLE LAYER 179 5. REPULSION
BETWEEN TWO PLANAR DOUBLE LAYERS 180 6. THE ZETA POTENTIAL 183 A.
ELECTROPHORESIS 183 B. ELECTROOSMOSIS 185 C. STREAMING POTENTIAL 187 D.
SEDIMENTATION POTENTIAL 188 E. INTERRELATIONSHIPS IN ELECTROKINETIC
PHENOMENA 188 F. POTENTIAL, SURFACE CHARGE, AND COLLOIDAL STABILITY 189
7. ELECTROCAPILLARITY 192 A. THERMODYNAMICS OF THE ELECTROCAPILLARY
EFFECT 195 B. EXPERIMENTAL METHODS 197 C. RESULTS FOR THE
MERCURY-AQUEOUS SOLUTION INTERFACE 199 D. EFFECT OF UNCHARGED SOLUTES
AND CHANGES OF SOLVENT 200 E. OTHER ELECTROCAPILLARY SYSTEMS 202 8. THE
ELECTRIFIED SOLID-LIQUID INTERFACE 202 A. ELECTRODE-SOLUTION INTERFACE
203 B. ELECTROCHEMISTRY IN DISPERSED PHASES 204 C.
PHOTOELECTROCHEMISTRY; SOLAR ENERGY CONVERSION 204 9. TVPES OF
POTENTIALS AND THE MEANING OF POTENTIAL DIFFERENCE WHEN TWO PHASES ARE
INVOLVED 205 A. THE VARIOUS TYPES OF POTENTIALS 205 X CONTENTS B. VOLTA
POTENTIALS, SURFACE POTENTIAL DIFFERENCES, AND THE THERMIONIC WORK
FUNCTION 208 C. ELECTRODE POTENTIALS 209 D. IRREVERSIBLE ELECTRODE
PHENOMENA 212 10. PROBLEMS 215 GENERAL REFERENCES 217 TEXTUAL REFERENCES
218 VI. LONG-RANGE FORCES 225 1. INTRODUCTION 225 2. FORCES BETWEEN
ATOMS AND MOLECULES 226 3. LONG-RANGE FORCES 232 A. THE MICROSCOPIC
APPROACH 232 B. THE RETARDED DISPERSION INTERACTION 234 C. EXPERIMENTAL
MEASUREMENTS 236 4. LONG-RANGE FORCES IN SOLUTION 239 A. DISPERSION
FORCES IN CONDENSED MEDIA 240 B. ELECTRIC DOUBLE-LAYER REPULSION 240 C.
FORCES DUE TO SOLVENT STRUCTURE 243 D. THIN-FILM VISCOSITY 246 5. FORCES
IN BIOLOGICAL SYSTEMS 246 6. THE DISJOINING PRESSURE 247 7. ANOMALOUS
WATER 248 8. DIPOLE-INDUCED DIPOLE PROPAGATION 248 9. PROBLEMS 250
GENERAL REFERENCES 252 TEXTUAL REFERENCES 252 VII. SURFACES OF SOLIDS
257 1. INTRODUCTION 257 A. THE SURFACE MOBILITY OF SOLIDS 257 B. EFFECT
OF PROCESSING ON THE CONDITION OF SOLID SURFACES 259 2. THERMODYNAMICS
OF CRYSTALS 259 A. SURFACE TENSION AND SURFACE FREE ENERGY 259 B. THE
EQUILIBRIUM SHAPE OF A CRYSTAL 261 C. THE KELVIN EQUATION 262 3.
THEORETICAL ESTIMATES OF SURFACE ENERGIES AND FREE ENERGIES 263 A.
COVALENTLY BONDED CRYSTALS 263 B. RARE-GAS CRYSTALS 264 C. IONIC
CRYSTALS 267 D. MOLECULAR CRYSTALS 269 E. METALS 269 4. FACTORS
AFFECTING THE SURFACE ENERGIES AND SURFACE TENSIONS OF ACTUAL CRYSTALS
271 A. STATE OF SUBDIVISION 271 B. DEVIATIONS FROM IDEALITY 271 C.
FRACTAL SURFACES 272 D. DISLOCATIONS 275 CONTENTS XI 5. EXPERIMENTAL
ESTIMATES OF SURFACE ENERGIES AND FREE ENERGIES.. 278 A. METHODS
DEPENDING ON THE DIRECT MANIFESTATION OF SURFACE TENSIONAL FORCES 278 B.
SURFACE ENERGIES FROM HEATS OF SOLUTION 280 C. RELATIVE SURFACE TENSIONS
FROM EQUILIBRIUM CRYSTAL SHAPES 280 D. DEPENDENCE OF OTHER PHYSICAL
PROPERTIES ON SURFACE ENERGY CHANGES AT A SOLID INTERFACE 281 6.
REACTIONS OF SOLID SURFACES 282 7. PROBLEMS 285 GENERAL REFERENCES 287
TEXTUAL REFERENCES 287 VIII. SURFACES OF SOLIDS: MICROSCOPY AND
SPECTROSCOPY 293 1. INTRODUCTION 293 2. THE MICROSCOPY OF SURFACES 293
A. OPTICAL AND ELECTRON MICROSCOPY 293 B. SCANNING PROBE MICROSCOPIES
294 C. FIELD EMISSION AND FIELD ION MICROSCOPIES 299 D. LOW-ENERGY
ELECTRON DIFFRACTION (LEED) 302 3. SPECTROSCOPIC METHODS 306 A. AUGER
ELECTRON SPECTROSCOPY (AES) 306 B. PHOTOELECTRON SPECTROSCOPY (XPS,
ESCA) 308 C. ION SCATTERING (ISS, LEIS) 308 4. OTHER TECHNIQUES 311 5.
PROBLEMS 312 GENERAL REFERENCES 318 TEXTUAL REFERENCES 319 IX. THE
FORMATION OF A NEW PHASE-NUCLEATION AND CRYSTAL GROWTH 328 1.
INTRODUCTION 328 2. CLASSIC NUCLEATION THEORY 329 3. EXPERIMENTAL
NUCLEATION STUDIES 336 A. ONE-COMPONENT SYSTEMS 336 B. BINARY SYSTEMS
AND SOLUTIONS 338 4. CRYSTAL GROWTH .. 339 5. EPITAXIAL GROWTH AND
SURFACE NUCLEATION 341 6. PROBLEMS 342 GENERAL REFERENCES 343 TEXTUAL
REFERENCES 343 X. THE SOLID-LIQUID INTERFACE*CONTACT ANGLE 347 1.
INTRODUCTION 347 2. SURFACE ENERGIES FROM SOLUBILITY CHANGES 347 3.
SURFACE ENERGIES FROM IMMERSION, ADSORPTION, AND ENGULFMENT STUDIES 348
A. ENTHALPY OF IMMERSION 348 CONTENTS B. SURFACE ENERGY AND FREE ENERGY
CHANGES FROM ADSORPTION STUDIES 350 C. ENGULFMENT 352 4. CONTACT ANGLE
352 A. YOUNG S EQUATION 352 5. CONTACT ANGLE HYSTERESIS 355 A.
HETEROGENEOUS SURFACES 355 B. SURFACE ROUGHNESS 358 C. LIQUID-SURFACE
INTERACTIONS: SURFACE CHANGES AND AUTOPHOBICITY . 359 D. DYNAMIC
CONTACT ANGLES 361 6. EXPERIMENTAL METHODS AND MEASUREMENTS OF CONTACT
ANGLE 362 A. EXPERIMENTAL METHODS TO MEASURE CONTACT ANGLE 362 B.
RESULTS OF CONTACT ANGLE MEASUREMENTS 364 7. THEORIES OF CONTACT ANGLE
PHENOMENA 372 A. THERMODYNAMICS OF THE YOUNG EQUATION 372 B.
SEMIEMPIRICAL MODELS: THE GIRIFALCO-GOOD-FOWKES-YOUNG EQUATION 375 C.
POTENTIAL-DISTORTION MODEL 377 D. THE MICROSCOPIC MENISCUS PROFILE 378
8. PROBLEMS 380 GENERAL REFERENCES 382 TEXTUAL REFERENCES 383 XL THE
SOLID-LIQUID INTERFACE*ADSORPTION FROM SOLUTION 390 1. ADSORPTION OF
NONELECTROLYTES FROM DILUTE SOLUTION 390 A. ISOTHERMS 391 B.
SELF-ASSEMBLING MONOLAYERS 394 C. MULTILAYER ADSORPTION 397 2. POLYMER
ADSORPTION 398 3. IRREVERSIBLE ADSORPTION 404 4. SURFACE AREA
DETERMINATION 405 5. ADSORPTION IN BINARY LIQUID SYSTEMS 406 A.
ADSORPTION AT THE SOLID-SOLUTION INTERFACE 406 B. HEAT OF ADSORPTION AT
THE SOLID-SOLUTION INTERFACE 411 6. ADSORPTION OF ELECTROLYTES 412 A.
STERN LAYER ADSORPTION 412 B. SURFACTANT ADSORPTION 414 C. COUNTERION
ADSORPTION-ION EXCHANGE 416 7. PHOTOPHYSICS AND PHOTOCHEMISTRY OF THE
ADSORBED STATE 418 A. PHOTOPHYSICS OF ADSORBED SPECIES 418 B.
PHOTOCHEMISTRY AT THE SOLID-SOLUTION INTERFACE 419 8. PROBLEMS 420
GENERAL REFERENCES 422 TEXTUAL REFERENCES 422 CONTENTS XIII XII.
FRICTION, LUBRICATION, AND ADHESION 431 1. INTRODUCTION 431 2. FRICTION
BETWEEN UNLUBRICATED SURFACES 431 A. AMONTONS LAW 431 B. NATURE OF THE
CONTACT BETWEEN TWO SOLID SURFACES 432 C. ROLE OF SHEARING AND
PLOWING*EXPLANATION OF AMONTONS LAW 434 D. STATIC AND STICK-SLIP
FRICTION 436 E. ROLLING FRICTION 437 3. TWO SPECIAL CASES OF FRICTION
437 A. USE OF SKID MARKS TO ESTIMATE VEHICLE SPEEDS 437 B. ICE AND SNOW
438 4. METALLIC FRICTION*EFFECT OF OXIDE FILMS 439 5. FRICTION BETWEEN
NONMETALS 440 A. RELATIVELY ISOTROPIE CRYSTALS 440 B. LAYER CRYSTALS 440
C. POLYMERS 441 6. SOME FURTHER ASPECTS OF FRICTION 442 7. FRICTION
BETWEEN LUBRICATED SURFACES 443 A. BOUNDARY LUBRICATION 443 B. THE
MECHANISM OF BOUNDARY LUBRICATION 447 C. FORCES AND FRICTION BETWEEN
SMOOTH SURFACES 450 8. ADHESION 452 A. IDEAL ADHESION 452 B. POLYMER
ADHESION 455 C. PRACTICAL ADHESION 455 9. PROBLEMS 458 GENERAL
REFERENCES 459 TEXTUAL REFERENCES 459 XIII. WETTING, FLOTATION, AND
DETERGENCY 465 1. INTRODUCTION 465 2. WETTING 465 A. WETTING AS A
CONTACT ANGLE PHENOMENON 465 B. WETTING AS A CAPILLARY ACTION PHENOMENON
469 3. WATER REPELLENCY 470 4. FLOTATION 471 A. THE ROLE OF CONTACT
ANGLE IN FLOTATION 473 B. FLOTATION OF METALLIC MINERALS 476 C.
FLOTATION OF NONMETALLIC MINERALS 478 5. PROPERTIES OF ASSOCIATION
COLLOIDS*MICELLES 479 6. DETERGENCY 484 A. GENERAL ASPECTS OF SOIL
REMOVAL 484 B. FACTORS IN DETERGENT ACTION 486 C. ADSORPTION OF
DETERGENTS ON FABRICS 487 D. DETERGENTS IN COMMERCIAL USE 488 7.
PROBLEMS 489 XIV CONTENTS GENERAL REFERENCES 491 TEXTUAL REFERENCES 491
XIV. EMULSIONS, FOAMS, AND AEROSOLS 500 1. INTRODUCTION 500 2.
EMULSIONS*GENERAL PROPERTIES 501 3. FACTORS DETERMINING EMULSION
STABILIZATION 503 A. MACROSCOPIC THEORIES OF EMULSION STABILIZATION 504
B. SPECIFIC CHEMICAL AND STRUCTURAL EFFECTS 505 C. LONG-RANGE FORCES AS
A FACTOR IN EMULSION STABILITY 506 D. STABILIZATION OF EMULSIONS BY
SOLID PARTICLES 510 4. THE AGING AND INVERSION OF EMULSIONS 510 A.
FLOCCULATION AND COAGULATION KINETICS 511 B. INVERSION AND BREAKING OF
EMULSIONS 513 5. THE HYDROPHILE-LIPOPHILE BALANCE 513 6. MICROEMULSIONS
516 7. FOAM STRUCTURE 519 8. FOAM DRAINAGE 521 A. DRAINAGE OF SINGLE
FILMS 521 B. DRAINAGE OF FOAMS 523 9. FOAM STABILITY 524 10. AEROSOLS
525 11. PROBLEMS 526 GENERAL REFERENCES 527 TEXTUAL REFERENCES 528 XV.
MACROMOLECULAR SURFACE FILMS, CHARGED FILMS, AND LANGMUIR-BLODGETT
LAYERS 537 1. INTRODUCTION 537 2. LANGMUIR FILMS OF POLYMERS 537 A.
ADSORPTION AND PHASE BEHAVIOR 537 B. DYNAMICS AND RHEOLOGY 541 3.
LANGMUIR FILMS OF PROTEINS 542 4. FILMS OF OTHER BIOLOGICAL SUBSTANCES
544 5. MEMBRANES, BILAYERS, AND VESICLES 548 6. FILMS AT LIQUID-LIQUID
INTERFACES AND ON NONAQUEOUS LIQUID SURFACES 551 7. CHARGED FILMS 553 A.
EQUATION OF STATE FOR CHARGED FILMS 553 B. INFLUENCE OF SUBPHASE PH ON
THE STATE OF MONOMOLECULAR FILMS 557 8. LANGMUIR-BLODGETT FILMS 557 A.
STRUCTURE AND CHARACTERIZATION OF LB FILMS 558 B. MIXED LB FILMS AND
FILMS OF POLYMERS AND COLLOIDS 560 C. STUDIES OF THE LB DEPOSITION
PROCESS 562 9. PROBLEMS 562 GENERAL REFERENCES 563 TEXTUAL REFERENCES
563 CONTENTS XV XVI. THE SOLID-GAS INTERFACE*GENERAL CONSIDERATIONS 571
1. INTRODUCTION 571 2. THE SURFACE AREA OF SOLIDS 572 A. THE MEANING OF
SURFACE AREA 572 B. SURFACES AS HAVING A FRACTAL GEOMETRY 574 C. METHODS
REQUIRING KNOWLEDGE OF THE SURFACE FREE ENERGY OR TOTAL ENERGY 576 D.
RATE OF DISSOLVING 577 E. THE MERCURY POROSIMETER 577 F. OTHER METHODS
OF SURFACE AREA DETERMINATION 580 3. THE STRUCTURE AND CHEMICAL NATURE
OF SOLID SURFACES 581 4. THE NATURE OF THE SOLID-ADSORBATE COMPLEX 582
A. EFFECT OF ADSORPTION ON ADSORBATE PROPERTIES 582 B. EFFECT OF THE
ADSORBATE ON THE ADSORBENT 589 C. THE ADSORBATE-ADSORBENT BOND 591 5.
PROBLEMS 592 GENERAL REFERENCES 593 TEXTUAL REFERENCES 594 XVII.
ADSORPTION OF GASES AND VAPORS ON SOLIDS 599 1. INTRODUCTION 599 2. THE
ADSORPTION TIME 601 3. THE LANGMUIR ADSORPTION ISOTHERM 603 A. KINETIC
DERIVATION 604 B. STATISTICAL THERMODYNAMIC DERIVATION 606 C. ADSORPTION
ENTROPIES 609 D. LATERAL INTERACTION 613 E. EXPERIMENTAL APPLICATIONS OF
THE LANGMUIR EQUATION 615 4. EXPERIMENTAL PROCEDURES 615 5. THE BET AND
RELATED ISOTHERMS 617 A. DERIVATION OF THE BET EQUATION 618 B.
PROPERTIES OF THE BET EQUATION 620 C. MODIFICATIONS OF THE BET EQUATION
621 6. ISOTHERMS BASED ON THE EQUATION OF STATE OF THE ADSORBED FILM 622
A. FILM PRESSURE-AREA DIAGRAMS FROM ADSORPTION ISOTHERMS... 623 B.
ADSORPTION ISOTHERMS FROM TWO-DIMENSIONAL EQUATIONS OF STATE 623 7. THE
POTENTIAL THEORY 625 A. THE POLANYI TREATMENT 625 B. ISOTHERMS BASED ON
AN ASSUMED VARIATION OF POTENTIAL WITH DISTANCE 627 C. THE POLARIZATION
MODEL 629 8. COMPARISON OF THE SURFACE AREAS FROM THE VARIOUS MULTILAYER
MODELS 630 9. THE CHARACTERISTIC ISOTHERM AND RELATED CONCEPTS 631 10.
CHEMICAL PHYSICS OF SUBMONOLAYER ADSORPTION 634 11. PHASE
TRANSFORMATIONS IN THE MULTILAYER REGION 639 12. THERMODYNAMICS OF
ADSORPTION 641 XVI CONTENTS A. THEORETICAL CONSIDERATIONS 641 B.
EXPERIMENTAL HEATS AND ENERGIES OF ADSORPTION 647 13. CRITICAL COMPANSON
OF THE VARIOUS MODELS FOR ADSORPTION 652 A. THE LANGMUIR-BET MODEL 652
B. TWO-DIMENSIONAL EQUATION OF STATE TREATMENTS 653 C. THE POTENTIAL
MODEL 654 14. PHYSICAL ADSORPTION ON HETEROGENEOUS SURFACES 655 A.
DISTRIBUTION OF SITE ENERGY PATCHES 655 B. THERMODYNAMICS OF ADSORPTION
ON HETEROGENEOUS SURFACES 659 C. POINT VERSUS PATCH SITE ENERGY
DISTRIBUTIONS 660 D. GEOMETRIE HETEROGENEITY 660 15. RATE OF ADSORPTION
661 16. ADSORPTION ON POROUS SOLIDS*HYSTERESIS 662 A. MOLECULAR SIEVES
662 B. CAPILLARY CONDENSATION 664 C. MICROPORE ANALYSIS 669 17. PROBLEMS
672 GENERAL REFERENCES 676 TEXTUAL REFERENCES 676 XVIII. CHEMISORPTION
AND CATALYSIS 685 1. INTRODUCTION 685 2. CHEMISORPTION: THE MOLECULAR
VIEW 686 A. LEED STRUCTURES 686 B. SURFACE MICROSCOPIES 688 C.
SPECTROSCOPY OF CHEMISORBED SPECIES 689 D. WORK FUNCTION AND RELATED
MEASUREMENTS 693 E. PROGRAMMED DESORPTION 694 3. CHEMISORPTION ISOTHERMS
698 A. VARIABLE HEAT OF ADSORPTION 698 B. EFFECT OF SITE AND ADSORBATE
COORDINATION NUMBER 701 C. ADSORPTION THERMODYNAMICS 702 4. KINETICS OF
CHEMISORPTION 703 A. ACTIVATION ENERGIES 703 B. RATES OF ADSORPTION 705
C. RATES OF DESORPTION 707 5. SURFACE MOBILITY 709 6. THE CHEMISORPTION
BOND 712 A. SOME GENERAL ASPECTS 712 B. METALS 715 C. SEMICONDUCTORS 717
D. ACID-BASE SYSTEMS 718 7. MECHANISMS OF HETEROGENEOUS CATALYSIS 720 A.
ADSORPTION OR DESORPTION AS THE RATE-DETERMINING STEP 720 B. REACTION
WITHIN THE ADSORBED FILM AS THE RATE-DETERMINING STEP 722 CONTENTS XVII
8. INFLUENCE OF THE ADSORPTION ISOTHERM ON THE KINETICS OF HETEROGENEOUS
CATALYSIS 724 A. UNIMOLECULAR SURFACE REACTIONS 724 B. BIMOLECULAR
SURFACE REACTIONS 726 9. MECHANISMS OF A FEW CATALYZED REACTIONS 728 A.
AMMONIA SYNTHESIS 729 B. FISCHER-TROPSCH REACTIONS 730 C. HYDROGENATION
OF ETHYLENE 733 D. CATALYTIC CRACKING OF HYDROCARBONS AND RELATED
REACTIONS.. 734 E. OXIDATION OF CO 735 F. PHOTOCHEMICAL AND
PHOTOASSISTED PROCESSES AT SURFACES 738 10. PROBLEMS 739 GENERAL
REFERENCES 742 TEXTUAL REFERENCES 744 INDEX 757
|
| any_adam_object | 1 |
| author | Adamson, Arthur W. Gast, Alice P. 1958- |
| author_GND | (DE-588)137230532 |
| author_facet | Adamson, Arthur W. Gast, Alice P. 1958- |
| author_role | aut aut |
| author_sort | Adamson, Arthur W. |
| author_variant | a w a aw awa a p g ap apg |
| building | Verbundindex |
| bvnumber | BV011689741 |
| classification_rvk | VE 7000 VE 7001 |
| classification_tum | PHY 650f CHE 180f |
| ctrlnum | (OCoLC)263940491 (DE-599)BVBBV011689741 |
| dewey-full | 541.33 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.33 |
| dewey-search | 541.33 |
| dewey-sort | 3541.33 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 6. ed. |
| format | Book |
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| id | DE-604.BV011689741 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:14:06Z |
| institution | BVB |
| isbn | 9780471148739 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007882023 |
| oclc_num | 263940491 |
| open_access_boolean | |
| owner | DE-29 DE-29T DE-703 DE-19 DE-BY-UBM DE-20 DE-91G DE-BY-TUM DE-M49 DE-BY-TUM DE-M347 DE-634 DE-83 DE-188 |
| owner_facet | DE-29 DE-29T DE-703 DE-19 DE-BY-UBM DE-20 DE-91G DE-BY-TUM DE-M49 DE-BY-TUM DE-M347 DE-634 DE-83 DE-188 |
| physical | XXI, 784 S. Ill., graph. Darst. |
| publishDate | 1997 |
| publishDateSearch | 1997 |
| publishDateSort | 1997 |
| publisher | Wiley |
| record_format | marc |
| series2 | A Wiley-Interscience publication |
| spelling | Adamson, Arthur W. Verfasser aut Physical chemistry of surfaces Arthur W. Adamson and Alice P. Gast 6. ed. New York [u.a.] Wiley 1997 XXI, 784 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-Interscience publication Chemistry, Physical and theoretical Surface chemistry Oberfläche (DE-588)4042907-6 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Oberflächenphysik (DE-588)4134881-3 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 s DE-604 Oberflächenphysik (DE-588)4134881-3 s Oberfläche (DE-588)4042907-6 s Physikalische Chemie (DE-588)4045959-7 s 1\p DE-604 Gast, Alice P. 1958- Verfasser (DE-588)137230532 aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007882023&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Adamson, Arthur W. Gast, Alice P. 1958- Physical chemistry of surfaces Chemistry, Physical and theoretical Surface chemistry Oberfläche (DE-588)4042907-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd Oberflächenphysik (DE-588)4134881-3 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| subject_GND | (DE-588)4042907-6 (DE-588)4126166-5 (DE-588)4134881-3 (DE-588)4045959-7 |
| title | Physical chemistry of surfaces |
| title_auth | Physical chemistry of surfaces |
| title_exact_search | Physical chemistry of surfaces |
| title_full | Physical chemistry of surfaces Arthur W. Adamson and Alice P. Gast |
| title_fullStr | Physical chemistry of surfaces Arthur W. Adamson and Alice P. Gast |
| title_full_unstemmed | Physical chemistry of surfaces Arthur W. Adamson and Alice P. Gast |
| title_short | Physical chemistry of surfaces |
| title_sort | physical chemistry of surfaces |
| topic | Chemistry, Physical and theoretical Surface chemistry Oberfläche (DE-588)4042907-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd Oberflächenphysik (DE-588)4134881-3 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| topic_facet | Chemistry, Physical and theoretical Surface chemistry Oberfläche Oberflächenchemie Oberflächenphysik Physikalische Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007882023&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT adamsonarthurw physicalchemistryofsurfaces AT gastalicep physicalchemistryofsurfaces |