Fundamentals of polymers:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
McGraw-Hill
1998
|
| Schriftenreihe: | Chemical engineering series
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 2. Aufl. u.d.T.: Kumar, Anil: Fundamentals of polymer engineering |
| Beschreibung: | XIV, 544 S. graph. Darst. |
| ISBN: | 0070252246 |
Internformat
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Datensatz im Suchindex
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| adam_text | FUNDAMENTALS OF POLYMERS ANIL KUMAR INDIAN INSTITUTE OF TECHNOLOGY
KANPUR, INDIA RAKESH K. GUPTA WEST VIRGINIA UNIVERSITY THE MCGRAW-HILL
COMPANIES, INC. NEW YORK ST. LOUIS SAN FRANCISCO AUCKLAND BOGOTA CARACAS
LISBON LONDON MADRID MEXICO CITY MILAN MONTREAL NEW DELHI SAN JUAN
SINGAPORE SYDNEY TOKYO TORONTO CONTENTS PREFACE XIII CHAPTER 1
INTRODUCTION 1 1.1 DEFINING POLYMERS 1 1.2 CLASSIFICATION OF POLYMERS
AND SOME FUNDAMENTAL CONCEPTS 3 1.3 CHEMICAL CLASSIFICATION OF POLYMERS
BASED ON POLYMERIZATION MECHANISMS 10 1.4 MOLECULAR WEIGHT DISTRIBUTIONS
12 1.5 POLYMERIE SUPPORTS IN ORGANIC SYNTHESIS AND POLYMERIE CATALYSTS
15 1.6 CONFIGURATIONS AND CRYSTALLINITY OF POLYMERIE MATERIALS 18 1.7
CONFORMATION OF POLYMER MOLECULES 23 1.8 CONCLUSION 24 REFERENCES 24
PROBLEMS 25 CHAPTER 2 EFFECT OF CHEMICAL STRUCTURE ON POLYMER PROPERTIES
29 2.1 INTRODUCTION 29 2.2 EFFECT OF TEMPERATURE ON POLYMERS 29 2.3
ADDITIVES FOR PLASTICS 34 2.4 RUBBERS 41 2.5 CELLULOSE PLASTICS 46 2.6
COPOLYMERS AND BLENDS 47 2.7 CROSS-LINKING REACTIONS 51 2.8 ION EXCHANGE
RESINS 57 2.9 CONCLUSION 63 REFERENCES 63 PROBLEMS 65 CHAPTER 3 STEP
GROWTH POLYMERIZATION 72 3.1 INTRODUCTION 72 3.2 ESTERIFICATION OF
HOMOLOGOUS SERIES AND THE EQUAL REACTIVITY HYPOTHESIS 73 3.3 KINETICS OF
A*R*B POLYMERIZATION USING THE EQUAL REACTIVITY HYPOTHESIS 75 VII VLLL
CONTENTS 3.4 AVERAGE MOLECULAR WEIGHT IN STEP GROWTH POLYMERIZATION OF
ARB MONOMERS 79 3.5 EQUILIBRIUM STEP GROWTH POLYMERIZATION 82 3.6
MOLECULAR WEIGHT DISTRIBUTION IN STEP GROWTH POLYMERIZATION 84 3.7
EXPERIMENTAL RESULTS 87 3.8 CONCLUSION 100 APPENDIX: THE SOLUTION OF MWD
THROUGH THE GENERATING FUNCTION TECHNIQUE IN STEP GROWTH POLYMERIZATION
101 REFERENCES 103 PROBLEMS 105 CHAPTER 4 REACTION ENGINEERING OF STEP
GROWTH POLYMERIZATION 112 4.1 INTRODUCTION 112 4.2 ANALYSIS OF SEMIBATCH
REACTORS 115 4.3 MWD OF ARB POLYMERIZATION IN HOMOGENOUS CONTINUOUS-FLOW
STIRRED-TANK REACTORS (HCSTRS) 121 4.4 ADVANCED STAGE OF POLYMERIZATION
124 4.5 CONCLUSION 127 APPENDIX: SIMILARITY SOLUTION OF STEP GROWTH
POLYMERIZATION IN FILMS WITH FINITE MASS TRANSFER 127 REFERENCES 132
PROBLEMS 132 CHAPTER 5 CHAIN GROWTH POLYMERIZATION 139 5.1 INTRODUCTION
139 5.2 RADICAL POLYMERIZATION 142 5.3 KINETIC MODEL OF RADICAL
POLYMERIZATION 147 5.4 AVERAGE MOLECULAR WEIGHT IN RADICAL
POLYMERIZATION 148 5.5 VERIFICATION OF THE KINETIC MODEL AND THE GEL
EFFECT IN RADICAL POLYMERIZATION 150 5.6 EQUILIBRIUM OF RADICAL
POLYMERIZATION 157 5.7 TEMPERATURE EFFECTS IN RADICAL POLYMERIZATION 160
5.8 IONIC POLYMERIZATION 161 5.9 ANIONIC POLYMERIZATION 166 5.10
ZIEGLER-NATTA CATALYSTS IN STEREOREGULAR POLYMERIZATION 168 5.11 KINETIC
MECHANISM IN HETEROGENEOUS STEREOREGULAR POLYMERIZATION 170 5.12
STEREOREGULATION BY ZIEGLER-NATTA CATALYST 173 5.13 RATES OF
ZIEGLER-NATTA POLYMERIZATION 174 5.14 AVERAGE CHAIN LENGTH OF THE
POLYMER IN STEREOREGULAR POLYMERIZATION 178 5.15 DIFFUSIONAL EFFECT IN
ZIEGLER-NATTA POLYMERIZATION 179 5.16 CONCLUSION 181 REFERENCES 181
PROBLEMS 183 CONTENTS IX CHAPTER 6 REACTION ENGINEERING OF CHAIN GROWTH
POLYMERIZATION 190 6.1 INTRODUCTION 190 6.2 DESIGN OF TUBULAER REACTORS
191 6.3 COPOLYMERIZATION 204 6.4 CONCLUSION 212 APPENDIX: SOLUTION OF
EQUATIONS DESCRIBING ISOTHERMAL RADICAL POLYMERIZATION 212 REFERENCES
217 PROBLEMS 218 CHAPTER 7 EMULSION POLYMERIZATION 224 7.1 INTRODUCTION
224 7.2 AQUEOUS EMULSIFIER SOLUTIONS 225 7.3 SMITH AND EWART THEORY FOR
STATE II OF EMULSION POLYMERIZATION 228 7.4 ESTIMATION OF THE TOTAL
NUMBER OF PARTICLES, N, 236 7.5 MONOMER CONCENTRATION IN POLYMER
PARTICLES, [M] 237 7.6 DETERMINATION OF MOLECULAR WEIGHT IN EMULSION
POLYMERIZATION 241 7.7 EMULSION POLYMERIZATION IN HOMOGENEOUS
CONTINUOUS-FLOW STIRRED-TANK REACTORS (HCSTRS) 245 7.8 TIME-DEPENDENT
EMULSION POLYMERIZATION 247 REFERENCES 254 PROBLEMS 255 CHAPTER 8
MEASUREMENT OF MOLECULAR WEIGHT AND ITS DISTRIBUTION 258 258 259 260 267
270 273 278 282 282 283 286 286 287 291 305 306 308 8.1 8.2 8.3 8.4 8.5
8.6 8.7 8.8 INTRODUCTION END-GROUP ANALYSIS COLLIGATIVE PROPERTIES LIGHT
SCATTERING ULTRACENTRIFUGATION INTRINSIC VISCOSITY GEL PERMEATION
CHROMATOGRAPHY CONCLUSION REFERENCES PROBLEMS CHAPTER 9 THERMODYNAMICS
OF POLYMER MIXTURES 9.1 9.2 9.3 9.4 9.5 9.6 INTRODUCTION CRITERIA FOR
POLYMER SOLUBILITY THE FLORY-HUGGINS THEORY FREE VOLUME THEORIES THE
SOLUBILITY PARAMETER POLYMER BLENDS X CONTENTS 9.7 CONCLUSION 309
REFERENCES 310 PROBLEMS 311 CHAPTER 10 THEORY OF RUBBER ELASTICITY 312
10.1 INTRODUCTION 312 10.2 PROBABILITY DISTRIBUTION FOR THE FREELY
JOINTED CHAIN 313 10.3 ELASTIC FORCE BETWEEN CHAIN ENDS 318 10.4
STRESS-STRAIN BEHAVIOR 321 10.5 THE STRESS TENSOR (MATRIX) 323 10.6
MEASURES OF FINITE STRAIN 325 10.7 THE STRESS CONSTITUTIVE EQUATION 329
10.8 VULCANIZATION OF RUBBER AND SWELLING EQUILIBRIUM 330 10.9
CONCLUSION 333 REFERENCES 334 PROBLEMS 335 CHAPTER 11 POLYMER
CRYSTALLIZATION 337 11.1 INTRODUCTION 337 11.2 ENERGETICS OF PHASE
CHANGE 342 11.3 OVERALL CRYSTALLIZATION RATE 345 11.4 EMPIRICAL RATE
EXPRESSIONS*THE AVRAMI EQUATION 347 11.5 CRYSTALLIZATION OF MISCIBLE
BLENDS 353 11.6 MELTING OF CRYSTALS 355 11.7 INFLUENCE OF POLYMER CHAIN
EXTENSION AND ORIENTATION 356 11.8 POLYMERS WITH LIQUID CRYSTALLINE
ORDER 357 11.9 STRUCTURE DETERMINATION 360 11.10 WORKING WITH
SEMICRYSTALLINE POLYMERS 370 11.11 CONCLUSION 371 REFERENCES 371
PROBLEMS 374 CHAPTER 12 MECHANICAL PROPERTIES 376 12.1 INTRODUCTION 376
12.2 STRESS-STRAIN BEHAVIOR 377 12.3 THE GLASS TRANSITION TEMPERATURE
383 12.4 DYNAMIC MECHANICAL EXPERIMENTS 387 12.5 TIME-TEMPERATURE
SUPERPOSITION 389 12.6 POLYMER FRACTURE 392 12.7 CRAZING AND SHEAR
YIELDING 395 12.8 FATIGUE FAILURE 399 12.9 IMPROVING MECHANICAL
PROPERTIES 401 REFERENCES 402 PROBLEMS 404 CHAPTER 13 POLYMER DIFFUSION
407 13.1 INTRODUCTION 407 13.2 FUNDAMENTALS OF MASS TRANSFER 408
CONTENTS XI 13.3 13.4 13.5 13.6 13.7 13.8 13.9 13.10 DIFFUSION
COEFFICIENT MEASUREMENT DIFFUSIVITY OF SPHERES AT INFINITE DILUTION
DIFFUSION COEFFICIENT FOR NON-THETA SOLUTIONS FREE VOLUME THEORY OF
DIFFUSION IN RUBBERY POLYMERS GAS DIFFUSION IN GLASSY POLYMERS ORGANIC
VAPOR DIFFUSION IN GLASSY POLYMERS* CASE II DIFFUSION POLYMER-POLYMER
DIFFUSION CONCLUSION REFERENCES PROBLEMS CHAPTER 14 FLOW BEHAVIOR OF
POLYMERIE FLUIDS 14.1 14.2 14.3 14.4 14.5 14.6 14.7 14.8 14.9 14.10
14.11 INTRODUCTION VISCOMETRIC FLOWS CONE-AND-PLATE VISCOMETER THE
CAPILLARY VISCOMETER EXTENSIONAL VISCOMETERS BOLTZMANN SUPERPOSITION
PRINCIPLE DYNAMIC MECHANICAL PROPERTIES THEORIES OF SHEAR VISCOSITY
CONSTITUTIVE BEHAVIOR OF DILUTE POLYMER SOLUTIONS CONSTITUTIVE BEHAVIOR
OF CONCENTRATED SOLUTIONS AND MELTS CONCLUSION REFERENCES PROBLEMS
CHAPTER 15 POLYMER PROCESSING 15.1 15.2 15.3 15.4 15.5 INTRODUCTION
EXTRUSION INJECTION MOLDING FIBER SPINNING CONCLUSION REFERENCES
PROBLEMS 411 419 422 423 428 431 434 437 438 441 444 444 447 448 453 457
461 463 466 472 481 486 486 488 492 492 493 506 519 530 530 533
PERMISSIONS 535 INDEX 539
|
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| discipline | Chemie / Pharmazie Physik |
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| indexdate | 2024-07-09T18:12:03Z |
| institution | BVB |
| isbn | 0070252246 |
| language | English |
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| physical | XIV, 544 S. graph. Darst. |
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| spelling | Kumar, Anil Verfasser aut Fundamentals of polymers Anil Kumar ; Rakesh K. Gupta New York [u.a.] McGraw-Hill 1998 XIV, 544 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemical engineering series 2. Aufl. u.d.T.: Kumar, Anil: Fundamentals of polymer engineering Polymerization Polymers Polymere (DE-588)4046699-1 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Polymere (DE-588)4046699-1 s Chemie (DE-588)4009816-3 s DE-604 Gupta, Rakesh K. Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007792242&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kumar, Anil Gupta, Rakesh K. Fundamentals of polymers Polymerization Polymers Polymere (DE-588)4046699-1 gnd Chemie (DE-588)4009816-3 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4009816-3 |
| title | Fundamentals of polymers |
| title_auth | Fundamentals of polymers |
| title_exact_search | Fundamentals of polymers |
| title_full | Fundamentals of polymers Anil Kumar ; Rakesh K. Gupta |
| title_fullStr | Fundamentals of polymers Anil Kumar ; Rakesh K. Gupta |
| title_full_unstemmed | Fundamentals of polymers Anil Kumar ; Rakesh K. Gupta |
| title_short | Fundamentals of polymers |
| title_sort | fundamentals of polymers |
| topic | Polymerization Polymers Polymere (DE-588)4046699-1 gnd Chemie (DE-588)4009816-3 gnd |
| topic_facet | Polymerization Polymers Polymere Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007792242&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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