Inorganic biochemistry: an introduction
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York, NY [u.a.]
Wiley-VCH
1997
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 440 S. graph. Darst. |
| ISBN: | 0471188956 |
Internformat
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| 245 | 1 | 0 | |a Inorganic biochemistry |b an introduction |c J. A. Cowan |
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Datensatz im Suchindex
| _version_ | 1804126047056166912 |
|---|---|
| adam_text | Contents
Chapter 1. Fundamentals of Inorganic Biochemistry
Part A. Fundamentals of Inorganic Solution Chemistry 2
1.1 The Elements 2
1.2 Formal Oxidation States and Coordination
Geometries of Biologically Important Metal Ions
3
1.3 Classifications of Metal Ions and Ligands: Hard-
Soft Acid-Base (HSAB) Theory 7
1.4 Stability Constants 8
1.5 Stabilization of Oxidation States 11
1.6 Ligand Field Stabilization Energy 12
1.7 Kinetics and Mechanisms of Reactions Involving
Metal Complexes 16
1.8 Electron-Transfer Reactions 20
Part B. Fundamentals of Reaction Kinetics
and Thermodynamics 24
1.9 Rate Laws and Rate Constants 24
1.10 Thermodynamics and Equilibrium 28
1.11 Catalysis 32
Part C. Fundamentals of Biochemistry 36
1.12 Biological Ligands 36
1.13 The Relationship Between Nucleotide and Protein
Sequence 48
xi
xii CONTENTS
1.14 Cell Biology 49
1.15 Molecular Biology 53
Notes 57
Further Reading 58
Problems 60
Chapter 2. Experimental Methods 65
Part A. Physicochemical Methods 65
2.1 Introduction to Spectroscopy 65
2.2 Optical Spectroscopy 69
2.3 Magnetic Resonance and Related Properties 76
2.4 Solution Methods Dependent on X-Radiation and
¦y-Radiation 92
2.5 Electrochemical Methods 98
PartB. Biochemical Methods 108
2.6 Enzyme Kinetics 108
2.7 Measuring the Molecular Mass of a Protein 114
2.8 Measuring the Molecular Mass and Length of
Polynucleotides 115
2.9 Measurement of Macromolecule-Ligand Binding
Affinities 115
2.10 Protein Isolation and Purification 116
Notes 118
Further Reading 119
Problems 122
Chapter 3. Transport and Storage 133
3.1 Introduction 133
3.2 Metal Ion Uptake and Transmembrane Ion
Transport 137
3.3 Transport and Storage of Metal Ions
in Vivo 147
Notes 161
Further Reading 162
Problems 163
Chapter 4. Metalloproteins and Metalloenzymes:
(T) Oxygen Carriers and Hydrolases 167
4.1 Oxygen Carriers 168
4.2 Hydrolase Enzymes 179
4.3 Hydro-Lyase Enzymes—Aconitase 190
Notes 194
CONTENTS xiii
Further Reading 198
Problems 198
Chapter 5. Metalloproteins and Metalloenzymes:
(II) Redox Chemistry 203
5.1 Introduction 203
5.2 Prosthetic Centers, Cofactors, and Coenzymes in
Metalloredox Proteins and Enzymes 205
5.3 Electron-Transfer Pathways in Respiratory
Metabolism 221
5.4 Electron-Transfer Pathways in Nonrespiratory
Metabolism 231
5.5 Protein-Protein Electron Transfer 242
Notes 247
Further Reading 248
Problems 250
Chapter 6. Alkali and Alkaline Earth Metals 257
6.1 Overview of the Biological Chemistry of Group IA
and HA Metals 257
6.2 Membrane Translocation 260
6.3 Alkali Metals and the Regulation of Membrane
Potentials 262
6.4 Enzyme Activation 268
6.5 Complexes with Nucleic Acids 273
6.6 Cell Walls and Membranes 278
6.7 Biominerals 279
Notes 284
Further Reading 285
Problems 286
Chapter 7. Metals in the Regulation of Biochemical
Events 291
7.1 Calcium as a Secondary Messenger 292
7.2 Regulation of Cellular Concentrations of Metal
Ions 303
Notes 314
Further Reading 314
Problems 314
Chapter 8. Cell Toxicity and Chemotherapeutics 319
8.1 Oxygen Toxicity 320
8.2 Metal Toxicity 338
xiv CONTENTS
8.3 Coordination Complexes as
Therapeutic Agents 342
Notes 349
Further Reading 351
Problems 352
Chapter 9. Metal Complexes as Probes of Structure and
Reactivity 357
9.1 Nucleic Acids 357
9.2 Metal Substitution: A Probe of Structure and
Reactivity 364
Notes 382
Further Reading 382
Problems 383
Chapter 10. Case Studies 389
10.1 Cytochrome c Oxidase 389
10.2 Mercuric Reductase 400
10.3 Bleomycin 406
10.4 Final Remarks 416
Notes 416
Further Reading 417
Appendices 419
Solutions to Problems Lacking Original Literature
References 427
Index 431
|
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| author | Cowan, James A. |
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| discipline | Chemie / Pharmazie Chemie |
| edition | 2. ed. |
| format | Book |
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| spellingShingle | Cowan, James A. Inorganic biochemistry an introduction Anorganische Chemie (DE-588)4002145-2 gnd Metallproteide (DE-588)4169623-2 gnd Reaktivität (DE-588)4208182-8 gnd Biochemie (DE-588)4006777-4 gnd Metallion (DE-588)4169597-5 gnd Bioanorganische Chemie (DE-588)4126727-8 gnd Biologie (DE-588)4006851-1 gnd Komplexe (DE-588)4133953-8 gnd |
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| title | Inorganic biochemistry an introduction |
| title_auth | Inorganic biochemistry an introduction |
| title_exact_search | Inorganic biochemistry an introduction |
| title_full | Inorganic biochemistry an introduction J. A. Cowan |
| title_fullStr | Inorganic biochemistry an introduction J. A. Cowan |
| title_full_unstemmed | Inorganic biochemistry an introduction J. A. Cowan |
| title_short | Inorganic biochemistry |
| title_sort | inorganic biochemistry an introduction |
| title_sub | an introduction |
| topic | Anorganische Chemie (DE-588)4002145-2 gnd Metallproteide (DE-588)4169623-2 gnd Reaktivität (DE-588)4208182-8 gnd Biochemie (DE-588)4006777-4 gnd Metallion (DE-588)4169597-5 gnd Bioanorganische Chemie (DE-588)4126727-8 gnd Biologie (DE-588)4006851-1 gnd Komplexe (DE-588)4133953-8 gnd |
| topic_facet | Anorganische Chemie Metallproteide Reaktivität Biochemie Metallion Bioanorganische Chemie Biologie Komplexe Einführung Lehrbuch |
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