The theory of atomic spectra:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Univ. Press
1963
|
| Ausgabe: | Reprint. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 441 S. graph. Darst. |
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Datensatz im Suchindex
| _version_ | 1811101451759386624 |
|---|---|
| adam_text |
T H E
THEORYOFATOMICSPECTRA
by
E U CONDON, PH D
WAYMANCROWPROFESSOROFPHYSICS,WASHINGTONUNIVERSITY
STLOUIS,MISSOURI
and
G H SHORTLEY, Ph D
VICE-PRESIDENT amp;DIRECTOR,WASHINGTONOPERATIONS
BOOZ,ALLENAPPLIEDRESEARCH,INC
-CAMBRIDGE
AT THE UNIVERSITY PRESS
CONTENTS
PAGE
Preface to the 1963 impression • xiii
Preface xiv
CHAPTER I
INTRODUCTION 1
CHAPTER II
THE QUANTUM MECHANICAL METHOD 12
SECTION
l2 Symbolic algebra of states and observal les 12
22 Representations of states and observables 15
32 Continuous eigenvalues and the Schrodinger representation 20
42 The statistical interpretation 24
52 The laws of quantum mechanics 25
62 Schrodinger's equation 26
72 Matrix mechanics '27
82 Perturbation theory 30
92 Resume of the perturbation theory 34
102 Remarks on the perturbation theory 35
ll2 Perturbation caused by a single state 37
122 The analysis of non-commuting vectors , 43
CHAPTER III
ANGULAR MOMENTUM 45
l3 Definition of angular momentum 45
23 Allowed values of angular momentum 46
33 The matrices of angular momentum 48
43 Orbital angular momentum 50
53 Spin angular momentum 54
63 Vector addition of angular momenta 56
7s The matrix of (J1+J2)2 • 58
83 Matrix of Tin the j m scheme Selection rule on J 59
93 Dependence of the matrix of T on m 61
103 The matrices of J1 and J2, where Jx +J=J\ 64
viii CONTENTS
CHAPTER III (continued)
SECTIONPAGE
ll3 Matrix of a vector P which commutes with 67
123 Matrix of P'Q 7 0
133 Sum rules 71
143 Transformation amplitudes for vector addition 73
CHAPTER IV
THE THEORY OF RADIATION 79
l4 Transition probabilities • • 79
24 Classical electromagnetic theory 83
34 Expansion of the retarded potential 84
44 The correspondence principle for emission 87
i54Thedipole-radiationfield90
64 The quadrupole-radiation field 93
74 Spectral lines in natural excitation : 97
84 Induced emission and absorption 100
94 Dispersion theory Scattering Raman effect 103
104 Natural shape of absorption lines 109
CHAPTER V _
ONE-ELECTRON SPECTRA 112
Is Central-force problem 112
I
2s Radial functions for hydrogen • 114
35 The relativity correction - 118
45 Spin-orbit interaction 120
55 Sketch of the relativistic theory 125
65 Intensities in hydrogen 131
75 Experimental results for hydrogenic spectra 137
85 General structure of the alkali spectra 141
9s Intensities in alkali spectra 147
105 Zeeman effect 149
CONTENTS ix
CHAPTER VI
PAGE
SECTIONTHE CENTRAL-FIELD APPROXIMATION 158
1® The Hamiltonian for many-electron atoms 158
2® Equivalence degeneracy 160
3® The dynamical equivalence of the electrons 162
4® The Pauli exclusion principle 166
5® Conventions concerning quantum numbers Closed shells 168
6® Matrix components for Si/(i) ' 169
7® Matrix components for 171
8® Matrix components of electrostatic interaction 174
9® Special izat ion for closed shells 177
10® One electron outside closed shells 183
11® Odd and even states 185
CHAPTER VII
THE RUSSELL-SAUNDERS CASE: ENERGY LEVELS 187
17 The I/S-coupling scheme 188
27 Term energies 191
37 The Lande interval rule 193
47 Absolute term intervals 195
57 Formulai and experimental comparison 197
67 Terms in the wp configurations , 207
77 The triplet terms of helium 210
CHAPTER VIII
THE RUSSELL-SAUNDERS CASE: EIGENFUNCTIONS 213
18 Vector coupling in antisymmetric state-i 213
28 Genealogical characterization of Z/$-coupling terms 216
38 Lande intervals for terms of coupled groups 219
48 Calculation of eigenfunctions by direct diagonalization 220
58 Calculation of - eigenfunctions using angular-momentum
operators 226
68 Calculation of eigenfunctions from vector-coupling formulas 228
78 Separation of the 2D's of d3 • 233
X CONTENTS
CHAPTER IX
PAGE
THE RUSSELL-SAUNDERS CASE: LINE STRENGTHS 236
SECTION
l9 Configuration selection rules 236
29 Line strengths in Russell-Saunders multisets 237
39 Multiplet strengths in a transition array 244
49 Multiplet strengths obtained from spectroscopic stability 249
59 Quadrupole multiplets 252
\ CHAPTER X
jj COUPLING257
110 The jy-coupling scheme and the spin-orbit interaction 257
210 The addition of a weak electrostatic interaction 259
310 Eigenfunctions 262
410 Line strengths 264
CHAPTER XI
INT ERMEDIATECOUPLING266
111 Matrix of spin-orbit interaction for configurations consisting
of coupled groups 266
211 Matrix of spin-orbit interaction obtained from the eigen
functions 270
3U Illustrations of the transition from LS t jj coupling 271
411 Line strengths in intermediate coupling 277
5U The forbidden lines of astrophysical interest 282
CHAPTER XII
TRANSFORMATIONS IN THE THEORY
OF COMPLEX SPECTRA 284
112 Configurations containing almost closed shells 284
212 The transformation to LS coupling 285
312 The transformation to jj coupling 287
412 The transformation between zero-order states 287
512 The transformation nlmsml^nljm 290
612ThetransformationjjJM=*=?SLJM291
CONTENTS Xi
CHAPTER XIII
CONFIGURATIONS CONTAINING ALMOST PAGE
SECTIONCLOSEDSHELLSX-RAYS295
113 The electrostatic energy in LS coupling 295
213 The spin-orbit interaction 299
313 Pure almost-closed-shell configurations 300
413 The rare-gas spectra 301
513 The configurations p amp; s and d9s 304
613 The configuration php in the rare gases 306
The configuration ph d in the rare gases 312
813 Line strengths 316
913 X-ray spectra 316
1013 Line strengths in X-ray spectra 322
1113 X-ray satellites 323
CHAPTER XIV
CENTRAL FIEL DS 327
114 The periodic system 327
214 The statistical method of Fermi-Thomas 335
314 The Wentzel-Brillouin-Kramers approximation 339
414 Numerical integration of the radial equation 344
514 Normal state of helium 345
614 Excited levels in helium 348
714 Normal states of first-row atoms 351
814 Hartree's self-consistent fields 354
914 Survey of consistent-field results 358
1014 Self-consistent fields for oxygen 362
i CHAPTER XV
CONFIGURATION INTERACTION 365
115 Interaction of sd and p2 in magnesium 366
215 Perturbed series 367
315 Auto-ionization 369
415 Many-electron jumps 375
515 Spin-orbit perturbation of doublet intensities 376
xii CONTENTS
CHAPTER XVI
PAGE
SE0TI0N THE ZEEMAN EFFECT 378
l18 The'normal'Zeeman effect 378
216 The weak-field case: Russell-Saunders terms 380
316 Weak fields: general case 384
416 Intensities in the Zeeman pattern: weak fields 386
516 The Paschen-Back effect 388
618 The Paschen-Back effect: illustrative examples 390
718 Quadrupole lines 395
CHAPTER XVII
THE STARK EFFECT 397
117 Hydrogen 398
217 St amp;rk effect at the series limit 404
317 General theory for non-hydrogenic atoms 409
417 Hehum 413
517 Alkali metals 415
CHAPTER XVIII
THE NUCLEUS IN ATOMIC SPECTRA 418
118 Effect of finite mass 418
218 Local nuclear fields 420
318 Nuclear spin in one-electron spectra 421
418 The hyperfine structure of two-electron spectra 424
518 Zeeman effect of hyperfine structure 426
APPENDIX
UNIVERSAL CONSTANTS AND NATURAL
ATOMIC UNITS 428
List of Principal Tables 434
Index of Subjects 435
Index of Names 439 |
| any_adam_object | 1 |
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| discipline | Chemie / Pharmazie Physik |
| edition | Reprint. |
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| publisher | Univ. Press |
| record_format | marc |
| spelling | Condon, Edward Uhler 1902-1974 Verfasser (DE-588)118669877 aut The theory of atomic spectra by E. U. Condon and G. H. Shortley Reprint. Cambridge Univ. Press 1963 XV, 441 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Quantentheorie Quantum theory Spectrum analysis Atomtheorie (DE-588)4143338-5 gnd rswk-swf Spektrum (DE-588)4056139-2 gnd rswk-swf Atomphysik (DE-588)4003423-9 gnd rswk-swf Theorie (DE-588)4059787-8 gnd rswk-swf Atomspektroskopie (DE-588)4143333-6 gnd rswk-swf Atomspektrum (DE-588)4143334-8 gnd rswk-swf Spektroskopie (DE-588)4056138-0 gnd rswk-swf 1\p (DE-588)4151278-9 Einführung gnd-content Atomspektrum (DE-588)4143334-8 s Atomspektroskopie (DE-588)4143333-6 s Theorie (DE-588)4059787-8 s 2\p DE-604 Atomphysik (DE-588)4003423-9 s 3\p DE-604 Spektroskopie (DE-588)4056138-0 s 4\p DE-604 Spektrum (DE-588)4056139-2 s 5\p DE-604 Atomtheorie (DE-588)4143338-5 s 6\p DE-604 Shortley, George 1910- Verfasser (DE-588)122807960 aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007713868&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 6\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Condon, Edward Uhler 1902-1974 Shortley, George 1910- The theory of atomic spectra Quantentheorie Quantum theory Spectrum analysis Atomtheorie (DE-588)4143338-5 gnd Spektrum (DE-588)4056139-2 gnd Atomphysik (DE-588)4003423-9 gnd Theorie (DE-588)4059787-8 gnd Atomspektroskopie (DE-588)4143333-6 gnd Atomspektrum (DE-588)4143334-8 gnd Spektroskopie (DE-588)4056138-0 gnd |
| subject_GND | (DE-588)4143338-5 (DE-588)4056139-2 (DE-588)4003423-9 (DE-588)4059787-8 (DE-588)4143333-6 (DE-588)4143334-8 (DE-588)4056138-0 (DE-588)4151278-9 |
| title | The theory of atomic spectra |
| title_auth | The theory of atomic spectra |
| title_exact_search | The theory of atomic spectra |
| title_full | The theory of atomic spectra by E. U. Condon and G. H. Shortley |
| title_fullStr | The theory of atomic spectra by E. U. Condon and G. H. Shortley |
| title_full_unstemmed | The theory of atomic spectra by E. U. Condon and G. H. Shortley |
| title_short | The theory of atomic spectra |
| title_sort | the theory of atomic spectra |
| topic | Quantentheorie Quantum theory Spectrum analysis Atomtheorie (DE-588)4143338-5 gnd Spektrum (DE-588)4056139-2 gnd Atomphysik (DE-588)4003423-9 gnd Theorie (DE-588)4059787-8 gnd Atomspektroskopie (DE-588)4143333-6 gnd Atomspektrum (DE-588)4143334-8 gnd Spektroskopie (DE-588)4056138-0 gnd |
| topic_facet | Quantentheorie Quantum theory Spectrum analysis Atomtheorie Spektrum Atomphysik Theorie Atomspektroskopie Atomspektrum Spektroskopie Einführung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007713868&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT condonedwarduhler thetheoryofatomicspectra AT shortleygeorge thetheoryofatomicspectra |