Principles of colloid and surface chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Dekker
1997
|
| Ausgabe: | 3. ed., rev. and expanded |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 650 S. Ill., graph. Darst. |
| ISBN: | 0824793978 9780824793975 |
Internformat
MARC
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| 100 | 1 | |a Hiemenz, Paul C. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Principles of colloid and surface chemistry |c Paul C. Hiemenz ; Raj Rajagopalan |
| 250 | |a 3. ed., rev. and expanded | ||
| 264 | 1 | |a New York [u.a.] |b Dekker |c 1997 | |
| 300 | |a XIX, 650 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Coloides | |
| 650 | 4 | |a Química de superficies | |
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| 650 | 0 | 7 | |a Oberflächenchemie |0 (DE-588)4126166-5 |2 gnd |9 rswk-swf |
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| 689 | 1 | |5 DE-604 | |
| 700 | 1 | |a Rajagopalan, Raj |e Verfasser |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804125906747260928 |
|---|---|
| adam_text | Contents
Preface to the Third Edition ///
Acknowledgments vii
Preface to the Second Edition /x
Preface to the First Edition x;
1. Colloid and Surface Chemistry: Scope and Variables 1
1.1 Introduction 1
1.2 The Importance of the Surface for Small Particles 6
1.3 Classification of Colloids Based on Affinity to Carrier Fluid 10
1.4 Concept of Stability of Colloidal Systems 14
1.5 Some Physical Characteristics of Colloids 19
1.6 Some Classical and Emerging Experimental Tools 38
1.7 An Overview of the Book 56
Review Questions 57
References 57
Problems 59
2. Sedimentation and Diffusion and Their Equilibrium 62
2.1 Introduction 62
2.2 Sedimentation: Some Basic Considerations 65
2.3 Gravitational Sedimentation 67
2.4 Centrifugal Sedimentation 74
2.5 Diffusion 78
2.6 Brownian Motion and Diffusion 85
2.7 The Random Coil and Random Walk Statistics 94
2.8 Equilibrium Between Sedimentation and Diffusion 98
Review Questions 101
References 101
Problems 102
3. Solution Thermodynamics: Osmotic and Donnan Equilibria 105
3.1 Introduction 105
3.2 Osmotic Pressure: Thermodynamic Foundations 108
3.3 Osmometry: Some Applications 114
3.4 Statistical Foundations of Solution Thermodynamics 120
3.5 Osmotic Equilibrium in Charged Systems 132
3.6 Some Applications of Osmotic Phenomena 139
xv
xvj Contents
Review Questions *4
References 141
Problems 142
4. The Rheology of Dispersions 145
4.1 Introduction 145
4.2 Newton s Law of Viscosity 148
4.3 Concentric-Cylinder and Cone-and-Plate Viscometers 150
4.4 The Poiseuille Equation and Capillary Viscometers 154
4.5 The Equation of Motion: The Navier-Stokes Equation 158
4.6 Einstein s Theory of Viscosity of Dispersions 161
4.7 Deviations from the Einstein Model 168
4.8 Non-Newtonian Behavior 174
4.9 Viscosity of Polymer Solutions 181
Review Questions 188
References 188
Problems 189
5. Static and Dynamic Light Scattering and Other Radiation Scattering 193
5.1 Introduction 193
5.2 Interaction of Radiation with Matter 196
5.3 Scattering by Small Particles: Theory of Rayleigh Scattering 202
5.4 Experimental Aspects of Light Scattering 207
5.5 Extension to Larger Particles and to Intraparticle Interference Effects 213
5.6 Interference Effects and Structure of Particles 223
5.7 Scattering by Large, Absorbing Particles 229
5.8 Dynamic Light Scattering 236
Review Questions 242
References 243
Problems 244
6. Surface Tension and Contact Angle: Application to Pure Substances 248
6.1 Introduction 248
6.2 Surface Tension and Contact Angle: A First Look 251
6.3 Thermodynamics of Surfaces: Surface Tension as Surface Free Energy 255
6.4 Surface Tension: Implications for Curved Interfaces and Capillarity 257
6.5 Effects of Curved Interfaces on Phase Equilibria and Nucleation:
The Kelvin Equation 261
6.6 Surface Tension and Contact Angle: Their Relation to Wetting
and Spreading Phenomena
6.7 Contact Angles: Some Complications
6.8 Measuring Surface Tension and Contact Angle: Round Two 2^
6.9 Contact of Liquids with Porous Solids and Powders 276
6.10 Molecular Interpretation of Surface Tension 283
Review Questions 286
References 291
Problems 293
7. Adsorption from Solution and Monolayer Formation 297
7.1 Introduction 297
7.2 Insoluble Monolayers: Spreading of Surfactants on Aqueous Surfaces 300
Contents xvjj
7.3 Experimental Measurement of Film Pressure 304
7.4 Results of Film Balance Studies 308
7.5 Viscous Behavior of Two-Dimensional Phases 318
7.6 Applications of Monolayers and Monolayer Concepts 320
7.7 Adsorption from Solution: Thermodynamics 323
7.8 The Gibbs Equation: Experimental Results 327
7.9 Adsorption on Solid Surfaces 331
7.10 Applications of Adsorption from Solution 338
7.11 Adsorption in the Presence of an Applied Potential 343
Review Questions 348
References 348
Problems 349
8. Colloidal Structures in Surfactant Solutions: Association Colloids 355
8.1 Introduction 355
8.2 Surfactants in Solution: Experimental Observations and Models 357
8.3 Structure of Micelles 362
8.4 Molecular Architecture of Surfactants, Packing Considerations,
and Shapes of Micelles 367
8.5 Critical Micelle Concentration and the Thermodynamics of Micellization 370
8.6 Solubilization 375
8.7 Catalysis by Micelles 380
8.8 Reverse Micelles 386
8.9 Emulsions and Microemulsions 389
8.10 Some Applications of Microemulsions 392
8.11 Biological Membranes 395
Review Questions 398
References 399
Problems 399
9. Adsorption at Gas-Solid Interfaces 405
9.1 Introduction 405
9.2 Experimental and Theoretical Treatments of Adsorption: An Overview 409
9.3 Thermodynamics of Adsorption: Phenomenological Perspective 413
9.4 Thermodynamics of Adsorption: A Statistical Perspective 419
9.5 Multilayer Adsorption: The Brunauer-Emmett-Teller Equation 425
9.6 Energetics of Adsorption 433
9.7 Adsorption in Porous Solids 436
9.8 Adsorption on Crystal Surfaces 439
9.9 Metal Surfaces and Heterogeneous Catalysis 451
Review Questions 455
References 456
Problems 456
10. van der Waals Forces 462
10.1 Introduction 462
10.2 van der Waals Forces and Their Importance in Colloid and
Surface Chemistry 464
10.3 Molecular Interactions and Power Laws 467
10.4 Molecular Origins and the Macroscopic Implications of
van der Waals Forces 471
xviH Contents
10.5 van der Waals Forces Between Large Particles and Over Large Distances 479
10.6 Calculating van der Waals Forces Between Macroscopic Bodies 483
10.7 Theories of van der Waals Forces Based on Bulk Properties 486
10.8 Effect of the Medium on the van der Waals Attraction 490
Review Questions 495
References 495
Problems 496
11. The Electrical Double Layer and Double-Layer Interactions 499
11.1 Introduction 499
11.2 Surface Charges and Electrical Double Layer: Background 502
11.3 The Capacitor Model of the Double Layer 504
11.4 The Diffuse Double Layer: The Debye-Huckel Approximation 508
11.5 The Debye-Hiickel Approximation: Results 512
11.6 The Electrical Double Layer: Gouy-Chapman Theory 516
11.7 Overlapping Double Layers and Interparticle Repulsion 520
11.8 Not-Quite-Indifferent Electrolytes: Stern Adsorption 527
Review Questions 530
References 530
Problems 531
12. Electrophoresis and Other Electrokinetic Phenomena 534
12.1 Introduction 534
12.2 Mobilities of Small Ions and Macroions in Electric Fields: A Comparison 536
12.3 Zeta Potential: Thick Electrical Double Layers 538
12.4 Zeta Potential: Thin Electrical Double Layers 544
12.5 Zeta Potential: General Theory for Spherical Particles 546
12.6 Electroosmosis 550
12.7 Streaming Potential 553
12.8 The Surface of Shear and Viscoelectric Effect 555
12.9 Experimental Aspects of Electrophoresis 559
12.10 Determining the Surface Charge from Electrokinetic Measurements 565
12.11 Applications of Electrokinetic Phenomena 567
Review Questions 570
References 570
Problems 571
13. Electrostatic and Polymer-Induced Colloid Stability 575
13.1 Introduction 575
13.2 Interparticle Forces and the Structure and Stability of Dispersions 578
13.3 TheDerjaguin-Landau-Verwey-Overbeek Theory of Colloid Stability 585
13.4 Theory of Coagulation in Dilute Dispersions 592
13.5 Polymer-Colloid Mixtures: A Phenomenological Perspective 604
13.6 Polymer-Induced Forces 610
13.7 Steric Stabilization: A Model for the Initial Encounter 614
Review Questions 619
References 620
Problems 621
Contents xix
Appendix A: Examples of Expansions Encountered in This Book 625
Reference 625
Appendix B: Units: CGS-SI Interconversions 626
References 626
Appendix C: Statistics of Discrete and Continuous Distributions of Data 637
C.I Introduction 631
C.2 Discrete Distributions 631
C.3 Theoretical Distribution Functions 634
References 637
Appendix D: List of Worked-Out Examples 638
Index 641
|
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| edition | 3. ed., rev. and expanded |
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| id | DE-604.BV011394073 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:09:00Z |
| institution | BVB |
| isbn | 0824793978 9780824793975 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007659109 |
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| physical | XIX, 650 S. Ill., graph. Darst. |
| publishDate | 1997 |
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| publisher | Dekker |
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| spelling | Hiemenz, Paul C. Verfasser aut Principles of colloid and surface chemistry Paul C. Hiemenz ; Raj Rajagopalan 3. ed., rev. and expanded New York [u.a.] Dekker 1997 XIX, 650 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Coloides Química de superficies Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 s DE-604 Kolloidchemie (DE-588)4134420-0 s Rajagopalan, Raj Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007659109&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hiemenz, Paul C. Rajagopalan, Raj Principles of colloid and surface chemistry Coloides Química de superficies Kolloidchemie (DE-588)4134420-0 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4134420-0 (DE-588)4126166-5 |
| title | Principles of colloid and surface chemistry |
| title_auth | Principles of colloid and surface chemistry |
| title_exact_search | Principles of colloid and surface chemistry |
| title_full | Principles of colloid and surface chemistry Paul C. Hiemenz ; Raj Rajagopalan |
| title_fullStr | Principles of colloid and surface chemistry Paul C. Hiemenz ; Raj Rajagopalan |
| title_full_unstemmed | Principles of colloid and surface chemistry Paul C. Hiemenz ; Raj Rajagopalan |
| title_short | Principles of colloid and surface chemistry |
| title_sort | principles of colloid and surface chemistry |
| topic | Coloides Química de superficies Kolloidchemie (DE-588)4134420-0 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Coloides Química de superficies Kolloidchemie Oberflächenchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007659109&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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