Molecular rhenium oxides as oxidation catalysts:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
1996
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 199 S. graph. Darst. |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV011020851 | ||
| 003 | DE-604 | ||
| 005 | 19970521 | ||
| 007 | t | ||
| 008 | 961024s1996 d||| m||| 00||| engod | ||
| 016 | 7 | |a 949005894 |2 DE-101 | |
| 035 | |a (OCoLC)45671708 | ||
| 035 | |a (DE-599)BVBBV011020851 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-91 |a DE-29T |a DE-12 |a DE-11 |a DE-188 | ||
| 082 | 0 | |a 545.23 |b C817m |2 21 | |
| 100 | 1 | |a Correia, João Domingos Galamba |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Molecular rhenium oxides as oxidation catalysts |c João Domingos Galamba Correia |
| 264 | 1 | |c 1996 | |
| 300 | |a 199 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a München, Techn. Univ., Diss., 1996 | ||
| 650 | 4 | |a Oxidation-reduction reaction | |
| 650 | 4 | |a Rhenium trioxide | |
| 650 | 0 | 7 | |a Rheniumoxide |0 (DE-588)4349834-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Katalytische Oxidation |0 (DE-588)4163425-1 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Katalytische Oxidation |0 (DE-588)4163425-1 |D s |
| 689 | 0 | 1 | |a Rheniumoxide |0 (DE-588)4349834-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007378095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-007378095 | |
Datensatz im Suchindex
| _version_ | 1807320444966010880 |
|---|---|
| adam_text |
CONTENTS
A
INTRODUCTION
1
B
RESULTS
AND
DISCUSSION
7
1
MTO-CATALYZED
AROMATIC
OXIDATION
8
1.1
QUINONES-APPLICATIONS
8
1.2
GENERAL
PROCEDURES
FOR
THE
PREPARATION
OF
P-QUINONES
10
1.3
2
-METHYL-1,4-NAPHTHOQUINONE
(VITAMIN
K3)
-
PREPARATION
13
1.4
MTO-CATALYZED
AROMATIC
OXIDATION
WITH
H2O2
16
1.4.1
A
NEW
WAY
TO
VITAMIN
K3
-
CATALYTIC
OXIDATION
OF
2-METHYLNAPHTHALENE
17
1.4.2
OXIDATION
OF
SUBSTITUTED
BENZENES
AND
POLYCYCLIC
ARENES
23
1.4.3.
THE
SYSTEM
MTO/H2O2/ACOH:
MECHANISTIC
CONSIDERATIONS
30
1.4.3.1
ELECTROPHILIC
CHARACTER
OF
CH
3
REO(O2)2*H2O
(4)
30
1.4.3.2
OXYGEN-TRANSFER
MECHANISM
(PROPOSED)
30
1.4.4
MECHANISM
OF
NAPHTHOQUINONE
FORMATION
34
1.4.5
FURTHER
EXAMPLES
OF
MTO-CATALYZED
ARENE
OXIDATION
38
1.4.5.1
CATALYTIC
OXIDATION
OF
PHENOLS
TO
P-QUINONES
38
1.4.5.2
CATALYTIC
OXIDATION
OF
METHOXYBENZENES
TO
P-BENZOQUINONES
39
1.4.5.3
CATALYTIC
OXIDATION
OF
BENZALDEHYDES
TO
PHENOLS
42
1.4.5.4
CATALYTIC
OXIDATION
OF
ANISOLE
TO
O
AND
P
METHOXYPHENOL
42
2
NEW
CATALYTIC
APPLICATIONS
OF
RHENIUM
OXIDES
IN
OXIDATION
REACTIONS
WITH
H2O2
44
2.1
CATALYTIC
AROMATIC
OXIDATION
44
2.1.1
CATALYTIC
OXIDATION
OF
2,3-DIMETHYLNAPHTHALENE
UNDER
ACIDIC
CONDITIONS
44
2.1.2
CATALYTIC
OXIDATION
OF
2,3-DIMETHYLNAPHTHALENE
UNDER
NON-ACIDIC
CONDITIONS
47
2.1.3
RE2O?-CATALYZED
OXIDATION
OF
2-METHYLNAPHTHALENE
50
2.1.4
RE2O7-CATALYZED
OXIDATION
OF
1,3,5-TRIMETHYLBENZENE
52
2.2
CATALYTIC
OXIDATION
OF
[(Q
5-C5ME5)RE(CO)
3
]
(RE
1
)
TO
L(N5
-C
5
ME
5
)REO3
](RE
VI
')
52
2.3
CATALYTIC
EPOXIDATION
OF
OLEFINS
54
2.4
CATALYTIC
ACTIVE
SPECIES
55
2.4.1
SYSTEM
REO3/H2C 2
55
2.4.1.1
UV/VIS
SPECTROSCOPIC
STUDIES
55
2.4.1.2
ISOLATION
57
2.4.1.3
PROPOSED
SRUCTURE
58
2.4.2
SYSTEM
RE2O7/H2C 2
59
2.4.2.1
ISOLATION.
SPECTROSCOPIC
STUDIES
59
2.4.2.2
SOLID
STATE
STRUCTURE
OF
THE
DIGLYME
ADDUCT
OF
P-OXO-BIS[AQUO(OXO)DIPEROXORHENIUM(VII)]
(28B)
63
2.4.2.3
DECOMPOSITION
OF
28B
66
2.4.2.4
[CH
3
REO(O
2
)2*H2O]
(4)
VERSUS
[OLREO^H^OY
(28A)
67
2.4.3
PROPOSED
CATALYTIC
ACTIVE
SPECIES
FOR
OTHER
RHENIUM(VII)
TRIOXIDES
68
3
RE-CATALYZED
BAEYER-VILLIGER
OXIDATION
70
3.1
INTRODUCTION
70
3.2
MTO-CATALYZED
BAEYER-VILLIGER
OXIDATION
71
3.2.1
CATALYTIC
REACTIONS
71
3.2.2
COMPARISON
WITH
OTHER
ESTABLISHED
SYSTEMS
74
3.2.3
MECHANISTIC
CONSIDERATIONS
75
3.3
REOS-CATALYZED
BAEYER-VILLIGER
OXIDATION
79
4
LEWIS-BASE
ADDUCTS
OF
ORGANORHENIUM(VII)
OXIDES
83
4.1
DYNAMIC
BEHAVIOR
IN
SOLUTION
83
4.1.1
ORGANORHENIUM(VII)
OXIDES
IN
SOLUTION
83
4.1.1.1
SOLVENT
AND
TEMPERATURE
EFFECTS
83
4.1.1.2
OXO-LIGANDS
EXCHANGE
84
4.1.2
BASE
ADDUCTS
OF
ORGANORHENIUMFVII)
OXIDES
IN
SOLUTION
86
4.1.2.1
SOLVENT
EFFECTS
86
4.1.2.2
TEMPERATURE
EFFECTS
87
4.1.2.3
OXO-LIGAND
AND
LEWIS
BASE
EXCHANGE
PHENOMENA
89
4.1.3
BASE-FUNCTIONALIZED
ORGANORHENIUMFVII)
OXIDES
93
4.1.3.1
STRUCTURE
IN
SOLUTION
93
4.1.4
CONCLUSION
95
5
LEWIS-BASE
ADDUCTS
OF
MTOFVII).
CATALYSIS
-
NEW
ASPECTS
97
5.1
N-OXIDES
IN
THE
SYSTEM
MTO/H2O2/N-BASE
97
5.2
MTO-CATALYZED
OXIDATION
OF
TERTIARY
AMINES
WITH
H2O2
100
5.3
N-OXIDE-BASE
ADDUCTS
OF
MTO
101
5.3.1
SYNTHESIS
AND
SPECTROSCOPY
101
5.3.2
DYNAMIC
BEHAVIOR
IN
SOLUTION
104
5.3.3
SOLID
STATE
STRUCTURE
OF
(4-TERT-BUTYLPYRIDINE
IV-OXIDE)
METHYLTRIOXORHENIUM(VII)
(33C)
105
5.3.4
CATALYTIC
PROPERTIES
OF
N
AND
IV-OXIDE-BASE
ADDUCTS
OF
MTO,
A
COMPARATIVE
STUDY
107
5.3.4.1
(4-TERT-BUTYLPYRIDINE
LV-OXIDE)METHYL(OXO)BIS(N
2
-PEROXO)-
RHENIUMFVII)
(35).
SYNTHESIS
AND
SPECTROSCOPY
113
5.3.4.2
CHIRAL
PYRIDINE
N-OXIDES
AS
LIGANDS
114
5.4
MTO-CATALYZED
SULFOXIDATION
WITH
H2O2.
INFLUENCE
OF
CHIRAL
LIGANDS
116
5.5
17
O
NMR
SPECTROSCOPIC
STUDIES
ON
THE
PEROXO
COMPLEX
4
AND
ITS
DERIVATIVES
119
5.6
INFLUENCE
OF
HMPT
ON
THE
MTO/H2O2
CATALYTIC
SYSTEM
120
5.6.1
CATALYSIS
120
5.6.2
(HEXAMETHYLPHOSPHORAMIDE)METHYL(OXO)BIS(N
2
-PEROXO)-
RHENIUM(VII)
(39).
SYNTHESIS,
SPECTROSCOPY,
STRUCTURE
122
5.7
MTO-CATALYZED
OXIDATION
REACTIONS
WITH
THE
UREA
HYDROGEN
PEROXIDE
COMPLEX
(UHP)
125
5.8
DONOR-FUNCTIONALIZED
ALKYLRHENIUM(VII)
OXIDES.
CATALYSIS
126
6
RE-CATALYZED
DIELS-ALDER
REACTION
128
6.1
INTRODUCTION
128
6.2
MTO-CATALYZED
DIELS-ALDER
REACTION
131
6.3
RE2O7-CATALYZED
DIELS-ALDER
REACTION
132
6.4
RHENIUMFV)
COMPLEXES
AS
CATALYSTS
137
C
EXPERIMENTAL
DETAILS
139
1
GENERAL
140
2
PHYSICAL
MEASUREMENTS
AND
INSTRUMENTATION
141
3
SYNTHESIS
OF
IMPORTANT
COMPOUNDS
142
4
MTO-CATALYZED
OXIDATION
OF
AROMATIC
COMPOUNDS
144
5
RE-CATALYZED
OXIDATION
OF
SUBSTITUTED
NAPHTHALENES
150
6
OXIDATION
OF
[(T]
5
-C
3
ME
5
)RE(CO)3)
TO
KN
5
-CSME
S
)REO3]
153
7
THE
CATALYTIC
SYSTEM
REOS/HAOJ
153
8
THE
CATALYTIC
SYSTEM
RE2O7/H2C 2
157
9
BAEYER-VILLIGER
OXIDATION
159
10
LEWIS-BASE
ADDUCTS
OF
ORGANORHENIUMFVII)
OXIDES
161
11
LEWIS-BASE
ADDUCTS
OF
MTO(VU).
CATALYSIS
-
NEW
ASPECTS
161
12
RE-CATALYZED
DIELS-ALDER
REACTION
170
D
TABLES
172
E
ABSTRACT
177
F
REFERENCES
183
G
APPENDIX
196
PUBLISHED
PARTS
OF
THIS
THESIS
197
CURRICULUM
VITAE
199 |
| any_adam_object | 1 |
| author | Correia, João Domingos Galamba |
| author_facet | Correia, João Domingos Galamba |
| author_role | aut |
| author_sort | Correia, João Domingos Galamba |
| author_variant | j d g c jdg jdgc |
| building | Verbundindex |
| bvnumber | BV011020851 |
| ctrlnum | (OCoLC)45671708 (DE-599)BVBBV011020851 |
| dewey-full | 545.23 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 545 - [Unassigned] |
| dewey-raw | 545.23 |
| dewey-search | 545.23 |
| dewey-sort | 3545.23 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-08-14T00:24:49Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007378095 |
| oclc_num | 45671708 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-29T DE-12 DE-11 DE-188 |
| owner_facet | DE-91 DE-BY-TUM DE-29T DE-12 DE-11 DE-188 |
| physical | 199 S. graph. Darst. |
| publishDate | 1996 |
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| spelling | Correia, João Domingos Galamba Verfasser aut Molecular rhenium oxides as oxidation catalysts João Domingos Galamba Correia 1996 199 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 1996 Oxidation-reduction reaction Rhenium trioxide Rheniumoxide (DE-588)4349834-6 gnd rswk-swf Katalytische Oxidation (DE-588)4163425-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Katalytische Oxidation (DE-588)4163425-1 s Rheniumoxide (DE-588)4349834-6 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007378095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Correia, João Domingos Galamba Molecular rhenium oxides as oxidation catalysts Oxidation-reduction reaction Rhenium trioxide Rheniumoxide (DE-588)4349834-6 gnd Katalytische Oxidation (DE-588)4163425-1 gnd |
| subject_GND | (DE-588)4349834-6 (DE-588)4163425-1 (DE-588)4113937-9 |
| title | Molecular rhenium oxides as oxidation catalysts |
| title_auth | Molecular rhenium oxides as oxidation catalysts |
| title_exact_search | Molecular rhenium oxides as oxidation catalysts |
| title_full | Molecular rhenium oxides as oxidation catalysts João Domingos Galamba Correia |
| title_fullStr | Molecular rhenium oxides as oxidation catalysts João Domingos Galamba Correia |
| title_full_unstemmed | Molecular rhenium oxides as oxidation catalysts João Domingos Galamba Correia |
| title_short | Molecular rhenium oxides as oxidation catalysts |
| title_sort | molecular rhenium oxides as oxidation catalysts |
| topic | Oxidation-reduction reaction Rhenium trioxide Rheniumoxide (DE-588)4349834-6 gnd Katalytische Oxidation (DE-588)4163425-1 gnd |
| topic_facet | Oxidation-reduction reaction Rhenium trioxide Rheniumoxide Katalytische Oxidation Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007378095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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