Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure:
Gespeichert in:
1. Verfasser: | |
---|---|
Format: | Abschlussarbeit Buch |
Sprache: | German |
Veröffentlicht: |
1996
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | 101 S. |
Internformat
MARC
LEADER | 00000nam a2200000 c 4500 | ||
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001 | BV010929867 | ||
003 | DE-604 | ||
005 | 20180725 | ||
007 | t | ||
008 | 960904s1996 m||| 00||| ger d | ||
016 | 7 | |a 948521996 |2 DE-101 | |
035 | |a (OCoLC)614098786 | ||
035 | |a (DE-599)BVBBV010929867 | ||
040 | |a DE-604 |b ger |e rakddb | ||
041 | 0 | |a ger | |
049 | |a DE-703 |a DE-12 |a DE-29T |a DE-355 |a DE-11 |a DE-188 | ||
084 | |a VC 7600 |0 (DE-625)147095: |2 rvk | ||
084 | |a WF 9100 |0 (DE-625)148449: |2 rvk | ||
100 | 1 | |a Rödel, Thomas |d 1967- |e Verfasser |0 (DE-588)1081776315 |4 aut | |
245 | 1 | 0 | |a Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure |c vorgelegt von Thomas Rödel |
264 | 1 | |c 1996 | |
300 | |a 101 S. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
502 | |a Bayreuth, Univ., Diss., 1996 | ||
650 | 0 | 7 | |a Mykotoxin |0 (DE-588)4040984-3 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Citrinin |0 (DE-588)4423473-9 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Chemische Synthese |0 (DE-588)4133806-6 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Asymmetrische Synthese |0 (DE-588)4135603-2 |2 gnd |9 rswk-swf |
655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
655 | 7 | |a Pullvillorsäure |2 gnd |9 rswk-swf | |
689 | 0 | 0 | |a Mykotoxin |0 (DE-588)4040984-3 |D s |
689 | 0 | 1 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
689 | 0 | |5 DE-604 | |
689 | 1 | 0 | |a Citrinin |0 (DE-588)4423473-9 |D s |
689 | 1 | 1 | |a Asymmetrische Synthese |0 (DE-588)4135603-2 |D s |
689 | 1 | |5 DE-604 | |
689 | 2 | 0 | |a Pullvillorsäure |A f |
689 | 2 | 1 | |a Asymmetrische Synthese |0 (DE-588)4135603-2 |D s |
689 | 2 | |5 DE-604 | |
856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007311064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-007311064 |
Datensatz im Suchindex
_version_ | 1807501909067563008 |
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adam_text |
INHALTSVERZEICHNIS
SEIFE
I.
THEORETISCHER
TEIL
1
A.
ENANTIOSELEKTIVE
SYNTHESE
VON
(3R,4S)
-(-)
-CITRININ
1.
EINLEITUNG
1
2.
SYNTHESE
VON
PHENOL
A
[
(-)-2]
UND
6
PHENOL
B
[
()
-2]
3.
SYNTHESE
VON
(-)
-CITRININ
[(-)-!]
UND
16
()-CITRININ
[()-L]
4.
SYNTHESE
VON
2,4-BIS(BENZYLOXY)
-
18
6-BROMTOLUOL
(3)
5.
HERSTELLUNG
VON
(2S)
-(-)
TRANS
2,3
-DIMETHYL
20
OXIRAN
[
(-)-4]
B.
ENANTIOSELEKTIVE
SYNTHESE
VON
()-(+)
UND
(S)-(-)
PULVILLORSAEURE
1.
EINLEITUNG
22
2.
SYNTHESE
VON
(R)
-(
+
)-,
(S)
-(-)
-
UND
()
-
25
1
(3-,
5
-DIHYDROXYPHENYL)
HEPTAN-2-OL
(25)
3.
SYNTHESE
VON
(R)
-(
+
)-,
(S)
-
(-)
-
UND
()
-
30
PULVILLORSAEURE
(24)
4.1.
HERSTELLUNG
VON
(R)
-(+)
-PENTYLOXIRAN
[(
+
)-26]
33
4.2.
SYNTHESE
VON
(S)
-(-)
-PENTYLOXIRAN
[(-)-26]
35
XI.
EXPERIMENTELLER
TEIL
36
1.
ALLGEMEINE
BEMERKUNGEN
36
2.
SYNTHESEBESCHREIBUNGEN
39
2.1.
SYNTHESE
VON
PHENOL
A
[
(-)-2]
UND
39
PHENOL
B
[
()
-2]
(2S,3S)-ERYTHRO
(-)-3-[3,5-BIS
(BENZYLOXY)
-
39
2-METHYLPHENYL]
BUTAN-2-OL
[
(-)-6]
()-ERYTHRO-3
[3,
5-BIS(BENZYLOXY)
-
40
2-METHYLPHENYL]BUTAN-2-OL
[
()
-6]
(1R,
2S)
-
THREO
(
+
)
-2
[3,
5-BIS
(BENZYLOXY)
-
40
2-METHYLPHENYL]-1-METHYLPROPYL-FORMIAT
[
(
+
)-9]
(E)
-2
[3,
5-BIS(BENZYLOXY)-2-METHYLPHENYL]
-
42
BUT-2-EN
[
(E)
-12]
(Z)
-2-[3,5-BIS(BENZYLOXY)-2-METHYLPHENYL]
-
42
BUT-2-EN
[(Z)-14]
3-[3,
5-BIS(BENZYLOXY)-2-METHYLPHENYL]
-
43
BUT-L-EN
(13)
(1R,
2S)
-
THREO
(-)
-2
[3,
5-BIS
(BENZYLOXY)
-
44
2-METHYLPHENYL]-1-METHYLPROPYL-BENZOAT
[(-)-8]
()
-
THREO-2
[3,
5-BIS
(BENZYLOXY)
-
45
2-METHYLPHENYL]-1-METHYLPROPYL
4-NITROBENZOAT
T()-10]
(1R,
2S)
-
THREO
(-)-2-[3,
5-BIS(BENZYLOXY)
-
46
2-METHYLPHENYL]-1-METHYLPROPYL
3,
5-DINITROBENZOAT
[
(
)-LL]
()
-
THREO-2
[3,
5-BIS(BENZYLOXY)
-
47
2-METHYLPHENYL]-1-METHYLPROPYL
3,
5-DINITROBENZOAT
[
()
-11]
(2H,3S)
-THREO
(-)-3-[3,
5-BIS(BENZYLOXY)
-
47
2-METHYLPHENYL]
BUTAN-2-OL
[
(-)-7]
AUS
(
+
)-9
(1R,2S,
AS)
-
THREO
2-[3,
5-BIS
(BENZYLOXY)
-
48
2-METHYLPHENYL]-1-METHYLPROPYL-A-METHOXY
A-TRIFLUORMETHYLPHENYLACETAT
(15)
(17?,2S,AS)
-
UND
(IS,
2R,AS)
-
THREO-2
49
[3,
5-BIS(BENZYLOXY)-2-METHYLPHENYL]
-
1-METHYLPROPYL-A-METHOXY-A-TRIFLUORMETHYL
PHENYLACETAT
(15
UND
16)
(2R,
3S)
-
THREO
(-)
-3
-
[3,
5-BIS
(BENZYLOXY)
-
50
2-METHYLPHENYL]
BUTAN-2-OL
[
(-)-7]
AUS
(-)-8
()
-
THREO-3
[3,
5-BIS(BENZYLOXY)
-
50
2-METHYLPHENYL]
BUTAN-2-OL
[
()
-7]
(2R,3S)-THREO
(-)-3-(3,
5-DIHYDROXY
51
2-METHYLPHENYL)BUTAN-2-OL
[
(-)-2]
AUS
(-)-7,
HYDROLYSEPRODUKT
VON
(+)-9
(2K,3S)-THREO
(-)-3-(3,
5-DIHYDROXY
52
2-METHYLPHENYL)
BUTAN-2-OL
[(-)-2]
AUS
(-)-7,
HYDROLYSEPRODUKT
VON
(-)-8
()-THREO-3
(3,
5-DIHYDROXY
52
2-METHYLPHENYL)BUTAN-2-OL
[
()
-2]
2.2.
SYNTHESE
VON
(-)-CITRININ
[(-)-L]
UND
53
()
-CITRININ
[()-L]
(IS,
27?)
-2,
6-DIHYDROXY-4
(2-HYDROXY
53
1-METHYLPROPYL)-3-METHYLBENZOESAEURE
(
(IS,2R)
-17]
()-THREO-2,6-DIHYDROXY-4-(2-HYDROXY
53
1-METHYLPROPYL)-3-METHYLBENZOESAEURE
[
()
-17]
(-)
-THREO-4,6-DIHYDRO-8-HYDROXY-3,4,5
54
TRIMETHYL-6-OXO-3H-2-BENZOPYRAN
7-CARBONSAEURE
[(-)
-CITRININ,
(-)-1]
()-4,6-DIHYDRO-8-HYDROXY-3,4,5
55
TRIMETHYL-6-OXO-3H-2-BENZOPYRAN
7-CARBONSAEURE
[
()-CITRININ,
()
-1]
2.3.
SYNTHESE
VON
2,4
-BIS(BENZYLOXY)
-
56
6-BROMTOLUOL
(3)
1
-BROM
3,
5-DINITRO-BENZOL
(18)
56
1
(BENZYLOXY)-3-BROM-5-NITROBENZOL
(20)
56
1,
3-BIS(BENZYLOXY)-5-BROMBENZOL
(19)
57
2,
4-BIS(BENZYLOXY)-6-BROMBENZALDEHYD
(21)
58
2,4
-BIS(BENZYLOXY)-6-BROMTOLUOL
(3)
59
2.4.
HERSTELLUNG
VON
(2S)
-(-)
-TRANS-2,3-DIMETHYL
61
OXIRAN
[
(-)-4]
(2S,
3S)
-
(
+
)
-2,3-BUTANDIOL
[(
+
)-22]
61
(2S,3R)-2-ACETOXY-3-BROMBUTAN
(23)
61
(2S)
-(-)
TRANS-2
,
3-DIMETHYLOXIRAN
[
(
-
-4]
62
2.5.
SYNTHESE
VON
()-(+)-,
(S)
-
(-)
-
UND
()
-
63
1-(3,5
-DIHYDROXYPHENYL)HEPTAN-2-OL
(25)
(S)
-(
+
)-1-[3,5
-BIS(BENZYLOXY)PHENYL]
-
63
HEPTAN-2-OL
[(+)-27]
(2S,AS)-1-[3,
5-BIS(BENZYLOXY)PHENYL]
-
64
HEPT-2-YL-A-METHOXY--TRIFLUORMETHYL
PHENYLACETAT
(29)
(H)
-(-)-1-(3,5
-BIS(BENZYLOXY)PHENYL]
-
65
HEPTAN-2-OL
[
(-)-27]
(2R,AS)
-1-[3,
5-BIS(BENZYLOXY)PHENYL]
-
66
HEPT-2-YL-A-METHOXY- X-TRIFLUORMETHYL
PHENYLACETAT
(30)
(S)
-(+)-1-[3,
5-BIS(BENZYLOXY)PHENYL]
-
67
HEPT-2-YL-BENZOAT
[(+)-31]
(S)
-
(
+
)
-1
[3,
5-BIS
(BENZYLOXY)PHENYL]
-
68
HEPTAN-2-OL
[
(
+
)-27]
AUS
(
+
)-31
()
-1
[3,5-BIS(BENZYLOXY)PHENYL]
-
68
HEPTAN-2-OL
[
()
-27]
(S)
-(-)-1-(3,5
-DIHYDROXYPHENYL)
-
69
HEPTAN-2-OL
[(
-
)-25]
(R)
-(+)-1-(3,5
-DIHYDROXYPHENYL)
-
69
HEPTAN-2-OL
[
(
+
)-25]
()
-1-(3,5
-DIHYDROXYPHENYL)
-
70
HEPTAN-2-OL
[
()
-25]
2.6.
SYNTHESE
VON
(R)
-(+)-,
(S)-(-)
UND
()
-
71
PULVILLORSAEURE
(24)
(S)
-(+)-2,
6-DIHYDROXY-4-(2-HYDROXYHEPTYL)
-
71
BENZOESAEURE
[
(+)-32]
(R)
-(-)-2,
6-DIHYDROXY-4-(2-HYDROXYHEPTYL)
-
72
BENZOESAEURE
[
(
-
)-32]
()
-2,
6-DIHYDROXY-4-(2-HYDROXYHEPTYL)
-
72
BENZOESAEURE
[
()
-32]
()-3,4-DIHYDRO-6,8-DIHYDROXY-L,L-DIMETHYL
72
3
-PENTYL
-
1H
2
-BENZOPYRAN
7
CARBONSAEURE
[
()
-33]
(S)
-(-)-4,
6-DIHYDRO-8-HYDROXY-6-OXO
73
3
-PENTYL
-3H
2
-BENZOPYRAN
7
-CARBONSAEURE
[(-)
-PULVILLORSAEURE,
(-)-24]
(R)
-(+)-4,
6-DIHYDRO-8-HYDROXY-6-OXO
74
3
-PENTYL
-
3H
2
-BENZOPYRAN
7
-CARBONSAEURE
[(+)
-PULVILLORSAEURE,
(+)-24]
()
-4,6-DIHYDRO-8-HYDROXY-6-OXO
74
3
-
PENTYL
-3
H
2
-
BENZOPYRAN
-
7
-
CARBONSAEURE
[
()-PULVILLORSAEURE,
()-24]
3,
4-DIHYDRO-6
,
8-DIHYDROXY-3-PENTYL
74
L-TRIDEUTEROMETHOXY-LH-2-BENZOPYRAN
7
-CARBONSAEURE
(34)
2.7.1.
HERSTELLUNG
VON
(R)
-(+)
-PENTYLOXIRAN
[
(
+
)-26]
75
()
-1,
2-HEPTANDIOL
[
()
-35]
75
L-HYDROXYHEPTAN-2-ON
(36)
76
(R)-2-ACETOXY-L-BROMHEPTAN
[
(R)
-37]
UND
76
(S)
-L-ACETOXY-2-BROMHEPTAN
[
(S)
-38]
(R)
-(+)
-PENTYLOXIRAN
[(+)-26]
77
2.7.2.
SYNTHESE
VON
(S)
-(-)
-PENTYLOXIRAN
[(- -26]
78
(4S)
-(
+
)-2,
2-DIMETHYL-4-(1-PENTYL)
-
78
[1,3]
DIOXOLAN
[(
+
)-39]
(S)-2-ACETOXY-L-BROMHEPTAN
[ S)-37]
UND
78
(R)
-L-ACETOXY-2-BROMHEPTAN
[
(R)
-38]
(S)
-(-)
-PENTYLOXIRAN
[
(-)-26]
80
III.
ZUSAMMENFASSUNG
81
IV.
SUMMARY
88
V.
LITERATUR
95
VI.
DANK
100
VII.
ERKLAERUNG
101 |
any_adam_object | 1 |
author | Rödel, Thomas 1967- |
author_GND | (DE-588)1081776315 |
author_facet | Rödel, Thomas 1967- |
author_role | aut |
author_sort | Rödel, Thomas 1967- |
author_variant | t r tr |
building | Verbundindex |
bvnumber | BV010929867 |
classification_rvk | VC 7600 WF 9100 |
ctrlnum | (OCoLC)614098786 (DE-599)BVBBV010929867 |
discipline | Chemie / Pharmazie Biologie |
format | Thesis Book |
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genre | (DE-588)4113937-9 Hochschulschrift gnd-content Pullvillorsäure gnd |
genre_facet | Hochschulschrift Pullvillorsäure |
id | DE-604.BV010929867 |
illustrated | Not Illustrated |
indexdate | 2024-08-16T00:29:07Z |
institution | BVB |
language | German |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007311064 |
oclc_num | 614098786 |
open_access_boolean | |
owner | DE-703 DE-12 DE-29T DE-355 DE-BY-UBR DE-11 DE-188 |
owner_facet | DE-703 DE-12 DE-29T DE-355 DE-BY-UBR DE-11 DE-188 |
physical | 101 S. |
publishDate | 1996 |
publishDateSearch | 1996 |
publishDateSort | 1996 |
record_format | marc |
spelling | Rödel, Thomas 1967- Verfasser (DE-588)1081776315 aut Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure vorgelegt von Thomas Rödel 1996 101 S. txt rdacontent n rdamedia nc rdacarrier Bayreuth, Univ., Diss., 1996 Mykotoxin (DE-588)4040984-3 gnd rswk-swf Citrinin (DE-588)4423473-9 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Asymmetrische Synthese (DE-588)4135603-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Pullvillorsäure gnd rswk-swf Mykotoxin (DE-588)4040984-3 s Chemische Synthese (DE-588)4133806-6 s DE-604 Citrinin (DE-588)4423473-9 s Asymmetrische Synthese (DE-588)4135603-2 s Pullvillorsäure f DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007311064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Rödel, Thomas 1967- Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure Mykotoxin (DE-588)4040984-3 gnd Citrinin (DE-588)4423473-9 gnd Chemische Synthese (DE-588)4133806-6 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
subject_GND | (DE-588)4040984-3 (DE-588)4423473-9 (DE-588)4133806-6 (DE-588)4135603-2 (DE-588)4113937-9 |
title | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure |
title_auth | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure |
title_exact_search | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure |
title_full | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure vorgelegt von Thomas Rödel |
title_fullStr | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure vorgelegt von Thomas Rödel |
title_full_unstemmed | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure vorgelegt von Thomas Rödel |
title_short | Enantioselektive Synthese von (3R,4S)-(-)-Citrinin und (R)-(+)-Pulvillorsäure |
title_sort | enantioselektive synthese von 3r 4s citrinin und r pulvillorsaure |
topic | Mykotoxin (DE-588)4040984-3 gnd Citrinin (DE-588)4423473-9 gnd Chemische Synthese (DE-588)4133806-6 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
topic_facet | Mykotoxin Citrinin Chemische Synthese Asymmetrische Synthese Hochschulschrift Pullvillorsäure |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007311064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT rodelthomas enantioselektivesynthesevon3r4scitrininundrpulvillorsaure |