Aquatic chemistry: chemical equilibria and rates in natural waters
"Like the previous editions, this substantially revised and updated Third Edition has been written to provide readers with a solid understanding of the general chemical principles underlying natural water chemistry: chemical thermodynamics and kinetics, acids and bases, dissolved carbon dioxide...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
1996
|
| Ausgabe: | 3. ed. |
| Schriftenreihe: | A Wiley-interscience publication
Environmental science and technology |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | "Like the previous editions, this substantially revised and updated Third Edition has been written to provide readers with a solid understanding of the general chemical principles underlying natural water chemistry: chemical thermodynamics and kinetics, acids and bases, dissolved carbon dioxide, atmosphere-water interactions, metal ions in aqueous solutions, precipitation and dissolution, oxidation and reduction, equilibria, and the solid-solution interface." "To help the reader grasp the essential elements of aquatic chemistry, the authors illustrate key principles with numerous quantitative examples and a full range of problem-solving methods, including algebraic, graphical, and numerical methods based on digital computation." "Designed for both reference as well as classroom use, Aquatic Chemistry, in this new edition, remains the authoritative resource on the fundamentals of natural water chemistry."--BOOK JACKET. |
| Beschreibung: | XVI, 1022 S. graph. Darst. |
| ISBN: | 0471511846 0471511854 9780471511854 |
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| 245 | 1 | 0 | |a Aquatic chemistry |b chemical equilibria and rates in natural waters |c Werner Stumm ; James J. Morgan |
| 250 | |a 3. ed. | ||
| 264 | 1 | |a New York [u.a.] |b Wiley |c 1996 | |
| 300 | |a XVI, 1022 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a A Wiley-interscience publication | |
| 490 | 0 | |a Environmental science and technology | |
| 520 | 1 | |a "Like the previous editions, this substantially revised and updated Third Edition has been written to provide readers with a solid understanding of the general chemical principles underlying natural water chemistry: chemical thermodynamics and kinetics, acids and bases, dissolved carbon dioxide, atmosphere-water interactions, metal ions in aqueous solutions, precipitation and dissolution, oxidation and reduction, equilibria, and the solid-solution interface." "To help the reader grasp the essential elements of aquatic chemistry, the authors illustrate key principles with numerous quantitative examples and a full range of problem-solving methods, including algebraic, graphical, and numerical methods based on digital computation." "Designed for both reference as well as classroom use, Aquatic Chemistry, in this new edition, remains the authoritative resource on the fundamentals of natural water chemistry."--BOOK JACKET. | |
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Datensatz im Suchindex
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| adam_text | Medea-3
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ADAM-730075
730075
###### Fernleihe [K] ////////////
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[ADAM] ADAM
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[014ADAMJ
TUM
München - ADAM
Catalogue
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(lauer^sb-muenche
13.03.2009
13.03.2009
ABHOL
Benutzer/Abhol-Code:
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###
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Benachrichtigung:
Signatur:
BV010884024 SYS007277792
Zeitschnft:
Körperschaft:
Ort:
New York [u.a.]
Jahrgang:
1996
Artikel: Autor:
Stumm, Werner
Artikel: Titel:
Aquatic chemistry
Band/Heft:
Seiten:
zusätzliche Hinweise: Typ: Inhaltsverzeichnis###Farbe: s/w (Text)###Auflösung: 300dpi
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CONTENTS
1.
Introduction
1
1.1
Scope of Aquatic Chemistry
1
1.2
The Solvent Water
6
1.3
Solute Species
9
Suggested Readings
11
Appendix
1.1:
Some Useful Quantities, Units, Conversion
Factors, Constants, and Relationships
11
2.
Chemical Thermodynamics and Kinetics
16
2.1
Introduction
16
2.2
Chemical Thermodynamic Principles
20
2.3
Systems of Variable Composition: Chemical
Thermodynamics
29
2.4
Gibbs Energy and Systems of Variable Chemical
Composition
32
2.5
Chemical Potentials of Pure Phases and Solutions
35
2.6
Chemical Potentials of Aqueous Electrolytes
38
2.7
The Equilibrium Constant
41
2.8
The Gibbs Energy of a System
44
2.9
Driving Force for Chemical Reactions
49
2.10
Temperature and Pressure Effects on Equilibrium
52
2.11
Equilibrium Tools
57
2.12
Kinetics and Thermodynamics: Time and Reaction
Advancement,
ξ
58
2.13
Rate and Mechanism
61
2.14
Concentration Versus Time
64
2.15
Theory of Elementary Processes
69
2.16
Elementary Reactions and ACT
76
2.17
Equilibrium Versus Steady State in Flow Systems
79
Suggested Readings
81
Problems
82
Answers to Problems
85
XI
xii Contents
во
3.
Adds and Bases °°
3.1
Introduction ^
3.2
The Nature of Acids and Bases
9°
3.3
The Strength of an Acid or Base
92
3.4
Activity and
pH
Scales 97
3.5
Equilibrium Calculations
Ю5
3.6 pH
as a Master Variable; Equilibrium Calculations Using
a Graphical Approach
118
3.7
Ionization Fractions of Acids, Bases, and Ampholytes
127
3.8 Titration
of Acids and Bases
13°
3.9
Buífer
Intensity and Neutralizing Capacity
134
3.10
Organic Acids 140
Suggested Readings I44
Problems I44
Answers to Problems
147
4.
Dissolved Carbon Dioxide
148
4.1
Introduction
4.2
Dissolved Carbonate Equilibria (Closed System)
150
4.3
Aqueous Carbonate System Open to the Atmosphere
157
4.4
Alkalinity and Acidity, Neutralizing Capacities
163
4.5
Alkalinity Changes
172
4.6
Analytical Considerations: Gran Plots
179
4.7
Equilibrium with Solid Carbonates
186
4.8
Kinetic Considerations
192
4.9
Carbon Isotopes and Isotope Fractionation
195
Suggested Readings
202
Problems
202
Answers to Problems
204
5.
Atmosphere-Water Interactions
206
5.1
Introduction
206
5.2
Anthropogenic Generation of Acidity in the Atmosphere
207
5.3
Gas-Water Partitioning: Henry s Law
212
5.4
Gas-Water Equilibria in Closed and Open Systems
216
5.5
Washout of Pollutants from the Atmosphere
227
5.6
Fog
229
5.7
Aerosols
233
5.8
Acid Rain-Acid Lakes
235
5.9
The Volatility of Organic Substances
238
5.10
Gas Transfer Across Water-Gas Interface
241
Suggested Readings
248
Problems
249
Answers to Problems
251
Contents xiii
6.
Metal Ions in Aqueous Solution: Aspects of Coordination
Chemistry
252
6.1
Introduction
252
6.2
Protons and Metal Ions
258
6.3
Hydrolysis of Metal Ions
263
6.4
Solubility and Hydrolysis: Solid Hydroxides and Metal
Oxides
272
6.5
Chelates
275
6.6
Metal Ions and Ligands: Classification of Metals
281
6.7
Speciation in Fresh Waters
289
6.8
Seawater Speciation
305
6.9
Kinetics of Complex Formation
311
Suggested Readings
319
Problems
320
Answers to Problems
322
Appendix
6.1:
Stability Constants
325
Appendix
6.2:
The Various Scales for Equilibrium
Constants, Activity Coefficients, and
pH 335
7.
Precipitation and Dissolution
349
7.1
Introduction
349
7.2
The Solubility of Oxides and Hydroxides
359
7.3
Complex Formation and Solubility of (Hydr)oxides
368
7.4
Carbonates
370
7.5
The Stability of Hydroxides, Carbonates, and Hydroxide
Carbonates
389
7.6
Sulfides
and Phosphates
398
7.7
The Phase Rule: Components, Phases, and Degrees of
Freedom
409
7.8
Solubility of Fine Particles
413
7.9
Solid Solutions
416
Suggested Readings
420
Problems
420
Answers to Problems
424
8.
Oxidation and Reduction; Equilibria and Microbial
Mediation
425
8.1
Introduction
425
8.2
Redox
Equilibria and the Electron Activity
426
8.3
The Electrode Potential: The Nemst Equation and the
Electrochemical Cell
441
8.4
ρε-ρΗ,
Potential-pH
Diagrams
455
8.5
Redox
Conditions in Natural Waters
464
8.6
Effect of Complex Formers on the
Redox
Potential
489
xiv
Contents
8.7
Measuring the
Redox
Potential in Natural Waters
491
8.8
The Potentiometric Determination of Individual Solutes
«ю
Suggested Readings
Problems
2
Answers to Problems
Appendix
8.1:
Activity Ratio Diagrams for
Redox
Systems
513
9.
The Solid-Solution Interface 516
9.1
Introduction
516
9.2
Adsorption 5t*
9.3
Adsorption Isotherms
_
521
9.4
Hydrous Oxide Surfaces; Reactions with H+, OH
,
Metal
Ions, and Ligands
533
9.5
Surface Charge and the Electric Double Layer
549
9.6
Correcting Surface Complex Formation Constants for
Surface Charge 568
9.7 Sorption
of
Hydrophobie
Substances on Organic Carbon-
Bearing Particles
575
9.8
Ion Exchange
586
9.9
Transport of (Ad)sorbable Constituents in Groundwater
and Soil Systems
594
Suggested Readings
599
Problems
601
Appendix
9.1:
The Gouy-Chapman Theory
604
Appendix
9.2:
Contact Angle, Adhesion and Cohesion, the
Oil-Water Interface
608
10.
Trace Metals: Cycling, Regulation, and Biological Role
614
10.1
Introduction: Global Cycling of Metals
614
10.2
Analytical Approaches to Chemical Speciation
615
10.3
Classification of Metal Ions and the Inorganic Chemistry
of Life
625
10.4
Organometallic and Organometalloidal Compounds
628
10.5
Bioavaikbffity and
Toxicity
632
10.6
Metal Ions as Micronutrients
637
10.7
The Interaction of Trace Metals with Phytoplankton at
the Molecular Level
641
10.8
Regulation of Trace Elements by the Solid-Water
Interface in Surface Waters
648
Ю.9
Regulation of Dissolved Heavy Metals in Rivers, Lakes,
and Oceans
654
10.10
Quality Criteria in Fresh Waters: Some Aspects
666
Suggested Readings
670
Contents xv
11.
Kinetics of
Redox
Processes
672
11.1
Introduction
672
11.2
How Good an
Oxidant
Is O2?
672
11.3
Can
ρε
Be Defined for a Nonequilibrium System?
677
11.4
Kinetics of
Redox
Processes: Case Studies
679
11.5
Oxidants Used in Water and Waste Technology: A Few
Case Studies
691
11.6
Linear Free Energy Relations (LFERs)
702
11.7
The Marcus Theory of Outer-Sphere Electron Transfer:
An Introduction
703
11.8
Nucleophile-Electrophile Interactions and
Redox
Reactions Involving Organic Substances
710
11.9
Corrosion of Metals as an Electrochemical Process
720
Suggested Readings
725
12.
Photochemical Processes
726
12.1
Introduction
726
12.2
Absorption of Light
729
12.3
Photoreactants
735
12.4
Photoredox Reactions: Photolysis of Transition Metal
Complexes
743
12.5
Photochemical Reactions in Atmospheric Waters: Role of
Dissolved Iron Species
744
12.6
Heterogeneous Photochemistry
748
12.7
Semiconducting Minerals
753
Suggested Readings
759
13.
Kinetics at the Solid-Water Interface: Adsorption,
Dissolution of
Minerais, Nucleation,
and Crystal Growth
760
13.1
Introduction
760
13.2
Kinetics of Adsorption
760
13.3
Surface-Controlled Dissolution of Oxide Minerals: An
Introduction to Weathering
771
13.4
Simple Rate Laws in Dissolution
776
13.5
Rates of
СаСОз
Dissolution (and of CaCO3 Crystal
Growth)
788
13.6
Inhibition of Dissolution
795
13.7
Nucleation
and Crystal Growth
800
Suggested Readings
816
14.
Particle-Particle Interaction: Colloids, Coagulation, and
Filtration gig
14.1
Colloids
818
14.2
Particle Size Distribution
826
xvi Contents
14.3
Surface
Charge
of Colloids
834
14.4
Colloid Stability: Qualitative Considerations
837
14.5
Effects of Surface Speciation on Colloid Stability
842
14.6
Some Water-Technological Considerations in
Coagulation, Filtration, and Flotation
852
14.7
Filtration Compared with Coagulation
857
14.8
Transport in Aggregation and Deposition
858
Suggested Readings
866
Appendix
14.1:
A Physical Model (DLVO) for Colloid
Stability
867
15.
Regulation of the Chemical Composition of Natural Waters
872
15.1
Introduction
872
15.2
Weathering and the Proton Balance
875
15.3
Isothermal Evaporation
880
15.4
Buffering
884
15.5
Interactions Between Organisms and Abiotic
Environment: Redfield Stoichiometry
886
15.6
The Oceans: Relative Constancy of the Composition and
Chemical Equilibria
895
15.7
Constancy of Composition: Steady State
897
15.8 Hydrothermal
Vents
901
15.9
The Sediment-Water Interface
903
15.10
Biological Regulation of the Composition
908
15.11
Global Cycling: The Interdependence of Biogeochemical
Cycles
914
15.12
The Carbon Cycle
916
15.13
Nitrogen Cycles: Pollution by Nitrogen Compounds
927
15.14
The Sulfur Cycle
932
Suggested Readings
933
References
935
Appendixes: Thermodynamic Data
976
1
Revised Chemical Equilibrium Data for Major Water-
Mineral Reactions
977
2
Thermodynamic Data for Trace Metal Speciation in Seawater
984
3
Thermodynamic Properties
990
Index
1005
|
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| dewey-search | 359.9 546.22 |
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| discipline | Chemie / Pharmazie Allgemeines Biologie Militärwissenschaft Umwelt Geographie |
| edition | 3. ed. |
| format | Book |
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| id | DE-604.BV010884024 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:00:32Z |
| institution | BVB |
| isbn | 0471511846 0471511854 9780471511854 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007277792 |
| oclc_num | 31754493 |
| open_access_boolean | |
| owner | DE-703 DE-91 DE-BY-TUM DE-M49 DE-BY-TUM DE-29T DE-29 DE-19 DE-BY-UBM DE-1102 DE-634 DE-83 DE-11 DE-188 |
| owner_facet | DE-703 DE-91 DE-BY-TUM DE-M49 DE-BY-TUM DE-29T DE-29 DE-19 DE-BY-UBM DE-1102 DE-634 DE-83 DE-11 DE-188 |
| physical | XVI, 1022 S. graph. Darst. |
| publishDate | 1996 |
| publishDateSearch | 1996 |
| publishDateSort | 1996 |
| publisher | Wiley |
| record_format | marc |
| series2 | A Wiley-interscience publication Environmental science and technology |
| spelling | Stumm, Werner 1924-1999 Verfasser (DE-588)140381414 aut Aquatic chemistry chemical equilibria and rates in natural waters Werner Stumm ; James J. Morgan 3. ed. New York [u.a.] Wiley 1996 XVI, 1022 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-interscience publication Environmental science and technology "Like the previous editions, this substantially revised and updated Third Edition has been written to provide readers with a solid understanding of the general chemical principles underlying natural water chemistry: chemical thermodynamics and kinetics, acids and bases, dissolved carbon dioxide, atmosphere-water interactions, metal ions in aqueous solutions, precipitation and dissolution, oxidation and reduction, equilibria, and the solid-solution interface." "To help the reader grasp the essential elements of aquatic chemistry, the authors illustrate key principles with numerous quantitative examples and a full range of problem-solving methods, including algebraic, graphical, and numerical methods based on digital computation." "Designed for both reference as well as classroom use, Aquatic Chemistry, in this new edition, remains the authoritative resource on the fundamentals of natural water chemistry."--BOOK JACKET. Chemische reacties gtt Eau - Chimie Evenwichten gtt Waterkwaliteit gtt Water chemistry Hydrochemie (DE-588)4072678-2 gnd rswk-swf Hydrochemie (DE-588)4072678-2 s DE-604 Morgan, James J. Verfasser aut Digitalisierung TU Muenchen application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007277792&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stumm, Werner 1924-1999 Morgan, James J. Aquatic chemistry chemical equilibria and rates in natural waters Chemische reacties gtt Eau - Chimie Evenwichten gtt Waterkwaliteit gtt Water chemistry Hydrochemie (DE-588)4072678-2 gnd |
| subject_GND | (DE-588)4072678-2 |
| title | Aquatic chemistry chemical equilibria and rates in natural waters |
| title_auth | Aquatic chemistry chemical equilibria and rates in natural waters |
| title_exact_search | Aquatic chemistry chemical equilibria and rates in natural waters |
| title_full | Aquatic chemistry chemical equilibria and rates in natural waters Werner Stumm ; James J. Morgan |
| title_fullStr | Aquatic chemistry chemical equilibria and rates in natural waters Werner Stumm ; James J. Morgan |
| title_full_unstemmed | Aquatic chemistry chemical equilibria and rates in natural waters Werner Stumm ; James J. Morgan |
| title_short | Aquatic chemistry |
| title_sort | aquatic chemistry chemical equilibria and rates in natural waters |
| title_sub | chemical equilibria and rates in natural waters |
| topic | Chemische reacties gtt Eau - Chimie Evenwichten gtt Waterkwaliteit gtt Water chemistry Hydrochemie (DE-588)4072678-2 gnd |
| topic_facet | Chemische reacties Eau - Chimie Evenwichten Waterkwaliteit Water chemistry Hydrochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007277792&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT stummwerner aquaticchemistrychemicalequilibriaandratesinnaturalwaters AT morganjamesj aquaticchemistrychemicalequilibriaandratesinnaturalwaters |