Electrochemical phase formation and growth: an introduction to the initial stages of metal deposition
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Weinheim [u.a.]
VCH
1996
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 410 S. Ill., graph. Darst. |
| ISBN: | 3527294228 |
Internformat
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| 100 | 1 | |a Budevski, Evgeni |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Electrochemical phase formation and growth |b an introduction to the initial stages of metal deposition |c E. Budevski ; G. Staikov ; W. J. Lorenz |
| 264 | 1 | |a Weinheim [u.a.] |b VCH |c 1996 | |
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| 650 | 7 | |a Réactions chimiques |2 ram | |
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| 650 | 4 | |a Electroplating | |
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Datensatz im Suchindex
| _version_ | 1804125288242610176 |
|---|---|
| adam_text | E. BUDEVSKI, G. STAIKOV, W J. LORENZ ELECTROCHEMICAL PHASE FORMATION AND
GROWTH AN INTRODUCTION TO THE INITIAL STAGES OF METAL DEPOSITION VCH
WEINHEIM * NEW YORK BASEL * CAMBRIDGE * TOKYO CONTENTS 1 FUNDAMENTALS OF
ELECTROCRYSTALLIZATION OF METALS 1 1.1 THERMODYNAMIC AND KINETIC ASPECTS
1 1.2 METAL DEPOSITION MECHANISMS 4 1.3 TOPICS OF THIS BOOK 7 2
CRYSTALLINE METAL SURFACES 9 2.1 STRUCTURAL ASPECTS 9 CLOSE-PACKED 2D
AND 3D CRYSTAL STRUCTURES 9 CRYSTAL IMPERFECTIONS AND SURFACE
INHOMOGENEITIES 12 SURFACE RECONSTRUCTION 13 SURFACE ROUGHNESS AND THE
KINK POSITION 16 STEP ROUGHNESS 19 2.2 ATOMIC DYNAMICS 20 ATOM EXCHANGE
FREQUENCIES 20 LOCAL, PARTIAL, AND OVERALL CURRENT DENSITIES 23 KINK
ATOMS AND THE NERNST EQUILIBRIUM POTENTIAL 24 EXCHANGE CURRENT DENSITY
OF KINK ATOMS 25 CONCENTRATION OF ADATOMS 26 EXCHANGE CURRENT DENSITY OF
ADATOMS 28 MEAN RESIDENCE TIME AND SURFACE DISPLACEMENT OF ADATOMS 29
2.3 SURFACE PROFILE MOBILITY 29 SURFACE DIFFUSION AND MEAN DISPLACEMENT
OF ADATOMS 30 SURFACE DIFFUSION. THE EXACT SOLUTION 30 DIRECT TRANSFER
36 CURRENT DENSITY ON A STEPPED CRYSTAL FACE 37 2.4 CONCLUSIONS 39 VIII
CONTENTS 3 UNDERPOTENTIAL DEPOSITION OF METALS * 2D PHASES 41 3.1
HISTORICAL BACKGROUND 41 3.2 PHENOMENOLOGY 43 3.3 THERMODYNAMICS 52
THERMODYNAMIC FORMALISM 52 ADSORPTION ISOTHERM MODEIS 55 EXPERIMENTAL
RESULTS 58 3.4 STRUCTURES OF 2D ME A DS PHASES 63 DEGREE OF REGISTRY 63
INTERNAL STRAIN 68 ELECTROCHEMICAL RESULTS 71 COMPARATIVE AND EX SITU
UHV RESULTS 74 IN SITU SURFACE ANALYTICAL RESULTS 75 3.5 KINETICS 101
QUASI-HOMOGENEOUS SUBSTRATE SURFACE APPROACH 102 INHOMOGENEOUS SUBSTRATE
SURFACE APPROACH 107 PHASE TRANSITIONS 111 3.6 2D AND 3D ME-S ALLOY
FORMATION 128 PHENOMENOLOGY 128 THERMODYNAMICS 129 STRUCTURES OF 2D AND
3D ME ALLOYS 134 KINETICS 140 3.7 CONCLUSION 146 4 INITIAL STAGES OF
BULK PHASE FORMATION 149 4.1 EQUILIBRIUM FORM OF CRYSTALS AND FORMS OF
GROWTH 149 EQUILIBRIUM FORM 149 CRYSTAL-SUBSTRATE INTERACTION 150
GIBBS-WULFF-KAISHEW THEOREM 152 TWO-DIMENSIONAL CRYSTAL 154 FORMS OF
GROWTH 156 CONTENTS IX ENERGY OF CLUSTER FORMATION 157 3D NUCLEATION 157
2D NUCLEATION 160 GIBBS-THOMSON EQUATION 161 4.2 NUCLEATION RATE 163
CLASSICAL APPROACH (VOLMER AND WEBER) 163 KINETIC APPROACH (BECKER AND
DOERING) 165 BINDING ENERGIES AND ENERGY OF NUCLEATION 166 ATOMISTIC
MODEL 168 NUCLEATION RATE EQUATION 171 SMALL CLUSTER MODEL 173
EXPERIMENTAL RESULTS 174 4.3 3D PHASE FORMATION ON UPD MODIFIED FOREIGN
SUBSTRATE SURFACES 180 UPD-OPD TRANSITIONS 181 NUCLEATION AND GROWTH 182
EPITAXY 184 EXPERIMENTAL RESULTS 185 4.4 CONCLUSIONS 199 5 GROWTH OF
CRYSTALLINE FACES 201 5.1 DISLOCATION-FREE CRYSTAL FACES 201 PREPARATION
OF SINGLE CRYSTAL FACES BY ELECTRODEPOSITION 203 DOUBLE PULSE TECHNIQUE
207 NUCLEATION RATE-OVERVOLTAGE DEPENDENCE 210 TIME DISTRIBUTION OF THE
NUCLEATION EVENTS 213 FORM OF GROWTH OF MONATOMIC LAYERS 214 PROPAGATION
RATE OF MONATOMIC STEPS 216 SPACE DISTRIBUTION OF NUCLEATION EVENTS 221
PROPAGATION RATE OF POLYATOMIC STEPS 223 MECHANISM OF METAL DEPOSITION
AND ADATOM CONCENTRATION 225 X CONTENTS 5.2 GROWTH KINETICS OF PERFECT
FACES 226 MONONUCLEAR LAYER-BY-LAYER GROWTH 227 MULTINUCLEAR MONOLAYER
FORMATION 227 DEPOSITION KINETICS ON QUASI-PERFECT CRYSTAL FACES 231 5.3
REAL CRYSTAL FACES 235 DISLOCATIONS 235 SPIRAL GROWTH MECHANISM 237
THEORY OF SPIRAL GROWTH 239 GROWTH MORPHOLOGY 245 STEADY STATE AND
TRANSIENT CURRENT DENSITIES 252 IMPEDANCE BEHAVIOR 257 5.4 CONCLUSIONS
260 6 METAL DEPOSITS AND SURFACE STRUCTURING AND MODIFIKATION .263 6.1
FORMATION OF COMPACT ME DEPOSITS 263 PHENOMENOLOGICAL CLASSIFICATION OF
3D ME DEPOSITS 263 TEXTURE, EPITAXY AND MORPHOLOGY OF 3D ME DEPOSITS 264
IMPEDANCE STUDIES OF 3D ME DEPOSITION 270 METAL DEPOSITION BY PULSE
TECHNIQUES 271 LASER-INDUCED METAL DEPOSITION 275 ELECTRODEPOSITION OF
3D ME ALLOYS 280 6.2 THEORETICAL CONSIDERATIONS 280 6.3 ULTRATHIN METAL
FILMS AND HETEROSTRUCTURES 283 ULTRATHIN METAL FILMS ON FOREIGN METAL
SUBSTRATES 286 HETEROSTRUCTURES ON FOREIGN METAL SUBSTRATES 288
ULTRATHIN METAL FILMS ON SEMICONDUCTOR SUBSTRATES 294 6.4 SURFACE
STRUCTURING AND MODIFICATION 299 METAL SINGLE CRYSTAL SURFACES 300
HOPGSURFACES 304 HTSC THIN FILM SURFACES 308 SEMICONDUCTOR SINGLE
CRYSTAL SURFACES 311 6.5 CONCLUSIONS 312 CONTENTS XI 7 OUTLOOK 315 8
APPENDICES 317 8.1 COMPILATION OF EXPERIMENTALLY STUDIED ME-S(KKL) UPD
SYSTEMS 317 REFERENCES TO APPENDIX 8.1 322 8.2 THERMODYNAMICS OF AN
IDEALLY POLARIZABLE ELECTRODE 327 8.3 MEAN FIELD THEORY AND ADSORPTION
ISOTHERMS 333 8.4 MONTE CARLO SIMULATION OF /N ADSORPTION 335 8.5
TRANSFER FUNCTION OF ME UPD ON INHOMOGENEOUS SUBSTRATE SURFACES 337 8.6
THERMODYNAMICS OF 3D ME-S BULK ALLOY ELECTRODE 339 8.7 INSTANTANEOUS AND
PROGRESSIVE NUCLEATION 342 9 REFERENCES 343 9.1 CHAPTERL 343 9.2
CHAPTER2 344 9.3 CHAPTER3 346 9.4 CHAPTER4 362 9.5 CHAPTER5 366 9.6
CHAPTEROE 371 9.8 CHAPTER8 380 10 ABBREVIATIONS AND SYMBOLS 381 10.1
ABBREVIATIONS 381 10.2 SYMBOLS 383 AUTHOR INDEX 393 SUBJECT INDEX 405
|
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| id | DE-604.BV010804145 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:59:10Z |
| institution | BVB |
| isbn | 3527294228 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007217814 |
| oclc_num | 34943369 |
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| owner_facet | DE-355 DE-BY-UBR DE-29T DE-91G DE-BY-TUM DE-83 DE-188 |
| physical | XI, 410 S. Ill., graph. Darst. |
| publishDate | 1996 |
| publishDateSearch | 1996 |
| publishDateSort | 1996 |
| publisher | VCH |
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| spelling | Budevski, Evgeni Verfasser aut Electrochemical phase formation and growth an introduction to the initial stages of metal deposition E. Budevski ; G. Staikov ; W. J. Lorenz Weinheim [u.a.] VCH 1996 XI, 410 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Cristal (verre) - Croissance ram Cristaux - Croissance ram Dépôt électrolytique ram Métaux - Surfaces ram Réactions chimiques ram Crystal growth Electroplating Metals Surfaces Galvanische Abscheidung (DE-588)4316091-8 gnd rswk-swf Elektrokristallisation (DE-588)4151822-6 gnd rswk-swf Metall (DE-588)4038860-8 gnd rswk-swf Chemische Metallabscheidung (DE-588)4279388-9 gnd rswk-swf Elektrokristallisation (DE-588)4151822-6 s DE-604 Chemische Metallabscheidung (DE-588)4279388-9 s Metall (DE-588)4038860-8 s Galvanische Abscheidung (DE-588)4316091-8 s Stajkov, Georgi Verfasser aut Lorenz, Wolfgang Joachim 1933- Verfasser (DE-588)106361279 aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007217814&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Budevski, Evgeni Stajkov, Georgi Lorenz, Wolfgang Joachim 1933- Electrochemical phase formation and growth an introduction to the initial stages of metal deposition Cristal (verre) - Croissance ram Cristaux - Croissance ram Dépôt électrolytique ram Métaux - Surfaces ram Réactions chimiques ram Crystal growth Electroplating Metals Surfaces Galvanische Abscheidung (DE-588)4316091-8 gnd Elektrokristallisation (DE-588)4151822-6 gnd Metall (DE-588)4038860-8 gnd Chemische Metallabscheidung (DE-588)4279388-9 gnd |
| subject_GND | (DE-588)4316091-8 (DE-588)4151822-6 (DE-588)4038860-8 (DE-588)4279388-9 |
| title | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition |
| title_auth | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition |
| title_exact_search | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition |
| title_full | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition E. Budevski ; G. Staikov ; W. J. Lorenz |
| title_fullStr | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition E. Budevski ; G. Staikov ; W. J. Lorenz |
| title_full_unstemmed | Electrochemical phase formation and growth an introduction to the initial stages of metal deposition E. Budevski ; G. Staikov ; W. J. Lorenz |
| title_short | Electrochemical phase formation and growth |
| title_sort | electrochemical phase formation and growth an introduction to the initial stages of metal deposition |
| title_sub | an introduction to the initial stages of metal deposition |
| topic | Cristal (verre) - Croissance ram Cristaux - Croissance ram Dépôt électrolytique ram Métaux - Surfaces ram Réactions chimiques ram Crystal growth Electroplating Metals Surfaces Galvanische Abscheidung (DE-588)4316091-8 gnd Elektrokristallisation (DE-588)4151822-6 gnd Metall (DE-588)4038860-8 gnd Chemische Metallabscheidung (DE-588)4279388-9 gnd |
| topic_facet | Cristal (verre) - Croissance Cristaux - Croissance Dépôt électrolytique Métaux - Surfaces Réactions chimiques Crystal growth Electroplating Metals Surfaces Galvanische Abscheidung Elektrokristallisation Metall Chemische Metallabscheidung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007217814&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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