Photodegradation of polymers: physical characteristics and applications ; with 26 tables
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1996
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 212 S. Ill., graph. Darst. |
| ISBN: | 3540607161 |
Internformat
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| 100 | 1 | |a Rabek, Jan F. |e Verfasser |4 aut | |
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Datensatz im Suchindex
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| adam_text | JAN F. RABEK PHOTODEGRADATION OF POLYMERS PHYSICAL CHARACTERISTICS AND
APPLICATIONS WITH 94 FIGURES AND 26 TABLES SPRINGER CONTENTS PREFACE VII
1 ABSORPTION OF RADIATION 1 1.1 RADIATION AND ITS ENERGY 1 1.2 SI UNITS
USED IN PHOTOCHEMISTRY 2 1.3 ABSORPTION CROSS SECTION 2 1.4 PRACTICAL
ASPECTS OF THE LAMBERT-BEER EQUATION 4 2 ELECTRONICALLY EXCITED STATES
IN POLYMERS 9 2.1 FORMATION OF EXCITED STATES 9 2.2 RADIATIVE PROCESSES
10 2.3 RADIATIONLESS TRANSITIONS 10 2.4 EXCITATION OF CHROMOPHORES 11
2.5 LUMINESCENCE EMISSION FROM CHROMOPHORES 13 2.6 KINETICS OF
PHOTOPHYSICAL PROCESSES 14 2.7 QUENCHING PROCESSES OF EXCITED STATES 16
2.8 QUENCHING PROCESSES IN SOLUTION 16 2.9 QUENCHING PROCESSES IN
POLYMER MATRICES 19 3 ELECTRONIC ENERGY TRANSFER PROCESSES IN POLYMERS
20 3.1 ENERGY TRANSFER IN PHOTODEGRADATION PROCESSES 20 3.2 PHYSICAL
ASPECTS OF ELECTRONIC ENERGY TRANSFER 20 3.3 RADIATIVE ENERGY TRANSFER
21 3.4 ELECTRON EXCHANGE ENERGY TRANSFER 22 3.5 RESONANCE EXCITATION
ENERGY TRANSFER 23 3.6 EFFICIENCY OF ENERGY TRANSFER 26 3.7
SPECTROSCOPIC OVERLAP INTEGRAL 28 3.8 ENERGY TRANSFER PROCESSES IN
SOLUTION 28 3.9 DIFFUSION-CONTROLLED REACTIONS 29 3.10 SOLVENT EFFECTS
31 3.11 VISCOSITY EFFECTS 32 3.12 ENERGY TRANSFER IN RIGID POLYMER
MATRIX 33 3.13 SPECTROSCOPIC METHODS FOR THE DETERMINATION OF ELECTRONIC
ENERGY TRANSFER PROCESSES 36 3.14 SINGLET-SINGLET ENERGY TRANSFER IN
POLYMERS 38 3.15 TRIPLET-TRIPLET ENERGY TRANSFER IN POLYMERS 38 X
CONTENTS 3.16 ENERGY TRANSFER FROM CARBONYL GROUPS TO HYDROPEROXIDES .
39 3.17 ENERGY TRANSFER FROM PHENYL GROUP TO HYDROPEROXIDES .... 40 3.18
EXCITED STATE ANNIHILATION PROCESSES 41 3.19 ENERGY MIGRATION IN
POLYMERS 42 3.20 ENERGY MIGRATION IN EXCIMER-FORMING POLYMERS 46 4
PHOTO-OXIDATIVE DEGRADATION 51 4.1 INTRODUCTION TO PHOTOCHEMICAL
REACTIONS IN POLYMERS 51 4.2 PHOTOCHEMICAL LAWS 51 4.3 PHOTOCHEMICAL
ACTIVATION 52 4.4 PHOTODISSOCIATION OF A MOLECULE 53 4.5 QUANTUM YIELDS
OF PHOTODEGRADATION 54 4.6 ABSORPTION OF RADIATION BY POLYMERS 55 4.7
FORMATION OF UV/LIGHT ABSORBING IMPURITIES 57 4.8 PHOTOINITIATION OF
POLYMER DEGRADATION 59 4.9 GENERAL MECHANISM OF POLYMER PHOTO-OXIDATIVE
DEGRADATION 60 4.10 CHAIN PROPAGATION 61 4.11 PHOTOCHAIN-OXIDATION
REACTION 62 4.12 MAIN CHAIN SCISSION 62 4.13 CHAIN BRANCHING 63 4.14
TERMINATION REACTION 64 4.15 DARK PROCESSES IN PHOTODEGRADATION OF
POLYMERS 65 4.16 HYDROGEN ATOM ABSTRACTION 65 4.17 FORMATION OF HYDROXY
AND/OR HYDROPEROXY GROUPS 66 4.18 HOMOLYTIC DECOMPOSITION OF
HYDROPEROXIDES 67 4.19 PHOTODECOMPOSITION OF HYDROPEROXIDE GROUPS 68
4.20 REACTIONS OF HYDROXY (HO) AND HYDROPEROXY (HO2) RADICALS WITH
POLYMERS 69 4.21 FORMATION OF CARBONYL GROUPS 71 4.22 FORMATION OF
CARBOXYLIC AND PER-CARBOXYLIC GROUPS 74 4.23 NORRISH TYPE I AND TYPE II
REACTIONS 77 4.24 FORMATION OF A, ^-UNSATURATED CARBONYL GROUPS 79 4.25
CONVERSION OF POLYMERIC FREE RADICALS UNDER UV/VISIBLE RADIATION AND
WARMING 80 4.26 PHOTODEGRADATION OF CHLORINATED POLYMERS 81 4.27 PHENYL
RING-OPENING PHOTO-REACTIONS 82 4.28 PHOTOFRIES REARRANGEMENT IN
POLYMERS 82 4.29 PHOTO-OXYGENATION OF POLYMERS BY SINGLET OXYGEN 83 4.30
PHOTOINITIATED DEGRADATION OF POLYMERS 87 4.31 PHOTOINITIATED
DEGRADATION OF POLYMERS BY DYES 89 4.32 PHOTOINDUCED ELECTRON TRANSFER
97 5 PHYSICAL FACTORS WHICH INFLUENCE PHOTODEGRADATION 98 5.1 EFFECT OF
FREE VOLUME 98 5.2 EFFECT OF THE GLASS TRANSITION TEMPERATURE 100 5.3
EFFECT OF CRYSTALLINITY 102 CONTENTS XI 5.4 LOCALIZATION OF THE
OXIDATION PROCESSES IN SEMICRYSTALLINE POLYMERS 104 5.5
CHEMICRYSTALLIZATION PROCESS 104 5.6 EFFECT OF POLYMER MOLECULAR WEIGHT
105 5.7 EFFECT OF THE FORMATION OF HYDROGEN BONDS 106 5.8 CAGE
RECOMBINATION 107 6 KINETIC TREATMENTS OF DEGRADATION 10 9 6.1
PHOTODEGRADATION IN ISOTHERMAL AND NON-ISOTHERMAL CONDITIONS 109 6.2
DECAY OF FREE RADICALS IN A POLYMER MATRIX 110 6.3 SPIN TRAPPING OF
POLYMERIC RADICALS 112 6.4 PHOTODEPOLYMERIZATION 114 6.5 KINETICS OF
PHOTODEGRADATION 117 6.6 NUMBER OF MAIN CHAIN SCISSIONS 119 6.7 QUANTUM
YIELD OF CHAIN SCISSION 120 6.8 QUANTUM YIELD OF CROSSLINKING 121 6.9
PRINCIPLES GOVERNING THE CHANGES IN MOLECULAR WEIGHT AND MOLECULAR
WEIGHT DISTRIBUTION DURING POLYMER PHOTODEGRADATION 125 6.10 REACTION
KINETICS OF POLYMER PHOTO-OXIDATION 126 6.11 DIFFUSION CONTROLLED
OXIDATION OF POLYMERS 131 6.12 OXIDATION PROFILES 133 7 PHOTODEGRADATION
OF SOLID POLYMERS 136 7.1 DIFFERENCES BETWEEN PHOTODEGRADATION OF
POLYMERS IN SOLID AND LIQUID PHASES 136 7.2 POLYMER MECHANICAL
PROPERTIES AFFECTED BY DEGRADATION ... 137 7.3 ROLE OF WATER IN THE
DEGRADATION PROCESSES 138 7.4 EFFECT OF ORIENTATION ON DEGRADATION 140
7.5 DEGRADATION OF POLYMERS UNDER DEFORMATION FORCES 141 7.6 FEEDBACK IN
POLYMER DEGRADATION 142 7.7 STRESS-ACCELERATED PHOTO-OXIDATION OF
POLYMERS 143 7.8 PHOTODEGRADATION OF POLYMERS FOR SOLAR ENERGY DEVICES .
. . 144 8 PHOTODECOMPOSITION OF POLYMERS BY LASER RADIATION 146 8.1
ABLATIVE PHOTODECOMPOSITION OF POLYMERS 146 8.2 PHOTOKINETIC ETCHING 158
8.3 THERMAL PROCESSING OF POLYMERS BY VISIBLE AND INFRARED LASER
RADIATION 158 9 PRACTICAL ASPECTS OF POLYMER PHOTODEGRADATION 161 9.1
PHOTODEGRADATION OF POLYMERS UNDER WEATHERING CONDITIONS 161 9.2
PHOTODEGRADATION OF POLYMERS IN NATURAL WATERS 161 XII CONTENTS 9.3
PHOTODEGRADATION OF POLYMERS UNDER MARINE EXPOSURE CONDITIONS 163 9.4
HYDROLYSIS PROCESSES DURING AGEING OF POLYMERS 164 9.5 PLASTIC
ECOLOGICAL PROBLEMS 165 9.6 PHOTODEGRADABLE POLYMERS WITH CONTROLLED
LIFETIMES 166 9.7 ECOLYTE PLASTICS 168 9.8 PLASTIC PROTECTIVE FILMS 170
9.9 RECOVERY OF PHOTODEGRADED POLYMERS 171 9.10 PHOTODEGRADATION OF
POLYMERS IN THE POLLUTED ATMOSPHERE . . 171 9.11 PHOTODEGRADATION OF
POLYMERS IN THE STRATOSPHERE 173 9.12 PHOTODEGRADATION OF POLYMERS IN
SPACE 175 9.13 ATOMIC OXYGEN REACTIONS WITH POLYMERS 180 9.14 POLYMERIC
PHOTOINITIATORS OPERATING WITH A FRAGMENTATION MECHANISM 183 9.15
POSITIVE-WORKING PHOTORESISTS 187 10 REFERENCES 193 INDEX 209
|
| any_adam_object | 1 |
| author | Rabek, Jan F. |
| author_facet | Rabek, Jan F. |
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| author_sort | Rabek, Jan F. |
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| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften Chemie |
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| indexdate | 2024-07-09T17:58:11Z |
| institution | BVB |
| isbn | 3540607161 |
| language | English |
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| physical | XII, 212 S. Ill., graph. Darst. |
| publishDate | 1996 |
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| spelling | Rabek, Jan F. Verfasser aut Photodegradation of polymers physical characteristics and applications ; with 26 tables Jan F. Rabek Berlin [u.a.] Springer 1996 XII, 212 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Alterung (DE-588)4142063-9 gnd rswk-swf Degradation (DE-588)4200268-0 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Fotochemische Reaktion (DE-588)4138378-3 gnd rswk-swf Polymere (DE-588)4046699-1 s Degradation (DE-588)4200268-0 s Fotochemische Reaktion (DE-588)4138378-3 s DE-604 Alterung (DE-588)4142063-9 s Reaktionsmechanismus (DE-588)4177123-0 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007176621&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Rabek, Jan F. Photodegradation of polymers physical characteristics and applications ; with 26 tables Alterung (DE-588)4142063-9 gnd Degradation (DE-588)4200268-0 gnd Polymere (DE-588)4046699-1 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Fotochemische Reaktion (DE-588)4138378-3 gnd |
| subject_GND | (DE-588)4142063-9 (DE-588)4200268-0 (DE-588)4046699-1 (DE-588)4177123-0 (DE-588)4138378-3 |
| title | Photodegradation of polymers physical characteristics and applications ; with 26 tables |
| title_auth | Photodegradation of polymers physical characteristics and applications ; with 26 tables |
| title_exact_search | Photodegradation of polymers physical characteristics and applications ; with 26 tables |
| title_full | Photodegradation of polymers physical characteristics and applications ; with 26 tables Jan F. Rabek |
| title_fullStr | Photodegradation of polymers physical characteristics and applications ; with 26 tables Jan F. Rabek |
| title_full_unstemmed | Photodegradation of polymers physical characteristics and applications ; with 26 tables Jan F. Rabek |
| title_short | Photodegradation of polymers |
| title_sort | photodegradation of polymers physical characteristics and applications with 26 tables |
| title_sub | physical characteristics and applications ; with 26 tables |
| topic | Alterung (DE-588)4142063-9 gnd Degradation (DE-588)4200268-0 gnd Polymere (DE-588)4046699-1 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Fotochemische Reaktion (DE-588)4138378-3 gnd |
| topic_facet | Alterung Degradation Polymere Reaktionsmechanismus Fotochemische Reaktion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007176621&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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