Solving problems with NMR spectroscopy:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
San Diego [u.a.]
Acad. Press
1996
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 430 S. graph. Darst. |
| ISBN: | 0120663201 |
Internformat
MARC
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| 245 | 1 | 0 | |a Solving problems with NMR spectroscopy |c Atta-ur-Rahman and Muhammad Iqbal Choudhary |
| 264 | 1 | |a San Diego [u.a.] |b Acad. Press |c 1996 | |
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Datensatz im Suchindex
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| adam_text | *F SOLVING PROBLEMS WITH NMR SPECTROSCOPY ATTA-UR-RAHMAN AND MUHAMMAD
IQBAL CHOUDHARY H.E.J. RESEARCH INSTITUTE OF CHEMISTRY UNIVERSITY OF
KARACHI, KARACHI-75270, PAKISTAN ACADEMIC PRESS SAN DIEGO -F NEW YORK
* BOSTON * LONDON * SYDNEY * TOKYO + TORONTO CONTENTS FOREWORD * RICHARD
R. ERNST XI FOREWORD * LLOYD M. JACKMAN XIII PREFACE XV CHAPTER 1 THE
BASICS OF MODERN NMR SPECTROSCOPY 1.1 WHAT IS NMR? 1 1.1.1 THE BIRTH OF
A SIGNAL 3 1.2 INSTRUMENTATION 9 1.2.1 THE MAGNET 11 1.2.2 THE PROBE 11
1.2.3 PROBE TUNING 13 1.2.4 SHIMMING 15 1.2.5 DEUTERIUM LOCK 20 1.3
CREATING NMR SIGNALS 20 1.3.1 EFFECTS OF PULSES 22 1.3.2 ROTATING FRAME
OFREFERENCE 27 1.3.3 FREE INDUCTION DECAY 30 1.3.4 FOURIER
TRANSFORMATION 32 1.3.5 DATA ACQUISITION AND STORAGE 35 1.3.6 DIGITAL
RESOLUTION 41 1.3.7 PEAK FOLDING 43 1.3.8 THE DYNAMIC RANGE PROBLEM 43 +
+ + + + VI CONTENTS 1.3.9 QUADRATURE DETECTION 48 1.3.10 SIGNAL-TO-NOISE
RATIO 52 1.3.11 APODIZATION 55 1.3.12 PULSE WIDIH CALIBRATION 60 1.3.13
COMPOSITE PULSES 65 1.3.14 PHASE CYCLING 67 1.3.15 PHASE CYCLING AND
COHERENCE TRANSFER PATHWAYS 70 SOLUTIONS TO PROBLEMS 74 REFERENCES 89
CHAPTER 2 SPIN-ECHO AND POLARIZATION TRANSFER 2.1 SPIN-ECHO FORMATION IN
HOMONUCLEAR AND HETERONUCLEAR SYSTEMS 91 2.1.1 SPIN-ECHO PRODUCTION 91
2.1.2 SPIN-ECHO PRODUCTION IN A HETERONUCLEAR AX SPIN SYSTEM 95 2.1.3
ATTACHED PROTON TEST (APT), GATED SPIN-ECHO (GASPE), AND SPIN-ECHO
FOURIER TRANSFORM (SEFT) 97 2.1.4 NONOBSERVABLE MAGNETIZATION BY 90
PULSES: MIXING SPIN STATES 102 2.2 CROSS-POLARIZATION 103 2.2.1 INEPT
108 2.2.2 REFOCUSED INEPT 116 2.2.3 DEPT 117 2.3 POLARIZATION TRANSFER
IN REVERSE 121 SOLUTIONS TO PROBLEMS 131 REFERENCES 146 CHAPTER 3 THE
SECOND DIMENSION 3.1 DATA ACQUISITION IN 2D NMR 156 3.1.1 PULSE SEQUENCE
156 3.1.2 SETTING PULSE LENGTHS AND DELAYS 156 3.1.3 SPECTRAL WIDTHS
(SW, AND SW 2 ) 157 3.1.4 NUMBER OFDATA POINTS IN T, AND T 2 159 3.1.5
NUMBER OFTRANSIENTS 160 3.1.6 DUMMY SCANS AND RELAXATION DELAYS BETWEEN
SUCCESSIVE PULSES 160 CONTENTS 3.2 DATA PROCESSING IN 2D NMR 163 3.2.1
DC CORRECTIAN 164 3.2.2 PEAK SHAPES IN 2D NMR SPECTRA 165 3.3 PLOTTING
OF 2D SPECTRA 175 SOLUTIONS TO PROBLEMS 175 REFERENCES 185 CHAPTER 4
NUCLEAR OVERHAUSER EFFECT 4.1 NOE AND SELECTIVE POPULATION TRANSFER 188
4.2 RELAXATION 189 4.3 MECHANISM OF NOE 190 4.4 FACTORS AFFECTING NOE
195 4.4.1 INTERNUCLEAR DISTANCE AND NOE 197 4.4.2 THREE-SPIN SYSTEM 198
4.4.3 THREE-SPIN EFFECTS 200 4.4.4 NONLINEAR ARRANGEMENT 201 4.4.5 NOE
DIFFERENCE SPECTRA 203 4.5 SOME PRACTICAL HINTS 204 4.5.1 SOLVENT 204
4.5.2 TEMPERATURE 205 4.5.3 SAMPLE PURITY 205 SOLUTIONS TO PROBLEMS 207
REFERENCES 211 CHAPTER 5 IMPORTANT 2D NMR EXPERIMENTS 5.1 HOMO-AND
HETERONUCLEAR /RESOLVED SPECTROSCOPY 213 5.1.1 HETERONUCLEAR 2D
J-RESOLVED SPECTROSCOPY 213 5.1.2 HOMONUCLEAR 2D J-RESOLVED SPECTROSCOPY
227 5.2 HOMONUCLEAR AND HETERONUCLEAR SHIFT- CORRELATION SPECTROSCOPY
235 5.2.1 HOMONUCLEAR SHISS-CORRELATION SPECTROSCOPY (COSY) 235 5.2.2
HETERONUCLEAR SHISS-CORRELATION SPECTROSCOPY 254 VI 11 CONTENTS 5.3
TWO-DIMENSIONAL NUCLEAR OVERHAUSER SPECTROSCOPY 259 5.3.1 NOESY 259
5.3.2 PHASE-SENSITIVE NOESY 261 5.3.3 CAMELSPIN, OR ROESY
(ROTATING-FRAME OVERHAUSER ENHANCEMENT SPECTROSCOPY) 262 5.3.4
HETERONUCLEAR NOE SPECTROSCOPY (HOESY) 262 5.3.5 RELAYED NOE EXPERIMENTS
265 5.4 TWO-DIMENSIONAL CHEMICAL EXCHANGE SPECTROSCOPY 265 5.5
HOMONUCLEAR HARTMANN-HAHN SPECTROSCOPY (HOHAHA), OR TOTAL CORRELATION
SPECTROSCOPY (TOCSY) 267 5.5.1 HETERONUCLEAR HARTMANN-HAHN SPECTROSCOPY
268 5.6 INVERSE NMR SPECTROSCOPY 271 5.6.1 H-DETECTED HETERONUCLEAR
MULTIPLE-QUANTUM COHERENCE (HMQC) SPECTRA 271 5.6.2 HETERONUCLEAR
MULTIPLE-BOND CONNECTIVITY (HMBC) SPECTRA 273 5.7 INADEQUATE 274
SOLUTIONS TO PROBLEMS 305 REFERENCES 343 CHAPTER 6 THE THIRD DIMENSION
6.1 BASIC PHILOSOPHY 345 6.2 TYPES AND POSITIONS OF PEAKS IN 3D SPECTRA
348 REFERENCES 362 CHAPTER 7 RECENT DEVELOPMENTS IN NMR SPECTROSCOPY 7.1
SELECTRVE PULSES IN MODERN NMR SPECTROSCOPY 365 7.2 ONE-DIMENSIONAL
EXPERIMENTS USING SOFT PULSES 366 7.2.1 1D COSY 367 7.2.2 1D RELAYED
COSY 368 7.2.3 SELINQUATE 369 7.2.4 1D NOESY 369 7.2.5 1D RELAYED NOESY
369 7.2.6 1D TOCSY 370 CONTENTS IX 7.2.7 1DR0ESY 371 7.3 HETERONUCLEAR
SELECTIVE ID NMR EXPERIMENTS 371 7.3.1 SEUNCOR 371 7.3.2 ID HMQC-TOCSY
371 7.3.3 SELECLIVE HETERONUCLEAR ^-RESOLVED EXPERIMENT 372 7.3.4
SELECTIVE INEPT 373 7.4 TWO-DIMENSIONAL EXPERIMENTS USING SOFT PULSES
373 7.4.1 SEMISOFT COSY 374 7.4.2 SEMISOFT NOESY 376 7.4.3 HETERONUCLEAR
MULTIPLE-BOND CORRELATION, SELECTIVE (HMBCS) 376 7.4.4 SEMISOFT TOCSY
377 7.5 SOFT EXCITATION IN TWO DIMENSIONS 377 7.5.1 SOFTH,H-COSY 378
7.5.2 SOFT NOESY 379 7.5.3 SOFTH,C-COSY 379 7.6 THREE-DIMENSIONAL
EXPERIMENTS USING SOFT PULSES 380 7.7 FIELD GRADIENTS 381 7.7.1 MAGNETIC
RESONANCE IMAGITIG (MRI) 382 7.7.2 GRADIENT-ACCELERATED SPECTROSCOPY
(GAS): AN ALTERNATIVE TO PHASE CYCLING 384 REFERENCES 389 CHAPTER 8
LOGICAL PROTOCOLS FOR SOLVING COMPLEX STRUCTURAL PROBLEMS 8.1
3-HYDROXYLUPANINE (1) 394 8.2 (+)-BUXALONGIFOLAMIDINE (2) 398 REFERENCES
409 GLOSSARY 411 INDEX 421
|
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| author | Atta-ur-Rahman 1942- Choudhary, Muhammad Iqbal |
| author_GND | (DE-588)111146356 |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 543 - Analytical chemistry |
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| dewey-sort | 3543.66 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
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| id | DE-604.BV010734882 |
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| indexdate | 2024-07-09T17:57:58Z |
| institution | BVB |
| isbn | 0120663201 |
| language | English |
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| physical | XVI, 430 S. graph. Darst. |
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| spelling | Atta-ur-Rahman 1942- Verfasser (DE-588)111146356 aut Solving problems with NMR spectroscopy Atta-ur-Rahman and Muhammad Iqbal Choudhary San Diego [u.a.] Acad. Press 1996 XVI, 430 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Spectroscopie de la résonance magnétique nucléaire ram NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Matériel didactique NMR-Spektroskopie (DE-588)4075421-2 s DE-604 Choudhary, Muhammad Iqbal Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007167060&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Atta-ur-Rahman 1942- Choudhary, Muhammad Iqbal Solving problems with NMR spectroscopy Spectroscopie de la résonance magnétique nucléaire ram NMR-Spektroskopie (DE-588)4075421-2 gnd |
| subject_GND | (DE-588)4075421-2 |
| title | Solving problems with NMR spectroscopy |
| title_auth | Solving problems with NMR spectroscopy |
| title_exact_search | Solving problems with NMR spectroscopy |
| title_full | Solving problems with NMR spectroscopy Atta-ur-Rahman and Muhammad Iqbal Choudhary |
| title_fullStr | Solving problems with NMR spectroscopy Atta-ur-Rahman and Muhammad Iqbal Choudhary |
| title_full_unstemmed | Solving problems with NMR spectroscopy Atta-ur-Rahman and Muhammad Iqbal Choudhary |
| title_short | Solving problems with NMR spectroscopy |
| title_sort | solving problems with nmr spectroscopy |
| topic | Spectroscopie de la résonance magnétique nucléaire ram NMR-Spektroskopie (DE-588)4075421-2 gnd |
| topic_facet | Spectroscopie de la résonance magnétique nucléaire NMR-Spektroskopie Matériel didactique |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007167060&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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