The physics of polymers: concepts for understanding their structures and behavior
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1996
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 439 S. Ill., graph. Darst. |
| ISBN: | 3540607684 |
Internformat
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Datensatz im Suchindex
| _version_ | 1828843468960563200 |
|---|---|
| adam_text |
GERT R. STROBL
THE PHYSICS OF POLYMERS
CONCEPTS
FOR UNDERSTANDING
THEIR
STRUCTURES AND BEHAVIOR
WITH218FIGURES
J
S SPRINGER
CONTENTS
1.
THE CONSTITUTION AND ARCHITECTURE OF CHAINS
1
1.1 FURTHER READING
11
2.
SINGLE CHAIN CONFORMATIONS
13
2.1 ROTATIONAL ISOMERIC STATES 13
2.2 HELICES 17
2.3 COILS 20
2.3.1 IDEAL CHAINS 23
2.3.2 EXPANDED CHAINS 43
2.4 THE ISING-CHAIN 53
2.5 FURTHER READING
61
3.
LIQUID EQUILIBRIUM STATES
63
3.1 DILUTE AND SEMI-DILUTE POLYMER SOLUTIONS 64
3.1.1 OSMOTIC PRESSURE 65
3.1.2 SCREENING EFFECT 76
3.2 POLYMER MIXTURES 83
3.2.1 FLORY-HUGGINS TREATMENT OF COMPATIBILITY 83
3.2.2 PHASE SEPARATION MECHANISMS 100
3.2.3 CRITICAL FLUCTUATIONS AND SPINODAL DECOMPOSITION . . . 107
3.3
BLOCK COPOLYMERS 129
3.3.1 PHASE BEHAVIOR 129
3.3.2 LAYERED STRUCTURES 133
3.3.3 PRETRANSITIONAL PHENOMENA 135
3.4 FUXTHER READING 141
4.
METASTABLE PARTIALLY CRYSTALLINE STATES
143
4.1 STRUCTURE CHARACTERISTICS 145
4.2 PRIMARY CRYSTALLIZATION 157
4.2.1 SPHERULITE NUCLEATION AND GROWTH 158
4.2.2 SPINODAL MODE 173
4.3 SECONDARY CRYSTALLIZATION 176
4.3.1 INSERTION MODE 181
X
CONTENTS
4.3.2 SURFACE CRYSTALLIZATION AND MELTING 185
4.4 FURTHER READING 189
5. MECHANICAL AND DIELECTRIC RESPONSE
191
5.1 RESPONSE FUNCTIONS 192
5.1.1
VISCOELASTICITY 192
5.1.2 ORIENTATIONAL POLARIZATION 196
5.1.3 GENERAL RELATIONSHIPS 197
5.2 RELAXATORY MODES 204
5.2.1 SINGLE-TIME RELAXATION PROCESS 205
5.2.2 RETARDATION AND RELAXATION TIME SPECTRA 209
5.3 SPECIFIC RELAXATION PROCESSES AND FLOW BEHAVIOR 213
5.3.1 LOCAL PROCESSES 214
5.3.2 GLASS-RUBBER TRANSITION AND MELT FLOW 217
5.3.3 GLASS TRANSITION TEMPERATURE 237
5.3.4 RELAXATION IN PARTIALLY CRYSTALLINE SYSTEMS 244
5.4 FURTHER READING 255
6. MICROSCOPIC DYNAMICAL MODELS
257
6.1 THE FLUCTUATION-DISSIPATION THEOREM 257
6.2 THE ROUSE-MODEL 262
6.2.1 STRESS RELAXATION 269
6.2.2 DIELECTRIC NORMAL MODE 274
6.3 ENTANGLEMENT EFFECTS 277
6.3.1 THE REPTATION MODEL 282
6.4 HYDRODYNAMIC INTERACTION IN SOLUTIONS 287
6.4.1 INTRINSIC VISCOSITY 293
6.5 FURTHER READING 296
7. NON-LINEAR MECHANICAL BEHAVIOR
297
7.1 RUBBER ELASTICITY 301
7.1.1 THE FIXED JUNCTION MODEL OF IDEAL RUBBERS 304
7.1.2 THE CAUCHY STRAIN TENSOR 311
7.1.3 FINGER'S CONSTITUTIVE EQUATION 315
7.2 NON-NEWTONIAN MELT FLOW 325
7.2.1 RHEOLOGICAL MATERIAL FUNCTIONS 325
7.2.2 THE LODGE LIQUID 332
7.2.3 STRESS-OPTICAL RULE AND NETWORK MODEL 339
7.3 FURTHER READING 348
8. YIELD PROCESSES AND FRACTURE
349
8.1 SHEAR YIELDING 353
8.1.1 MECHANICS OF NECK FORMATION 353
8.1.2 STRUCTURE CHANGES ON COLD-DRAWING 359
CONTENTS
XI
8.2 CRAZING 368
8.3 BRITTLE FRACTURE 374
8.3.1 LINEAR FRACTURE MECHANICS 376
8.3.2 SLOW MODE OF CRACK GROWTH 380
8.4 FURTHER READING 385
APPENDIX: SCATTERING EXPERIMENTS
387
A.L FUNDAMENTALS 387
A.L.L BASIC EQUATIONS 387
A.1.2 TIME-RESOLVED SCATTERING EXPERIMENTS 392
A.2 ABSOLUTE INTENSITIES 395
A.3 LOW ANGLE SCATTERING PROPERTIES 398
A.3.1 GUINIER'S LAW 398
A.3.2 FORWARD SCATTERING 400
A.4 SPECIAL POLYMER SYSTEMS 401
A.4.1 BINARY MIXTURES AND BLOCK COPOLYMERS 401
A.4.2 TWO-PHASE LAYER SYSTEMS 408
A.5 FURTHER READING 415
GLOSSARY OF SYMBOLS
417
FIGURE REFERENCES
425
BIBLIOGRAPHY
429
SUBJECT INDEX
433 |
| any_adam_object | 1 |
| author | Strobl, Gert R. 1941- |
| author_GND | (DE-588)115460977 |
| author_facet | Strobl, Gert R. 1941- |
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| building | Verbundindex |
| bvnumber | BV010720115 |
| callnumber-first | Q - Science |
| callnumber-label | QC173 |
| callnumber-raw | QC173.4.P65 |
| callnumber-search | QC173.4.P65 |
| callnumber-sort | QC 3173.4 P65 |
| callnumber-subject | QC - Physics |
| classification_rvk | UV 1000 VE 8000 |
| classification_tum | CHE 710f WER 550f |
| ctrlnum | (OCoLC)34515388 (DE-599)BVBBV010720115 |
| dewey-full | 530.4/13 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 530 - Physics |
| dewey-raw | 530.4/13 |
| dewey-search | 530.4/13 |
| dewey-sort | 3530.4 213 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Chemie Werkstoffwissenschaften |
| format | Book |
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| indexdate | 2025-04-08T14:04:04Z |
| institution | BVB |
| isbn | 3540607684 |
| language | German |
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| physical | XI, 439 S. Ill., graph. Darst. |
| publishDate | 1996 |
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| spelling | Strobl, Gert R. 1941- Verfasser (DE-588)115460977 aut The physics of polymers concepts for understanding their structures and behavior Gert R. Strobl Berlin [u.a.] Springer 1996 XI, 439 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Fysische eigenschappen gtt Kristallen gtt Mechanische eigenschappen gtt Polymeren gtt Structuur gtt Verstrooiing gtt Polymers Physik (DE-588)4045956-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Polymere (DE-588)4046699-1 s Physik (DE-588)4045956-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007158437&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Strobl, Gert R. 1941- The physics of polymers concepts for understanding their structures and behavior Fysische eigenschappen gtt Kristallen gtt Mechanische eigenschappen gtt Polymeren gtt Structuur gtt Verstrooiing gtt Polymers Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4045956-1 (DE-588)4046699-1 (DE-588)4123623-3 |
| title | The physics of polymers concepts for understanding their structures and behavior |
| title_auth | The physics of polymers concepts for understanding their structures and behavior |
| title_exact_search | The physics of polymers concepts for understanding their structures and behavior |
| title_full | The physics of polymers concepts for understanding their structures and behavior Gert R. Strobl |
| title_fullStr | The physics of polymers concepts for understanding their structures and behavior Gert R. Strobl |
| title_full_unstemmed | The physics of polymers concepts for understanding their structures and behavior Gert R. Strobl |
| title_short | The physics of polymers |
| title_sort | the physics of polymers concepts for understanding their structures and behavior |
| title_sub | concepts for understanding their structures and behavior |
| topic | Fysische eigenschappen gtt Kristallen gtt Mechanische eigenschappen gtt Polymeren gtt Structuur gtt Verstrooiing gtt Polymers Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Fysische eigenschappen Kristallen Mechanische eigenschappen Polymeren Structuur Verstrooiing Polymers Physik Polymere Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007158437&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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