Pyrite oxidation and its control: solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton [u.a.]
CRC Press
1995
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 293 S. Ill., graph. Darst. |
| ISBN: | 0849347327 |
Internformat
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| 245 | 1 | 0 | |a Pyrite oxidation and its control |b solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation |c V. P. (Bill) Evangelou |
| 264 | 1 | |a Boca Raton [u.a.] |b CRC Press |c 1995 | |
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| 650 | 4 | |a Microencapsulation | |
| 650 | 4 | |a Pyrites |x Oxidation | |
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Datensatz im Suchindex
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| adam_text | PYRITE OXIDATION AND ITS CONTROL SOLUTION CHEMISTRY, SURFACE CHEMISTRY,
* ACID MINE DRAINAGE (AMD), MOLECULAR OXIDATION MECHANISMS, MICROBIAL
ROLE, KINETICS, CONTROL, AMELIORATES AND LIMITATIONS, MICROENCAPSULATION
V. P. (BILL) EVANGELOU, PH.D. PROFESSOR OF SOILAVATER PHYSICAL CHEMISTRY
UNIVERSITY OF KENTUCKY, LEXINGTON CRC PRESS BOCA RATON NEW YORK LONDON
TOKYO TABLE OF CONTENTS INTRODUCTION 1 PARTI REVIEW OF BASIC CONCEPTS OF
SURFACE CHEMISTRY AND CHEMISTRY AND CONTROL OF ACID DRAINAGE CHAPTER 1 A
REVIEW ON SOLUTION/MINERAL CHEMISTRY 7 1.1 ION ACTIVITY VERSUS
CONCENTRATION 7 1.1.1 SOLUTION PH 8 1.1.2 MINERAL SOLUBILITY 9 1.1.3 ION
PAIRING 10 1.1.4 IONIC STRENGTH AND ION PAIRING 13 1.1.5 SPECIFIC
CONDUCTANCE 15 1.2 ACIDITY/ALKALINITY 20 1.2.1 ALKALINITY SPECIATION 22
1.2.2 NEUTRALIZATION POTENTIAL 24 1.2.3 ALKALINITY CONTRIBUTION BY CACO
3 25 1.3 PRACTICAL IMPLICATIONS 27 CHAPTER 2 ELECTROCHEMICAL AND
PHYSICAL PROPERTIES OF GEOLOGIC MATERIAL 29 2.1 INTRODUCTION 29 2.2
ALUMINOSILICATE MINERALS 29 2.3 METAL-OXIDES 30 2.4 ORGANIC MATTER 31
2.4.1 CHEMISTRY OF HUMIC SUBSTANCES 31 2.5 CLAY MINERAL SURFACE CHARGE
32 2.5.1 PERMANENT STRUCTURAL CHARGE 33 2.5.2 VARIABLE CHARGE 36 2.6
REACTION AMONG HUMIC SUBSTANCES, CLAYS, AND METALS 44 2.6.1 MECHANISMS
OF COMPLEX FORMATION 45 2.7 PZC PH AND POTENTIAL PYRITE OXIDATION
IMPLICATIONS 48 CHAPTER 3 CHEMICAL AND PHYSICAL PROPERTIES OF MINE WASTE
53 3.1 MINE WASTE 53 3.2 CHEMICAL AND PHYSICAL PROPERTIES 59 3.2.1 MINE
WASTE 1 SURFACE CHEMISTRY 63 3.2.2 TECHNIQUE COMPARISONS 65 3.2.3 MINE
WASTE SOLUTION CHEMISTRY 69 CHAPTER 4 ACID DRAINAGE PRODUCTION
CHEMISTRY AND PREDICTION 77 4.1 PYRITE OCCURRENCE, FORMATION, MORPHOLOGY
AND CHEMISTRY 77 4.2 TRANSITIONAL METAL-PYRITE OXIDATION 82 4.2.1 EFFECT
OF FERRIC HYDROXIDE SPECIES ON PYRITE OXIDATION. 83 4.2.2 GALVANIC
EFFECT ON METAL-DISULFIDE OXIDATION 85 4.2.3 FERROLYSIS 86 4.3
PREDICTING ACID DRAINAGE POTENTIAL 87 4.3.1 DETERMINATION OF POTENTIAL
ACIDITY 87 4.3.2 ACID-BASE ACCOUNTING 88 4.3.3 SIMULATED WEATHERING
TECHNIQUES 88 4.3.4 COMPUTER SIMULATION MODELS 89 CHAPTER 5 ACID
DRAINAGE CONTROL AND ITS LIMITATIONS 95 5.1 PREVENTION TECHNOLOGIES 95
5.2 ALKALINE EARTH CARBONATES 95 5.2.1 COATING LIMITATIONS 103 5.2.2
KINETIC LIMITATIONS 112 5.2.3 PLACEMENT LIMITATIONS 115 5.2.4 CHEMICAL
EQUILIBRIA LIMITATIONS 117 5.2.5 ANOXIC LIMITATIONS 121 5.3 HYDROLOGIC
INFLUENCES 126 5.4 BACTERICIDES 127 5.5 INUNDATION 128 5.6 ALKALINE
RECHARGE TRENCHES 129 5.7 WETLAND SYSTEMS 129 5.8 ORGANIC WASTE 130 5.9
MACROENCAPSULATION 130 5.10 MICROENCAPSULATION 130 PARTD MOLECULAR
CHEMISTRY OF PYRITE OXIDATION KINETICS AND PYRITE REDOX CHEMISTRY
CHAPTER 6 MECHANISMS AND KINETICS OF PYRITE OXIDATION 137 6.1 STRUCTURAL
CHEMISTRY 137 6.2 REACTION PROGRESS VARIABLES (RPV) 138 6.3 REACTION
MECHANISMS 139 6.3.1 OTHER MECHANISMS OF PYRITE OXIDATION 144 6.3.2
ELECTROCHEMICAL MECHANISMS OF PYRITE OXIDATION 147 6.4 PYRITE SURFACE
FUNCTIONAL GROUPS 148 6.4.1 PYRITE OXIDATION EFFECTS BY IRON-CARBONATE
COMPLEXES. 156 6.5 KINETICS OF PYRITE OXIDATION 159 6.5.1 EMPIRICAL
PYRITE OXIDATION RATE LAWS 161 6.5.2 APPLICATION OF PYRITE OXIDATION
KINETICS 164 6.5.3 SHRINKING CORE MODEL KINETICS 168 6.6 EFFECT OF
ANIONS ON OXIDATION OF FE 2+ 170 CHAPTER 7 PYRITE REDOX CHEMISTRY 173
7.1 GENERAL INFORMATION ON RESEARCH APPROACH 173 7.2 PYRITE STABILITY
DIAGRAMS 175 7.3 EH MEASUREMENTS 180 PART M ROLE OF BACTERIA ON PYRITE
OXIDATION CHAPTER 8 ROLE OF BACTERIA ON PYRITE OXIDATION 185 8.1
MECHANISMS OF BACTERIAL PYRITE OXIDATION 185 8.1.1 DIRECT METABOLIC
OXIDATION 187 8.1.2 INDIRECT METABOLIC OXIDATION 188 8.2 KINETICS OF
BACTERIALLY MEDIATED OXIDATION OF FE 2+ 189 8.3 MICHAELIS-MENTEN
KINETICS 193 8.3.1 MICHAELIS-MENTEN STEADY-STATE 196 8.3.2
MICHAELIS-MENTEN RAPID EQUILIBRIUM 197 8.4 SURFACE CATALYZED OXIDATION
200 8.4.1 COMPETITIVE INHIBITION 200 8.4.2 UNCOMPETITIVE INHIBITION 202
8.4.3 COMPETITIVE/UNCOMPETITIVE INHIBITION 204 8.4.4 EXPERIMENTAL DATA
205 8.5 OTHER MICROBIAL PROCESSES 211 PART IV ADVANCES ON PYRITE
MICROENCAPSULATION TECHNOLOGIES CHAPTER 9 PHOSPHATE INFLUENCE ON PYRITE
OXIDATION 215 9.1 A REVIEW 215 9.2 FUNCTIONAL PREDICTION TECHNOLOGIES
216 9.3 ABATEMENT TECHNOLOGIES 219 9.4 MICROENCAPSULATION 221 9.5
MECHANISMS 223 9.6 MICROENCAPSULATION 223 9.6.1 H 2 O 2 224 9.6.2
PHOSPHATE 226 9.6.3 EDTA 228 9.6.4 MICHAELIS-MENTEN KINETICS/APPLICATION
229 9.6.5 SURFACE ANALYSIS 231 9.6.6 EFFECTIVENESS 235 CHAPTER 10
PRELIMINARY DATA ON PYRITE MICROENCAPSULATION IN MINE WASTE 237 10.1 PH
237 10.2 TEMPERATURE 239 10.3 H 2 O 2 240 10.4 PHOSPHATE 242 10.5 SODIUM
ACETATE (NAAC) EFFECT ON PYRITE OXIDATION 244 10.6 PH, PHOSPHATE AND H 2
O 2 246 10.7 COATING EVALUATION IN LARGE COLUMNS 249 10.8 CONCLUSIONS
257 PARTV SUMMARY SUMMARY 261 REFERENCES 265 SUBJECT INDEX 287
|
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| id | DE-604.BV010584959 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:55:28Z |
| institution | BVB |
| isbn | 0849347327 |
| language | English |
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| physical | 293 S. Ill., graph. Darst. |
| publishDate | 1995 |
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| publisher | CRC Press |
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| spelling | Evangelou, V. P. Verfasser aut Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation V. P. (Bill) Evangelou Boca Raton [u.a.] CRC Press 1995 293 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Acid mine drainage Microencapsulation Pyrites Oxidation Oxidation (DE-588)4137187-2 gnd rswk-swf Pyrit (DE-588)4176502-3 gnd rswk-swf Pyrit (DE-588)4176502-3 s Oxidation (DE-588)4137187-2 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007057459&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Evangelou, V. P. Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation Acid mine drainage Microencapsulation Pyrites Oxidation Oxidation (DE-588)4137187-2 gnd Pyrit (DE-588)4176502-3 gnd |
| subject_GND | (DE-588)4137187-2 (DE-588)4176502-3 |
| title | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation |
| title_auth | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation |
| title_exact_search | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation |
| title_full | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation V. P. (Bill) Evangelou |
| title_fullStr | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation V. P. (Bill) Evangelou |
| title_full_unstemmed | Pyrite oxidation and its control solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation V. P. (Bill) Evangelou |
| title_short | Pyrite oxidation and its control |
| title_sort | pyrite oxidation and its control solution chemistry surface chemistry acid mine drainage amd molecular oxidation mechanisms microbial role kinetics control ameliorates and limitations microencapsulation |
| title_sub | solution chemistry, surface chemistry, acid mine drainage (AMD), molecular oxidation mechanisms, microbial role, kinetics, control, ameliorates and limitations, microencapsulation |
| topic | Acid mine drainage Microencapsulation Pyrites Oxidation Oxidation (DE-588)4137187-2 gnd Pyrit (DE-588)4176502-3 gnd |
| topic_facet | Acid mine drainage Microencapsulation Pyrites Oxidation Oxidation Pyrit |
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