Metals and ligand reactivity: an introduction to the organic chemistry of metal complexes
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Weinheim [u.a.]
VCH
1996
|
| Ausgabe: | New, rev. and expanded ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 308 S. Ill., graph. Darst. |
| ISBN: | 3527292772 3527292780 |
Internformat
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| 100 | 1 | |a Constable, Edwin C. |d 1955- |e Verfasser |0 (DE-588)1055760237 |4 aut | |
| 245 | 1 | 0 | |a Metals and ligand reactivity |b an introduction to the organic chemistry of metal complexes |c Edwin C. Constable |
| 250 | |a New, rev. and expanded ed. | ||
| 264 | 1 | |a Weinheim [u.a.] |b VCH |c 1996 | |
| 300 | |a XIV, 308 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Ligand |0 (DE-588)4035711-9 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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| adam_text | CONTENTS PREFACE TO THE SECOND EDITION . VII PREFACE TO THE FIRST
EDITION VIII ABBREVIATIONS AND SOME COMMON LIGANDS XIII 1 INTRODUCTION 1
1.1 GENERAL 1 1.1.1 CO-ORDINATION COMPOUNDS 1 1.2 CRYSTAL FIELD THEORY 3
1.2.1 CRYSTAL FIELD STABILISATION ENERGIES 6 1.2.2 THE SPECTROCHEMICAL
SERIES 6 1.2.3 THE NEPHELAUXETIC EFFECT 7 1.3 MOLECULAR ORBITAL AND
LIGAND FIELD THEORIES 8 1.3.1 MOLECULAR WAVE FUNCTIONS AND VALENCE BOND
THEORY 9 1.3.2 MOLECULAR ORBITAL THEORY 10 1.3.3 LIGAND FIELD THEORY 13
1.4 THE ELECTRONEUTRALITY PRINCIPLE 16 1.5 REPRISE 16 1.6 PRINCIPLES OF
REACTIVITY AND MECHANISM 16 1.6.1 THERMODYNAMIC AND KINETIC CONSTRAINTS
UPON REACTIVITY 17 1.7 SUMMARY 20 2 THE METAL-LIGAND INTERACTION 22 2.1
GENERAL 22 2.2 CONFORMATIONAL CHANGES 23 2.2.1 STERIC CONSEQUENCES OF
METAL-LIGAND BONDING 24 2.2.2 GEOMETRICAL CONSEQUENCES OF CHELATION 25
2.2.3 CHEMICAL CONSEQUENCES OF LONE PAIR NON-AVAILABILITY 30 2.3
POLARISATION OF THE LIGAND 31 2.3.1 THE NATURE OF IONIC INTERACTIONS 32
2.3.2 ENHANCEMENT OF LIGAND POLARISATION - INTRINSIC EFFECTS , . 34 2.4
*-BONDING CHANGES 39 2.4.1 SYMMETRY AND REACTIVITY 40 2.5 CONCLUSIONS 44
3 REACTIONS OF CO-ORDINATED CARBONYL COMPOUNDS WITH NUCLEOPHILES 46 3.1
GENERAL 46 3.2 NUCLEOPHILIC ATTACK ON CO-ORDINATED ESTERS AND AMIDES 48
3.2.1 ATTACK BY CO-ORDINATED NUCLEOPHILE 49 3.3 HYDROLYSIS OF AMINO ACID
ESTERS AND AMIDES 50 3.4 OTHER REACTIONS OF NUCLEOPHILES AND CARBONYL
COMPOUNDS 57 3.5 CONCLUSIONS 62 4 OTHER REACTIONS OF CO-ORDINATED
LIGANDS WITH NUCLEOPHILES 63 4.1 GENERAL 63 4.2 REACTIONS OF
NUCLEOPHILES WITH SP HYBRIDISED CARBON CENTRES 65 4.2.1 NUCLEOPHILIC
ATTACK ON CO-ORDINATED NITRILES 65 4.3 REACTIONS OF NUCLEOPHILES WITH SP
2 HYBRIDISED CARBON CENTRES 72 4.3.1 HYDROLYSIS OF IMINES 72 4.3.2
REDUCTION OF IMINES 78 4.3.3 REACTIONS OF CYANATES 78 4.4 REACTIONS OF
NUCLEOPHILES WITH SP 3 HYBRIDISED CARBON CENTRES 80 4.4.1 HYDROLYSIS OF
THIOETHERS AND RELATED REACTIONS 80 4.4.2 ARBUZOV REACTIONS 84 4.5
HYDROLYSIS OF PHOSPHATE ESTERS AND RELATED REACTIONS 85 4.6 CONCLUSIONS
87 5 STABILISATION OF ANIONS AND REACTIONS OF CO-ORDINATED LIGANDS WITH
ELECTROPHILES 89 5.1 GENERAL INTRODUCTION 89 5.2 STABILISATION OF
ENOLATES 89 5.3 REACTIVITY OF CO-ORDINATED ENOLATES WITH ELECTROPHILES
91 5.4 REACTIONS OF CO-ORDINATED AMINES 102 5.4.1 AMINE DEPROTONATION
AND THE S N L CB MECHANISM 109 5.5 FORMATION AND REACTIVITY OF IMINES
ILL 5.5.1 FORMATION BY CONDENSATION OF AN AMINE WITH A CARBONYL COMPOUND
... 112 5.5.2 TRANSIMINATION 116 5.6 REACTIONS OF CO-ORDINATED CYANIDE
119 5.7 REACTIONS OF CO-ORDINATED WATER OR HYDROXIDE 120 5.7.1
INTRAMOLECULAR ATTACK BY CO-ORDINATED HYDROXIDE 121 5.7.2 INTERMOLECULAR
ATTACK BY CO-ORDINATED HYDROXIDE 127 5.8 REACTIONS OF CO-ORDINATED
THIOLATE 128 5.9 OTHER REACTIONS OF ESTERS AND AMIDES WITH CO-ORDINATED
NUCLEOPHILES . . 133 5.10 CONCLUSIONS . 134 6 CYCLIC LIGANDS AND THE
TEMPLATE EFFECT 135 6.1 WHAT IS A MACROCYCLE? 135 6.1.1 THE SYNTHESIS OF
LARGE CYCLIC MOLECULES 136 6.2 THE TEMPLATE METHOD 138 6.2.1 WHY USE
TEMPLATE REACTIONS? 141 6.3 METAL ION CONTROL OF RING CLOSURE REACTIONS
142 6.3.1 NUCLEOPHILIC DISPLACEMENT 142 6.3.2 IMINE FORMATION 145 6.3.3
C-C BOND FORMATION 148 6.4 STOICHIOMETRY - [1+1], [2+2] OR OTHER? 150
6.5 THE MACROCYCLIC EFFECT 153 6.5.1 ORIGIN OF THE MACROCYCLIC EFFECT
154 6.6 METAL ION DEPENDENCE 158 6.6.1 MACROCYCLIC HOLE SIZE - AN ABUSED
CONCEPT 158 6.7 CONSEQUENCES OF METAL ION/HOLE SIZE MISMATCH 162 6.7.1
THE METAL ION DOES NOT ACT AS A TEMPLATE 163 6.7.2 CONTROL OVER THE RING
SIZE 163 6.7.3 CONFORMATIONAL CHANGE MAY ALTER THE APPARENT HOLE SIZE
165 6.7.4 MISMATCH IN SIZES MAKES THE METAL ION LABILE 167 6.7.5
METAL-DIRECTED REARRANGEMENT TO PRODUCE A MORE SUITABLE CAVITY .... 168
6.7.6 REARRANGEMENT RELATED TO CO-ORDINATION GEOMETRY 174 6.8
MULTICOMPONENT ASSEMBLY OF MACROCYCLES 175 6.9 INTO THE THIRD DIMENSION
179 6.10 CONCLUSIONS 180 7 THE THREE-DIMENSIONAL TEMPLATE EFFECT,
SUPRAMOLECULAR CHEMISTRY AND MOLECULAR TOPOLOGY 183 7.1 THE
THREE-DIMENSIONAL TEMPLATE EFFECT 183 7.2 TEMPLATE CONDENSATIONS AT
KINETICALLY INERT OCTAHEDRAL METAL CENTRES . . 183 7.2.1 MOLECULAR
TOPOLOGY 185 7.2.2 MORE ENCAPSULATING LIGANDS FROM TWO REACTANTS 187
7.2.3 ENCAPSULATING LIGANDS FROM MORE THAN TWO COMPONENTS 188 7.2.4 SOME
MECHANISTIC AND STEREOCHEMICAL ASPECTS OF SEPULCHRATES AND RELATED
ENCAPSULATING LIGANDS 199 7.3 SUPRAMOLECULAR CHEMISTRY 202 7.3.1 WHAT IS
SUPRAMOLECULAR CHEMISTRY? 202 7.3.2 MOLECULAR RECOGNITION,
COMPLEMENTARITY AND SELF-ASSEMBLY 205 7.3.3 METAL ION COMPLEMENTARITY
AND METALLOSUPRAMOLECULAR CHEMISTRY .... 210 7.4 BUILDING HELICAL
COMPLEXES 212 7.4.1 DOUBLE-HELICAL STRUCTURES 212 7.4.2 TRIPLE-HELICAL
STRUCTURES 218 7.5 CATENANES - MOLECULAR DAISY CHAINS 221 7.6 TYING
MOLECULES IN KNOTS 228 7.7 CONCLUSIONS 231 8 AROMATIC AND HETEROCYCLIC
LIGANDS 233 8.1 INTRODUCTION 233 8.2 ELECTROPHILIC AROMATIC SUBSTITUTION
233 8.3 NUCLEOPHILIC AROMATIC SUBSTITUTION 236 8.4 HETEROAROMATIC
LIGANDS 240 8.5 REACTIONS OF FIVE-MEMBERED HETEROCYCLES 241 8.6
NUCLEOPHILIC REACTIONS OF CO-ORDINATED PYRIDINES 245 8.7 ELECTROPHILIC
REACTIONS OF CO-ORDINATED PYRIDINES 258 8.8 SUMMARY 261 9 OXIDATION AND
REDUCTION OF CO-ORDINATED LIGANDS 263 9.1 INTRODUCTION - THE MEANING OF
OXIDATION AND REDUCTION 263 9.2 OXIDATION BY LOSS OF ELECTRONS 265 9.3
OXIDATION BY C-H BOND CLEAVAGE 271 9.4 OXIDATION BY OXYGEN ATOM TRANSFER
278 9.5 SUMMARY 287 10 ENVOI 288
|
| any_adam_object | 1 |
| author | Constable, Edwin C. 1955- |
| author_GND | (DE-588)1055760237 |
| author_facet | Constable, Edwin C. 1955- |
| author_role | aut |
| author_sort | Constable, Edwin C. 1955- |
| author_variant | e c c ec ecc |
| building | Verbundindex |
| bvnumber | BV010409235 |
| classification_rvk | VH 9700 |
| classification_tum | CHE 332f CHE 334f CHE 331f |
| ctrlnum | (OCoLC)246808180 (DE-599)BVBBV010409235 |
| discipline | Chemie / Pharmazie Chemie |
| edition | New, rev. and expanded ed. |
| format | Book |
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| id | DE-604.BV010409235 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:52:01Z |
| institution | BVB |
| isbn | 3527292772 3527292780 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006932228 |
| oclc_num | 246808180 |
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| physical | XIV, 308 S. Ill., graph. Darst. |
| publishDate | 1996 |
| publishDateSearch | 1996 |
| publishDateSort | 1996 |
| publisher | VCH |
| record_format | marc |
| spelling | Constable, Edwin C. 1955- Verfasser (DE-588)1055760237 aut Metals and ligand reactivity an introduction to the organic chemistry of metal complexes Edwin C. Constable New, rev. and expanded ed. Weinheim [u.a.] VCH 1996 XIV, 308 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Ligand (DE-588)4035711-9 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 gnd rswk-swf Reaktivität (DE-588)4208182-8 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 s Ligand (DE-588)4035711-9 s Reaktivität (DE-588)4208182-8 s DE-604 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006932228&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Constable, Edwin C. 1955- Metals and ligand reactivity an introduction to the organic chemistry of metal complexes Ligand (DE-588)4035711-9 gnd Metallkomplexe (DE-588)4038898-0 gnd Reaktivität (DE-588)4208182-8 gnd |
| subject_GND | (DE-588)4035711-9 (DE-588)4038898-0 (DE-588)4208182-8 |
| title | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes |
| title_auth | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes |
| title_exact_search | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes |
| title_full | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes Edwin C. Constable |
| title_fullStr | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes Edwin C. Constable |
| title_full_unstemmed | Metals and ligand reactivity an introduction to the organic chemistry of metal complexes Edwin C. Constable |
| title_short | Metals and ligand reactivity |
| title_sort | metals and ligand reactivity an introduction to the organic chemistry of metal complexes |
| title_sub | an introduction to the organic chemistry of metal complexes |
| topic | Ligand (DE-588)4035711-9 gnd Metallkomplexe (DE-588)4038898-0 gnd Reaktivität (DE-588)4208182-8 gnd |
| topic_facet | Ligand Metallkomplexe Reaktivität |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006932228&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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