Diazo chemistry: 2 Aliphatic, inorganic and organometallic compounds
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim [u.a.]
VCH
1995
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 522 S. graph. Darst. |
| ISBN: | 3527292225 |
Internformat
MARC
| LEADER | 00000nam a2200000 cc4500 | ||
|---|---|---|---|
| 001 | BV010337798 | ||
| 003 | DE-604 | ||
| 005 | 19950904 | ||
| 007 | t | ||
| 008 | 950811s1995 d||| |||| 00||| eng d | ||
| 020 | |a 3527292225 |9 3-527-29222-5 | ||
| 035 | |a (OCoLC)312359851 | ||
| 035 | |a (DE-599)BVBBV010337798 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-29T |a DE-355 |a DE-91G |a DE-19 |a DE-703 |a DE-634 |a DE-11 |a DE-188 | ||
| 082 | 0 | |a 547.043 |2 20 | |
| 084 | |a VK 7400 |0 (DE-625)147419:253 |2 rvk | ||
| 100 | 1 | |a Zollinger, Heinrich |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Diazo chemistry |n 2 |p Aliphatic, inorganic and organometallic compounds |c Heinrich Zollinger |
| 264 | 1 | |a Weinheim [u.a.] |b VCH |c 1995 | |
| 300 | |a XIII, 522 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Diazo compounds | |
| 773 | 0 | 8 | |w (DE-604)BV009693990 |g 2 |
| 856 | 4 | 2 | |m GBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006880512&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-006880512 | ||
Datensatz im Suchindex
| _version_ | 1804124758972825600 |
|---|---|
| adam_text | HEINRICH ZOLLINGER DIAZO CHEMISTRY II ALIPHATIC, INORGANIC AND
ORGANOMETALLIC COMPOUNDS VCH WEINHEIM * NEW YORK BASEL * CAMBRIDGE *
TOKYO CONTENTS SYMBOLS, QUANTITIES AND UNITS XV ABBREVIATIONS AND
ACRONYMS XVI 1 INTRODUCTION 1 1.1 HISTORY OF ALIPHATIC, INORGANIC, AND
ORGANOMETALLIC DIAZO COMPOUNDS 1 1.2 NOMENCLATURE AND GENERAL REFERENCES
5 2 METHODS FOR THE PREPARATION OF ALKANE, ALKENE, AND ALKYNE DIAZO
COMPOUNDS 11 2.1 STABLE ALIPHATIC DIAZONIUM IONS 11 2.2 INTRODUCTION TO
THE METHODS FOR THE SYNTHESIS OF ALIPHATIC DIAZO COMPOUNDS 15 2.3
PREPARATION OF ALIPHATIC DIAZO COMPOUNDS BY NITROSATION OF ALIPHATIC
AMINES 20 2.4 CLEAVAGE OF N-ALKYL-YV-NITROSO AMIDES 28 2.5 SYNTHESES
STARTING WITH KETONES OR ALDEHYDES 34 2.5.1 DEHYDROGENATION OF
HYDRAZONES 34 2.5.2 BAMFORD-STEVENS REACTION 40 2.5.3 FORSTER REACTION
46 2.5.4 MISCELLANEOUS REACTIONS 47 2.6 DIAZO TRANSFER TO ACTIVE
METHYLENE COMPOUNDS 48 2.7 DIAZO TRANSFER TO ALKENES 63 2.8 DIAZO
TRANSFER TO ALKYNES 75 2.9 DIAZOETHENE AND ITS DERIVATIVES 81 2.10
SYNTHESIS OF ALKENEDIAZONIUM SALTS 83 2.11 SYNTHESIS OF COMPOUNDS WITH A
C SP -ATTACHED DIAZONIO GROUP 91 3 INORGANIC DIAZO COMPOUNDS AND METAL
COMPLEXES WITH DINITROGEN AS LIGAND 95 3.1 ADDITION PRODUCTS OF
DINITROGEN TO NONMETALLIC INORGANIC SPECIES 95 3.2 DIAZO DERIVATIVES OF
POLYHEDRAL BORON HYDRIDES 101 3.3 ADDITION PRODUCTS OF DINITROGEN TO
TRANSITION METAL COMPLEXES 107 3.4 SHORT REVIEW ON THE CHEMISTRY OF
NITROGEN FIXATION 114 4 KINETICS AND MECHANISM OF ALIPHATIC
DIAZOTIZATIONS 121 4.1 NITROSATION OF ALKYLAMINES 121 4.2
CARCINOGENICITY OF IV-NITROSOAMINES 127 XII CONTENTS 4.3 MECHANISMS OF
DIAZOALKANE SYNTHESES 132 4.4 ACID-BASE EQUILIBRIA OF ALIPHATIC DIAZO
COMPOUNDS 138 5 THE STRUCTURE OF ALIPHATIC DIAZO COMPOUNDS 145 5.1
ALIPHATIC DIAZONIUM IONS 145 5.2 DIAZOALKANES AND RELATED COMPOUNDS 146
5.3 THEORETICAL INVESTIGATIONS ON ALIPHATIC DIAZONIUM SALTS, AND ON
ALKANE, ALKENE, AND ALKYNE DIAZO COMPOUNDS 161 5.4 ISOMERS OF
DIAZOMETHANE 173 6 REACTIONS OF ALIPHATIC DIAZO AND DIAZONIUM COMPOUNDS
NOT INVOLVING INITIAL DEDIAZONIATION 191 6.1 AZO COUPLING REACTIONS OF
ALIPHATIC DIAZONIUM IONS AND RELATED PROCESSES 191 6.2 INTRODUCTION TO
1,3-DIPOLAR CYCLOADDITIONS 195 6.3 MECHANISM OF 1,3-DIPOLAR
CYCLOADDITIONS 200 6.4 REGIO- AND DIASTEREOSELECTIVITY OF DIPOLAR
CYCLOADDITIONS WITH DIAZOALKANES 212 6.5 CYCLOADDITION REACTIONS WITH
DIAZOALKANES IN ORGANIC SYNTHESIS 228 7 DEDIAZONIATION REACTIONS
INVOLVING DIAZONIUM ION INTERMEDIATES 241 7.1 INTRODUCTION TO
DEAMINATION MECHANISMS 241 7.2 ROUTES TO ALKANEDIAZONIUM IONS 244 7.3
DEAMINATION MECHANISMS OF OPEN-CHAIN AMINES: SUBSTITUTION PRODUCTS 253
7.4 ELIMINATIONS AND REARRANGEMENTS IN DEAMINATION OF OPEN-CHAIN AMINES
271 7.5 DEAMINATION OF ALICYCLIC AMINES 278 7.6 A CHALLENGE TO REVISIT
DEAMINATION MECHANISMS 290 7.7 SYNTHETIC APPLICATIONS OF DEAMINATION
REACTIONS 295 7.8 SUMMARY AND OUTLOOK (BY WOLFGANG KIRMSE) 302 8
DEDIAZONIATION REACTIONS INVOLVING CARBENE AND CARBENOID INTERMEDIATES
305 8.1 INTRODUCTION TO GENERAL CARBENE CHEMISTRY 305 8.2 FORMATION OF
CARBENES AND CARBENOIDS BY DEDIAZONIATION OF DIAZOALKANES 314 8.3
ADDITION OF CARBENES TO ALKENES 318 8.4 ADDITION OF CARBENES AND CARBENE
PRECURSORS TO AROMATIC HYDROCARBONS AND TO FULLERENE[60] 324 8.5
INSERTION, ABSTRACTION, AND REARRANGEMENT REACTIONS OF CARBENES 335 8.6
CARBENES FROM A-DIAZOCARBONYL COMPOUNDS: THE WOLFF REARRANGEMENT AND THE
ARNDT-EISTERT REACTION 344 8.7 TRANSFORMATIONS INVOLVING METAL
CARBENOIDS 358 8.8 ENANTIOSELECTIVE REACTIONS OF CARBENOIDS 373 CONTENTS
XIII 9 MISCELLANEOUS REACTIONS INVOLVING DIAZO AND RELATED COMPOUNDS 38
3 9.1 ELECTROPHILIC AND NUCLEOPHILIC SUBSTITUTION AT THE C(A)-ATOM OF
DIAZO COMPOUNDS 383 9.2 THE N(/3)-ELECTROPHILICITY OF ALIPHATIC DIAZO
COMPOUNDS 395 9.3 ELECTRON TRANSFER TO AND FROM DIAZO COMPOUNDS: ION
RADICALS 400 9.4 OXIDATIONS AND REDUCTIONS OF DIAZO COMPOUNDS 408 9.5
DEDIAZONIATIONS OF ALKENEDIAZONIUM IONS 414 10 METAL COMPLEXES OF
DIAZONIUM AND DIAZO COMPOUNDS 421 10.1 STRUCTURE OF METAL COMPLEXES
CONTAINING ARENEDIAZONIUM IONS AS LIGANDS 421 10.2 SYNTHESIS OF
ARYLDIAZENIDO METAL COMPLEXES 430 10.3 DIAZOALKANES AS LIGANDS IN
TRANSITION METAL COMPLEXES 439 11 EPILOGUE: FROM PETER GRIESS DISCOVERY
TO ORGANOMETALLIC DIAZO COMPOUNDS 455 REFERENCES 459 INDEX 507
|
| any_adam_object | 1 |
| author | Zollinger, Heinrich |
| author_facet | Zollinger, Heinrich |
| author_role | aut |
| author_sort | Zollinger, Heinrich |
| author_variant | h z hz |
| building | Verbundindex |
| bvnumber | BV010337798 |
| classification_rvk | VK 7400 |
| ctrlnum | (OCoLC)312359851 (DE-599)BVBBV010337798 |
| dewey-full | 547.043 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.043 |
| dewey-search | 547.043 |
| dewey-sort | 3547.043 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01194nam a2200313 cc4500</leader><controlfield tag="001">BV010337798</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">19950904 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">950811s1995 d||| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3527292225</subfield><subfield code="9">3-527-29222-5</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)312359851</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV010337798</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-29T</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-91G</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-634</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.043</subfield><subfield code="2">20</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VK 7400</subfield><subfield code="0">(DE-625)147419:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zollinger, Heinrich</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Diazo chemistry</subfield><subfield code="n">2</subfield><subfield code="p">Aliphatic, inorganic and organometallic compounds</subfield><subfield code="c">Heinrich Zollinger</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Weinheim [u.a.]</subfield><subfield code="b">VCH</subfield><subfield code="c">1995</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIII, 522 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Diazo compounds</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="w">(DE-604)BV009693990</subfield><subfield code="g">2</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">GBV Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006880512&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-006880512</subfield></datafield></record></collection> |
| id | DE-604.BV010337798 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:50:46Z |
| institution | BVB |
| isbn | 3527292225 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006880512 |
| oclc_num | 312359851 |
| open_access_boolean | |
| owner | DE-29T DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-703 DE-634 DE-11 DE-188 |
| owner_facet | DE-29T DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-703 DE-634 DE-11 DE-188 |
| physical | XIII, 522 S. graph. Darst. |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | VCH |
| record_format | marc |
| spelling | Zollinger, Heinrich Verfasser aut Diazo chemistry 2 Aliphatic, inorganic and organometallic compounds Heinrich Zollinger Weinheim [u.a.] VCH 1995 XIII, 522 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Diazo compounds (DE-604)BV009693990 2 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006880512&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zollinger, Heinrich Diazo chemistry Diazo compounds |
| title | Diazo chemistry |
| title_auth | Diazo chemistry |
| title_exact_search | Diazo chemistry |
| title_full | Diazo chemistry 2 Aliphatic, inorganic and organometallic compounds Heinrich Zollinger |
| title_fullStr | Diazo chemistry 2 Aliphatic, inorganic and organometallic compounds Heinrich Zollinger |
| title_full_unstemmed | Diazo chemistry 2 Aliphatic, inorganic and organometallic compounds Heinrich Zollinger |
| title_short | Diazo chemistry |
| title_sort | diazo chemistry aliphatic inorganic and organometallic compounds |
| topic | Diazo compounds |
| topic_facet | Diazo compounds |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006880512&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV009693990 |
| work_keys_str_mv | AT zollingerheinrich diazochemistry2 |