Rigid polymer networks:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | German |
| Published: |
Berlin [u.a.]
Springer
1994
|
| Series: | Advances in polymer science
118 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 214 - 231 |
| Physical Description: | XVI, 240 S. graph. Darst. |
| ISBN: | 3540583408 0387583408 |
Staff View
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| 100 | 1 | |a Aharoni, Shaul M. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Rigid polymer networks |c by S. M. Aharoni ; S. F. Edwards |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1994 | |
| 300 | |a XVI, 240 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Advances in polymer science |v 118 | |
| 500 | |a Literaturverz. S. 214 - 231 | ||
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| 650 | 7 | |a Polymeren |2 gtt | |
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| 650 | 7 | |a Réseaux polymères |2 ram | |
| 650 | 7 | |a Vloeibare kristallen |2 gtt | |
| 650 | 4 | |a Polymer networks | |
| 650 | 4 | |a Polymers | |
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Record in the Search Index
| _version_ | 1805067230210162688 |
|---|---|
| adam_text |
TABLE
OF
CONTENTS
LIST
OF
SYMBOLS
.
XIII
1
INTRODUCTION
.
1
1.1
DEFINITIONS
.
1
1.2
GENERAL
CLASSIFICATION
OF
LIQUID-CRYSTAL
POLYMERS
AND
NETWORKS
.
7
1.2.1
DEFINITION
OF
LIQUID-CRYSTAL
POLYMERS
.
8
1.2.2
FLEXIBLE
CHAIN
POLYMERS
WITH
MESOGENIC
GROUPS
.
10
1.2.3
NETWORKS
WITH
FLEXIBLE
CHAINS
AND
STIFF
MESOGENIC
GROUPS
.
13
1.2.3.1
NETWORKS
WITH
STIFF
MAIN-CHAIN
MESOGENS,
FLEXIBLE
SPACERS
AND
FLEXIBLE
JUNCTIONS
.
13
1.2.3.2
NETWORKS
WITH
STIFF
MAIN-CHAIN
MESOGENS,
FLEXIBLE
SPACERS
AND
RIGID
BRANCHPOINTS
.
16
1.2.3.3
NETWORKS
WITH
STIFF
PENDANT
MESOGENS,
FLEXIBLE
MAIN-CHAINS
AND
FLEXIBLE
JUNCTIONS
.
18
1.2.3.4
NETWORKS
WITH
STIFF
PENDANT
MESOGENS
CONNECTED
AT
BOTH
ENDS
TO
FLEXIBLE
MAIN
CHAINS
.
21
1.2.4
NETWORKS
CONTAINING
NO
FLEXIBLE
SPACERS
.
25
1.2.4.1
UNIFORM
MAIN-CHAIN
MESOGENICITY:
FLEXIBLE,
WORMLIKE,
RODLIKE
.
26
1.2.4.2
LCPS
FROM
BIOLOGICAL
ORIGIN
AND
THEIR
NETWORKS
.
33
1.2.4.3
NETWORKS
WITH
UNIFORM
MAIN-CHAIN
MESOGENI-CITY
AND
FLEXIBLE
CROSSLINKING
RESIDUES
.
.
34
1.3
THE
FRACTAL
CHARACTER
OF
PRE-GEL
AND
POST-GEL
HIGHLY
BRANCHED
POLYMERS
.
38
2
EXCLUSIONS
.
43
3
SYNTHETIC
HIGHLIGHTS
.
46
3.1
ONE-STEP
AND
END-CAPPED
RIGID
NETWORKS
.
46
3.1.1
NETWORKS
WITH
STIFF
HYDROCARBON
SEGMENTS
.
46
3.1.1.1
POLYPHENYLENES
AND
POLY
(SUBSTITUTED
PHENYLENES)
.
.46
3.1.1.2
HYDROCARBON
NETWORKS
WITH
VERY
SHORT
AROMATIC
SEGMENTS
.
48
X
TABLE
OF
CONTENTS
3.1.1.3
STIFF
ALIPHATIC
SEGMENTS
.
52
3.1.1.4
OVERVIEW
.
52
3.1.2
AROMATIC
POLYAMIDE
NETWORKS
WITH
STIFF
SEGMENTS
AND
RIGID
BRANCHPOINTS
.
54
3.1.2.1
RIGID
POLYAMIDE
NETWORKS,
GELS
AND
FRACTAL
POLYMERS
PREPARED
IN
SOLUTION
IN
THE
PRESENCE
OF
TRIARYLPHOSPHITE
.
54
3.1.2.2
RIGID
POLYAMIDE
NETWORKS
AND
FRACTAL
POLYMERS
PREPARED
IN
SOLUTION
BY
OTHER
PROCEDURES
.
66
3.1.3
RIGID
AROMATIC
POLYESTER
NETWORKS
.
68
3.1.4
RIGID
AROMATIC
NETWORKS
CONTAINING
SINGLE-ATOM
BRIDGES
.
70
3.1.4.1
AROMATIC
HYDROCARBONS
WITH
METHYLENE
BRIDGES
.
.
.72
3.1.4.2
PHENOL-FORMALDEHYDE
TYPE
NETWORKS
.
73
3.1.4.3
FURAN-CONTAINING
NETWORKS
.
76
3.1.4.4
AROMATIC
POLYETHER
AND
ETHER-CONTAINING
NETWORKS
.
78
3.1.4.5
BRIDGED
AROMATIC
NETWORKS
WITH
UNCOMMON
ELECTRONIC
STRUCTURE
.
80
3.1.4.6
MORPHOLOGY
AND
POSSIBLE
FRACTALITY
.
84
3.1.5
RIGID
NETWORKS
WITH
TRIAZINE
BRANCHPOINTS
.
85
3.1.6
RIGID
NETWORKS
FROM
STIFF
END-CAPPED
SEGMENTS
.
92
3.1.6.1
NETWORKS
WITH
UNSATURATED
IMIDE
JUNCTION
PRECURSORS
.
93
3.1.6.2
NETWORKS
CROSSLINKED
BY
STRAINED-RING
PRECURSORS
.96
3.1.6.3
NETWORKS
CROSSLINKED
BY
ETHYNYL
END-CAPS
AND
PENDANT
GROUPS
.
102
3.2
TWO-STEP
AROMATIC
NETWORKS
.
107
3.2.1
TWO-STEP
AROMATIC
POLYAMIDE
NETWORKS
.
108
3.2.2.
TWO-STEP
NETWORKS
FROM
POLY
(ETHER
KETONE
KETONE)
(PEKK)
.
112
3.2.3
NETWORKS
FROM
AROMATIC
LINEAR
CHAINS
CREATED
BY
REACTING
BACKBONE
DIACETYLENE
OR
PENDANT
ACETYLENE
GROUPS
.
113
3.2.4
POTENTIAL
TWO-STEP
POLYARYLENE
NETWORKS
.
116
3.2.5
SUPERNETWORKS
.
117
4
FEATURES
.
121
4.1
PRE-GEL
STATE
.
121
4.1.1
FRACTAL
NATURE
OF
GROWING
ONE-STEP
SPECIES
AND
COMPARISON
WITH
TWO-STEP
SPECIES
.
121
4.1.2
C
O
*,
THE
CRITICAL
CONCENTRATION
FOR
GELATION
.
135
4.2
POST-GEL
STATE
.
142
4.2.1
FRACTAL
NATURE
OF
GELLED
RIGID
NETWORKS
.
142
4.2.2
MANIFESTATIONS
OF
RIGID
NETWORK
DEFECTS
.
149
4.2.3
MECHANICAL
PROPERTIES
OF
RIGID
NETWORKS
AND
THEIR
GELS
.
152
TABLE
OF
CONTENTS
XI
4.2.4
OBSERVATIONS
ON
EFFECTS
OF
GRAVITY
AND
FLOW-STRESS
DURING
THE
FORMATION
OF
RIGID
NETWORK
GELS
.
155
4.2.5
HIGH
TEMPERATURE
STABILITY
OF
RIGID
AROMATIC
NETWORKS.
.
157
4.3
SOME
PROPERTIES
OF
LIQUID-CRYSTAL
POLYMER
NETWORKS
.
159
4.4
MODES
OF
SEGMENTAL
DEFORMATION
.
161
4.4.1
DESCRIPTION
OF
SEGMENTS
.
161
4.4.1.1
MATHEMATICAL
DESCRIPTION
OF
THE
MOLECULES
.
161
4.4.1.2
GENERAL
EMPIRICAL
DESCRIPTION
OF
NETWORK
SEGMENTS
.
164
4.4.2
DEFORMATION
OF
AROMATIC
SEGMENTS
WITH
BRIDGES
CONSISTING
EXCLUSIVELY
OF
COAXIAL
SINGLE
BONDS
.
166
4.4.3
DEFORMATION
OF
STIFF
AROMATIC
SEGMENTS
WITH
BRIDGES
CONSISTING
OF
A
SINGLE
NON-COAXIAL
BOND
CONNECTING
TWO
COAXIAL
BONDS
BETWEEN
AROMATIC
GROUPS
.
168
4.4.4
DEFORMATION
OF
AROMATIC
SEGMENTS
WITH
SWIVELS
CONSISTING
OF
TWO
SINGLE
BONDS
CONNECTED
BY
A
SINGLE
ATOM
.
175
4.4.5
DEFORMATION
OF
NETWORKS
WITH
STIFF
AROMATIC
SEGMENTS
AND
RELATIVELY
FLEXIBLE
ALIPHATIC
JUNCTIONS
CREATED
FROM
REACTIVE
END-CAPS
.
177
4.5
QUESTIONS
OF
ELASTIC
CONSTANTS
.
179
5.
THEORY
.
192
5.1.
THE
PROBLEM
.
193
5.1.1
RESPONSES
OF
FLEXIBLE
AND
RIGID
NETWORKS
TO
STRESS
FIELDS
.
193
5.1.2
COMPLEXITIES
UNIQUELY
LINKED
TO
NETWORK
RIGIDITY
.
193
5.2
THEORETICAL
DESCRIPTION
OF
RIGID
NETWORKS
.
194
5.2.1
ONE-STEP
NETWORKS
.
194
5.2.1.1
GENERAL
MATHEMATICAL
DESCRIPTION
.
200
5.2.1.2
FIELD
FORMALISM
FOR
DEFORMATION
.
203
5.3
SIMPLER
THEORETICAL
APPROACHES
.
206
5.3.1
SIMPLE
CALCULATIONS
OF
THE
CONCENTRATED
RIGID
NETWORK
.
206
5.3.2
SIMPLE
CALCULATIONS
IN
A
DILUTE
RIGID
NETWORK
.
208
6
REFERENCES
.
214
AUTHOR
INDEX
VOLUMES
101-118
.
233
SUBJECT
INDEX
.
239 |
| any_adam_object | 1 |
| author | Aharoni, Shaul M. Edwards, Sam F. |
| author_facet | Aharoni, Shaul M. Edwards, Sam F. |
| author_role | aut aut |
| author_sort | Aharoni, Shaul M. |
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| callnumber-sort | QD 3281 P6 |
| callnumber-subject | QD - Chemistry |
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| classification_tum | CHE 713f |
| ctrlnum | (OCoLC)31725762 (DE-599)BVBBV010125395 |
| dewey-full | 547.7 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.7 |
| dewey-search | 547.7 |
| dewey-sort | 3547.7 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV010125395 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T03:30:56Z |
| institution | BVB |
| isbn | 3540583408 0387583408 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006724467 |
| oclc_num | 31725762 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-19 DE-BY-UBM DE-83 DE-11 DE-188 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-19 DE-BY-UBM DE-83 DE-11 DE-188 |
| physical | XVI, 240 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | Springer |
| record_format | marc |
| series | Advances in polymer science |
| series2 | Advances in polymer science |
| spelling | Aharoni, Shaul M. Verfasser aut Rigid polymer networks by S. M. Aharoni ; S. F. Edwards Berlin [u.a.] Springer 1994 XVI, 240 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advances in polymer science 118 Literaturverz. S. 214 - 231 Netwerkpolymeren gtt Polymeren gtt Polymères ram Réseaux polymères ram Vloeibare kristallen gtt Polymer networks Polymers Starrer Körper (DE-588)4182935-9 gnd rswk-swf Polymeres Netzwerk (DE-588)4307122-3 gnd rswk-swf Polymeres Netzwerk (DE-588)4307122-3 s Starrer Körper (DE-588)4182935-9 s DE-604 Edwards, Sam F. Verfasser aut Advances in polymer science 118 (DE-604)BV000000292 118 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006724467&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Aharoni, Shaul M. Edwards, Sam F. Rigid polymer networks Advances in polymer science Netwerkpolymeren gtt Polymeren gtt Polymères ram Réseaux polymères ram Vloeibare kristallen gtt Polymer networks Polymers Starrer Körper (DE-588)4182935-9 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd |
| subject_GND | (DE-588)4182935-9 (DE-588)4307122-3 |
| title | Rigid polymer networks |
| title_auth | Rigid polymer networks |
| title_exact_search | Rigid polymer networks |
| title_full | Rigid polymer networks by S. M. Aharoni ; S. F. Edwards |
| title_fullStr | Rigid polymer networks by S. M. Aharoni ; S. F. Edwards |
| title_full_unstemmed | Rigid polymer networks by S. M. Aharoni ; S. F. Edwards |
| title_short | Rigid polymer networks |
| title_sort | rigid polymer networks |
| topic | Netwerkpolymeren gtt Polymeren gtt Polymères ram Réseaux polymères ram Vloeibare kristallen gtt Polymer networks Polymers Starrer Körper (DE-588)4182935-9 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd |
| topic_facet | Netwerkpolymeren Polymeren Polymères Réseaux polymères Vloeibare kristallen Polymer networks Polymers Starrer Körper Polymeres Netzwerk |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006724467&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000000292 |
| work_keys_str_mv | AT aharonishaulm rigidpolymernetworks AT edwardssamf rigidpolymernetworks |