Chemistry in nuclear technology:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Reading, Mass. [u.a]
Addison-Wesley
1963
|
| Schriftenreihe: | Addison-Wesley series in nuclear science and engineering
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 374 S. |
Internformat
MARC
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| 245 | 1 | 0 | |a Chemistry in nuclear technology |c by Sigfred Peterson ; Raymond G. Wymer |
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| 650 | 4 | |a Radiochimie | |
| 650 | 4 | |a Nuclear engineering | |
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Datensatz im Suchindex
| _version_ | 1804124375263215616 |
|---|---|
| adam_text | CHEMISTRY
INNUCLEAR
TECHNOLOGY
by
SIGFREDPETERSON
and
RAYMONDGWYMER
Oak Ridge National Laborato-y
A
••
ADDISON-WESLEYPUBLISHINGCOMPANY,INC
READING,MASSACHUSETTS • PALOAITO • LONDON
CONTENTS
CHAPTER 1 INTRODUCTION
1-1 Nuclear reactors 1
1-2 Fuel for the nuclear rcactor 5
1-3 The recovery of spent reactor fuel 8
1-4 Chemistry of nonfuel reactor materials 9
CHAPTER 2 GENERAL CHEMICAL FUNDAMENTALS
2-1 The periodic table and structural chemistry 12
2-2 Solubility 18
2-3 Reversibility and chemical equilibria 19
2-4 Acid, base, and water ionization 21
2-5 Complex formation 25
2-6 Distribution equilibrium 26
2-7 Oxidation and reduction 28
2-8 Inorganic chemical nomenclature 30
2-9 Electromotive force and oxidation-reduction reactions 30
2-10 Thermodynamic representation of chemical forces 35
CHAPTER 3 RADIOACTIVITY AND NUCLEAR REACTIONS
3-1 Elementary properties of nuclei 41
3-2 Modes of radioactive decay 43
3-3 Rates of radioactive decay 49
3-4 Nuclear reactions 54
3-5 Nuclear fission 59
3-6 Nonfission reactions in nuclear reactors 62
CHAPTER 4 RADIOCHEMISTRY
4-1 Introduction 73
4-2 Adsorption 74
4-3 Radiochemical precipitation 75
4-4 Solvent extraction 77
4-5 Ion exchange 78
4-6 Gas radiochemistry 82
4-7 Oxidation-reduction 83
4-8 Analytical radiochemistry 84
4-9 Detection and measurement of radioactivity 85
CHAPTER 5 THE FISSION PRODUCTS
5-1 Fission-product yields 93
vii
Vlll CONTENTS
5-2 Estimation of fission-product activities and energies 98
5-3 Chemical and radioactive properties of the fission products 106
5-4 Selection of important fission products 113
CHAPTER 6 THE CHEMISTRY OF THORIUM AND PROTACTINIUM
6-1 Thorium and its compounds 117
6-2 The chemistry of thorium solutions 121
6-3 Protactinium 125
CHAPTER 7 URANIUM AND ITS COMPOUNDS
7-1 Uranium metal 131
7-2 Uranium hydride 133
7-3 Oxides 133
7-4 Fluorides 134
7-5 Chlorides, bromides, and iodides 138
7-6 Uranium oxyhalides 140
7-7 Uranium sulfides, selenides, and tellurides 140
7-8 Uranium compounds with other nonmetals 141
7-9 Organic compounds of uranium 142
CHAPTER 8 URANIUM SOLUTION CHEMISTRY
8-1 The oxidation states of uranium in aqueous solution 146
8-2 Uranium(IV) solutions 147
8-3 Uranium(VI) solutions 149
8-4 Solvent extraction of uranium(VI) 156
8-5 Nonaqueous uranium solutions 161
CHAPTER 9 THE TRANSURANIUM ELEMENTS
9-1 Importance of the transuranium elements 164
9-2 The general nature of the transuranium elements 165
9-3 Neptunium 166
9-4 The chemistry of plutonium in solution 168
9-5 Plutonium and its compounds 172
9-6 Americium 173
9-7 Curium 175
9-8 Transcurium elements 176
CHAPTER 10 RECOVERY OF URANIUM AND THORIUM FROM ORES
10-1 Sources of uranium and thorium 182
10-2 Processing of uranium ores 184
10-3 Uranium refining and chemical conversion 192
10-4 Thorium production 197
CONTENTS IX
CHAPTER 11 DISSOLUTION OF NUCLEAR FUELS
11-1 Nuclear fuel elements 203
11-2 Cladding removal 205
11-3 Dissolution of uranium metal fuel 210
11-4 Dissolution of uranium-aluminum alloy fuel 212
11-5 Dissolution of zirconium-alloy fuel 214
11-6 Dissolution of uranium oxide fuel 215
11-7 Dissolution of thorium-uranium oxide fuel 218
11-8 Dissolution of advanced gas-cooled reactor fuels 218
CHAPTER 12 PROCESSING OF IRRADIATED REACTOR FUELS
12-1 Radiation effects 222
12-2 Solvent extraction from aqueous systems 227
12-3 Redox Process 231
12-4 Purex Process 234
12-5 Thorex Process 237
12-6 TBP-25 Process 240
12-7 Ion exchange 240
12-8 Precipitation 243
12-9 Fluoride volatility processing 246
12-10 Pyroprocessing 250 -
CHAPTER 13 RADIOCHEMICAL PROCESSING PLANT,-
13-1 The layout of the radiochemical plant 260
13-2 The remotely operated processing area 262
13-3 Shielding of radiochemical plants 264
13-4 Processing of high-level alpha activity 268
13-5 Control of criticality 269
13-6 Maintenance of radiochemical plants 273
13-7 Economic considerations in radiochemical plants 276
CHAPTER 14 DISPOSAL AND TREATMENT OF RADIOACTIVE WASTES
14-1 Sources of radioactive wastes 280
14-2 Limitations on radioactive waste discharge 281
14-3 General principles of radioactive waste disposal 285
14-4 Disposal of high-level liquid wastes 287
14-5 Gaseous radioactive wastes 291
14-6 Treatment and disposal of low- and intermediate-level liquid
wastes 293
14-7 Solid radioactive wastes 295
14-8 Ultimate disposal of high-level wastes 297
14-9 Utilization of fission-product wastes 298
X CONTENTS
CHAPTER 15 ISOTOPE SEPARATION
15-1 Introduction 302
15-2 Principles of gaseous diffusion 303
15-3 Gaseous diffusion plants 308
15-4 Electromagnetic separation 308
15-5 Chemical exchange 310
15-6 Distillation 312
15-7 Heavy water production 313
15-8 Thermal diffusion 321
15-9 Miscellaneous isotope separation methods 322
15-10 Comparison of methods 323
CHAPTER 16 FLUID REACTOR FUELS
16-1 Aqueous fuel and blanket solutions 329
16-2 Aqueous fuel and blanket slurries 331
16-3 Radiation effects on aqueous homogeneous reactor systems 333
16-4 Materials of construction for aqueous react r systems 338
16-5 Chemical processing of aqueous reactor fuel 339
16-6 Molten salt systems 341
16-7 Liquid metal fuel systems 343
CHAPTER 17 CHEMISTRY OF REACTOR MATERIALS
17-1 Graphite 348
17-2 Water 349
17-3 Organic coolant-moderators 350
17-4 Beryllium 354
17-5 Zirconium and hafnium 355
17-6 Some useful nuclear poisons 357
APPENDIX A Table of Atomic Weights 1961 362
APPENDIX B Physical Constants and Conversion Factors 363
APPENDIX C Rapid Slide-Rule Calculation of Radii active Decay 364
ANSWERS TO SELECTED PROBLEMS 365
INDEX 367
|
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| discipline | Energietechnik |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T17:44:40Z |
| institution | BVB |
| language | English |
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| spelling | Peterson, Sigfred Verfasser aut Chemistry in nuclear technology by Sigfred Peterson ; Raymond G. Wymer Reading, Mass. [u.a] Addison-Wesley 1963 X, 374 S. txt rdacontent n rdamedia nc rdacarrier Addison-Wesley series in nuclear science and engineering Génie nucléaire Radiochimie Nuclear engineering Radiochemistry Radiochemie (DE-588)4138529-9 gnd rswk-swf Radiochemie (DE-588)4138529-9 s DE-604 Wymer, Raymond G. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006628147&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Peterson, Sigfred Wymer, Raymond G. Chemistry in nuclear technology Génie nucléaire Radiochimie Nuclear engineering Radiochemistry Radiochemie (DE-588)4138529-9 gnd |
| subject_GND | (DE-588)4138529-9 |
| title | Chemistry in nuclear technology |
| title_auth | Chemistry in nuclear technology |
| title_exact_search | Chemistry in nuclear technology |
| title_full | Chemistry in nuclear technology by Sigfred Peterson ; Raymond G. Wymer |
| title_fullStr | Chemistry in nuclear technology by Sigfred Peterson ; Raymond G. Wymer |
| title_full_unstemmed | Chemistry in nuclear technology by Sigfred Peterson ; Raymond G. Wymer |
| title_short | Chemistry in nuclear technology |
| title_sort | chemistry in nuclear technology |
| topic | Génie nucléaire Radiochimie Nuclear engineering Radiochemistry Radiochemie (DE-588)4138529-9 gnd |
| topic_facet | Génie nucléaire Radiochimie Nuclear engineering Radiochemistry Radiochemie |
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