Mineral surfaces:
The surfaces of minerals can now be studied at the molecular level, enabling understanding of the fundamentals of phenomena such as mineral breakdown, the sorption of species (including metals on mineral surfaces) and the role of minerals as catalysts. Such phenomena are central to an understanding...
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
London u.a.
Chapman & Hall
1995
|
| Ausgabe: | 1. ed. |
| Schriftenreihe: | Mineralogical Society of Great Britain and Ireland: The Mineralogical Society series
5 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | The surfaces of minerals can now be studied at the molecular level, enabling understanding of the fundamentals of phenomena such as mineral breakdown, the sorption of species (including metals on mineral surfaces) and the role of minerals as catalysts. Such phenomena are central to an understanding of many processes taking place at the Earth's surface, whether natural or resulting from human activity. They are also central to many industrial processes in the fields of mineral extraction and industrial mineral chemistry This text summarizes the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject and highlights most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review this rapidly developing field |
| Beschreibung: | VIII, 370 S. graph. Darst. |
| ISBN: | 0412563401 |
Internformat
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| 245 | 1 | 0 | |a Mineral surfaces |c ed. by D. J. Vaughan ... |
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| 490 | 1 | |a Mineralogical Society of Great Britain and Ireland: The Mineralogical Society series |v 5 | |
| 520 | 3 | |a The surfaces of minerals can now be studied at the molecular level, enabling understanding of the fundamentals of phenomena such as mineral breakdown, the sorption of species (including metals on mineral surfaces) and the role of minerals as catalysts. Such phenomena are central to an understanding of many processes taking place at the Earth's surface, whether natural or resulting from human activity. They are also central to many industrial processes in the fields of mineral extraction and industrial mineral chemistry | |
| 520 | |a This text summarizes the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject and highlights most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review this rapidly developing field | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | Contents
List of contributors ix
Preface xi
1 Mineral surfaces: an overview 1
D.J. Vaughan
1.1 Introduction 1
1.2 Surface science techniques 1
1.3 Applications of mineral surface science 2
1.4 This book 10
1.5 The future of mineral surface science 11
Appendix l.A Mineral surface science publications 11
Appendix l.B Surface science techniques discussed or
mentioned in this book 12
Appendix l.C Other techniques employed in surface science 13
References 15
2 Mineral surfaces: their characterization and their chemical,
physical and reactive nature 17
M.F. Hochella, Jr
2.1 Introduction 17
2.2 The tools of mineral surface science 19
2.3 The chemical and physical nature of mineral surfaces 38
2.4 Reactivity of mineral surfaces 42
2.5 Conclusions 52
Acknowledgeme nts 53
References 53
3 Mineral surfaces: theoretical approaches 61
J.A. Tossell
3.1 Introduction 61
3.2 Overview of recent state-of-the-art calculations 61
3.3 Models for mineral surfaces: infinite repeating unit vs.
local cluster 64
3.4 Quantum mechanical methods: HF and local density
functional theory 66
CONTENTS
3.5 Other properties that can be obtained from quantum
mechanical calculations 72
3.6 Advances in quantum computational capabilities and
associated problems 73
3.7 HF band theory: differences from molecular HF theory and
LDF band theory and accuracy of results 74
3.8 Qualitative MO theory of surface reconstruction: the example
of the (111) surface of ZnS, sphalerite 77
3.9 A case study comparing HF cluster and band theory and LDF
cluster results for CO adsorbed on MgO 80
3.10 Theory and experiment for the (111) and (110) surfaces of
Li2O, the (0001) surface of A12O3 and the (110) surface of
GaAs 81
3.11 Semi-empirical calculations and atomistic simulations in
surface science 82
3.12 Conclusions 83
Acknowledgements 83
References 84
4 New X-ray techniques and approaches to surface mineralogy 87
G.N. Greaves
4.1 Introduction 87
4.2 X-ray powder diffraction 88
4.3 X-ray absorption fine structure 96
4.4 Structure of microporous materials 106
4.5 Ceramic formation and mineral synthesis 110
4.6 Surface structure 115
Acknowledgements 125
References 125
5 Sorption at mineral-water interfaces: macroscopic and
microscopic perspectives 129
G.E. Brown, Jr, G.A. Parks and P.A. O Day
5.1 Introduction 129
5.2 Macroscopic studies of sorption at mineral-water interfaces 133
5.3 Microscopic properties of water at the mineral-water
interface 136
5.4 Microscopic studies of sorption on oxide, oxyhydroxide and
silicate surfaces 137
5.5 XAS studies of sorption reactions at mineral-water interfaces 157
5.6 Applications of other synchrotron-based surface methods to
absorbâtes at mineral-water interfaces 171
5.7 Conclusions and future possibilities 173
vi
CONTENTS
Acknowledgements 173
References 174
6 Surface chemistry during the dissolution of oxide and silicate
materials 185
W.H. Casey
6.1 Introduction 185
6.2 Rates far from equilibrium 185
6.3 Rates near equilibrium 202
6.4 Natural weathering 210
6.5 Conclusions 212
Acknowledgements 213
References 213
7 Electrochemistry and surface chemistry of sulfide minerals 219
G.H. Kelsall
7.1 Introduction 219
7.2 Electrochemical thermodynamics 221
7.3 Control of electrode potentials 230
7.4 Transport processes in electrochemical systems 234
7.5 Electrochemical kinetics 237
7.6 Mass transport controlled electrochemical reactions 241
7.7 Polarization curves 244
7.8 Mixed potential processes 247
7.9 Examples of the electrochemical behaviour of sulfide minerals 248
7.10 Conclusions 256
Appendix 7.A Nomenclature 257
References 258
8 Surface chemistry of sulfide flotation 261
P.E. Richardson
8.1 Introduction 261
8.2 Sulfide flotation: general 262
8.3 Self-induced flotation 263
8.4 Collector-induced flotation 273
8.5 Mixed potential theory 274
8.6 Flotation and xanthate reactions: single sulfide minerals 277
8.7 Mineral mixtures 292
8.8 Galvanic coupling between minerals 294
8.9 Depression of sulfide minerals 295
8.10 Summary 297
References 297
vu
CONTENTS
9 Clay mineral surfaces 303
R.A. Schoonheydt
9.1 Introduction 303
9.2 Smectites 306
9.3 Clay surfaces in aqueous suspension 312
9.4 Clay materials science 319
9.5 Future directions in clay materials research 325
Acknowledgements 327
References 327
10 Zeolite surfaces and reactivity 333
A. Dyer
10.1 Introduction
10.2 Zeolite structures
10.3 Creation of natural and synthetic zeolites and zeotypes
10.4 Zeolite characterization
10.5 Zeolite surfaces, internal and external
10.6 Zeolite properties
10.7 The future
10.8 Conclusions
References
Index
Vlll
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| spelling | Mineral surfaces ed. by D. J. Vaughan ... 1. ed. London u.a. Chapman & Hall 1995 VIII, 370 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Mineralogical Society of Great Britain and Ireland: The Mineralogical Society series 5 The surfaces of minerals can now be studied at the molecular level, enabling understanding of the fundamentals of phenomena such as mineral breakdown, the sorption of species (including metals on mineral surfaces) and the role of minerals as catalysts. Such phenomena are central to an understanding of many processes taking place at the Earth's surface, whether natural or resulting from human activity. They are also central to many industrial processes in the fields of mineral extraction and industrial mineral chemistry This text summarizes the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject and highlights most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review this rapidly developing field Chimie des surfaces ram Chimie minérale ram Minéralogie - Recherche ram Minéraux - Surfaces ram Mineralogical chemistry Mineralogy Research Minerals Surfaces Surface chemistry Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Oberflächeneigenschaft (DE-588)4219221-3 gnd rswk-swf Mineral (DE-588)4074836-4 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Mineral (DE-588)4074836-4 s Oberflächeneigenschaft (DE-588)4219221-3 s DE-604 Oberflächenchemie (DE-588)4126166-5 s Vaughan, David J. Sonstige oth Mineralogical Society of Great Britain and Ireland: The Mineralogical Society series 5 (DE-604)BV004224173 5 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006572821&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mineral surfaces Mineralogical Society of Great Britain and Ireland: The Mineralogical Society series Chimie des surfaces ram Chimie minérale ram Minéralogie - Recherche ram Minéraux - Surfaces ram Mineralogical chemistry Mineralogy Research Minerals Surfaces Surface chemistry Oberflächenchemie (DE-588)4126166-5 gnd Oberflächeneigenschaft (DE-588)4219221-3 gnd Mineral (DE-588)4074836-4 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4219221-3 (DE-588)4074836-4 (DE-588)4143413-4 |
| title | Mineral surfaces |
| title_auth | Mineral surfaces |
| title_exact_search | Mineral surfaces |
| title_full | Mineral surfaces ed. by D. J. Vaughan ... |
| title_fullStr | Mineral surfaces ed. by D. J. Vaughan ... |
| title_full_unstemmed | Mineral surfaces ed. by D. J. Vaughan ... |
| title_short | Mineral surfaces |
| title_sort | mineral surfaces |
| topic | Chimie des surfaces ram Chimie minérale ram Minéralogie - Recherche ram Minéraux - Surfaces ram Mineralogical chemistry Mineralogy Research Minerals Surfaces Surface chemistry Oberflächenchemie (DE-588)4126166-5 gnd Oberflächeneigenschaft (DE-588)4219221-3 gnd Mineral (DE-588)4074836-4 gnd |
| topic_facet | Chimie des surfaces Chimie minérale Minéralogie - Recherche Minéraux - Surfaces Mineralogical chemistry Mineralogy Research Minerals Surfaces Surface chemistry Oberflächenchemie Oberflächeneigenschaft Mineral Aufsatzsammlung |
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