Rheology: principles, measurements, and applications
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
VCH
1994
|
| Schriftenreihe: | Advances in interfacial engineering series
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII, 550 S. Ill., graph. Darst. |
| ISBN: | 1560815795 0471185752 9780471185758 |
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| 100 | 1 | |a Macosko, Christopher W. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Rheology |b principles, measurements, and applications |c Christopher W. Macosko |
| 264 | 1 | |a New York [u.a.] |b VCH |c 1994 | |
| 300 | |a XVIII, 550 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Advances in interfacial engineering series | |
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| 650 | 4 | |a Rheology | |
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RHEOLOGY
PRINCIPLES,
MEASUREMENTS,
AND
APPLICATIONS
CHRISTOPHER W. MACOSKO
I
-
56081
-5'79~5
1994 VCH PUBLISHERS. INC.
NEW YORK
PART I.
CONSTITUTIVE RELATIONS 1
1
L
ELASTIC SOLID
5
CHRISTOPHER W. MACOSKO
1.1
INTRODUCTION
5
1.2
THE STRESS TENSOR
8
1.2.1
NOTATION
I1
1.2.2
SYMMETRY
/6
1.2.3
PRESSURE
/8
1.3
PRINCIPAL STRESSES AND INVARIANTS
20
1.4
FINITE DEFORMATION TENSORS
24
1.4.1
FINGER TENSOR
29
1.4.2
STRAIN TENSOR
32
1.4.3
INVERSE DEFORMATION TENSORS
32
1.4.4
PRINCIPAL STRAINS
34
1.5
NEO-HOOKEAN SOLID
37
1.5.1
UNIAXIAL
EXTENSION
38
1.5.2
SIMPLE SHEAR
40
1.6
GENERAL ELASTIC SOLID
40
1.6.1
STRAIN-ENERGY FUNCTION
42
1.6.2
ANISOTROPY
44
1.6.3
RUBBER-LIKE LIQUIDS
45
1.7
EQUATIONS OF MOTION
45
1.7.1
MASS BALANCE
45
1.7.2
MOMENTUM BALANCE
47
1.8
BOUNDARY CONDITIONS
52
1.9
SUMMARY
58
1.10
EXERCISES
59
REFERENCES
62
2
/
VISCOUS LIQUID
65
CHRISTOPHER W. MACOSKO
2.1
INTRODUCTION
65
2.2
VELOCITY GRADIENT
68
2.2.1
RATE OF DEFORMATION TENSOR
72
2.3
NEWTONIAN FLUID
77
2.3.1
UNIAXIAL
EXTENSION
79
2.4
GENERAL VISCOUS FLUID
83
2.4.1
POWER LAW 84
2.4.2
CROSS MODEL
86
2.4.3
OTHER VISCOUS MODELS
86
2.4.4
THE IMPORTANCE OF 11,,,
89
2.4.5
EXTENSIONAL THICKENING MODELS
91
2.5
PLASTIC BEHAVIOR
92
2.5.1
OTHER VISCOPLASTIC MODELS
95
2.6
BALANCE EQUATIONS
98
2.6.1
EQUATIONS OF MOTION
99
2.6.2
BOUNDARY CONDITIONS
99
2.6.3
ENERGY EQUATION
/00
2.6.4
TEMPERATURE AND PRESSURE DEPENDENCE OF
VISCOSITY
/00
2.7
SUMMARY
104
2.8
EXERCISES
105
REFERENCES
/06
3 / LINEAR VISCOELASTICITY
109
CHRISTOPHER W. MACOSKO
3.1
INTRODUCTION
109
3.2
GENERAL LINEAR VISCOELASTIC MODEL
1/1
3.2.1
RELAXATION SPECTRUM
/15
3.2.2
LINEAR VISCOELASTICITY IN
THREE DIMENSIONS
/15
3.2.3
DIFFERENTIAL FORM
115
3.3
SMALL STRAIN MATERIAL FUNCTIONS
117
3.3.1
STRESS RELAXATION
118
3.3.2
CREEP
119
3.3.3
SINUSOIDAL OSCILLATIONS
12/
3.4
EXERCISES
/26
APPENDIX
3A 127
ROBERT B. SECOR
CURVE FITTING OF RELAXATION MODULUS
127
APPROXIMATING FORM
/27
ERROR MEASURE
/28
SEARCH PROCEDURES
129
REFERENCES
/33
4
/
NONLINEAR VISCOELASTICITY
135
RONALD G. LARSON
4.1
INTRODUCTION
/35
4.2
NONLINEAR PHENOMENA
/38
4.2.1
NORMAL STRESS DIFFERENCE IN SHEAR
138
4.2.2
SHEAR THINNING
139
4.2.3
INTERRELATIONS BETWEEN SHEAR
FUNCTIONS
140
4.2.4
EXTENSIONAL THICKENING
/42
4.3
SIMPLE NONLINEAR CONSTITUTIVE EQUATIONS
/46
4.3.1
SECOND-ORDER FLUID
/46
4.3.2
UPPER-CONVECTED MAXWELL EQUATION
149
4.3.3
LODGE INTEGRAL EQUATION
/53
4.4
MORE ACCURATE CONSTITUTIVE EQUATIONS
158
4.4.1
INTEGRAL CONSTITUTIVE EQUATIONS
/58
4.4.2
MAXWELL-TYPE DIFFERENTIAL CONSTITUTIVE
EQUATIONS
/66
4.5
SUMMARY
170
4.6
EXERCISES
17/
REFERENCES
172
PART II.
MEASUREMENTS: RHEOMETRY 175
5 / SHEAR RHEOMETRY: DRAG FLOWS 181
CHRISTOPHER W. MACOSKO
5.1
INTRODUCTION
181
5.2
SLIDING PLATES, FALLING BALL
/84
5.2.1
FALLING CYLINDER
185
5.2.2
FALLING BALL
187
5.2.3
ROLLING BALL
/87
5.3
CONCENTRIC CYLINDER RHEOMETER
/88
5.3.1
SHEAR STRESS
/90
5.3.2
SHEAR STRAIN AND RATE
191
5.3.3
NORMAL STRESSES IN COUETTE FLOW
/95
5.3.4
ROD CLIMBING
/98
5.3.5
END EFFECTS
200
5.3.6
SECONDARY FLOWS
202
5.3.7
SHEAR HEATING IN COUETTE FLOW
203
5.4
CONE AND PLATE RHEOMETER
205
5.4.1
SHEAR STRESS
206
5.4.2
SHEAR STRAIN RATE
207
5.4.3
NORMAL STRESSES
208
5.4.4
INERTIA AND SECONDARY FLOW
209
5.4.5
EDGE EFFECTS WITH CONE AND PLATE
2/3
5.4.6
SHEAR HEATING
2/6
5.4.7
SUMMARY
2/6
5.5
PARALLEL DISKS
2/7
5.5.1
NORMAL STRESSES
22/
5.6
DRAG FLOW INDEXERS
222
5.6.1
ROTATING DISK IN A SEA OF FLUID
223
5.6.2
ROTATING VANE
224
5.6.3
HELICAL SCREW RHEOMETER
224
5.6.4
INSTRUMENTED MIXERS
225
5.7
ECCENTRIC ROTATING GEOMETRIES
226
5.7.1
ROTATING CANTILIVER ROD
227
5.7.2
ECCENTRIC ROTATING DISKS
227
5.7.3
OTHER ECCENTRIC GEOMETRIES
23/
REFERENCES
231
6
/
SHEAR RHEOMETRY: PRESSURE
DRIVEN FLOWS
237
CHRISTOPHER W. MACOSKO
6.1
INTRODUCTION
237
6.2
CAPILLARY RHEOMETER
238
6.2.1
SHEAR RATE
240
6.2.2
WALL SLIP, MELT FRACTURE
244
6.2.3
TRUE SHEAR STRESS
247
6.2.4
SHEAR HEATING
252
6.2.5
EXTRUDATE SWELL
254
6.2.6
MELT INDEX
256
6.3
SLIT
RHEOMETRY
257
6.3.1
NORMAL STRESSES
260
6.3.2
EXIT PRESSURE
26/
6.3.3
PRESSURE HOLE
262
6.4
OTHER PRESSURE RHEOMETERS
266
6.4.1
AXIAL ANNULAR FLOW
266
6.4.2
TANGENTIAL ANNULAR FLOW
267
6.4.3
TILTED OPEN CHANNEL
268
6.4.4
SQUEEZING FLOW
270
6.5
COMPARISON OF SHEAR METHODS
275
6.6
SUMMARY
277
REFERENCES
280
7 / EXTENSIONAL RHEOMETRY 285
CHRISTOPHER W. MACOSKO
7.1
INTRODUCTION
285
7.2
SIMPLE EXTENSION
288
7.2.1
END CLAMPS
291
7.2.2
ROTATING CLAMPS
292
7.2.3
BUOYANCY BATHS
294
7.2.4
SPINNING DROP
296
7.3
LUBRICATED COMPRESSION
297
7.3.1
PLANAR SQUEEZING
303
7.4
SHEET STRETCHING, MULTIAXIAL EXTENSION
303
7.4.1
ROTATING CLAMPS
304
7.4.2
INFLATION METHODS
306
7.5
FIBER SPINNING
308
7.5.7
TUBELESS SIPHON
315
7.6
BUBBLE COLLAPSE
3/7
7.7
STAGNATION FLOWS
320
7.7.1
LUBRICATED DIES
322
7.7.2
UNLUBRICATED DIES
322
7.7.3
OPPOSED NOZZLES
323
7.8
ENTRANCE FLOWS
326
7.9
SUMMARY
332
REFERENCES
333
8
/
RHEOMETER DESIGN
337
CHRISTOPHER W. MACOSKO
8.1
INTRODUCTION
337
8.2
DRAG FLOW RHEOMETERS
338
8.2.1
CONTROLLED STRAIN
339
8.2.2
TORQUE MEASUREMENT
342
8.2.3
NORMAL STRESSES
345
8.2.4
ALIGNMENT
347
8.2.5
CONTROLLED STRESS
349
8.2.6
ENVIRONMENTAL CONTROL
352
8.3
DATA ANALYSIS
357
8.3.1
SINUSOIDAL OSCILLATIONS
359
8.3.2
TRANSIENT
363
8.4
PRESSURE-DRIVEN RHEOMETERS
364
8.5
EXTENSIONAL RHEOMETERS
368
8.6
PROCESS LINE RHEOMETERS
370
8.7
SUMMARY
373
REFERENCES
374
9
/
RHEO-OPTICS: FLOW BIREFRINGENCE
379
TIMOTHY P. LODGE
9.1
INTRODUCTION
379
9.2
REVIEW OF OPTICAL PHENOMENA
38/
9.2.1
ABSORPTION AND EMISSION
SPECTROSCOPIES
382
9.2.2
SCATTERING TECHNIQUES
382
9.2.3
BIREFRINGENCE AND DICHROISM
384
9.3
POLARIZED LIGHT
386
9.3.1
TRANSMISSION THROUGH A SERIES OF OPTICAL
ELEMENTS
390
9.4
FLOW BIREFRINGENCE: PRINCIPLES AND PRACTICE
393
9.4.1
THE STRESS-OPTICAL RELATION
393
9.4.2
RANGE OF APPLICABILITY OF THE STRESS-OPTICAL
RELATION
397
9.4.3
GEOMETRIES FOR MEASURING FLOW
BIREFRINGENCE
400
9.4.4
BIREFRINGENCE IN STEADY AND TRANSIENT
COUETTE FLOW
403
9.4.5
BIREFRINGENCE IN OSCILLATORY SHEAR
FLOW
405
9.4.6
EXPERIMENTAL CONSIDERATIONS
407
9.5
FLOW BIREFRINGENCE: APPLICATIONS
408
9.5.1
STRESS FIELD VISUALIZATION
408
9.5.2
EXTENSIONAL FLOW
409
9.5.3
DYNAMICS OF ISOLATED, FLEXIBLE
HOMOPOLYMERS
409
9.5.4
DYNAMICS OF ISOLATED BLOCK
COPOLYMERS
412
9.5.5
DYNAMICS OF BLOCK COPOLYMER MELTS
415
9.5.6
DYNAMICS OF A BINARY BLEND
415
9.5.7
BIREFRINGENCE IN TRANSIENT FLOWS
416
9.5.8
RHEO-OPTICS OF SUSPENSIONS
416
9.5.9
ROTATIONAL DYNAMICS OF RIGID RODS
417
9.6
SUMMARY
4/9
REFERENCES
419
PART
III.
APPLICATIONS
423
10
/
SUSPENSION RHEOLOGY
425
JAN MEWIS AND CHRISTOPHER W. MACOSKO
10.1
INTRODUCTION
425
10.2
DILUTE SUSPENSIONS OF SPHERES
428
10.2.1
HARD SPHERES
428
10.2.2
PARTICLE MIGRATION
430
10.2.3
EMULSIONS
434
10.2.4
DEFORMABLE SPHERES
437
10.3
PARTICLE-FLUID INTERACTIONS: DILUTE SPHEROIDS
439
10.3.1
ORIENTATION DISTRIBUTION
440
10.3.2
CONSTITUTIVE RELATIONS FOR SPHEROIDS
443
10.4
PARTICLE-PARTICLE INTERACTIONS
449
10.4.1
DISPERSION FORCES
450
10.4.2
ELECTROSTATIC FORCES
451
10.4.3
POLYMERIC (STERIC) FORCES
452
10.4.4
SCALING
454
10.5
BROWNIAN HARD PARTICLES
455
10.5.1
MONODISPERSE HARD SPHERES
455
10.5.2
PARTICLE SIZE DISTRIBUTION
458
10.5.3
NONSPHERICAL PARTICLES
459
10.5.4
NON-NEWTONIAN MEDIA
460
10.5.5
EXTENSIONAL FLOW OF ELLIPSOIDS
460
10.6
STABLE COLLOIDAL SUSPENSIONS
461
10.6.1
ELECTROSTATIC STABILIZATION
462
10.6.2
POLYMERIC (STERIC) STABILIZATION
464
10.7
FLOCCULATED SYSTEMS
465
10.7.1
STRUCTURE IN FLOCCULATED DISPERSIONS
465
10.7.2
STATIC PROPERTIES
467
10.7.3
FLOW BEHAVIOR
468
10.8
SUMMARY
470
REFERENCES
47/
11 / RHEOLOGY OF POLYMERIC LIQUIDS 475
MATTHEW TIRRELL
11.1
INTRODUCTION
475
11.2
POLYMER CHAIN CONFORMATION
476
11.3
ZERO SHEAR VISCOSITY
479
11.3.1
DILUTE SOLUTION
479
11.3.2
NONDILUTE POLYMERIC LIQUIDS
480
11.3.3
COIL OVERLAP
482
11.4
RHEOLOGY OF DILUTE POLYMER SOLUTIONS
487
11.4.1
ELASTIC DUMBBELL
487
11.4.2
ROUSE AND OTHER MULTIHEAD MODELS
495
11.5
CONCENTRATED SOLUTIONS AND MELTS
497
11.5.1
ENTANGLEMENTS
497
11.5.2
REPTATION MODEL
502
11.5.3
EFFECTS OF LONG CHAIN BRANCHING
505
11.5.4
EFFECT OF MOLECULAR WEIGHT
DISTRIBUTION
506
11.6
TEMPERATURE DEPENDENCE
5/0
11.7
SUMMARY
5/2
REFERENCES
512
APPENDIX
/
SOLUTIONS TO EXERCISES
CHAPTER I
515
CHAPTER 2
521
CHAPTER 3
527
CHAPTER 4
53/
INDEX
535 |
| any_adam_object | 1 |
| author | Macosko, Christopher W. |
| author_facet | Macosko, Christopher W. |
| author_role | aut |
| author_sort | Macosko, Christopher W. |
| author_variant | c w m cw cwm |
| building | Verbundindex |
| bvnumber | BV009902812 |
| callnumber-first | Q - Science |
| callnumber-label | QC189 |
| callnumber-raw | QC189.5 |
| callnumber-search | QC189.5 |
| callnumber-sort | QC 3189.5 |
| callnumber-subject | QC - Physics |
| classification_rvk | UF 3500 VE 5900 |
| classification_tum | PHY 216f |
| ctrlnum | (OCoLC)28799856 (DE-599)BVBBV009902812 |
| dewey-full | 531/.11 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 531 - Classical mechanics |
| dewey-raw | 531/.11 |
| dewey-search | 531/.11 |
| dewey-sort | 3531 211 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
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| id | DE-604.BV009902812 |
| illustrated | Illustrated |
| indexdate | 2025-01-07T11:06:06Z |
| institution | BVB |
| isbn | 1560815795 0471185752 9780471185758 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006558133 |
| oclc_num | 28799856 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-703 DE-384 DE-1102 DE-634 DE-83 DE-11 |
| owner_facet | DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-703 DE-384 DE-1102 DE-634 DE-83 DE-11 |
| physical | XVIII, 550 S. Ill., graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | VCH |
| record_format | marc |
| series2 | Advances in interfacial engineering series |
| spelling | Macosko, Christopher W. Verfasser aut Rheology principles, measurements, and applications Christopher W. Macosko New York [u.a.] VCH 1994 XVIII, 550 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advances in interfacial engineering series Reologie gtt Rhéologie Rheology Rheologie (DE-588)4049828-1 gnd rswk-swf Rheologie (DE-588)4049828-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006558133&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Macosko, Christopher W. Rheology principles, measurements, and applications Reologie gtt Rhéologie Rheology Rheologie (DE-588)4049828-1 gnd |
| subject_GND | (DE-588)4049828-1 |
| title | Rheology principles, measurements, and applications |
| title_auth | Rheology principles, measurements, and applications |
| title_exact_search | Rheology principles, measurements, and applications |
| title_full | Rheology principles, measurements, and applications Christopher W. Macosko |
| title_fullStr | Rheology principles, measurements, and applications Christopher W. Macosko |
| title_full_unstemmed | Rheology principles, measurements, and applications Christopher W. Macosko |
| title_short | Rheology |
| title_sort | rheology principles measurements and applications |
| title_sub | principles, measurements, and applications |
| topic | Reologie gtt Rhéologie Rheology Rheologie (DE-588)4049828-1 gnd |
| topic_facet | Reologie Rhéologie Rheology Rheologie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006558133&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT macoskochristopherw rheologyprinciplesmeasurementsandapplications |