Modern electroorganic chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin u.a.
Springer
1994
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| Schriftenreihe: | Springer lab manual
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 228 S. graph. Darst. |
| ISBN: | 3540575049 0387575049 |
Internformat
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| 100 | 1 | |a Kyriacou, Demetrios K. |e Verfasser |0 (DE-588)1325376884 |4 aut | |
| 245 | 1 | 0 | |a Modern electroorganic chemistry |c Demetrios Kyriacou |
| 264 | 1 | |a Berlin u.a. |b Springer |c 1994 | |
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Datensatz im Suchindex
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| adam_text | DEMETRIOS KYRIACOU MODERN ELECTROORGANIC CHEMISTRY WITH 16 FIGURES
SPRINGER-VERLAG BERLIN HEIDELBERG NEW YORK LONDON PARIS TOKYO HONG KONG
BARCELONA BUDAPEST CONTENTS 1 INTRODUCTION 1 1.1 ELECTROORGANIC
CHEMISTRY. HISTORICAL PERSPECTIVE 1 1.2 PERTINENT FUNDAMENTAL CONCEPTS
AND PRINCIPLES IN ORGANIC ELECTROCHEMISTRY 2 1.2.1 THE OVERALL CELL
REACTION 2 1.2.2 THE GENERALIZED ELECTROORGANIC REACTION 3 1.2.2.1
ELECTROCHEMICAL COUPLINGS AND CROSS COUPLINGS 6 1.2.2.2 THE ELECTRON
TRANSFER STEP. BASIC QUALITATIVE DESCRIPTION 6 1.2.3 THERMODYNAMIC AND
KINETIC ASPECTS 7 1.2.3.1 NERNSTIAN EQUATION. ELECTRODE POTENTIAL 7
1.2.3.1A FREE ENERGY OF CELL REACTION AND CELL POTENTIAL 9 1.2.3.2
KINETIC ASPECTS 10 1.2.4 PREPARATIVE ELECTROLYSIS UNDER ACTIVATION
(KINETIC) OR MASS-TRANSFER CONTROLLED CONDITIONS 12 1.2.5 THE ELECTRICAL
DOUBLE LAYER AND ITS SIGNIFICANCE IN ELECTROSYNTHESIS 14 REFERENCES 17 2
ANODIC REACTIONS 18 2.1 FUNDAMENTAL NATURE 18 2.2 HYDROCARBONS 19 2.2.1
SATURATED HYDROCARBONS 19 2.2.2 UNSATURATED HYDROCARBONS 22 2.2.3
FUNCTIONALIZATIONS OF HYDROCARBONS 25 2.3 HYDROXY COMPOUNDS 28 2.4
OXIDATIONS AT OXIDE COVERED ELECTRODES 30 2.5 PHENOLIC COMPOUNDS 36 2.6
CARBONYL COMPOUNDS 43 2.7 CARBOXYLIC ACIDS 47 2.7.1 GENERAL PERSPECTIVE
47 2.7.2 OXIDATIONS IN FLUOROSULFURIC ACID 52 2.7.3 KOLBE SYNTHESIS IN
SPE CELLS 52 2.7.4 PHOTOKOLBE SYNTHESIS 54 2.8 AMINES AND AMIDES 54 VIII
CONTENTS 2.8.1 AMINES, IN GENERAL 54 2.8.2 AMIDES 57 2.9 ETHERS AND
ESTERS 60 2.10 ORGANIC HALIDES 63 2.10.1 ALKYL HALIDES 63 2.10.2
AROMATIC HALIDES 64 2.11 N-HETEROCYCLICS 65 2.12 ORGANOSULFUR COMPOUNDS
74 2.12.1 SULFIDES 74 2.12.2 THIOLATES AND DITHIANES 75 2.12.3 SULFONIUM
SALTS 77 2.13 ANODIC CYANATIONS 79 2.14 ACETOXYLATIONS AND
ACETAMIDATIONS 83 2.14.1 ACETOXYLATIONS 83 2.14.2 ACETAMIDATIONS -
ELECTROCHEMICAL RITTER-TYPE REACTIONS 86 2.15 ANODIC HALOGENATIONS 88
2.16 HYDROXYLATIONS 91 2.17 ALKOXYLATIONS 92 2.18 PYRIDINATIONS 100 2.19
NITRATIONS 101 REFERENCES 102 3 CATHODIC ORGANIC REACTIONS 110 3.1
PHENOMENOLOGICAL NATURE 110 3.2 CARBON-HYDROGEN BOND FORMATIONS.
UNSATURATED SYSTEMS ILL 3.3 CARBONYL COMPOUNDS 113 3.3.1 GENERAL
REDUCTION MECHANISM 113 3.3.2 REACTIONS VIA THE CARBONYL ELECTROPHORE
114 3.4 CARBOXYLIC ACIDS AND ESTERS 119 3.4.1 PREPARATION OF METAL
CARBOXYLATES AND METAL ALKOXIDES 120 3.4.2 REDUCTION OF ESTERS 121 3.5
ORGANOHALIDES 122 3.5.1 GENERAL ELECTROREDUCTION MECHANISM 122 3.5.2
PRODUCTS FROM AROMATIC AND ALIPHATIC HALIDES 122 3.5.3 VARIOUS REDUCTIVE
DEHALOGENATIONS 127 3.5.4 ELECTROHYDROGENOLYSIS OF POLYHALOGENATED
COMPOUNDS 128 3.5.5 ELECTROCHEMICALLY INDUCED NUCLEOPHILIC S RN 1
SUBSTITUTIONS 131 3.5.6 ORGANIC FLUORIDES 133 CONTENTS IX 3.6
NITROCOMPOUNDS 133 3.6.1 YV-HETEROCYCLIZATIONS 134 3.6.2 REDUCTION ON
TRANSITION METAL ELECTRODES 138 3.7 IY-HETEROCYCLICS AND OTHER
HETEROATOM STRUCTURES 138 3.7.1 PYRIDINES, PURINES, AND SIMILAR
COMPOUNDS 138 3.7.2 PYRIDINIUM AND SIMILAR SALTS 141 3.7.3
JY-HETEROCYCLICS WITH CARBONYL GROUPS 142 3.8 ORGANOSULFUR COMPOUNDS 145
3.9 SOME SPECIAL CLEAVAGES OF C*O BONDS IN HYDROXY COMPOUNDS 148 3.9.1
CLEAVAGE OF ETHERS 150 3.10 ELECTROCARBOXYLATIONS 150 3.10.1
ELECTROREDUCTION OF CARBON DIOXIDE 150 3.10.2 CO 2 AS ELECTROPHILE 151
3.10.3 PHOTOELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE 153 3.11
NITRILES AND OXIMES 154 3.12 VARIOUS CATHODIC COUPLINGS 155 3.12.1
ACYLATIONS 155 3.12.2 ORGANOPHOSPHORUS COMPOUNDS : 156 3.12.3
ARENE-METAL COMPLEXES 157 3.12.4 CATHODIC REACTIONS (COUPLINGS) OF
ORGANOMETALLICS 158 REFERENCES 160 4 INDIRECT ELECTROORGANIC REACTIONS
(INDIRECT ELECTROLYSIS) .. . 166 4.1 INTRODUCTION 166 4.1.1 BASIC
MECHANISMS 166 4.2 OXIDATIVE INDIRECT REACTIONS 169 4.2.1 METALLIC IONS
AND OXYANIONS MEDIATORS 169 4.2.2 PAIRED OXIDATIVE PROCESSES 172 4.2.3
HALIDE IONS AS MEDIATORS 174 4.2.4 NITRATE ION AS MEDIATOR 178 4.2.5
ORGANIC MEDIATORS FOR OXIDATIONS 178 4.3 INDIRECT REDUCTIVE REACTIONS
182 4.3.1 METALLIC IONS A CATALYSTS 182 4.3.2 REDUCTIONS WITH AMALGAMS
185 4.3.3 REDUCTIONS WITH DIBORANE FORMED IN SITU 186 4.3.4 ORGANIC
MEDIATORS 187 REFERENCES 188 5 SOME SPECIAL TOPICS RELEVANT TO
ELECTROSYNTHESIS 192 5.1 ELECTROLYSIS IN TWO-PHASE SOLVENT SYSTEMS 192
5.2 SOLID POLYMER ELECTROLYTE - ELECTROLYSIS 194 5.3 REACTIONS VIA
ELECTRODE DISSOLUTION 196 X CONTENTS 5.4 ELECTROPOLYMERIZATIONS.
CONDUCTIVE POLYMERS 198 5.4.1 GENERAL VIEW 198 5.4.2 CONDUCTIVE POLYMERS
201 5.5 APPLICATIONS OF ELECTROCHEMICAL METHODOLOGY TO THE SYNTHESIS OF
NATURAL PRODUCTS 203 5.6 ELECTROREDUCTIVE CYCLIZATIONS FOR NATURAL
PRODUCT SYNTHESIS (LITTLE-BAIZER ERC REACTION) 206 5.7 ELECTROGENERATIVE
SYSTEMS 208 5.8 ELECTROGENERATED BASES 212 5.9 ELECTROREDUCTION OF
ENONES (A,(3-UNSATURATED KETONES) . . . 214 5.10 OXYGENATIONS. THE
SUPEROXIDE ION 215 REFERENCES 219 SUBJECT INDEX 225
|
| any_adam_object | 1 |
| author | Kyriacou, Demetrios K. |
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| dewey-ones | 547 - Organic chemistry |
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| dewey-search | 547.137 |
| dewey-sort | 3547.137 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| indexdate | 2024-07-09T17:39:29Z |
| institution | BVB |
| isbn | 3540575049 0387575049 |
| language | English |
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| publishDate | 1994 |
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| spelling | Kyriacou, Demetrios K. Verfasser (DE-588)1325376884 aut Modern electroorganic chemistry Demetrios Kyriacou Berlin u.a. Springer 1994 X, 228 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer lab manual Organische Chemie (DE-588)4043793-0 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Elektroorganische Synthese (DE-588)4151944-9 gnd rswk-swf Elektrochemie (DE-588)4014241-3 s Organische Chemie (DE-588)4043793-0 s DE-604 Elektroorganische Synthese (DE-588)4151944-9 s HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006417436&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kyriacou, Demetrios K. Modern electroorganic chemistry Organische Chemie (DE-588)4043793-0 gnd Elektrochemie (DE-588)4014241-3 gnd Elektroorganische Synthese (DE-588)4151944-9 gnd |
| subject_GND | (DE-588)4043793-0 (DE-588)4014241-3 (DE-588)4151944-9 |
| title | Modern electroorganic chemistry |
| title_auth | Modern electroorganic chemistry |
| title_exact_search | Modern electroorganic chemistry |
| title_full | Modern electroorganic chemistry Demetrios Kyriacou |
| title_fullStr | Modern electroorganic chemistry Demetrios Kyriacou |
| title_full_unstemmed | Modern electroorganic chemistry Demetrios Kyriacou |
| title_short | Modern electroorganic chemistry |
| title_sort | modern electroorganic chemistry |
| topic | Organische Chemie (DE-588)4043793-0 gnd Elektrochemie (DE-588)4014241-3 gnd Elektroorganische Synthese (DE-588)4151944-9 gnd |
| topic_facet | Organische Chemie Elektrochemie Elektroorganische Synthese |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006417436&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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