Diazo chemistry: 1 Aromatic and heteroaromatic compounds
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim [u.a.]
VCH
1994
|
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 453 S. graph. Darst. |
| ISBN: | 3527292136 1560818786 |
Internformat
MARC
| LEADER | 00000nam a2200000 cc4500 | ||
|---|---|---|---|
| 001 | BV009693997 | ||
| 003 | DE-604 | ||
| 005 | 00000000000000.0 | ||
| 007 | t | ||
| 008 | 940711s1994 d||| |||| 00||| engod | ||
| 020 | |a 3527292136 |9 3-527-29213-6 | ||
| 020 | |a 1560818786 |9 1-56081-878-6 | ||
| 035 | |a (OCoLC)60241197 | ||
| 035 | |a (DE-599)BVBBV009693997 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-355 |a DE-703 |a DE-29T |a DE-91G |a DE-19 |a DE-634 |a DE-83 |a DE-11 |a DE-188 | ||
| 082 | 0 | |a 547.043 | |
| 084 | |a VK 7400 |0 (DE-625)147419:253 |2 rvk | ||
| 100 | 1 | |a Zollinger, Heinrich |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Diazo chemistry |n 1 |p Aromatic and heteroaromatic compounds |c Heinrich Zollinger |
| 264 | 1 | |a Weinheim [u.a.] |b VCH |c 1994 | |
| 300 | |a XIII, 453 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 773 | 0 | 8 | |w (DE-604)BV009693990 |g 1 |
| 856 | 4 | 2 | |m GBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006411379&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-006411379 | ||
Datensatz im Suchindex
| _version_ | 1804124039637106688 |
|---|---|
| adam_text | HEINRICH ZOLLINGER DIAZO CHEMISTRY I AROMATIC AND HETEROAROMATIC
COMPOUNDS VCH WEINHEIM * NEW YORK BASEL * CAMBRIDGE * TOKYO CONTENTS 1
INTRODUCTION 1 1.1 HISTORY OF AROMATIC AND HETEROAROMATIC DIAZO
COMPOUNDS 1 1.2 NOMENCLATURE 3 1.3 GENERAL REFERENCES 9 2 METHODS FOR
THE PREPARATION OF AROMATIC AND HETEROAROMATIC DIAZO COM- POUNDS 11 2.1
DIAZOTIZATION OF AMINES WITH ALKALI NITRITE IN DILUTE AQUEOUS MINERAL
ACIDS 11 2.2 DIAZOTIZATION IN CONCENTRATED MINERAL ACID 20 2.3 ISOLATION
OF DIAZONIUM SALTS 24 2.4 DIAZOTIZATION OF 2- AND 4-AMINOPHENOLS 25 2.5
FORMATION OF DIAZONIUM SALTS UNDER ANHYDROUS CONDITIONS 30 2.6 OTHER
REACTIONS INVOLVING FORMATION OF AROMATIC DIAZONIUM IONS 32 3 KINETICS
AND MECHANISM OF DIAZOTIZATION 39 3.1 HISTORICAL DEVELOPMENT 39 3.2
INFLUENCE OF ACIDITY ON THE RATE AND MECHANISM OF DIAZOTIZATION IN
AQUEOUS SULFURIC AND PERCHLORIC ACIDS 44 3.3 NUCLEOPHILIC CATALYSIS OF
DIAZOTIZATION 54 3.4 TRANSFORMATION OF THE N-NITROSOAMINE INTERMEDIATE
INTO THE DIAZONIUM ION 58 4 THE STRUCTURE OF DIAZONIUM COMPOUNDS 65 4.1
INTRODUCTORY REMARKS 65 4.2 STRUCTURE OF ARENEDIAZONIUM SALTS 66 4.3
THEORETICAL INVESTIGATIONS 82 5 ACID-BASE AND ISOMERIZATION REACTIONS OF
DIAZO COMPOUNDS IN WATER 89 5.1 THE AROMATIC DIAZONIUM ION AS A DIBASIC
ACID 89 5.2 THE COMBINED SYSTEM OF ACID-BASE ADDITION, (Z)/(E)- AND PRO-
TOTROPIC ISOMERIZATION REACTIONS OF ARENEDIAZONIUM IONS 96 5.3 KINETICS
AND EQUILIBRIA OF ARENEDIAZONIUM IONS IN WATER 98 6 ADDITIONS OF OTHER
NUCLEOPHILES TO ARENEDIAZONIUM IONS 107 6.1 INTRODUCTION 107 6.2
O-COUPLING 108 CONTENTS 5-COUPLING 116 7V-COUPLING 120 P-COUPLING 126
C-COUPLING 127 INTRAMOLECULAR COUPLING 131 6.7.1 INTRODUCTION 131 6.7.2
7V-COUPLING 131 6.7.3 O-COUPLING 136 6.7.4 S-COUPLING 136 6.7.5
C-COUPLING 137 7 STRUCTURAL AND MECHANISTIC ASPECTS OF ADDITIONS OF
NUCLEOPHILES TO DIAZONIUM IONS 143 7.1 (Z)/()-ISOMERISM 143 7.2
INVESTIGATIONS ON REACTIVITIES BY THE INTERPRETATION OF SUBSTITUENT EF-
FECTS: THE HAMMETT AND RELATED EQUATIONS 148 7.3 THE ELECTRONIC
INFLUENCE OF THE DIAZONIO GROUP AS A SUBSTITUENT 151 7.4 INFLUENCE OF
SUBSTITUENTS ON THE ADDITION OF NUCLEOPHILES TO ARENEDIAZONIUM IONS 153
8 DEDIAZONIATION OF ARENEDIAZONIUM IONS 161 8.1 INTRODUCTION TO
DEDIAZONIATION IN GENERAL 161 8.2 MULTIPLICITY OF PATHWAYS AND PRODUCTS
162 8.3 THE D N + A N MECHANISM OF DEDIAZONIATION 166 8.4 MOLECULAR
ORBITAL INVESTIGATIONS ON HETEROLYTIC DEDIAZONIATIONS AND ON ARYL
CATIONS 177 8.5 DEDIAZONIATIONS VIA ARYNE INTERMEDIATES 183 8.6
DEDIAZONIATION INITIATED BY AN ELECTRON TRANSFER 188 8.7 SOLVENT EFFECTS
IN COMPETITIVE HOMOLYTIC AND HETEROLYTIC DEDIAZONIATION 197 8.8
DEDIAZONIATION IN ALKALINE AQUEOUS SOLUTIONS 200 8.9 DEDIAZONIATION IN
HIGHLY NUCLEOPHILIC SOLVENTS AND IN THE PRESENCE OF GOOD NUCLEOPHILES
205 8.10 DEDIAZONIATION IN ALCOHOLS 208 9 LOGIC, PSYCHOLOGY, AND
SERENDIPITY OF SCIENTIFIC DISCOVERIES - AN INTERLUDE 213 10 APPLICATIONS
OF HETEROLYTIC AND HOMOLYTIC DEDIAZONIATIONS IN ORGANIC SYNTHESES 221
10.1 INTRODUCTORY REMARKS 221 10.2 HYDRO-DE-DIAZONIATION 222 10.3
HYDROXY- AND MERCAPTO-DE-DIAZONIATIONS AND RELATED REACTIONS 225 10.4
FLUORO-DE-DIAZONIATION 228 XII 6.3 6.4 6.5 6.6 6.7 CONTENTS XIII 10.5
CHLORO-, BROMO-, AND CYANO-DE-DIAZONIATIONS: THE SANDMEYER REACTION 230
10.6 IODO-DE-DIAZONIATION AND RELATED REACTIONS 235 10.7
AZIDO-DE-DIAZONIATION 240 10.8 DEDIAZONIATION IN THE PRESENCE OF
CARBONYL, SULFONYL, AND RELATED COMPOUNDS 240 10.9 REPLACEMENT OF THE
DIAZONIO GROUP BY ALKENES AND ALKYNES: THE MEERWEIN REACTION 243 10.10
ARYLATION OF AROMATIC COMPOUNDS: THE GOMBERG-BACHMANN AND RELATED
REACTIONS 253 10.11 INTRAMOLECULAR ARYLATION OF AROMATIC AND ALKENE SP 2
-HYBRIDIZED CAR- BON ATOMS 261 10.12 METALLO-DE-DIAZONIATIONS AND
ARYLATION OF TRANSITION ELEMENTS 273 10.13 PHOTOLYTIC DEDIAZONIATIONS
AND THEIR APPLICATIONS IN SYNTHESIS AND IN IMAGE TECHNOLOGY 277 11
HOST-GUEST COMPLEXATION OF ARENEDIAZONIUM SALTS 289 11.1 FORMATION AND
STRUCTURE 289 11.2 COMPLEXATION EQUILIBRIA AND COMPLEX PROPERTIES 296 12
AZO COUPLING REACTIONS 305 12.1 INTRODUCTION 305 12.2 AROMATIC AND
HETEROAROMATIC DIAZO COMPONENTS 308 12.3 QUINONE DIAZIDES AS DIAZO
COMPONENTS 312 12.4 VARIOUS POTENTIAL DIAZO COMPONENTS 313 12.5 AROMATIC
AND HETEROAROMATIC COUPLING COMPONENTS 315 12.6 COUPLING COMPONENTS
CONTAINING ACTIVATED METHYL, METHYLENE, AND METHINE GROUPS 332 12.7
ACID-BASE PRE-EQUILIBRIA 346 12.8 THE SUBSTITUTION PROPER OF C-COUPLING
REACTIONS 354 12.9 MIXING AND DIFFUSION EFFECTS 372 12.10 INFLUENCE OF
THE REACTION MEDIUM 375 12.11 INORGANIC COUPLING COMPONENTS: POLYHEDRAL
BORON HYDRIDES 380 13 FORMATION AND REACTIONS OF TRIAZENES 385 13.1
INTRODUCTION TO PROPERTIES 385 13.2 N-AZO COUPLING REACTIONS 391 13.3
COMPETITIVE N- AND C-AZO COUPLING REACTIONS 395 13.4 REACTIONS OF
TRIAZENES 401 REFERENCES 405 INDEX 445
|
| any_adam_object | 1 |
| author | Zollinger, Heinrich |
| author_facet | Zollinger, Heinrich |
| author_role | aut |
| author_sort | Zollinger, Heinrich |
| author_variant | h z hz |
| building | Verbundindex |
| bvnumber | BV009693997 |
| classification_rvk | VK 7400 |
| ctrlnum | (OCoLC)60241197 (DE-599)BVBBV009693997 |
| dewey-full | 547.043 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.043 |
| dewey-search | 547.043 |
| dewey-sort | 3547.043 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01194nam a2200313 cc4500</leader><controlfield tag="001">BV009693997</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">00000000000000.0</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">940711s1994 d||| |||| 00||| engod</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3527292136</subfield><subfield code="9">3-527-29213-6</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">1560818786</subfield><subfield code="9">1-56081-878-6</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)60241197</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV009693997</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-355</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-29T</subfield><subfield code="a">DE-91G</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-634</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.043</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VK 7400</subfield><subfield code="0">(DE-625)147419:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zollinger, Heinrich</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Diazo chemistry</subfield><subfield code="n">1</subfield><subfield code="p">Aromatic and heteroaromatic compounds</subfield><subfield code="c">Heinrich Zollinger</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Weinheim [u.a.]</subfield><subfield code="b">VCH</subfield><subfield code="c">1994</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIII, 453 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="w">(DE-604)BV009693990</subfield><subfield code="g">1</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">GBV Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006411379&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-006411379</subfield></datafield></record></collection> |
| id | DE-604.BV009693997 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:39:20Z |
| institution | BVB |
| isbn | 3527292136 1560818786 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006411379 |
| oclc_num | 60241197 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-703 DE-29T DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-634 DE-83 DE-11 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-703 DE-29T DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-634 DE-83 DE-11 DE-188 |
| physical | XIII, 453 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | VCH |
| record_format | marc |
| spelling | Zollinger, Heinrich Verfasser aut Diazo chemistry 1 Aromatic and heteroaromatic compounds Heinrich Zollinger Weinheim [u.a.] VCH 1994 XIII, 453 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier (DE-604)BV009693990 1 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006411379&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zollinger, Heinrich Diazo chemistry |
| title | Diazo chemistry |
| title_auth | Diazo chemistry |
| title_exact_search | Diazo chemistry |
| title_full | Diazo chemistry 1 Aromatic and heteroaromatic compounds Heinrich Zollinger |
| title_fullStr | Diazo chemistry 1 Aromatic and heteroaromatic compounds Heinrich Zollinger |
| title_full_unstemmed | Diazo chemistry 1 Aromatic and heteroaromatic compounds Heinrich Zollinger |
| title_short | Diazo chemistry |
| title_sort | diazo chemistry aromatic and heteroaromatic compounds |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006411379&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV009693990 |
| work_keys_str_mv | AT zollingerheinrich diazochemistry1 |