Photoelectron spectroscopy: principles and applications
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin u.a.
Springer
1995
|
| Schriftenreihe: | Springer series in solid-state sciences
82 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturverz. S. 471 - 503 |
| Beschreibung: | XII, 511 S. zahlr. graph. Darst. |
| ISBN: | 3540191089 0387191089 |
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| 100 | 1 | |a Hüfner, Stefan |d 1935-2013 |e Verfasser |0 (DE-588)13202912X |4 aut | |
| 245 | 1 | 0 | |a Photoelectron spectroscopy |b principles and applications |c Stefan Hüfner |
| 264 | 1 | |a Berlin u.a. |b Springer |c 1995 | |
| 300 | |a XII, 511 S. |b zahlr. graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1826212317391486976 |
|---|---|
| adam_text |
STEFAN HUEFNER
PHOTOELECTRON
SPECTROSCOPY
PRINCIPLES
AND APPLICATIONS
WITH 352 FIGURES
SPRINGER-VERLAG
BERLIN
HEIDELBERG NEW YORK
LONDON
PARIS TOKYO
HONG
KONG BARCELONA
BUDAPEST
CONTENTS
1.
INTRODUCTION
1
1
.1
HISTORICAL DEVELOPMENT 1
1.2 THE ELECTRON ESCAPE DEPTH 8
1.3 PHOTOELECTRON SPECTROSCOPY
AND
INVERSE PHOTOELECTRON SPECTROSCOPY 11
1.4 A SIMPLE VIEW OF THE PHOTOEMISSION PROCESSI
THE
SUDDEN APPROXIMATION . . 16
1.5 EXPERIMENTAL ASPECTS 20
2.
CORE LEVELS AND FINAL STATES
27
2.1 CORE-LEVEL BINDING ENERGIES IN ATOMS AND MOLECULES 29
2.1.1
THE EQUIVALENT-CORE APPROXIMATION 29
2.1.2 CHEMICAL SHIFTS 31
2.2 CORE-LEVEL BINDING ENERGIES IN SOLIDS 35
2.2.1 THE BORN-HABER CYCLE IN INSULATORS 35
2.2.2 THEORY OF BINDING ENERGIES 37
2.2.3 DETERMINATION OF BINDING ENERGIES AND CHEMICAL SHIFTS
FROM
THERMODYNAMIC DATA 41
2.3 CORE POLARIZATION 49
2.4 FINAL-STATE MULTIPLETS IN RARE-EARTH VALENCE BANDS 55
2.5 CORE LEVELS OF ADSORBED MOLECULES 65
2.6 QUANTITATIVE CHEMICAL ANALYSIS FROM CORE-LEVEL INTENSITIES. 68
3.
CHARGE-EXCITATION FINAL STATES: SATELLITES
70
3.1 COPPER DIHALIDES: 3D TRANSITION METAL COMPOUNDS 71
3.1.1 CHARACTERISATION OF A SATELLITE 71
3.1.2 ANALYSIS OF CHARGE TRANSFER SATELLITES 76
3.2 THE 6-EV SATELLITE IN NICKEL 88
3.2.1 RESONANCE PHOTOEMISSION 90
3.2.2 SATELLITES IN OTHER METALS 96
3.3 THE GUNNARSSON-SCHOENHAMMER THEORY 100
3.4 PHOTOEMISSION SIGNALS AND NARROW BANDS IN METALS 104
4.
CONTINUOUS SATELLITES AND PLASMON SATELLITES:
XPS
PHOTOEMISSION IN NEARLY FREE ELECTRON SYSTEMS
112
4.1
THEORY 119
4.1.1 GENERAL 119
4.1.2 CORE-LINE SHAPE 121
IX
4.1.3 INTRINSIC PLASMONS 123
4.1.4 EXTRINSIC ELECTRON SCATTERING:
PLASMONS
AND BACKGROUND 124
4.1.5 THE TOTAL PHOTOELECTRON SPECTRUM 126
4.2 EXPERIMENTAL RESULTS 127
4.2.1 THE CORE LINE WITHOUT PLASMONS 127
4.2.2 CORE-LEVEL SPECTRA INCLUDING PLASMONS 129
4.2.3 VALENCE-BAND SPECTRA OF THE SIMPLE METALS 134
4.2.4 SIMPLE METALS: A GENERAL COMMENT 140
4.3 THE BACKGROUND CORRECTION 141
5. VALENCE ORBITALS IN SIMPLE MOLECULES
AND
INSULATING SOLIDS
146
5.1 UPS SPECTRA OF MONATOMIC GASES 146
5.2 PHOTOELECTRON SPECTRA OF DIATOMIC MOLECULES 147
5.3 BINDING ENERGY OF THE H
2
MOLECULE 154
5.4
HYDRIDES ISOELECTRONIC WITH NOBLE GASES 155
NEON (NE) 156
HYDROGEN FLUORIDE (HF) 156
WATER (H
2
0)
156
AMMONIA (NH
3
)
157
METHANE (CH
4
)
157
5.5 SPECTRA OF THE ALKALI HALIDES 158
5.6 TRANSITION-METAL DIHALIDES 164
5.7 HYDROCARBONS 166
5.7.1 GUIDELINES FOR THE INTERPRETATION OF SPECTRA
FROM
FREE MOLECULES 170
5.7.2. LINEAR POLYMERS 171
5.8 INSULATING SOLIDS 176
5.8.1 THE NIO PROBLEM 185
A) OUTLINE 185
B) ANALYSIS OF THE PHOTOEMISSION SPECTRA OF NIO 186
C)
THE OPTICAL GAP IN NIO 193
D) COMPARISON OF THE VALENCE
AND
CONDUCTION-BAND DATA OF NIO AND NIS 196
E) MOTT INSULATION 198
F) BAND STRUCTURES OF TRANSITION-METAL COMPOUNDS. . . 203
5.9
HIGH-TEMPERATURE SUPERCONDUCTORS 205
5.9.1 VALENCE-BAND ELECTRONIC STRUCTURE 207
A) CU
2
0
AND CUO 208
B) HIGH-TEMPERATURE SUPERCONDUCTORS 213
5.9.2 ELECTRON-DISPERSION RELATIONS 220
5.9.3 CORE-LEVEL SHIFTS 225
5.9.4 THE SUPERCONDUCTING GAP 228
5.10 ADSORBED MOLECULES 229
5.10.1
OUTLINE 229
5.10.2
CO ON METAL SURFACES 230
X
6. PHOTOEMISSION OF VALENCE ELECTRONS FROM
METALLIC
SOLIDS IN THE ONE-ELECTRON APPROXIMATION
242
6.1
THEORY OF PHOTOEMISSION:
A
SUMMARY OF THE THREE-STEP MODEL 244
6.2 DISCUSSION OF THE PHOTOCURRENT 252
6.2.1 KINEMATICS OF INTERNAL PHOTOEMISSION
IN
A POLYCRYSTALLINE SAMPLE 252
6.2.2 PRIMARY AND SECONDARY CONES
IN
THE PHOTOEMISSION FROM A REAL SOLID 260
6.2.3 ANGLE-INTEGRATED AND ANGLE-RESOLVED DATA COLLECTION . 261
6.3
PHOTOEMISSION FROM THE SEMI-INFINITE CRYSTAL:
THE
INVERSE LEED FORMALISM 270
6.3.1 BAND STRUCTURE OR ANGLE-RESOLVED UPS REGIME 276
6.3.2
XPS REGIME 276
6.3.3 SURFACE EMISSION 278
6.3.4 ONE-STEP CALCULATIONS 280
6.4 THERMAL EFFECTS 282
6.5 DIPOLE SELECTION RULES FOR DIRECT OPTICAL TRANSITIONS 290
7.
BANDSTRUCTURE
AND
ANGULAR-RESOLVED PHOTOEMISSION SPECTRA
297
7.1 FREE-ELECTRON FINAL-STATE MODEL 299
7.2 METHODS EMPLOYING CALCULATED BAND STRUCTURES 302
7.3
METHODS FOR THE ABSOLUTE DETERMINATION
OF
THE CRYSTAL MOMENTUM 304
7.3.1 TRIANGULATION OR ENERGY COINCIDENCE METHOD 305
7.3.2
BRAGG PLANE METHOD: VARIATION
OF
EXTERNAL EMISSION ANGLE AT FIXED PHOTON FREQUENCY
(DISAPPEARANCE/APPEARANCE
ANGLE METHOD). .
.
.
.
.
.
. 310
7.3.3
BRAGG PLANE METHOD: VARIATION OF PHOTON ENERGY
AT FIXED EMISSION ANGLE (SYMMETRY METHOD) 318
7.3.4
THE SURFACE EMISSION METHOD AND ELECTRON DAMPING . . 323
7.3.5
THE FERMI SURFACE METHOD 324
7.3.6 INTENSITIES AND THEIR USE
IN
BAND STRUCTURE DETERMINATIONS 327
7.3.7 SUMMARY 330
7.4 EXPERIMENTAL BAND STRUCTURES 331
7.4.1 TWO-DIMENSIONAL SYSTEMS 333
7.4.2 THREE-DIMENSIONAL SOLIDS: METALS AND SEMICONDUCTORS . 348
7.4.3
UPS BAND STRUCTURES AND XPS DENSITY OF STATES 353
7.5
A COMMENT 364
8.
SURFACE STATES, SURFACE EFFECTS
367
8.1 THEORETICAL CONSIDERATIONS 369
8.2 EXPERIMENTAL RESULTS ON SURFACE STATES 380
8.3 SURFACE CORE-LEVEL SHIFTS 393
XI
9. INVERSE PHOTOEMISSION SPECTROSCOPY
403
9.1 SURFACE STATES 407
9.2 BULK BAND STRUCTURES 412
9.3 ADSORBED MOLECULES 413
10.
SPIN-POLARIZED PHOTOEMISSION
420
10.1 GENERAL DESCRIPTION 420
10.2 EXAMPLES 421
11
.
PHOTOELECTRON DIFFRACTION
43
1
11.1 EXAMPLES 435
11.2 SUBSTRATE PHOTOELECTRON DIFFRACTION 441
11.3 ADSORBATE PHOTOELECTRON DIFFRACTION 451
11.4 COMMENT 454
APPENDIX
455
A.L TABLE OF BINDING ENERGIES 455
A.2 SURFACE AND BULK BRILLOUIN ZONES OF THE THREE LOW-INDEX
FACES
OF A FACE-CENTERED CUBIC (FCC) CRYSTAL FACE 461
A.3
COMPILATION OF WORK FUNCTIONS 469
REFERENCES
471
SUBJECT INDEX
505
XII |
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| spelling | Hüfner, Stefan 1935-2013 Verfasser (DE-588)13202912X aut Photoelectron spectroscopy principles and applications Stefan Hüfner Berlin u.a. Springer 1995 XII, 511 S. zahlr. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in solid-state sciences 82 Literaturverz. S. 471 - 503 Foto-elektronspectrometrie gtt Photoelectron spectroscopy Photoelektronenspektroskopie (DE-588)4174491-3 gnd rswk-swf Photoelektronenspektroskopie (DE-588)4174491-3 s DE-604 Springer series in solid-state sciences 82 (DE-604)BV000016582 82 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396580&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hüfner, Stefan 1935-2013 Photoelectron spectroscopy principles and applications Springer series in solid-state sciences Foto-elektronspectrometrie gtt Photoelectron spectroscopy Photoelektronenspektroskopie (DE-588)4174491-3 gnd |
| subject_GND | (DE-588)4174491-3 |
| title | Photoelectron spectroscopy principles and applications |
| title_auth | Photoelectron spectroscopy principles and applications |
| title_exact_search | Photoelectron spectroscopy principles and applications |
| title_full | Photoelectron spectroscopy principles and applications Stefan Hüfner |
| title_fullStr | Photoelectron spectroscopy principles and applications Stefan Hüfner |
| title_full_unstemmed | Photoelectron spectroscopy principles and applications Stefan Hüfner |
| title_short | Photoelectron spectroscopy |
| title_sort | photoelectron spectroscopy principles and applications |
| title_sub | principles and applications |
| topic | Foto-elektronspectrometrie gtt Photoelectron spectroscopy Photoelektronenspektroskopie (DE-588)4174491-3 gnd |
| topic_facet | Foto-elektronspectrometrie Photoelectron spectroscopy Photoelektronenspektroskopie |
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