Chemistry and light:
This new textbook provides a concise introduction to all aspects of light-induced processes in chemistry, physics and biology, as well as in medicine and industry. It is up-to-date with the latest advances in the field, in particular the probing of the fastest light-induced reactions on picosecond a...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Royal Society of Chemistry
1994
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | This new textbook provides a concise introduction to all aspects of light-induced processes in chemistry, physics and biology, as well as in medicine and industry. It is up-to-date with the latest advances in the field, in particular the probing of the fastest light-induced reactions on picosecond and femtosecond time scales, and is based on the photochemistry and photophysics degree course devised by the author Chemistry and Light is a must for final year undergraduates, as well as for post-graduate students. It will prove extremely useful for teachers in the preparation of courses and seminars and will provide essential background information for industrial chemists, in one complete source. The book reflects the enthusiasm the author has for his subject, as well as his talent for clear description. Chemistry and Light will be welcomed by students and researchers alike |
| Beschreibung: | XIV, 295 S. graph. Darst. |
| ISBN: | 0851868142 |
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| 520 | |a Chemistry and Light is a must for final year undergraduates, as well as for post-graduate students. It will prove extremely useful for teachers in the preparation of courses and seminars and will provide essential background information for industrial chemists, in one complete source. The book reflects the enthusiasm the author has for his subject, as well as his talent for clear description. Chemistry and Light will be welcomed by students and researchers alike | ||
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| adam_text | CHEMISTRY AND LIGHT PAUL SUPPAN PROFESSOR OF PHYSICAL CHEMISTRY,
UNIVERSITY OF FRIBOURG, SWITZERLAND _* ROYAL FAE . SOCIETY OF 8S *-A
CHEMISTRY CONTENTS CHAPTER 1 INTRODUCTION 1 1.1 LIGHT-INDUCED PROCESSES
IN EVERYDAY LIFE 1 1.1.1 PHOTODEGRADATION PROCESSES: THE NEGATIVE
ACTIONS OF LIGHT 2 1.1.2 IMAGING PROCESSES 3 1.2 GENERAL FEATURES OF
PHOTOCHEMICAL AND PHOTOPHYSICAL PROCESSES 3 1.2.1 THE PATHWAYS OF DARK
REACTIONS AND PHOTOCHEMICAL REACTIONS 4 1.2.2 THE MISTAKEN CONCEPT
OF CATALYSIS BY LIGHT 5 1.2.3 THE RANGE OF PHOTOCHEMICAL REACTIONS:
VIBRATIONAL PHOTOCHEMISTRY AND RADIATION CHEMISTRY 6 1.2.4 CHEMICAL
EFFECTS OF IONIZING RADIATION 8 CHAPTER 2 LIGHT AND MATTER 11 2.1
ELECTROMAGNETIC RADIATION 11 2.1.1 ENERGY, FREQUENCY, WAVELENGTH AND
VELOCITY OF ELECTROMAGNETIC RADIATION 12 2.1.2 THE PHOTOELECTRIC EFFECT
13 2.1.3 COMPTON SCATTERING 14 2.1.4 PHOTON MASS, PHOTON SPIN AND
MOMENTA 15 2.2 MATTER: MOLECULES AND ATOMS, NUCLEI AND ELECTRONS 16
2.2.1 THE PLANETARY MODEL OF THE ATOM: ORBITS AND ORBITALS 16 2.2.2
WAVEFUNCTIONS AND OPERATORS: THE SCHROEDINGER EQUATION 17 2.2.3 THE
PRINCIPLE OF EXCLUSION AND THE UNCERTAINTY PRINCIPLE 20 2.3 THE
INTERACTION OF LIGHT WITH MATTER 22 2.3.1 TRANSITION MOMENTS 23 2.3.2
ELECTRO-OPTICAL PHENOMENA 24 CHAPTER 3 THE ENERGY OF LIGHT: EXCITED
MOLECULES 27 3.1 ORBITALS AND STATES 27 3.1.1 EXCITED STATES OF ATOMS
AND ATOMIC SPECTRA 27 3.1.2 ATOMIC ABSORPTION AND EMISSION SPECTRA 28
CONTENTS 3.1.3 REAL ATOMIC SPECTRA: BROADENING OF ABSORPTION AND
EMISSION LINES 30 3.2 EXCITED STATES OF MOLECULES 30 3.2.1 DIATOMIC
MOLECULES 30 3.2.2 POLYATOMIC MOLECULES 40 3.2.3 LINEAR CONJUGATED
MOLECULES: THE POLYENES 42 3.2.4 CYCLIC CONJUGATED SYSTEMS: AROMATIC
MOLECULES 43 3.3 CHARGE TRANSFER IN EXCITED STATES; TICT STATES 46
3.3.1 CHARGE TRANSFER STATES IN ORGANIC MOLECULES 47 3.3.2 TWISTED
INTRAMOLECULAR CHARGE TRANSFER STATES 49 3.4 TRANSITIONS BETWEEN ENERGY
STATES 49 3.4.1 THERMAL POPULATION OF ELECTRONICALLY EXCITED STATES 51
3.4.2 RADIATIVE TRANSITIONS 51 3.4.3 NON-RADIATIVE TRANSITIONS 62 3.5
QUENCHING OF EXCITED STATES 65 3.5.1 ENERGY TRANSFER 66 3.5.2 QUENCHING
BY ELECTRON TRANSFER 68 3.5.3 THE HEAVY ATOM EFFECT 68 3.5.4
PARAMAGNETIC QUENCHING 69 3.5.5 CONCENTRATION QUENCHING 70 3.5.6 STATIC
AND DYNAMIC QUENCHING 70 3.6 ENERGY LEVELS IN SOLIDS 73 3.6.1 FERMI
LEVELS; DOPED SEMICONDUCTORS 74 3.7 THE PHYSICAL PROPERTIES OF EXCITED
MOLECULES 74 3.7.1 GEOMETRICAL CHANGES IN EXCITED STATES 75 3.7.2
ELECTRON DISTRIBUTIONS AND POLARIZABILITIES 76 3.8 THE EFFECT OF THE
ENVIRONMENT ON THE ENERGY STATES OF MOLECULES 77 3.8.1 NON-SPECIFIC
ELECTROSTATIC INTERACTIONS 77 3.8.2 SPECIFIC SOLUTE-SOLVENT ASSOCIATIONS
79 3.8.3 SOLVATOCHROMIC AND THERMOCHROMIC SHIFTS 79 3.8.4 ION SOLVATION:
THE BORN EQUATION 84 CHAPTER 4 THE CHEMISTRY OF EXCITED MOLECULES 87 4.1
DARK CHEMISTRY AND LIGHT-INDUCED CHEMISTRY 87 4.1.1 PATHWAYS OF DARK
AND LIGHT-INDUCED CHEMICAL REACTIONS 88 4.1.2 ADIABATIC AND
NON-ADIABATIC PROCESSES: THE ROLE OF THE ENERGY OF EXCITED STATES 89
4.1.3 IS THERE A TEMPERATURE EFFECT IN PHOTOCHEMICAL REACTIONS? 91 4.1.4
MONOPHOTONIC AND MULTIPHOTONIC PROCESSES 91 4.1.5 PRIMARY AND SECONDARY
PHOTOCHEMICAL PROCESSES 92 4.1.6 KINETICS OF PHOTOCHEMICAL REACTIONS 94
4.2 PHOTOIONIZATION, LIGHT-INDUCED ELECTRON CAPTURE AND ELECTRON
TRANSFER REACTIONS 95 4.2.1 INTRAMOLECULAR AND INTERMOLECULAR ELECTRON
TRANSFER 97 4.2.2 THE MARCUS-HUSH MODEL OF ELECTRON TRANSFER 101 4.3
ELECTRONICALLY EXCITED SUPER MOLECULES: EXCIMERS AND EXCIPLEXES 104 4.4
ORGANIC PHOTOCHEMISTRY 110 4.4.1 THE MECHANISMS OF PHOTOCHEMICAL
REACTIONS: QUENCHING, SENSITIZATION AND WAVELENGTH EFFECTS 111 4.4.2
UNIMOLECULAR REACTIONS 113 4.4.3 PROTOLYTIC EQUILIBRIA (ACID-BASE
REACTIONS) 126 4.4.4 BIMOLECULAR REACTIONS 130 4.5 PHOTOELECTROCHEMISTRY
140 4.5.1 REACTIONS AT ELECTRONICALLY EXCITED SEMICONDUCTOR ELECTRODES
141 4.6 INORGANIC PHOTOCHEMISTRY 142 4.6.1 EXCITED ATOM REACTIONS 143
4.6.2 PHOTOINDUCED REDOX REACTIONS OF IONS IN SOLUTION 143 4.6.3
PHOTOPHYSICS AND PHOTOCHEMISTRY OF METAL COMPLEXES 144 4.7
PHOTOCHEMISTRY IN SOLIDS AND ORGANIZED ASSEMBLIES 151 4.7.1 TYPES OF
SOLIDS 152 4.7.2 PHOTOCHEMICAL REACTIONS IN GLASSES 152 4.7.3 EXCITONS
IN POLYMERS AND CRYSTALS 153 4.7.4 BIMOLECULAR PHOTOCHEMICAL REACTIONS
IN SOLIDS 153 4.7.5 PHOTOCHEMISTRY IN MICELLES 154 4.8 CHEMILUMINESCENCE
155 4.8.1 ELECTROLUMINESCENCE / 155 4.8.2 CHEMILUMINESCENCE SENSITIZED
BY THE DECOMPOSITION OF CYCLIC PEROXIDES 156 4.8.3 CHEMILUMINESCENCE OF
FREE RADICAL REACTIONS 157 4.9 REACTIONS OF FREE RADICALS 157 4.9.1
RESONANCE STABILIZATION OF FREE RADICALS 158 4.9.2 THE REACTIONS OF FREE
RADICALS 159 4.9.3 MAGNETIC FIELD EFFECTS IN FREE RADICAL REACTIONS 159
4.9.4 EXCITED STATES OF FREE RADICALS 160 4.9.5 PHOTOCHEMICAL REACTIONS
OF FREE RADICALS 160 XLL CONTENTS CHAPTER 5 LIGHT AND LIFE 16 3 5.1
ULTRAVIOLET LIGHT IN BIOLOGY AND MEDICINE 164 5.2 PHOTOSYNTHESIS 165 5.3
VISION AND PHOTOTAXIS 171 5.4 PHOTORESPONSE MECHANISMS IN PLANTS AND
ANIMALS 175 5.5 PHOTOCHEMICAL DAMAGE IN LIVING SYSTEMS 176 5.5.1
PHOTOCHEMISTRY OF NUCLEIC ACIDS 177 5.5.2 PHOTOCHEMISTRY OF PROTEINS 180
5.6 PHOTOCHEMISTRY IN BIOSYNTHESIS 181 5.7 PHOTOMEDICINE 181 5.7.1 THE
REPAIR OF DETACHED RETINAS BY LASER WELDING 182 5.7.2 PHOTOCHEMICAL
EFFECTS OF VIS AND UV LIGHT 182 5.8 BIOLUMINESCENCE 184 5.8.1 THE ROLE
OF BIOLUMINESCENCE; ITS ORIGINS IN EVOLUTION 184 CHAPTER 6 LIGHT IN
INDUSTRY 186 6.1 PHOTOGRAPHIC PROCESSES 186 6.1.1 SPECTRAL SENSITIZATION
188 6.1.2 COLOUR PHOTOGRAPHY 190 6.1.3 INSTANT PHOTOGRAPHY 191 6.1.4
ELECTROPHOTOGRAPHY: THE PHOTOCOPYING PROCESS 192 6.2 PHOTOPOLYMERIZATION
AND PHOTOCHEMICAL DEGRADATION OF POLYMERS 193 6.2.1 PHOTOCHEMICAL CURING
OF SURFACE COATINGS 195 6.2.2 CHEMICAL STRUCTURES OF POLYMERS 195 6.2.3
PHOTOINITIATION OF POLYMERIZATION 197 6.2.4 PHOTODEGRADATION OF POLYMERS
AND PROTECTION METHODS 198 6.3 PHOTOCHEMISTRY IN SYNTHESIS 201 6.3.1
PHOTOEHLORINATION OF POLYMERS 202 6.3.2 THE SYNTHESIS OF CAPROLACTAM 202
6.3.3 THE SYNTHESES OF VITAMIN D AND OF ROSE OXIDE 203 6.3.4
PHOTOCHEMICAL REACTORS 204 9 6.4 PHOTOCHEMISTRY OF DYES AND PIGMENTS 205
6.5 PHOTOCHROMISM 207 6.6 ENERGY CONVERSION AND STORAGE 209 6.6.1
PHOTOELECTROCHEMICAL CELLS 210 6.7 ATMOSPHERIC POLLUTION AND THE OZONE
LAYER 211 6.7.1 THE OZONE LAYER; ITS PHOTOCHEMICAL FORMATION AND
DEGRADATION PROCESSES 213 6.7.2 TIME DEPENDENCE OF POLLUTANT
CONCENTRATIONS 214 CONTENTS XIII CHAPTER 7 EXPERIMENTAL TECHNIQUES 216
7.1 LIGHT SOURCES, FILTERS AND MONOCHROMATORS 216 7.1.1 SUNLIGHT, THE
FIRST LIGHT SOURCE 216 7.1.2 INCANDESCENT LAMPS AND ARE LAMPS 217 7.1.3
SOME OTHER LIGHT SOURCES 218 7.1.4 OPTICAL FILTERS 220 7.1.5
SPECTROGRAPHS AND MONOCHROMATORS 222 7.2 LASERS 225 7.2.1 GENERAL
PRINCIPLES; TWO-, THREE- AND FOUR-LEVEL LASERS 225 7.2.2 SOLID STATE
LASERS: RUBY AND ND/YAG 226 7.2.3 FREQUENCY CONVERSION OF LASER LIGHT
228 7.2.4 GAS LASERS 230 7.2.5 DYE LASERS 231 7.2.6 THE PROPERTIES OF
LASER LIGHT 232 7.2.7 SELF-PHASE MODULATION: WHITE LIGHT FROM
MONOCHROMATIC LASERS 233 7.3 LUMINESCENCE MEASUREMENTS 233 7.3.1
PHOTOLUMINESCENCE 234 7.3.2 ELECTROLUMINESCENCE 234 7.3.3
CHEMILUMINESCENCE AND BIOLUMINESCENCE 235 7.3.4 CORRECTION OF EMISSION
AND EXCITATION SPECTRA 235 7.3.5 LIGHT DETECTORS 236 7.3.6 SINGLE PHOTON
COUNTING 239 7.3.7 EXPERIMENTAL CONDITIONS FOR LUMINESCENCE MEASUREMENTS
240 7.3.8 LUMINESCENCE QUANTUM YIELD MEASUREMENTS 241 7.4 FLASH
PHOTOLYSIS 242 7.4.1 CONVENTIONAL (MICROSECOND) FLASH PHOTOLYSIS 242
7.4.2 NANOSECOND LASER FLASH PHOTOLYSIS 244 7.4.3 LUMINESCENCE KINETICS;
DECONVOLUTION 246 7.4.4 TIME-RESOLVED SPECTROSCOPY 248 7.4.5 SPECIAL
DETECTION TECHNIQUES IN FLASH PHOTOLYSIS: PHOTOCONDUCTIVITY, THERMAL
LENSING, PHOTOACOUSTICS, ETC. 250 7.5 QUANTUM YIELDS OF PHOTOCHEMICAL
REACTIONS: ACTINOMETRY 253 7.5.1 TYPES OF ACTINOMETERS 254 CHAPTER 8 THE
FRONTIERS OF PHOTOCHEMISTRY 256 8.1 PICOSECOND FLASH PHOTOLYSIS 257
8.1.1 SPECTROGRAPHIC PICOSECOND LASER FLASH PHOTOLYSIS 257 8.1.2 KINETIC
PICOSECOND LASER FLASH PHOTOLYSIS 258 8.1.3 SAMPLING TECHNIQUES FOR
REPETITIVE EVENTS 258 XIV CONTENTS 8.1.4 INDIRECT OPTICAL METHODS:
AUTOCORRELATION AND UP-CONVERSION 259 8.1.5 PICOSECOND LIGHT-INDUCED
PROCESSES 260 8.2 FEMTOSECOND FLASH PHOTOLYSIS 263 8.2.1 FEMTOSECOND
DETECTION METHODS 264 8.2.2 FEMTOSECOND PHOTOCHEMICAL PROCESSES 266 8.3
SUPRAMOLECULAR PHOTOCHEMISTRY 268 8.4 PHOTOCHEMISTRY IN MOLECULAR FILMS
271 8.5 PHOTOCHEMISTRY IN MOLECULAR BEAMS 274 8.5.1 MOLECULAR BEAM
PHOTOINDUCED REACTIONS 276 8.6 VIBRATIONAL PHOTOCHEMISTRY WITH INFRARED
LIGHT 278 8.7 SPECTRAL HOLE BURNING 280 APPENDICES 283 2A EXPERIMENTAL
MEASUREMENT OF THE PHOTON SPIN 283 3A RELATIONSHIPS BETWEEN EMISSION
RATE CONSTANTS AND ABSORPTION COEFFICIENTS 284 3B BANDGAP ENERGIES OF
SOME SEMICONDUCTORS 285 7A POLARIZABILITY AND HYPERPOLARIZABILITY 286 7B
SIGNAL-TO-NOISE RATIO 287 7C PROCEDURES OF DEOXYGENATION 288 FURTHER
READING 289 SUBJECT INDEX 292
|
| any_adam_object | 1 |
| author | Suppan, Paul |
| author_facet | Suppan, Paul |
| author_role | aut |
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| building | Verbundindex |
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| callnumber-label | QD708 |
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| callnumber-sort | QD 3708.2 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 8300 VH 5600 VK 5600 |
| classification_tum | PHY 524f CHE 625f BIO 148f CHE 725f CHE 812f CHE 189f |
| ctrlnum | (OCoLC)30033883 (DE-599)BVBBV009616755 |
| dewey-full | 541.3 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.3 |
| dewey-search | 541.3 |
| dewey-sort | 3541.3 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Biologie Chemie |
| format | Book |
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Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1="3" ind2=" "><subfield code="a">This new textbook provides a concise introduction to all aspects of light-induced processes in chemistry, physics and biology, as well as in medicine and industry. 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| id | DE-604.BV009616755 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:38:00Z |
| institution | BVB |
| isbn | 0851868142 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006355288 |
| oclc_num | 30033883 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-11 DE-525 |
| owner_facet | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-11 DE-525 |
| physical | XIV, 295 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | Royal Society of Chemistry |
| record_format | marc |
| spelling | Suppan, Paul Verfasser aut Chemistry and light Paul Suppan Cambridge Royal Society of Chemistry 1994 XIV, 295 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier This new textbook provides a concise introduction to all aspects of light-induced processes in chemistry, physics and biology, as well as in medicine and industry. It is up-to-date with the latest advances in the field, in particular the probing of the fastest light-induced reactions on picosecond and femtosecond time scales, and is based on the photochemistry and photophysics degree course devised by the author Chemistry and Light is a must for final year undergraduates, as well as for post-graduate students. It will prove extremely useful for teachers in the preparation of courses and seminars and will provide essential background information for industrial chemists, in one complete source. The book reflects the enthusiasm the author has for his subject, as well as his talent for clear description. Chemistry and Light will be welcomed by students and researchers alike Biologie ram Chimie des états excités Chimie ram Fotochemie gtt Fotoquimica larpcal Lumière ram Photochimie Photochimie ram Physique ram Spectrometrie gtt Photochemistry Photobiologie (DE-588)4174474-3 gnd rswk-swf Selbstreplikation (DE-588)4481488-4 gnd rswk-swf Fotophysik (DE-588)4193388-6 gnd rswk-swf Fotochemie (DE-588)4045873-8 gnd rswk-swf Selbstreplikation (DE-588)4481488-4 s Fotochemie (DE-588)4045873-8 s DE-604 Fotophysik (DE-588)4193388-6 s Photobiologie (DE-588)4174474-3 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006355288&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Suppan, Paul Chemistry and light Biologie ram Chimie des états excités Chimie ram Fotochemie gtt Fotoquimica larpcal Lumière ram Photochimie Photochimie ram Physique ram Spectrometrie gtt Photochemistry Photobiologie (DE-588)4174474-3 gnd Selbstreplikation (DE-588)4481488-4 gnd Fotophysik (DE-588)4193388-6 gnd Fotochemie (DE-588)4045873-8 gnd |
| subject_GND | (DE-588)4174474-3 (DE-588)4481488-4 (DE-588)4193388-6 (DE-588)4045873-8 |
| title | Chemistry and light |
| title_auth | Chemistry and light |
| title_exact_search | Chemistry and light |
| title_full | Chemistry and light Paul Suppan |
| title_fullStr | Chemistry and light Paul Suppan |
| title_full_unstemmed | Chemistry and light Paul Suppan |
| title_short | Chemistry and light |
| title_sort | chemistry and light |
| topic | Biologie ram Chimie des états excités Chimie ram Fotochemie gtt Fotoquimica larpcal Lumière ram Photochimie Photochimie ram Physique ram Spectrometrie gtt Photochemistry Photobiologie (DE-588)4174474-3 gnd Selbstreplikation (DE-588)4481488-4 gnd Fotophysik (DE-588)4193388-6 gnd Fotochemie (DE-588)4045873-8 gnd |
| topic_facet | Biologie Chimie des états excités Chimie Fotochemie Fotoquimica Lumière Photochimie Physique Spectrometrie Photochemistry Photobiologie Selbstreplikation Fotophysik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006355288&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT suppanpaul chemistryandlight |