Adsorption and chromatography:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Wiley [u.a.]
1953
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| Ausgabe: | 2. print. |
| Schriftenreihe: | Technique of organic chemistry
5 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 360 S. Ill., graph. Darst. |
Internformat
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Datensatz im Suchindex
| _version_ | 1804123405523353600 |
|---|---|
| adam_text | TECHNIQUEOFORGANICCHEMISTRY
Volume V
ADSORPTION AND
CHROMATOGRAPHY
HAROLD GOMES
ASSOCIATE PROFESSOR
YALE UNIVERSITY, NEW
CASSIDY
IN CHEMISTRY
HAVEN, CONNECTICUT
INTERSCIENCEPUBLISHERS,INC,
INTERSCIENCE PUBLISHERS
N E W
LTD ,
YORK
LONDON
TECHNIQUEOFORGANICCHEMISTRY
Volume V
• /
ADSORPTIONANDCHROMATOGRAPHY
CONTENTS
Preface vii
General References xvii
I Definitions—Molecular Aspects of Adsorption 1
I Definitions X
II Energy of Adsorption 6
III Molecular Aspects of Adsorption 7
1 Solid-Gas or Solid-Vapor Interface 7
2 Vapor-Liquid Interface 8
A Pure Liquid 8
b Vapor-Solution Interface 9
Soluble, Surface-Active Solute 9
Soluble, Nonsurface-Active Solute 18
Insoluble Adsorptive 18
3 Liquid-Liquid Interface 22
4 Liquid-Solid Interface • 24
A Solid-Pure Liquid Interface 25
B Solution-Solid Interface 27
5 Interfaces between Three Phases 39
IV Summary 41
II Measurement of Adsorption Treatmentof Data 47
I Introduction 47
II Solid-Gas Interface 48
1 Types of Isotherms 49
2 Theories of Adsorption 50
3 Surface Area of a Solid 54
III Vapor-Liquid Interface 56
1 Vapor-Pure Liquid 57
2 Solution-Vapor 57
A Introduction 57
B Measurement of Absolute Amount of Adsorption 59
c Soluble Adsorptive 60
Types of Data 61
D Insoluble Adsorptive 67
E Viscous Interfaces 67
xii CONTENTS
II Measurement of Adsorption (continued)
IV Solid-Liquid Interface 68
1 Solid-Pure Liquid 68
2 Solution-Solid 68
V Measurement of the Contact Angle 79
III Relations between Relative Adsorbal ility and Properties of
Phases 81
I Introduction 81
II Relation between Solubility and Adsorb ibility 81
1 Solution-Vapor Interface 83
A Pairs of Liquids 83
B Homologous Adsorptives 84
c Altered Solubilities 86
Alteration of Solubility by Tempi rature Change 86
Alteration of Solubility by Admix ture 88
2 Solution-Solid Interface 90
A Adsorption for Binary Mixtures 91
B Adsorption of Homologs from a Given Solvent to a Given
Adsorbent 94
c Adsorption of Isomers 94
D Adsorption of Substances Not Isomers or Homologs 94
E Effect of Temperature 94
F Effect of Admixture 95
G Comparison of Solvents 97
III Surface Tension of the Solvent 101
IV Polarity of the Solvent 101
V Polarity of the Adsorbent 104
IV Relatidns between Relative Extent of Adsorption and Properties of
Adsorptive 109
I Introduction 109
II Adsorption and Chemical Structure 109
1 Hydrocarbons and Some Derivativi - 110
2 Alcohols and Phenols Ill
3 Carbonyl Compounds 113
4 Fatty Acids 114
Class a 115
Class b •• 116
Class c 117
5 Aromatic Carboxylic Acids 118
6 Dicarboxylic Acids 118
7 Esters 121
8 Amines 122
9 Amino Acids 122
10 Carbohydrates 123
11 Lipids, etc 123
12 Corresponding and Related Compounds 124
13 Relation between Structure and Absorbability Summary 126
III Adsorption and Molecular Weight 128
IV Adsorption and Melting Point 128
CONTENTS Xiii
L
IV Relations between Relative Extent of Adsorption and Properties of
Adsorptive (continued)
V Adsorption and Shapes of Molecules 129
VI Adsorption and Surface Tension of the Pure Ad iorptive 131
VII Adsorption and Association of the Adsorptive 133
VIII , Adsorption and Ionization of the Adsorptive 134
IX Adsorption and Polarity 136
1 Dipole Moment 136
2 Solubility Behavior 139
3 Dielectric Constant 139
«
4 Polarizability 141
X Adsorption and Hydrogen Bonding Ability 145
XI Summary 147
V Summary of Relations Graded Eluents and Adsorbents 149
I Introduction 149
II Homology 149
III Graded Series of Eluents • 152
1 General Remarks 152
2 Class One—Gradations of Eluents Based on Differences between
Homologs 153
3 Class Two—-Gradations of Eluents Based on Differences in
Concentration 153
4 Class Three—Gradations of Eluents Bas( d on Differences in
Functionality 154
5 Use of a Graded Series of Eluents 155
V Graded Series of Adsorbents 157
1 General Remarks 157
2 Class One—Gradations of Adsorbents Base d on Differences in
Acjlivity 158
3 Class Two—Gradations of Adsorbents Bastd on Differences in
Functionality of the Surface 159
V Role of the Interface 160
VI Value of Heat of Wetting as a Guide 161
VII Prediction of Relative Extent of Adsorption 163
1 General Remarks 163
2 Relative Polar Character 163
VIII General Rules for Predicting Relative Extent of Adsorption 164
VI On the Nature of Separation Processes 167
I Introduction 167
II Cross-Table of Distribution Processes 167
III Operations Involved in the Processes 169
VII Batchwise Adsorption and Decolorization Lists of Adsorbents 177
I Introduction 177
II Batchwise Adsorption 181
1 Requirement of Contact , 181
2 Duration of Contact 181
3 Recognition of Adsorption 182
4 Some Applications of Adsorbents 182
5 Mobile Interfaces 185
III Decolorization 185
xiv CONTENTS
VII Batchwise Adsorption and Decolorization (continued)
IV Adsorbents 188
1 Aluminas and Related Materials 189
2 Charcoals and Carbons 190
3 Clays and Related Substances 192
4 Diatomaceous Earths Filter Aids 195
5 Ion Exchange-Resins and Zeolites 196
6 Silicas and Silica Gels 196
7 Additional Inorganic Substances U c :d as Adsorbents 197
8 Organic Substances Used as Adsorbents • 199
V Standardization and Evaluation of Adsorbents 200
1 General Adsorbents 200
2 Chromatographic Adsorbents 202
VI Activation of Adsorbents 205
VII Recovery of Adsorbents 206
VIII Chromatography (Tswett-Column Analysis, Chromatographic
Adsorption Analysis, Differential Countercurrent Adsorption
Analysis) 207
I Introduction 207
II Nature of Chromatography 208
III Theory of Chromatography 213
IV Apparatus and Materials 227
V Manipulations and Phenomena 239
VI Advantages and Limitations of Chromatography 253
VII Use in Testing Purity 258
VIII Chromatography with Mobile Interface? 260
1 Apparatus 260
j2 Procedure 261
IX Applications of Chromatography _ 263
IX Ion Exchange Methods 267
I Introduction 267
II Ion Exchange Substances 268
III, Types of Exchange Behavior 270
IV Types of Behavior Other than Exchange 272
V Qualitative and Quantitative Relations in Ion Exchange Action 275
VI Applications 285
VII Methods of Using Ion Exchangers 286
X Partition Chromatography 291
I Introduction 291
II Theory 292
III Partition Chromatography with Columns 293
1 General Description 294
2 Preparation of the Adsorbent 294
3 Use of Indicators 295
4 Developer Solutions 295
5 Qualitative Analysis 296
6 Quantitative Analysis 297
7 Examples 298
CONTENTS XV
X Partition Chromatography (continued)
I V Partition Chromatography with Strips and Sheets 300
1 General Description 301
2 Apparatus 302
3 Developers 304
4 Procedure for Strips 307
5 Procedure for Sheets 308
6 Rate of Movement of Zones 308
7 Qualitative Analysis 309
8 Quantitative Analysis 311
9 Some Variables Encountered 312
V Some Further Considerations 313
XI On the Use of Adsorption 319
I Introduction • 319
II Familiarizing Experiments 319
1 Decolorization 319
2 Chromatography 1 320
A Colored Adsorptives 320
B Colorless Substances 322
3 Use of Ion Exchangers 323
4 Partition Chromatography oh a Column 323
5 Partition Chromatography on Paper 324
III Solution of Problems of Separation 326
Author Index 329
Subject Index 341
Cumulative Indexes, Volumes I-V 357
If *
O
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| series2 | Technique of organic chemistry |
| spelling | Cassidy, Harold G. Verfasser aut Adsorption and chromatography Harold Gomes Cassidy 2. print. New York Wiley [u.a.] 1953 XIX, 360 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Technique of organic chemistry 5 Adsorptionschromatographie (DE-588)4068422-2 gnd rswk-swf Adsorption (DE-588)4000536-7 gnd rswk-swf Chromatographie (DE-588)4010153-8 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Chromatographie (DE-588)4010153-8 s DE-604 Adsorption (DE-588)4000536-7 s Organische Verbindungen (DE-588)4043816-8 s 1\p DE-604 Adsorptionschromatographie (DE-588)4068422-2 s 2\p DE-604 Technique of organic chemistry 5 (DE-604)BV001889799 5 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005989725&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Cassidy, Harold G. Adsorption and chromatography Technique of organic chemistry Adsorptionschromatographie (DE-588)4068422-2 gnd Adsorption (DE-588)4000536-7 gnd Chromatographie (DE-588)4010153-8 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| subject_GND | (DE-588)4068422-2 (DE-588)4000536-7 (DE-588)4010153-8 (DE-588)4043816-8 |
| title | Adsorption and chromatography |
| title_auth | Adsorption and chromatography |
| title_exact_search | Adsorption and chromatography |
| title_full | Adsorption and chromatography Harold Gomes Cassidy |
| title_fullStr | Adsorption and chromatography Harold Gomes Cassidy |
| title_full_unstemmed | Adsorption and chromatography Harold Gomes Cassidy |
| title_short | Adsorption and chromatography |
| title_sort | adsorption and chromatography |
| topic | Adsorptionschromatographie (DE-588)4068422-2 gnd Adsorption (DE-588)4000536-7 gnd Chromatographie (DE-588)4010153-8 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| topic_facet | Adsorptionschromatographie Adsorption Chromatographie Organische Verbindungen |
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