Lehrbuch der angewandten Chemie: 3 Quantitativ-anorganisches Praktikum
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Leipzig
Hirzel
1975
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| Ausgabe: | 2., durchges. Aufl. |
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| Beschreibung: | 604 S. Ill., graph. Darst. |
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| 245 | 1 | 0 | |a Lehrbuch der angewandten Chemie |n 3 |p Quantitativ-anorganisches Praktikum |c von Gerhard-Otfried Müller |
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| 300 | |a 604 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
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| adam_text | Titel: Bd. 3. Lehrbuch der angewandten Chemie. Quantitativ-anorganisches Praktikum
Autor: Müller, Gerhard-Otfried
Jahr: 1975
Inhaltsverzeichnis
1. Einleitung 13
Teil I
2. Die graytaietriselie Analyse............................................................................................16
2.1. Allgemeines ..........................................................................................................................16
2.2. Theorie der Milling..........................................................................................................17
2.2.1. Ionenkonzeatiation............................................................................................................17
2.2.2. Massenwirkungsgesetz (MWG) ........................................................................................20
2.2.3. Löslichkeitsprodukt ...............................................................22
2.2.4. Fällung von Sehwernietallhydroxiden............................................................................25
2.3. Beeinflussung der Fällung................................................................................................29
2.3.1. LöslicKkeitsheeinflussung..........................................................26
2.3.2. Auflösen des Niederschlages............................................................................................32
2.4. Berechnung der Analyse ..................................................................................................36
2.5. Analytische Geräte.............................................................38
2.6. Allgemeine Arbeitsweise....................................................................................................40
2.6.1. Einfache Bestimmungen....................................................................................................41
2.6.2. Trennungen........................................................................................................................42
2.6.3. Indirekte Analyse..............................................................................................................43
2.6.4. Planung und Protokollierung..........................................................................................44
2.7. Vorbehandlung und Aufschluß der Analysensubstanz................................................4a
2.8. Bildung des Niederschlages.................................................................................46
2.9. Fällen und Filtrieren........................................................................................................48
2.9.1. Verunreinigungen..............................................................................................................48
2.8.2. Alterung des Niederschlages............................................................................................50
2.9.3. Filtrieren ............................................................................................................................50
2.9.4. Auswaschen........................................................................................................................52
2.10. Trocknen, Veraschen und Glühen....................................................................................53
2.10.1. Trocknen .................................*........................................................53
2.10.2. Veraschen..................................................................................54
2.10.3. Glühen ................................................................................................................53
2.10.4. Platin-Geräte......................................................................................................................55
2.11. Die Wägung..........................................................................................56
2.11.1. Theorie der Wägung ....................................................................................................57
2.12. Spezielle Reagenzien .....................................................................................................60
2.12.1. Schwefelwasserstoff ..........................................................................................................60
2.12.2. Thiooarbaminat..................................................................................................................62
2.12.3. Thioharnstoff...............................................................................................................63
2.12.4. Organisehe Reagenzien....................................................................................................64
8. Die Tolumeirische Analyse..............................................................................................67
3.1. Allgemeines.........................................................................67
3.2. Die Meßgeräte..............................................................................68
3.2.1. Meßkolben.............................................................................................69
3.2.2. Meßzylinder........................................................................................................................69
3.2.3. Pipette ................................................................................................................................70
3.2.4. Bürette................................................................................................................................71
3.3. Reinigung der Meßgeräte ................................................................................................72
3.4. Eichung der Gefäße ..........................................................................................................72
3.4.1. Abgrenzung des Inhalts....................................................................................................73
3.4.2. Bestimmung des Wassergewichts....................................................................................73
3.5. Normallösungen..................................................................................................................74
3.6. Teilgebiete der Volumetrie ..............................................................................................77
3.6.1. ßedoxtitrationen (Oxydimetrie)......................................................................................77
3.6.1.1. Mauganometrie ..................................................................................................................82
3.6.1.2. Jodometrie..........................................................................................................................86
3.6.1.3. Jodatometrie......................................................................................................................91
3.6.1.4. Bromatometrie ..................................................................................................................93
3.6.1.5. Bromometrie und Chromatometrie .........................................................................94
3.6.1.6. Cerimetrie ..........................................................................................................................96
3.6.2. Sällungsanalysen ..............................................................................................................96
3.6.2.1. Argentometrie....................................................................................................................97
3.6.2.2. Andere fällungsanalytische Verfahren............................................................................108
3.6.2.3. Tüpfelanalysen ..................................................................................................................110
3.6.3. Chelatometrie..............................................................HO
3.6.4. JSeutralisationsanalysen....................................................................................................117
3.6.4.1. Säure-Base-Reaktion................................................................................................118
3.6.4.2. pH-Wert protolytisoher Reaktionen ..............................................................................123
3.6.4.3. Titrationskurven................................................................................................................125
3.6.4.4. Indikatoren ........................................................................................................................131
3.7. Durchführung und Auswertung der Maßanalysen........................................................147
3.7.1. Titrierfehler.................................................................................................148
4. Die eiet^roebemlselie Analyse............................................ 151
4.1. Allgemeines ........................................................................................................................151
4.2. Elefefcrolytische Bestimmungen........................................................................................152
4.2.1. Elektrogravimetrie............................................................................................................152
4.2.2. Coulometrie........................................................................................................................163
4.3. Potentiometrie ..................................................................................................................166
4.3.1. Wendepunktsmethode......................................................................................................170
4.3.2. Bezugssysteme ..........................................................................................173
4.3.3. Potentialmessung ..............................................................................................................175
4.3.4. Simultanbestimmungen......................................................180
4.4. Konduktometrie...........................................................182
4.4.1. Ionenbewegliehkeit und Überführungszahlen ..............................................................184
4.4.2. Titrationskurven...................................................................186
4.4.3. Messung .........................................................................................................................190
4.5. Polarolytische Verfahren..................................................................................................191
4.5.1. Polarographie......................................................................................................................191
4.5.2. Amperometrie....................................................................................................................198
4.5.3. Voltametrie ........................................................................................................................200
5. Die kolorimetrische Analyse.............................................. 203
5.1. Theoretische Grundlagen .....................»........................... 203
5.2. Kolorimetrische Meßgeräte................................................ 205
5.3. Allgemeine Arbeitsweise..................................................
208
Phasentrennung.....................................................
6.1. Verteilimgsverfahren ...............................................
6.1.1. Theoretische Grundlagen.............................................
6.1.2. Einfache und multiplikative Verteilung...............................
6.1.3. Anwendung der Verteilungsverfahren.................................
6.2. Chromatographie ...................................................
6.2.1. Säulenchromatographie.............................................
6.2.2. Papierchromatographie .............................................
7. Literaturverzeichnis.................................................
Teil II
8. Vorbemerkungen ...................................................
0. Die Kationen......................................................
9.1. Gruppe I...........................................................
9.1.1. Silber ............................................................
9.1.2. Quecksilber........................................................
9.1,3 Blei...............................................................
9.1.4. Thallium..........................................................
9.2. Gruppe IIa ........................................................
9.2.1. Wismut ...........................................................
9.2.2. Kupfer............................................................
9.2.3. Kadmium .........................................................
9.3. Gruppe IIb.........................................................
9.3.1. Arsen..............................................................
9.3.2. Antimon ...........................................................
9.3.3. Zinn...............................................................
9.3.4-. Gold............................................................
9.3.5. Platin .............................................................
9.3.6. Palladium..........................................................
9.3.7. Molybdän..........................................................
9.3.8. Selen ..............................................................
9.3.9. Tellur..............................................................
9.4. Gruppe III.........................................................
9.4.1. Lanthan ...........................................................
9.4.2. Oer................................................................
9.4.3. Zirkonium..........................................................
9.4.4. Thorium...........................................................
9.5. Gruppe IVa........................................................
9.5.1. Eisen..............................................................
9.5.2. Mangan............................................................
9.5.3. Kobalt.............................................................
9.5.4. Nickel.............................................................
9.5.5., Titan..............................................................
9.5.6. Uran..............................................................
9.6. Gruppe IVb........................................................
9.6,1. Aluminium.........................................................
0.6.2. Beryllium..........................................................
9.6.3. Chrom.............................................................
9.6.4. Zink ..............................................................
9.6.5. Indium ............................................................
9.6.6. Gallium............................................................
9
210
210
210
211
213
213
216
217
218
219
222
222
222
229
236
251
253
254
265
288
296
297
307
313
319
321
323
324
329
332
333
334
334
336
338
340
341
357
365
374
382
385
391
391
400
401
409
420
421
9.6.7, Niob ....................................................................................................................................424
9.6.8. Tantal..................................................................................................................................425
9.7. Gruppe V............................................................................................................................426
9.7.1. Wolfram..............................................................................................................................427
9.7.2. Vanadium ..........................................................................................................................430
9.8. Gruppe VI..........................................................................................................................434
9.8.1. Calcium ..............................................................................................................................434
9.8.2. Strontium............................................................................................................................443
9.8.3. Barium................................................................................................................................445
9.8.4. Magnesium..........................................................................................................................449
9.9. Gruppe VII ........................................................................................................................454
9.9.1. Natrium..............................................................................................................................454
9.9.2. Kalium................................................................................................................................462
9.9.3. Ammonium ........................................................................................................................467
9.9.4. Lithium.....................................................................................................469
10. Die Anionen............................................................ 471
10.1. Gruppe Ia.............................................................. 471
10.1.1. CMor.................................................................. 471
10.1.2. Chlorid ................................................................472
10.1.3. Chlorat................................................................ 477
10.1.4. Perchlorat.............................................................. 479
10.1.5. Brom.................................................................. 482
10.1.6. Bromid................................................................ 482
10.1.7. Jod ................................................................... 483
10.1.8. Jodid..................................................................483
10.1.9. Jodat ................................................................. 486
10.1.10. Perjodat............................................................... 487
10.1.11. Fluorid................................................................ 488
10.2. Gruppelb ............................................................. 491
10.2.1. Cyanid................................................................. 491
10.2.2. Rhodanid.............................................................. 494
10.2.3. Hexaeyanoferrat(II)-KompIex............................................ 497
10.2.4. Hexacyanoferrat(III)-Komplex ........................................... 499
10.3. Gruppe II.............................................................. 500
10.3.1. Sulfit ................................................................. 500
10.3.2. Sulfat ................................................................. 502
10.3.3. Sulfid ................................................................. 504
10.3.4. Thiosulfat.............................................................. 506
10.3.5. Dithionat.............................................................. 507
10.3.6. Persulfat............................................................... 507
10.4. Gruppe III ............................................................. 508
10.4.1. Nitrat................................................................. 509
10.4.2. Nitrit ................................................................. 510
10.5. Gruppe IV ............................................................. 513
10.5.1. Phosphat .............................................................. 513
10.5.2. Hypophosphat.......................................................... 521
10.5.3. Ptosphit............................................................... 521
10.5.4. Hypophosphit .......................................................... 523
10.8. Gruppe V .............................................................. 524
10.6.L Csrbonat .............................................................. 524
10.6.2. Aeetat.................................................................528
10.6.3. Formiat................................................................530
10.6.4. Tartrat................................................................ 531
10.6.6. Oxalat................................................................. 531
10.7. Gruppe VI............................................................. 532
10.7.1. Silikat................................................................. 532
10.7.2. Silicofluorid ............................................................ 534
10.7.3. Borat ................................................................. 534
10.7.4. Wasserstoffperoxid...................................................... 537
Teil m
11. Gesamtanalysen ........................................................ 538
11.1. Dolomit................................................................ 538
11.2. Messing................................................................ 542
11.3. Kupferkies............................................................. 545
12. Spezielle Bestimmnngsmetboden.......................................... 548
12.1. Ammoniakmetliode ..................................................... 548
12.2. Acetatmethode ......................................................... 548
12.3. Hexaminmethode....................................................... 549
12.4. Jodid-Jodat-Methode.................................................... 549
12.5. Nitritmetàode..........................................................550
12.6. Sulfatmethode.......................................................... 550
12.7. Anthranilsäure ......................................................... 550
12.8. Benzoinoxim (Cupron)...................................................551
12.9. Chinaldinsäure..........................................................551
12.10. Diacetyldioxim ......................................................... 552
12.11. Diphenylthioearbazon (Dithizon).......................................... 552
12.12. Dithiocarbaminat, disubstituiert .......................................... 553
12.13. 8-Hydroxychinolin(Oxin)................................................554
12.14. Kupferron.............................................................. 556
12.15. Mereaptobenzthiazol ..................................................... 557
12.16. a-Nitroso-ß-Naphthol....................................................558
12.17. a-ïïitro-/ß-Naphthol......................................................558
12.18. Pyridínkomplexe........................................................559
12.19. Salicylaldoxim.......................................................... 560
12.20. Thionalid.............................................................. 561
Anhang
13. Umrechnungsfaktoren ..................................................563
lé. Periodensystem .........................................................587
15. Internationale Atomgewichte der Elemente 1968 ............................588
Sachwörter- und Namenverzeichnis................................................. 591
|
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| language | German |
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| physical | 604 S. Ill., graph. Darst. |
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| spelling | Müller, Gerhard-Otfried Verfasser aut Lehrbuch der angewandten Chemie 3 Quantitativ-anorganisches Praktikum von Gerhard-Otfried Müller 2., durchges. Aufl. Leipzig Hirzel 1975 604 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier (DE-604)BV002346000 3 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005232928&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Müller, Gerhard-Otfried Lehrbuch der angewandten Chemie |
| title | Lehrbuch der angewandten Chemie |
| title_auth | Lehrbuch der angewandten Chemie |
| title_exact_search | Lehrbuch der angewandten Chemie |
| title_full | Lehrbuch der angewandten Chemie 3 Quantitativ-anorganisches Praktikum von Gerhard-Otfried Müller |
| title_fullStr | Lehrbuch der angewandten Chemie 3 Quantitativ-anorganisches Praktikum von Gerhard-Otfried Müller |
| title_full_unstemmed | Lehrbuch der angewandten Chemie 3 Quantitativ-anorganisches Praktikum von Gerhard-Otfried Müller |
| title_short | Lehrbuch der angewandten Chemie |
| title_sort | lehrbuch der angewandten chemie quantitativ anorganisches praktikum |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005232928&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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