Carbon-functional organosilicon compounds:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Plenum Press
1984
|
| Schriftenreihe: | Modern inorganic chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XIII, 303 S. graph. Darst. |
| ISBN: | 0306416719 |
Internformat
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Datensatz im Suchindex
| _version_ | 1804121943710892032 |
|---|---|
| adam_text | Titel: Carbon-functional organosilicon compounds
Autor: Chvalovský, Václav
Jahr: 1984
CONTENTS 1. SOME APPLICATIONS OF CARBON-FUNCTIONAL ORGANOSILICON COMPOUNDS Václav Chvalovský 1.1 INTRODUCTION 1 1.2 THE PRODUCTION OF CARBON-FUNCTIONAL ORGANOSILICON COMPOUNDS 2 1.3 USES AS DERIVATIZING AGENTS FOR NATURAL SUBSTANCES 4 1.4 USES AS STATIONARY PHASES FOR GAS-LIOUID CHROMATOGRAPHY 9 1.5 USES IN SURFACE TREATMENT OF INORGANIC MATERIALS 10 1.5.1 As Coupling Agents for Inorganic Fillers of Polymers 11 1.5.2 For Immobilization of Peptides and Proteins on Solid Carriers 18 1.5.3 For Immobilization of Metal Complex Catalysts 25 1.6 REFERENCES 28 2. INTRAMOLECULAR INTERACTION IN THE CHEMICAL BEHAVIOR OF CARBON-FUNCTIONAL ORGANOSILICON COMPOUNDS Josef Pola 2.1 INTRODUCTION 35 2.2 SUBSTITUENT EFFECTS OF SILYL GROUPS IN ORGANIC REACTIONS 39 ix
x CONTENTS 2.2.1 Reactions of Organometallic Compounds 39 2.2.2 Reactions of Alkenes 40 2.2.3 Reactions of Aromatic Compounds 46 2.2.4 Reactions of Compounds with Keto, Carboxyl, and Carbalkoxyl Groups 53 2.2.5 Reactions of Amines 55 2.2.6 Reactions of Alcohols, and Their Esters, Acetals, and Ethers 59 2.2.7 Reactions of Thiols and Sulfides 72 2.2.8 Reactions of Alkyl Halides 73 2.3 REACTIONS WITH PATHWAY DOMINATED BY THROUGH-SPACE INTERACTION BETWEEN SILICON AND A FUNCTIONAL GROUP 82 2.3.1 Reactions Involving 1,2-Interaction 83 2.3.2 Reactions Involving 1,3-Interaction 93 2.3.3 Reactions Involving 1,4-Interaction 98 2.3.4 Reactions Involving 1,5- or 1,6-Interaction 107 2.4 REFERENCES 111 3. NMR SPECTROSCOPY IN THE INVESTIGATION AND ANALYSIS OF CARBON-FUNCTIONAL ORGANOSILICON COMPOUNDS Jan Schraml 3.1 INTRODUCTION 121 3.2 29 Si NMR SPECTROSCOPY 123 3.2.1 Experimental Aspects 123 3.2.2 29 Si Chemical Shifts - Basic Facts 129 3.2.3 29 Si Shielding Theory and Model 132 3.2.4 29 Si Spin-Spin Coupling Constants 142 3.3 ALIPHATIC CARBON-FUNCTIONAL COMPOUNDS 142 3.3.1 ^H NMR Spectroscopy 143 3.3.2 -*- 2 C NMR Spectroscopy 153 3.3.3 29 Si NMR Spectroscopy 155 3.3.4 Typical Results 161
CONTENTS xi 3.4 AROMATIC CARBON-FUNCTIONAL COMPOUNDS 202 3.4.1 NMR Spectroscopy of Functional Groups 203 3.4.2 NMR Spectroscopy of Silyl Groups SiX^X^X^ 212 3.4.3 NMR Spectroscopy of the Connecting Chain 217 3.5 CONCLUSIONS 219 3.6 REFERENCES 220 4. THEORETICAL ASPECTS OF BONDING IN ORGANOSILICON CHEMISTRY Robert Ponec 4.1 INTRODUCTION 233 4.2 VALENCE SHELL EXPANSION FROM THE POINT OF VIEW OF QUANTUM THEORY 234 4.2.1 The Concept of Orbitals 234 4.2.2 Classification of Atomic Orbitals 235 4.2.3 Transformation Properties of d Orbitals 237 4.2.4 d Orbitals and Hybridization 241 4.2.5 Other Factors Influencing the Utilization of d Orbitals in Bonding 245 4.2.6 The Variational Principle and d Orbital Participation 247 4.3 HYPERCONJUGATION 250 4.3.1 General Introduction 250 4.3.2 Hyperconjugation in Organosilicon Chemistry 250 4.3.3 Theoretical Aspects of Hyperconjugation 254 4.3.4 Hyperconjugation and the Accuracy of a Localized Description of Bonding 257 4.4 ELECTRONEGATIVITY 259 4.5 ELECTRONIC EFFECTS OF SILYL SUBSTITUENTS AND THE POSSIBILITIES OF THEIR CHARACTERIZATION 263 4.5.1 Linear Free Energy Relationships 263
xii CONTENTS 4.5.2 Fourier Component Analysis of Internal Rotation 267 4.5.3 The a-Effect and Acid-Base Properties 271 4.6 THE CHEMISTRY OF SILICENIUM IONS AND SILYL ANIONS 275 4.6.1 Silicenium Ions 275 4.6.2 Silyl Anions 277 4.7 COMMON ASPECTS OF CHEMICAL REACTIVITY OF CARBON-FUNCTIONAL ORGANOSILICON COMPOUNDS 277 4.8 THE CHEMISTRY OF MULTIPLE BONDED SILICON 282 4.9 CONCLUSIONS 288 4.10 ACKNOWLEDGMENT 291 4.11 REFERENCES 292 INDEX 299
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| id | DE-604.BV007624299 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:06:01Z |
| institution | BVB |
| isbn | 0306416719 |
| language | English |
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| physical | XIII, 303 S. graph. Darst. |
| publishDate | 1984 |
| publishDateSearch | 1984 |
| publishDateSort | 1984 |
| publisher | Plenum Press |
| record_format | marc |
| series2 | Modern inorganic chemistry |
| spelling | Carbon-functional organosilicon compounds ed. by Václav Chvalovský ... New York [u.a.] Plenum Press 1984 XIII, 303 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Modern inorganic chemistry Literaturangaben Organosilicon compounds Siliciumorganische Verbindungen (DE-588)4077449-1 gnd rswk-swf Siliciumorganische Verbindungen (DE-588)4077449-1 s DE-604 Chvalovský, Václav Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004989550&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Carbon-functional organosilicon compounds Organosilicon compounds Siliciumorganische Verbindungen (DE-588)4077449-1 gnd |
| subject_GND | (DE-588)4077449-1 |
| title | Carbon-functional organosilicon compounds |
| title_auth | Carbon-functional organosilicon compounds |
| title_exact_search | Carbon-functional organosilicon compounds |
| title_full | Carbon-functional organosilicon compounds ed. by Václav Chvalovský ... |
| title_fullStr | Carbon-functional organosilicon compounds ed. by Václav Chvalovský ... |
| title_full_unstemmed | Carbon-functional organosilicon compounds ed. by Václav Chvalovský ... |
| title_short | Carbon-functional organosilicon compounds |
| title_sort | carbon functional organosilicon compounds |
| topic | Organosilicon compounds Siliciumorganische Verbindungen (DE-588)4077449-1 gnd |
| topic_facet | Organosilicon compounds Siliciumorganische Verbindungen |
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