Optical activity and chiral discrimination: proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Reidel
1979
|
| Schriftenreihe: | NATO Advanced Study Institutes series
Series C, Mathematical and physical sciences ; 48 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 372 S. |
Internformat
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Datensatz im Suchindex
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| adam_text | IMAGE 1
OPTICAL ACTIVITY AND
CHIRAL DISCRIMINATION PROCEEDINGS OFTHE NATO ADVANCED STUDY INSTITUTE
HELD AT THE UNIVERSITY OF SUSSEX, FAIMER, ENGLAND, SEPTEMBER 10-22, 1978
EDITED BY
STEPHEN F. MASON DEPARTMENT OFCHEMISTRY, UNIVERSITY OF LONDON KING S
COLLEGE, LONDON, ENGLAND
UNIVERSITATSBIBUOTHEK HANNOVER TECHNISCHE SNFORMATIONSBIBLIOTHEK
D. REIDEL PUBLISHING COMPANY DORDRECHT : HOLLAND / BOSTON : U.S.A. /
LONDON : ENGLAND
PUBLISHED IN COOPERATION WITH NATO SCIENTIFIC AFFAIRS DIVISION
?!)
IMAGE 2
CONTENTS
PREFACE
PART I OPTICAL ACTIVITY
I GENERAL MODELS FOR OPTICAL ACTIVITY 1
STEPHEN F. MASON - HISTORICAL INTRODUCTION 1
- ROTATIONAL AND DIPOLE STRENGTHS 3
- QUANTUM MECHANICAL MODELS FOR OPTICAL ACTIVITY 4 - THE ONE-ELECTRON
MECHANISM 6
- THE DYNAMIC-COUPLING ITIJ - VZ MECHANISM 10
- THE NON-DEGENERATE V - V-2 MECHANISM 15
- THE DEGENERATE I - P2 MECHANISM 17
- REFERENCES 22
II
CHIROPTICAL PROPERTIES OF ORGANIC COMPOUNDS: CHIRALITY AND SECTOR RULES
25
G. SNATZKE - INTRODUCTION 25
- THE CHIRAL FIRST SPHERE 29
- THE CHIRAL SECOND SPHERE 33
- THE CHIRAL THIRD SPHERE 35
- GENERALIZATION OF SECTOR RULES 38
- REFERENCES 40
III CHIROPTICAL PROPERTIES OF ORGANIC COMPOUNDS: SOME APPLICATIONS TO
UNSATURATED SYSTEMS 43
G. SNATZKE - THE 2IR-SYSTEM 43
- THE 47R-SYSTEM 48
- CONJUGATED ENONES 53
- OTHER UNSATURATED SYSTEMS 54
- REFERENCES 55
IV CIRCULAR DICHROISM AND FLUORESCENCE DETECTED CIRCULAR DICHROISM OF
MACROMOLECULES 57
I. TINOCO, JR. - INTRODUCTION 57
- CIRCULAR DICHROISM OF LARGE MOLECULES 58
- A FREE ELECTRON ON A HELIX 60
- CIRCULAR DICHROISM OF POLYNUCLEOTIDES AND NUCLEIC ACIDS 66
- FLUORESCENCE DETECTED CIRCULAR DICHROISM 71
- FLUORESCENCE DETECTED CIRCULAR DICHROISM STUDIES OF TRANSFER RNA 75
- FLUORESCENCE DETECTED CIRCULAR DICHROISM STUDIES OF DINUCLEOSIDE
PHOSPHATES 79
- REFERENCES 84
IMAGE 3
VI CONTENTS
-= - (J?) NATURAL AND MAGNETIC CIRCULAR DICHROISM
SPECTROSCOPY IN THE VACUUM ULTRAVIOLET 87
OTTO SCHNEPP - INTRODUCTION 87
- INSTRUMENTATION AND TECHNIQUES 90
- NATURAL CIRCULAR DICHROISM RESULTS 92
- MAGNETIC CIRCULAR DICHROISM RESULTS 100
- REFERENCES 105
VI THE OPTICAL ACTIVITY OF LANTHANIDE AND TRANSITION METAL COMPLEXES 107
F.S. RICHARDSON
- INTRODUCTION 107
- MODELS FOR D-D OPTICAL ACTIVITY 110
- DESCRIPTION OF INDEPENDENT SYSTEMS/PERTURBATION MODEL 12 2
- VIBRONIC INTERACTIONS 141
- SPIN-FORBIDDEN TRANSITIONS 142
- SINGLE-CRYSTAL SPECTRA 14 3
- SPECTRA-STRUCTURE RELATIONSHIPS 145
- OTHER TOPICS 154
- REFERENCES 155
VII THE LIGAND POLARIZATION MODEL FOR THE SPECTRA OF METAL COMPLEXES 161
S.F. MASON
- INTRODUCTION 161
- TRANSITION-PROBABILITY ANOMALIES OF CRYSTAL FIELD THEORY 162
- TRANSITION PROBABILITIES IN THE LIGAND POLARIZATION MODEL 164
- LIGAND POLARIZATION OPTICAL ACTIVITY 169
- REFERENCES 184
VIII CIRCULAR POLARIZATION DIFFERENTIALS IN THE LUMINESCENCE OF CHIRAL
SYSTEMS 189
F.S. RICHARDSON - INTRODUCTION 189
- THEORY 191
- CPL AS A STRUCTURE PROBE 204
- MEASUREMENT TECHNIQUES 212
- REFERENCES 215
IMAGE 4
CONTENTS WI
IX RAMAN OPTICAL ACTIVITY 219
L.D. BARRON - INTRODUCTION 219
- THE MOLECULAR POLARIZABILITY AND OPTICAL ACTIVITY TENSORS 222
- THE RAYLEIGH AND RAMAN CIRCULAR INTENSITY DIFFERENCES 229
- THE GENERATION OF RAYLEIGH AND RAMAN OPTICAL ACTIVITY WITHIN CHIRAL
MOLECULES 233
- EXPERIMENTAL 250
- REFERENCES 260
X VIBRATIONAL CIRCULAR DICHROISM: THE EXPERIMENTAL VIEWPOINT 263
P.J. STEPHENS AND R. CLARK - INTRODUCTION AND HISTORY 263
- INSTRUMENTATION 265
- RESULTS 273
- THEORY 282
- CONCLUSION 285
- REFERENCES 286
XI A VIBRATIONAL ROTATIONAL STRENGTH OF EXTRAORDINARY INTENSITY.
AZIDOMETHEMOGLOBIN A. 289
CURTIS MARCOTT, HENRY A. HAVEL, BO HEDLUND, JOHN OVEREND AND ALBERT
MOSCOWITZ - VCD OF AZIDE GROUP 289
- REFERENCES AND NOTES 291
PART II CHIRAL DISCRIMINATION
XII CHIRAL DISCRIMINATION 293
D.P. CRAIG - INTRODUCTION 294
- THE CALCULATION OF DISCRIMINATING INTERACTIONS 300 - FORMS OF
INTERACTION HAMILTONIAN 302
- ELECTROSTATIC INTERACTIONS 304
- DISPERSIVE DISCRIMINATION 308
- THE RESONANCE DISCRIMINATION 315
- SHORT-RANGE TERMS 315
- REFERENCES 318
IMAGE 5
CONTENTS
XIII THE DISPERSION AND OTHER CHIRAL DISCRIMINATIONS 319
S.F. MASON
- INTRODUCTION 319
- THE DISPERSION CHIRAL DISCRIMINATION ENERGIES 321 - THE EXTENDED
TRANSITION MONOPOLE MODEL 325
- CONTACT DISCRIMINATION 327
- NON-CONTACT DISCRIMINATION 330
- THE CHIRAL DISCRIMINATION OF THE WEAK NUCLEAR INTERACTION 334
- REFERENCES 335
XIV DIASTEREOISOMERIC DISCRIMINATIONS IN CHIRAL METAL COMPLEXES 339
R.D. GILLARD - INTRODUCTION 340
- INTRAMOLECULAR EFFECTS 342
- INTERMOLECULAR EFFECTS 346
- REFERENCES 350
XV THE ORIGIN OF THE PFEIFFER EFFECT 353
R.D. GILLARD
- REFERENCES 366
INDEX 369
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| spelling | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 ed. by Stephen F. Mason Dordrecht Reidel 1979 XI, 372 S. txt rdacontent n rdamedia nc rdacarrier NATO Advanced Study Institutes series : Series C, Mathematical and physical sciences 48 Rotationsdispersion (DE-588)4178488-1 gnd rswk-swf Zirkulardichroismus (DE-588)4010215-4 gnd rswk-swf Chiralität Chemie (DE-588)4147732-7 gnd rswk-swf (DE-588)1071861417 Konferenzschrift gnd-content Chiralität Chemie (DE-588)4147732-7 s DE-604 Zirkulardichroismus (DE-588)4010215-4 s Rotationsdispersion (DE-588)4178488-1 s Mason, Stephen Finney 1923- Sonstige (DE-588)11808755X oth NATO Advanced Study Institutes series Series C, Mathematical and physical sciences ; 48 (DE-604)BV000003915 48 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004900607&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 NATO Advanced Study Institutes series Rotationsdispersion (DE-588)4178488-1 gnd Zirkulardichroismus (DE-588)4010215-4 gnd Chiralität Chemie (DE-588)4147732-7 gnd |
| subject_GND | (DE-588)4178488-1 (DE-588)4010215-4 (DE-588)4147732-7 (DE-588)1071861417 |
| title | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 |
| title_auth | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 |
| title_exact_search | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 |
| title_full | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 ed. by Stephen F. Mason |
| title_fullStr | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 ed. by Stephen F. Mason |
| title_full_unstemmed | Optical activity and chiral discrimination proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 ed. by Stephen F. Mason |
| title_short | Optical activity and chiral discrimination |
| title_sort | optical activity and chiral discrimination proceedings of the nato advanced study institute held at the university of sussex falmer england september 10 22 1978 |
| title_sub | proceedings of the NATO Advanced Study Institute, held at the University of Sussex, Falmer, England, September 10 - 22, 1978 |
| topic | Rotationsdispersion (DE-588)4178488-1 gnd Zirkulardichroismus (DE-588)4010215-4 gnd Chiralität Chemie (DE-588)4147732-7 gnd |
| topic_facet | Rotationsdispersion Zirkulardichroismus Chiralität Chemie Konferenzschrift |
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