Absolute configuration of metal complexes:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
1971
|
| Schriftenreihe: | Interscience monographs on chemistry : inorganic chemistry section
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 349 S. Ill., graph. Darst. |
Internformat
MARC
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| 100 | 1 | |a Hawkins, Clifford J. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Absolute configuration of metal complexes |c Clifford J. Hawkins |
| 264 | 1 | |a New York [u.a.] |b Wiley |c 1971 | |
| 300 | |a X, 349 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 490 | 0 | |a Interscience monographs on chemistry : inorganic chemistry section | |
| 650 | 7 | |a Circulair dichroïsme |2 gtt | |
| 650 | 7 | |a Configuratie-interactie |2 gtt | |
| 650 | 7 | |a Estereoquimica |2 larpcal | |
| 650 | 7 | |a Geometrische isomerie |2 gtt | |
| 650 | 7 | |a NMR |2 gtt | |
| 650 | 7 | |a Stereochemie |2 gtt | |
| 650 | 7 | |a Structuuranalyse |2 gtt | |
| 650 | 7 | |a Symmetrie |2 gtt | |
| 650 | 4 | |a Metal complexes | |
| 650 | 4 | |a Organometallic compounds | |
| 650 | 4 | |a Stereochemistry | |
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Datensatz im Suchindex
| _version_ | 1804121295636398080 |
|---|---|
| adam_text | Titel: Absolute configuration of metal complexes
Autor: Hawkins, Clifford J
Jahr: 1971
Contents
Ligand
Abbreviations
ix
Chapter
1
—Introduction
........
1
Stereoisomerism
and
Absolute
Configuration
.
1
Geometrical
Isomerism
......
2
Optical
Isomerism
and
Diastereoisomerism
.
.
6
Methods
of
Determining
Absolute
Configurations
16
Chirality
........
16
Chapter
2
—Notation
of
Absolute
Configuration
....
20
Preamble
........
20
Notation
for
the
Distribution
of
Chelate
Rings
.
20
Notation
of
Conformation
for
Chelate
Rings
28
Notation
for
the
Distribution
of
Unidentate
Ligands
29
Notation
for
the
Dissymmetry
from
an
Unsymmetrical
Chelate
........
29
Notation
for
Complex
Containing
an
Asymmetric
Ligand
........
30
Summary
of
Adopted
Symbolism
.
.
.
31
Chapter
3
—Conformational
Analysis
....
33
Introduction
........
33
Van
der
Waals
Forces
......
34
Torsional
Barriers
.......
52
Angle-bending
Energy
......
58
Bond-length
Distortion
Energy
.....
60
Computational
Methods
for
Conformational
Analysis
61
Entropy
of
Ring
Conformations
•
63
Five-membered
Diamine
Rings
.....
63
Six-membered
Diamine
Rings
.....
86
Five-membered
Amino
Acid
Rings
....
94
Correlation
of
Predicted
Structures
with
Real
Structures
99
Experimental
Conformational
Analysis
.
.
.
101
vii
CONTENTS
viii
Chapter
4
—Absolute
Configurations
by
X-ray
Analysis
.
113
Normal
Diffraction
and
Friedel’s
Law
.
.
.
113
Anomalous
Dispersion
and
Absolute
Configuration
.
115
Bijvoet’s
Method
:
Method
A
.
.
.
.
.
118
Pepinsky
and
Okaya’s
Method:
Method
B
.
.
.
123
The
Quadratic-equation
Method:
Method
C
.
.
125
The
Crystal-engineering
Method:
Method
D
.
.
126
Conformations
of
Chelate
Rings
....
126
Chapter
5
—Circular
Dichroism
148
Historical
........
148
Interaction
of
Light
with
an
Optically
Active
Medium
.
149
Rotational
Strength
of
Chromophores
.
.
.
153
The
Cotton
Effect
.
.
.
.
.
.
.
154
Absorption
Spectra
of
Metal
Complexes
.
.
.
157
General
Theories
of
Optical
Activity
.
.
.
.
167
Empirical
Methods
Based
on
the
d-d
Transitions
.
176
Nonempirical
Methods
......
227
Chapter
6
—Nuclear
Magnetic
Resonance
.....
257
Theory
.........
257
Geometrical
Isomers
......
268
Diamine
Complexes
......
278
Amino
Acid
Complexes
.
.
.
.
.
.291
Polyaminocarboxylate
Complexes
....
296
Pseudotetrahedral
Complexes
.....
299
Chapter
7—Miscellaneous
Techniques
......
304
Infrared
Spectroscopy
......
304
Delèpine’s
Active
Racemate
Method
....
310
Diastereoisomer
Solubility
Criterion
.
.
.
.
310
Chemical
Correlations
.
.
.
.
.
313
Other
Methods
.......
315
Chapter
8
—Geometrical
Isomerism
.
.
.
318
Infrared
Spectroscopy
.
.
.
.
.
.
318
Electronic
Absorption
Spectroscopy
....
327
Other
Methods
.......
332
Index
335
|
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV007108651 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:55:43Z |
| institution | BVB |
| language | English |
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| physical | X, 349 S. Ill., graph. Darst. |
| psigel | TUB-nveb |
| publishDate | 1971 |
| publishDateSearch | 1971 |
| publishDateSort | 1971 |
| publisher | Wiley |
| record_format | marc |
| series2 | Interscience monographs on chemistry : inorganic chemistry section |
| spelling | Hawkins, Clifford J. Verfasser aut Absolute configuration of metal complexes Clifford J. Hawkins New York [u.a.] Wiley 1971 X, 349 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Interscience monographs on chemistry : inorganic chemistry section Circulair dichroïsme gtt Configuratie-interactie gtt Estereoquimica larpcal Geometrische isomerie gtt NMR gtt Stereochemie gtt Structuuranalyse gtt Symmetrie gtt Metal complexes Organometallic compounds Stereochemistry Konfiguration Chemie (DE-588)4129572-9 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 s Konfiguration Chemie (DE-588)4129572-9 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004526250&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hawkins, Clifford J. Absolute configuration of metal complexes Circulair dichroïsme gtt Configuratie-interactie gtt Estereoquimica larpcal Geometrische isomerie gtt NMR gtt Stereochemie gtt Structuuranalyse gtt Symmetrie gtt Metal complexes Organometallic compounds Stereochemistry Konfiguration Chemie (DE-588)4129572-9 gnd Metallkomplexe (DE-588)4038898-0 gnd |
| subject_GND | (DE-588)4129572-9 (DE-588)4038898-0 |
| title | Absolute configuration of metal complexes |
| title_auth | Absolute configuration of metal complexes |
| title_exact_search | Absolute configuration of metal complexes |
| title_full | Absolute configuration of metal complexes Clifford J. Hawkins |
| title_fullStr | Absolute configuration of metal complexes Clifford J. Hawkins |
| title_full_unstemmed | Absolute configuration of metal complexes Clifford J. Hawkins |
| title_short | Absolute configuration of metal complexes |
| title_sort | absolute configuration of metal complexes |
| topic | Circulair dichroïsme gtt Configuratie-interactie gtt Estereoquimica larpcal Geometrische isomerie gtt NMR gtt Stereochemie gtt Structuuranalyse gtt Symmetrie gtt Metal complexes Organometallic compounds Stereochemistry Konfiguration Chemie (DE-588)4129572-9 gnd Metallkomplexe (DE-588)4038898-0 gnd |
| topic_facet | Circulair dichroïsme Configuratie-interactie Estereoquimica Geometrische isomerie NMR Stereochemie Structuuranalyse Symmetrie Metal complexes Organometallic compounds Stereochemistry Konfiguration Chemie Metallkomplexe |
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