Negative ions and the magnetron:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London
Wiley
1969
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 156 S. graph. Darst. |
Internformat
MARC
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| 100 | 1 | |a Page, Francis M. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Negative ions and the magnetron |c F. M. Page ; G. C. Goode |
| 264 | 1 | |a London |b Wiley |c 1969 | |
| 300 | |a XIII, 156 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 4 | |a Intercambio de Iones | |
| 650 | 4 | |a Magnetrones (621-381-334) | |
| 650 | 4 | |a Anions | |
| 650 | 4 | |a Magnetrons | |
| 650 | 0 | 7 | |a Anion |0 (DE-588)4130938-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Magnetron |0 (DE-588)4037035-5 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
| _version_ | 1804121283284172800 |
|---|---|
| adam_text | Negative Ions and
the Magnetron
F M Page
Professor, Department of Chemistry,
University of Aston in Birmingham
G C Goode
Research Fellow,
University oj Sheffield
»
WILEY-1NTERSCIENC1
a division of John Wiley amp; Sons Ltd ,
London New York Sydney Toronto
Contents
1 The Modes of Formation and Importance of Negative Ions
1 1 Introduction 1
1 2 Ionization Potential and Electron Affinity 1
1 3 Electron Affinities of Molecules 2
1 4 Electronegativity 4
1 5 Formation of Negative Ions 5
1 6 Negative Ions in Flames and Discharges 9
2 The Experimental Determination of Electron Affinities
2 1 Early Work
2 2 Gaseous Equilibria
2 3 Spectroscopic Methods
2 4 Electron Capture Studies
2 5 The Magnetron Technique
2 6 The Theory of the Magnetron
2 7 The Design of the Apparatus
2 8 Other Designs of Magnetron
2 9 The Measurement of Filament Temperat tire
2 10 Thermionic Work Functions
3 The Classification of Results
3 1 The Effects of Filament Temperature 31
3 2 The Simple Energetic Treatment 32
3 3 Kinetic Treatment of Ion Formation 33
3 4 The Mechanism of Ion Formation 34
3 5 The Diagnosis of Reaction Type 37
3 6 Considerations of Energy 38
3 7 Variation of the Filament Material 40
3 8 Consideration of the Entropy of the Reaction 41
4 The Emission of Electrons and Ions as a Rate Process
4 1 Introduction 44
xi
xii Contents
4 2 The Theory of Rate Processes 44
4 3 The Emission of Electrons 46
4 4 The Emission of Ions 48
4 5 Application to the Magnetron 51
5 The Effects of Adsorption
5 1 Measurements at Real Pressures 54
5 2 Elevated Work Functions 55
5 3 Experimental Observations 58
5 4 Lowered Work Functions 60
5 5 The Transmission Coefficient of an Ideal Double Layer 61
5 6 Work Functions in the Presence of Tetracyanoethylene 63
5 7 Adsorption and Ion Formation 65
5 8 Adsorption of Hydrogen Atoms 66
5 9 Adsorption of Halogens 67
5 10 Heats of Adsorption of Radicals 68
6 The Correction of the Observed Results to Standard Conditions
6 1 The Need for Correction 71
6 2 The Kinetic Approach 71
6 3 Transition State Approach 74
6 4 Direct Capture Processes 75
6 5 Dissociation Without Adsorption 75
6 6 Dissociation With Adsorption 76
7 Polarization Capture Affinities
7 1 rtie Classification of Negative Ions 78
7 2 Polarization Affinities 79
8 Direct Capture rt Affinities
8 1 Experimental Results 83
8 2 The Additivity of Electron Affinities 83
8 3 The Analysis of the Measured Affi nities 85
8 4 Group Contribution 85
9 An Electrostatic Approach to the Prediction of n Electron Affinities
9 1 Introduction ! 87
9 2 The Field Due to an Assembly of Dipoles 87
9 3 The Calculation of Electron Affinities by Electrostatics 89
9 4 Charge-Transfer Spectra 94
9 5 The Electrostatic Energy of the Complex 96
10 cr-Affinities
10 1 Introduction 103
10 2 Electron Affinities of Atoms and Radicals 103
Contents
10 3 Valence States and Promotion Energies
10 4 The Method of Hinze and Jaffe
10 5 The Prediction of Electron Affinities
10 6 Atomic Electron Affinities
10 7 The Predicted Electron Affinities of Groups I and II
10 8 The Predicted Electron Affinities of G roup Ilia
10 9 The Predicted Electron Affinities of Group IVa
10 10 The Electron Affinities of Group V
10 11 The Electron Affinities of Groups IV and VII
11 o-Capture by Carbon
11 1 Introduction
11 2 Valence States of Carbon Anions
12 a-Capture by Other Elements
12 1 Introduction
12 2 Experimental Results
Appendices:
I List of Substances Studied in the Magnetron
II Stabilities of Negative Ions
III Compilations of Data
Author Index
Subject Index
»
xiii
|
| any_adam_object | 1 |
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| discipline | Chemie / Pharmazie Physik |
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| id | DE-604.BV007098980 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:55:31Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004517835 |
| oclc_num | 48787 |
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| owner_facet | DE-355 DE-BY-UBR DE-29T DE-91 DE-BY-TUM DE-83 DE-188 |
| physical | XIII, 156 S. graph. Darst. |
| psigel | TUB-nveb |
| publishDate | 1969 |
| publishDateSearch | 1969 |
| publishDateSort | 1969 |
| publisher | Wiley |
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| spelling | Page, Francis M. Verfasser aut Negative ions and the magnetron F. M. Page ; G. C. Goode London Wiley 1969 XIII, 156 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Intercambio de Iones Magnetrones (621-381-334) Anions Magnetrons Anion (DE-588)4130938-8 gnd rswk-swf Magnetron (DE-588)4037035-5 gnd rswk-swf Magnetron (DE-588)4037035-5 s DE-604 Anion (DE-588)4130938-8 s Goode, G. C. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517835&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Page, Francis M. Goode, G. C. Negative ions and the magnetron Intercambio de Iones Magnetrones (621-381-334) Anions Magnetrons Anion (DE-588)4130938-8 gnd Magnetron (DE-588)4037035-5 gnd |
| subject_GND | (DE-588)4130938-8 (DE-588)4037035-5 |
| title | Negative ions and the magnetron |
| title_auth | Negative ions and the magnetron |
| title_exact_search | Negative ions and the magnetron |
| title_full | Negative ions and the magnetron F. M. Page ; G. C. Goode |
| title_fullStr | Negative ions and the magnetron F. M. Page ; G. C. Goode |
| title_full_unstemmed | Negative ions and the magnetron F. M. Page ; G. C. Goode |
| title_short | Negative ions and the magnetron |
| title_sort | negative ions and the magnetron |
| topic | Intercambio de Iones Magnetrones (621-381-334) Anions Magnetrons Anion (DE-588)4130938-8 gnd Magnetron (DE-588)4037035-5 gnd |
| topic_facet | Intercambio de Iones Magnetrones (621-381-334) Anions Magnetrons Anion Magnetron |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517835&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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