Spectroscopy and structure of metal chelate compounds:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Wiley
1968
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 382 S. Ill. |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804121282329968640 |
|---|---|
| adam_text | SPECTROSCOPY AND
STRUCTURE OF
METAL CHELATE COMPOUNDS
KAZUO NAKAMOTO
Illinois Institute of Technology
PAUL J MCCARTHY, S J
Canisius College
JOHN WILEY amp; SONS, INC
New York • London • Sydney
CONTENTS
1 X-Ray and Neutron Diffraction
Yoshihiko Saito 1
1-1 THEORY 2
A Principles of X-ray Diffraction 2
B Neutron Diffraction 13
C Examples 15
1-2 APPLICATIONS 26
A Conformation of the Chelate Ring 26
B Determination of Absolute Configuration 37
C Determination of cis-trans Isomerism 39
D Determination of Linkage Isomerism 41
E Unidentate and Bidentate Coordination 43
F Polymerization of Metal Chelates 45
G Less Usual Coordination Numbers 49
H Metal-Metal Interaction 53
I Intermolecular Interaction in the Crystal 56
J Distortion of the Chelate Ring 58
K Biologically Interesting Compounds 60
REFERENCES 66
2 Visible and Ultraviolet Spectroscopy
Curtis R Hare 13
2-1 THEORY 74
A Crystal Field Theory 76
B Ligand Field Theory 80
C Molecular Orbital Theory 91
D Spectrochemical and Nephelauxetic Series 97
E Intensities 98
F Lower Symmetry Fields 99
2-2 APPLICATIONS 103
A Pseudo-octahedral Fields 103
ix
x Contents
B Pseudo-tetrahedral Fields 113
C Five-Coordination 117
D Square-Planar Coordination 124
E Trigonal Prismatic Coordination 129
F Equilibria 130
G Crystal Spectra 136
H Biological Applications 141
REFERENCES 149
3 Optical Rotatory Dispersion and Circular Dichroism
Junnosuke Fujita and Yoichi Shimura 156
3-1 THEORY 157
A Definitions and Units 157
B Symmetry Requirements for Optical Activity 164
C Curve Analysis 169
D Optical Rotatory Power of Metal Complexes 175
3-2 APPLICATIONS 179
A Optical Activity and Absolute Configuration 179
B Isomerism Due to Non-planarity of Chelate Rings 184
C Isomers of Amino Acid Complexes 190
D Vicinal Effect 194
E Ion-pair Formation 201
F Assignment of Transitions 203
REFERENCES 207
4 Infrared Spectroscopy
Kazuo Nakamoto 216
4-1 THEORY 217
A Empirical Interpretation of Spectra 217
B Normal Coordinate Analysis 223
4-2 APPLICATIONS 236
A Conformational Isomerism 236
B Geometrical Isomerism 244
C Linkage Isomerism 249
D Unidentate and Bidentate Coordination 258
E Spectra and the Strength of Coordinate Bonds 268
F Equilibrium Studies in Aqueous Solution 275
REFERENCES 282
5 Electron Spin Resonance Spectroscopy
Shizuo Fujiwara 286
5-1 THEORY 287
Contents xi
5-2 APPLICATIONS 289
A ESR Parameters and Chemical Bonding 289
B ESR Relaxation and Nature of Chemical Bonding 296
C Miscellaneous Applications 300
REFERENCES 302
6 Nuclear Magnetic Resonance Spectroscopy
Paul J McCarthy, S J 309
6-1 THEORY 309
A Basic Principles 309
B An Example 314
6-2 APPLICATIONS 318
A Diamagnetic Chelates: Structure and Bonding 318
B Paramagnetic Chelates: Spin Densities, Structures, and
Bonding 335
C Structure and Bonding in Materials of Biological Interest 353
D Reaction Rates 359
E Equilibrium Studies 361
F Stability of Chelates 363
REFERENCES 365
Abbreviations 375
Index 377
|
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| author | Nakamoto, Kazuo McCarthy, Paul J. 1924- |
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| dewey-ones | 547 - Organic chemistry |
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| discipline | Chemie / Pharmazie |
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| language | English |
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| spelling | Nakamoto, Kazuo Verfasser aut Spectroscopy and structure of metal chelate compounds Kazuo Nakamoto ; Paul J. McCarthy New York Wiley 1968 XI, 382 S. Ill. txt rdacontent n rdamedia nc rdacarrier Chelaten gtt Chélates ram Complexes métalliques ram Molecuulstructuur gtt Organometaalcomplexen gtt Spectroscopie ram Spectrumanalyse gtt Chelates Spectra Spectrum analysis Chelate (DE-588)4123003-6 gnd rswk-swf Metallchelate (DE-588)4169575-6 gnd rswk-swf Spektroskopie (DE-588)4056138-0 gnd rswk-swf Struktur (DE-588)4058125-1 gnd rswk-swf Metallchelate (DE-588)4169575-6 s Spektroskopie (DE-588)4056138-0 s DE-604 Struktur (DE-588)4058125-1 s Chelate (DE-588)4123003-6 s McCarthy, Paul J. 1924- Verfasser (DE-588)14011582X aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517211&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nakamoto, Kazuo McCarthy, Paul J. 1924- Spectroscopy and structure of metal chelate compounds Chelaten gtt Chélates ram Complexes métalliques ram Molecuulstructuur gtt Organometaalcomplexen gtt Spectroscopie ram Spectrumanalyse gtt Chelates Spectra Spectrum analysis Chelate (DE-588)4123003-6 gnd Metallchelate (DE-588)4169575-6 gnd Spektroskopie (DE-588)4056138-0 gnd Struktur (DE-588)4058125-1 gnd |
| subject_GND | (DE-588)4123003-6 (DE-588)4169575-6 (DE-588)4056138-0 (DE-588)4058125-1 |
| title | Spectroscopy and structure of metal chelate compounds |
| title_auth | Spectroscopy and structure of metal chelate compounds |
| title_exact_search | Spectroscopy and structure of metal chelate compounds |
| title_full | Spectroscopy and structure of metal chelate compounds Kazuo Nakamoto ; Paul J. McCarthy |
| title_fullStr | Spectroscopy and structure of metal chelate compounds Kazuo Nakamoto ; Paul J. McCarthy |
| title_full_unstemmed | Spectroscopy and structure of metal chelate compounds Kazuo Nakamoto ; Paul J. McCarthy |
| title_short | Spectroscopy and structure of metal chelate compounds |
| title_sort | spectroscopy and structure of metal chelate compounds |
| topic | Chelaten gtt Chélates ram Complexes métalliques ram Molecuulstructuur gtt Organometaalcomplexen gtt Spectroscopie ram Spectrumanalyse gtt Chelates Spectra Spectrum analysis Chelate (DE-588)4123003-6 gnd Metallchelate (DE-588)4169575-6 gnd Spektroskopie (DE-588)4056138-0 gnd Struktur (DE-588)4058125-1 gnd |
| topic_facet | Chelaten Chélates Complexes métalliques Molecuulstructuur Organometaalcomplexen Spectroscopie Spectrumanalyse Chelates Spectra Spectrum analysis Chelate Metallchelate Spektroskopie Struktur |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517211&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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