The structure of lipids by spectroscopic and x-ray techniques: With a chapter on separation techniques including thin layer and gas liquid chromatography
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Methuen
1965
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII,323 S.m.Abb.u.Tab.,2 Taf. |
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| 245 | 1 | 0 | |a The structure of lipids by spectroscopic and x-ray techniques |b With a chapter on separation techniques including thin layer and gas liquid chromatography |
| 264 | 1 | |a London |b Methuen |c 1965 | |
| 300 | |a XII,323 S.m.Abb.u.Tab.,2 Taf. | ||
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Record in the Search Index
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| adam_text | a
THESTRUCTUREOFLIPIDS
by Spectroscopic and
X-Ray Techniques
With a chapter on Separation Techniques
including thin layer and gas liquid chromatography
DCHAPMAN
University Chemical Laboratory, Cambridge
METHUEN AND CO LTD
11 NEW FETTER LANE LONDON EC4
«?v-
Contents
Preface page vii
Acknowledgements viii
1 Introduction 1
The Field of Lipids 1
Fatty acids 1
Simple lipids 2
Glycerides 2
Cholesterol and cholesterol esters 3
Glyceryl ethers 4
Fatty alcohols and waxes 4
Complex Lipids 4
Phosphoglycerides 5
Sphingolipids 5
Lipoproteins 6
2 Separation techniques 8
Separation of Lipoproteins 8
Isolation and Purification of Lipids 10
Counter current distribution 11
Chromatographic techniques 12
Column chromatography 12
Paper chromatography 14
Thin layer chromatography 15
Production of thin layers 16
Adsorbents 16
Spotting 16
Development 17
Detection of components 17
Partition chromatography 18
Reversed phase partition 18
Gas liquid chromatography 27
3 Ultraviolet spectroscopy 37
Theoretical Considerations 37
Intensity 39
Terminology 40
Quantitative analysis , 40
Experimental techniques 41
Technique 42
ix
d
X Contents G
Applications to lipids 42
Absorption spectra of fatty acids 42
Alkali isomerization methods 45
Oxidation 48
Lipoproteins 49
4 Infra-red and Baman spectroscopy 52
Theoretical considerations 52
Instruments and techniques 61
Quantitative measurements 63
Near infra-red spectroscopy 64
Vibrational spectra of polymethylene chains 65
Applications 68
Monocarboxylic acids 68
Formic and acetic acids 68
Unsaturated acids 80
Ethylenic CH-bending vibration 83
Branched chain acids 86
Esters 87
Alcohols 94
Anhydrous soaps 95
Glycerides 97
Triglycerides 97
Saturated triglycerides 98
Unsaturated triglycerides 102
Diglycerides 105
Monoglycerides 108
Cholesterol esters 110
Steroids 112
Phospholipids 113
Lipoproteins 128
5 Mass spectroscopy 133
Theoretical considerations 133
Experimental techniques 135
Inlet system 135
Ion source 137
Recording 138
Resolving power 138
Time-of-flight mass spectrometer 139
Applications 140
Hydrocarbons 140
Alcohols 142
Carboxylic acids 144
Methyl esters 146
Methyl esters of unsatu rated acids 148
Glycerides 153
Steroids 158
cv-
S
6 Nuclear magnetic resonance spectroscopy
Theoretical considerations
Nuclear relaxation
Broad-line spectroscopy
Applications
Hydrocarbons
Alcohols
Carboxylic acids
Glycerides
Liquid/solid content measurements
Future applications
High resolution spectroscopy
Chemical shift
Correlation with molecular structure
Spin-spin coupling
Classification of nuclear groups
The AB system
AB% systems
ABg systems
AB amp; systems
Internal rotation
Exchange effects
Experimental techniques
Resonance of other nuclei
Phosphorus
Nitrogen (14N)
Carbon (13C)
Applications
Alcohols
Monocarboxylic acids
Saturated
Hydroxy acids
Unsaturated
Acids with cyclic groups
Esters
Glycerides
Diglycerides
M onoglycerides
Natural oils
Phospholipids and cholesterol esters
7 Electron spin resonance spectroscopy
Theoretical considerations
Experimental techniques
Applications
Free radicals in solids
Free radicals in solution
Autoxidation studies
Studies of pyrolysis
Contents • xi
208 *
xii Contents
8 X-ray diffraction studies 221
Theoretical considerations 221
Symmetry of crystals 223
Experimental techniques 224
The Powder method 225
Interpretation of X-ray powder photographs 227
Single crystal methods 227
The Laue Method 227
Rotating crystal method227
Structure determination, 228
Low angle scattering 231
Long chain crystals and sub-cell theory 232
Sub-cell concept 235
Triclinia T packing 237
Common orthorhombic packing 0 _L 237
New orthorhombic packing 0 _L 238
New orthorhombic packing 01| 238
Orthorhombic packing 0 11 239
Hexagonal packing 239
Factors affecting polymorphism 240
Hydrocarbon packing in the liquid 241
Applications to lipids 241
Alcohols 241
• Carboxylic acids 243
| Saturated acids 243
Branched chain fatty acids 252
Unsaturated acids 254
Dicarboxylic acids 255
Esters 256
Ethyl esters 256
Methyl esters 257
Glycerides 260
Introduction 260
Nomenclatwre of glycerides 261
Mono-acid saturated triglycerides 262
Diacid saturated triglycerides 274
Triacid saturated triglycerides 278
Unsaturated triglycerides 280
Diglycerides 282
Monoglycerides 286
Summary of glyceride crystallization behaviour 290
Applications of polym orphism 291
Phospholipids 291
Phosphatidic acids 292
Cephalins {Phosphatidyl ethanolamines) 295
Lipid-water systems 300
Lipoproteins 304
9 Future developments and other techniques 316
Index 321
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:55:26Z |
| institution | BVB |
| language | English |
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| physical | XII,323 S.m.Abb.u.Tab.,2 Taf. |
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| publishDate | 1965 |
| publishDateSearch | 1965 |
| publishDateSort | 1965 |
| publisher | Methuen |
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| spelling | Chapman, Dennis Verfasser aut The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography London Methuen 1965 XII,323 S.m.Abb.u.Tab.,2 Taf. txt rdacontent n rdamedia nc rdacarrier Lipidios larpcal Chemistry Techniques, Analytical Lipids Lipide (DE-588)4035873-2 gnd rswk-swf Spektroskopie (DE-588)4056138-0 gnd rswk-swf Lipide (DE-588)4035873-2 s Spektroskopie (DE-588)4056138-0 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004514380&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chapman, Dennis The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography Lipidios larpcal Chemistry Techniques, Analytical Lipids Lipide (DE-588)4035873-2 gnd Spektroskopie (DE-588)4056138-0 gnd |
| subject_GND | (DE-588)4035873-2 (DE-588)4056138-0 |
| title | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_auth | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_exact_search | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_full | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_fullStr | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_full_unstemmed | The structure of lipids by spectroscopic and x-ray techniques With a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_short | The structure of lipids by spectroscopic and x-ray techniques |
| title_sort | the structure of lipids by spectroscopic and x ray techniques with a chapter on separation techniques including thin layer and gas liquid chromatography |
| title_sub | With a chapter on separation techniques including thin layer and gas liquid chromatography |
| topic | Lipidios larpcal Chemistry Techniques, Analytical Lipids Lipide (DE-588)4035873-2 gnd Spektroskopie (DE-588)4056138-0 gnd |
| topic_facet | Lipidios Chemistry Techniques, Analytical Lipids Lipide Spektroskopie |
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