The chemistry of rotational isomers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1993
|
| Schriftenreihe: | Reactivity and structure
30 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 172 S. graph. Darst. |
| ISBN: | 3540561935 0387561935 |
Internformat
MARC
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| 100 | 1 | |a Ōki, Michinori |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The chemistry of rotational isomers |c Michinori Ōki |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1993 | |
| 300 | |a X, 172 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Reactivity and structure |v 30 | |
| 650 | 7 | |a Isomérie |2 ram | |
| 650 | 7 | |a Rotation moléculaire |2 ram | |
| 650 | 4 | |a Isomerism | |
| 650 | 0 | 7 | |a Rotationsisomerie |0 (DE-588)4178498-4 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Rotationsisomerie |0 (DE-588)4178498-4 |D s |
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| 830 | 0 | |a Reactivity and structure |v 30 |w (DE-604)BV000895108 |9 30 | |
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Datensatz im Suchindex
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|---|---|
| adam_text | MICHINORI OKI THE CHEMISTRY OF RELATIONAL ISOMERS S*FTK» * WITH 3
FIGURES AND 42 TABLES SPRINGER-VERLAG BERLIN HEIDELBERG NEWYORK LONDON
PARIS TOKYO HONGKONG BARCELONA BUDAPEST TABLE OF CONTENTS 1 INTRODUCTION
1 1.1 THE FREE ROTATION CONCEPT 1 1.2 RECOGNITION OF ROTATIONAL
ISOMERS 2 1.3 ATROPISOMERS 5 1.4 ISOLATION OF ROTATIONAL ISOMERS 7 1.4.1
FACTORS AFFECTING BARRIER HEIGHTS 7 1.4.2 TRIPTYCENE DERIVATIVES 10
1.4.3 9-ARYLFLUORENES 12 1.5 CONCEPTS THAT NEED MODIFICATION 14 1.5.1
ARE THERE DEXTROROTATORY AND LEVOROTATORY GROUPS? 14 1.5.2 REACTIVITY OF
ROTATIONAL ISOMERS 15 1.6 REFERENCES 18 2 ROTAMER POPULATIONS 20 2.1
ESTIMATION OF ROTAMER POPULATIONS 20 2.1.1 VIBRATION SPECTROSCOPY 20
2.1.2 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 22 2.2 FACTORS THAT AFFECT
ROTAMER POPULATIONS 26 2.3 INFORMATION ON MOLECULAR INTERACTIONS
OBTAINED FROM ROTAMER POPULATIONS 29 2.3.1 TRIPTYCENES 29 2.3.1.1
LONG-RANGE COUPLING IN NMR SPECTRA 31 2.3.1.2 STERIC REPULSION 31
2.3.1.3 N-N* INTERACTIONS 32 2.3.1.4 N-A* INTERACTIONS 35 2.3.1.5
HYDROGEN BONDING INVOLVING A METHYL GROUP 38 2.3.2 9-ARYLFLUORENES 45
2.3.2.1 XH-II INTERACTIONS 45 2.3.2.2 N-N* INTERACTIONS 48 2.4
REFERENCES 49 3 BARRIERS TO ROTATION 51 3.1 ESTIMATION OF BARRIERS TO
ROTATION 51 3.1.1 COALESCENCE METHOD 51 3.1.2 LINE SHAPE ANALYSIS 54
3.1.3 SATURATION TRANSFER 57 3.1.4 THE 2D-NMR SPECTROSCOPY 58 X TABLE OF
CONTENTS 3.1.5 CLASSICAL KINETICS 59 3.1.6 RELIABILITY OF THE DATA 60
3.2 HIGH BARRIERS TO ROTATION IN THE 9-ARYLFLUORENE SERIES 62 3.2.1
ISOLATION OF ROTATIONAL ISOMERS 62 3.2.2 FACTORS AFFECTING THE
ROTATIONAL BARRIERS 63 3.2.2.1 EFFECTS OF THE STERIC SIZE OF THE
SUBSTITUENTS 63 3.2.2.2 GROUND STATE DESTABILIZATION 68 3.2.2.3 GROUND
STATE STABILIZATION 70 3.2.2.4 SOLVENT EFFECTS 73 3.3 HIGH BARRIERS TO
ROTATION IN 9-SUBSTITUTED TRIPTYCENE SERIES 75 3.3.1 TRIPTYCENES
CARRYING A 9-JERT-ALKYL SUBSTITUENT 75 3.3.2 TRIPTYCENES CARRYING A
9-SEC-ALKYL SUBSTITUENT 79 3.3.3 TRIPTYCENES CARRYING A 9-PN M-ALKYL
SUBSTITUENT 83 3.3.4 ATROPISOMERS ABOUT A CARBON-TO-HETEROATOM BOND 88
3.4 HIGH BARRIERS TO ROTATION IN MISCELLANEOUS COMPOUNDS 90 3.4.1
ATROPISOMERISM ABOUT AN SP 3 -SP 3 BOND 91 3.4.2 ATROPISOMERISM ABOUT AN
SP 3 ~SP 2 BOND 93 3.5 REFERENCES 96 4 REACTIVITY OF ROTATIONAL ISOMERS
98 4.1 REACTIVITY OF 9-ARYLFLUORENES 98 4.1.1 ADDITIONS AND ELIMINATIONS
98 4.1.1.1 ADDITIONS TO OLEFINS 98 4.1.1.2 ADDITION TO CARBONYL GROUPS
104 4.1.1.3 ELIMINATION REACTIONS 105 4.1.2 SUBSTITUTION REACTIONS 107
4.1.3 ACID-BASE PROPERTIES 113 4.1.3.1 ACIDS AND BASES IN SUBSTITUENTS
OF THE ARYL GROUP 113 4.1.3.2 DEPROTONATION AT THE 9-POSITION OF
FLUORENE 118 4.1.4 OTHER TYPES OF REACTION 122 4.1.4.1 RADICAL REACTIONS
OF 9-ARYLFLUORENE ROTAMERS 123 4.1.4.2 NITRENES AND CARBENES IN
ARYLFLUORENE ROTAMERS 125 4.2 REACTIVITY OF SUBSTITUTED TRIPTYCENES 130
4.2.1 RADICAL-FORMING REACTIONS 132 4.2.1.1 SUBSTITUTION OF A TERT-BUTYL
GROUP AND RELATED REACTIONS 132 4.2.1.2 THERMOLYSIS OF PEROXYESTERS 138
4.2.2 CATION-FORMING REACTIONS 143 4.2.2.1 LEWIS ACID-CATALYZED
LONIZATION OF HALOGEN COMPOUNDS 143 4.2.2.2 INTRAMOLECULAR
FRIEDEL-CRAFTS ACYLATION 145 4.2.2.3 DIAZOTIZATION OF AMINES 149 4.2.3
OTHER TYPES OF REACTIONS 156 4.2.3.1 REACTIONS OF CHLORIDES WITH
TERT-BUTYLLITHIUM 156 4.2.3.2 CHLORODECARBOXYLATION 158 4.2.3.3 BROMINE
ADDITION REACTIONS 159 4.3 REFERENCES 163
|
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| dewey-ones | 541 - Physical chemistry |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T16:44:12Z |
| institution | BVB |
| isbn | 3540561935 0387561935 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004000616 |
| oclc_num | 26850935 |
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| owner_facet | DE-355 DE-BY-UBR DE-12 DE-29T DE-703 DE-634 DE-83 DE-188 |
| physical | X, 172 S. graph. Darst. |
| publishDate | 1993 |
| publishDateSearch | 1993 |
| publishDateSort | 1993 |
| publisher | Springer |
| record_format | marc |
| series | Reactivity and structure |
| series2 | Reactivity and structure |
| spelling | Ōki, Michinori Verfasser aut The chemistry of rotational isomers Michinori Ōki Berlin [u.a.] Springer 1993 X, 172 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Reactivity and structure 30 Isomérie ram Rotation moléculaire ram Isomerism Rotationsisomerie (DE-588)4178498-4 gnd rswk-swf Rotationsisomerie (DE-588)4178498-4 s DE-188 Reactivity and structure 30 (DE-604)BV000895108 30 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004000616&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ōki, Michinori The chemistry of rotational isomers Reactivity and structure Isomérie ram Rotation moléculaire ram Isomerism Rotationsisomerie (DE-588)4178498-4 gnd |
| subject_GND | (DE-588)4178498-4 |
| title | The chemistry of rotational isomers |
| title_auth | The chemistry of rotational isomers |
| title_exact_search | The chemistry of rotational isomers |
| title_full | The chemistry of rotational isomers Michinori Ōki |
| title_fullStr | The chemistry of rotational isomers Michinori Ōki |
| title_full_unstemmed | The chemistry of rotational isomers Michinori Ōki |
| title_short | The chemistry of rotational isomers |
| title_sort | the chemistry of rotational isomers |
| topic | Isomérie ram Rotation moléculaire ram Isomerism Rotationsisomerie (DE-588)4178498-4 gnd |
| topic_facet | Isomérie Rotation moléculaire Isomerism Rotationsisomerie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004000616&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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