Tandem organic reactions:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
1992
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 502 S. Ill. |
| ISBN: | 0471570222 |
Internformat
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Datensatz im Suchindex
| _version_ | 1804120110701477888 |
|---|---|
| adam_text | TANDEM ORGANIC
REACTIONS
TSE-LOK HP
Department of Chemistry
National Taiwan University
A Wiley-Interscience Publication
JOHN WILEY amp; SONS, INC
New York • Chichester • Brisbane • Toronto • Singapore
CONTENTS
Preface ix
1 Introduction 1
2 Aldol Condensation 3
2 1 Michael-Aldol Tandems, 4
2 2 Claisen-Aldol and Multiple Aldol Condensations, 18
2 3 Retro-Aldol-Aldol Tandems, 22
2 4 Mannich-Aldol Tandems, 28
2 5 Rearrangement-Aldol Tandems, 29
2 6 Aldol-Type Reactions in Tandem with Other Processes, 31
3 Michael Reactions 33
3 1 Michael Reactions Initiated by Other Reactions, 34
3 2 Double Michael Reactions, 44
3 3 Reflexive Michael Reactions, SO
4 Tandem Vicinal Difunctionalization of Alkenes and Alkynes 57
4 1 Michael Reaction/Electrophilation, 57
4 2 uic-Difunctionalization of Temporarily Activated Alkenes, 68
4 3 Pauson-Khand Cyclization and Dotz Reaction, 70
4 4 Intramolecular Metallo-Ene Reactions and Related CC Bond
Formation Processes, 76
4 5 Cationic Polyene Cyclizations, 82
4 6 Miscellaneous u/c-Dialkylations, 86
vi CONTENTS
5 Dieckmann and Claisen Cyclizations 88
5 1 Michael-Dieckmann and Michael-Claisen Reaction
Tandems, 89
5 2 Alkylation-Dieckmann and Related Tandem Reactions, 94
5 3 Tandem Reactions Terminated by Claisen Condensation, 97
6 Mannich Reaction 100
6 1 Schiff Condensation-Mannich Cyclization, 100
6 2 Manifold Mannich Reactions, 106
6 3 Alkylation or Acylation-Mannich Cyclization, 109
6 4 Retro-Mannich Fragmentation-Mannich Cyclization, 117
6 5 Mannich Cyclization Following Oxidation or Reduction, 122
6 6 Cationic Aza-Cope Rearrangement-Mannich Cyclization and
Others, 124
7 Diels-AIder Reactions 131
7 1 Elimination/Diels-Alder Reaction Tandems, 131
7 2 Retro-Diels-Alder/Diels-Alder Reactions, 144
7 3 Electrocyclic/Diels-Alder Reactions, 150
7 4 Diels-AIder Reactions Preceded by Other Pericyclic
Reactions, 163
7 5 Acylation/Diels-AIder Reaction Tandems, 176
7 6 Oxidation or Reduction Initiated Diels-AIder Reactions, 178
7 7 Intramolecularization, 182
7 8 Assorted Triggers for the Diels-AIder Reaction, 188
8 Other Cycloadditions 202
81[2+ 2]-Cycloadditions, 202
82[2+2+ 2]-Cycloadditions, 205
8 3 Formation of Five-Membered Rings by Concerted
Cycloadditions, 209
8 4 Higher-Order Cycloadditions, 215
8 5 1,3-Dipolar Cycloadditions, 221
851 Tandem Dehydration-Cycloaddition, 221
852 Elimination-Cycloaddition, 222
853 Condensation-Cycloaddition, 224
854 Oxidation-Cycloaddition, 228
855 Cycloaddition of Photochemically Generated
1,3-Dipoles, 229
CONTENTS vii
9 Retro-Diels-Alder and Cheletropic Reactions 231
9 1 Diels-Alder/Retro-Diels-Alder Reaction Tandems, 231
9 2 Retro-Diels-Alder Reactions Following Other Processes, 250
9 3 Some Other Cheletropic Reactions, 257
10 Electrocyclic Reactions 259
10 1 Electrocyclic Reaction Cascades, 259
10 2 Cycloaddition or Cycloreversion/Electrocyclic Reaction
Tandems, 269
10 3 Rearrangement-Electrocyclic Reaction Tandems, 275
10 4 Electrocyclic Reactions Induced by Enolization, Elimination,
Condensation, or Other Processes, 281
11 Ene, Retro-Ene, and Some Other Thermal Reactions 297
11 1 Ene Reactions, 297
11 2 Retro-Ene Reactions, 303
11 3 Vinylcyclopropane-to-Cyclopentene Rearrangements, 305
12 Sigmatropic Rearrangements 308
12 1 [1 , H]-Sigmatropic Rearrangements, 308
12 2 [3 3]-Sigmatropic Rearrangements, 320
12 2 1 Cope Rearrangements, 321
12 211 Pericyclic Reaction-Induced Cope
Rearrangements, 321
12 212 Cope Rearrangements Induced by Other
Reactions, 338
12 2 2 Claisen and Other Hetero-Cope Rearrangements, 346
12 221 Claisen Rearrangements from Atypically
Generated Substrates, 346
12 222 Tandem Sigmatropy Ended by a Claisen
Rearrangement, 351
12 2 3 [2 3]-Sigmatropic Rearrangements, 357
12 2 4 Sigmatropic Rearrangements of Higher Orders, 360
13 Rearrangements and Fragmentations 361
13 1 Rearrangements, 361
13 1 1 Skeletal Rearrangement of Carbocations, 361
13 1 2 Anionic Rearrangements, 373
13 1 3 Other Rearrangements, 375
viii CONTENTS
13 2 Fragmentation Reactions, 377
13 2 1 Tandem Reactions Terminated in a Retro-Aldol or
retro-Claisen Fission, 377
13 2 2 Retro-Mannich Reactions, 390
13 2 3 Grob Fragmentation, 392
13 2 4 Other Fragmentations, 396
14 Free Radical Reactions 398
14 1 Vicinal CC Bond Formations, 399
14 2 1,3-Diyl Cycloadditions, 408
14 3 Addition-Fragmentation Tandems, 409
14 4 Reactions of Carbinyl Radicals Adjacent to a Small Ring, 412
14 5 Miscellaneous Radical Reaction Tandems, 413
15 Miscellaneous Tandem Reactions 416
15 1 Wittig and Related Reactions, 416
15 1 1 Michael-Wittig Reaction Tandems, 416
15 1 2 Wittig Reactions Preceded by Other Base-catalyzed
Processes, 421
15 1 3 Some Other Olefination Reactions, 424
15 2 Electrophilations, 426
15 3 Eliminations and Ring Openings, 442
15 4 Stitching of Alkenes and Alkynes, 445
15 5 Tandem Reactions Involving Oxidoreductions, 447
References 449
Index 493
|
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| spelling | Ho, Tse-Lok Verfasser aut Tandem organic reactions Tse-Lok Ho New York [u.a.] Wiley 1992 X, 502 S. Ill. txt rdacontent n rdamedia nc rdacarrier Chemische reacties gtt Composés organiques - Synthèse Composés organiques - Synthèse ram Natuurlijke stoffen gtt Réacions chimiques ram Réactions chimiques Chemical reactions Organic compounds Synthesis Tandem-Reaktion (DE-588)4306783-9 gnd rswk-swf Organische Synthese (DE-588)4075695-6 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Tandem-Reaktion (DE-588)4306783-9 s Organische Synthese (DE-588)4075695-6 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003707212&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ho, Tse-Lok Tandem organic reactions Chemische reacties gtt Composés organiques - Synthèse Composés organiques - Synthèse ram Natuurlijke stoffen gtt Réacions chimiques ram Réactions chimiques Chemical reactions Organic compounds Synthesis Tandem-Reaktion (DE-588)4306783-9 gnd Organische Synthese (DE-588)4075695-6 gnd |
| subject_GND | (DE-588)4306783-9 (DE-588)4075695-6 (DE-588)4143413-4 |
| title | Tandem organic reactions |
| title_auth | Tandem organic reactions |
| title_exact_search | Tandem organic reactions |
| title_full | Tandem organic reactions Tse-Lok Ho |
| title_fullStr | Tandem organic reactions Tse-Lok Ho |
| title_full_unstemmed | Tandem organic reactions Tse-Lok Ho |
| title_short | Tandem organic reactions |
| title_sort | tandem organic reactions |
| topic | Chemische reacties gtt Composés organiques - Synthèse Composés organiques - Synthèse ram Natuurlijke stoffen gtt Réacions chimiques ram Réactions chimiques Chemical reactions Organic compounds Synthesis Tandem-Reaktion (DE-588)4306783-9 gnd Organische Synthese (DE-588)4075695-6 gnd |
| topic_facet | Chemische reacties Composés organiques - Synthèse Natuurlijke stoffen Réacions chimiques Réactions chimiques Chemical reactions Organic compounds Synthesis Tandem-Reaktion Organische Synthese Aufsatzsammlung |
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