Electrosorption:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York
Plenum Pr.
1967
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV,221 S.m.Abb. |
Internformat
MARC
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| 650 | 4 | |a Adsorption | |
| 650 | 4 | |a Électrochimie | |
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Datensatz im Suchindex
| _version_ | 1804119991810785280 |
|---|---|
| adam_text | ELECTROSORPTION
Edited by
Eliezer Gileadi
Electrochemistry Laboratory
John Harrison Laboratory of Chemistry
University of Pennsylvania
Philadelphia, Pennsylvania
and
Institute of Chemistry
Tel-Aviv University
Tel-Aviv, Israel
With a Foreword by John O M Bockris
PLENUM PRESS • NEW YORK • 1967
Contents
fv
•: Chapter I
Adsorption in Electrochemistry 1
E Gileadi
1 Introduction 1
1 1 Special Aspects of Adsorption from Solution 1
2 Equations of State and Isotherms 3
2 1 Definitions and Use 3
2 2 Conversion of Equation of State to Isotherms 5
3 The Langmuir Isotherm 6
3 1 Value and Deficiency 6
3 2 Methods of Derivation 6
3 3 Langmuir-like Adsorption 8
331 Adsorption of Large Molecules 8
332 Adsorption from a Second Layer 9
3 4 Langmuir Adsorption from Solution 9
4 The Temkin Isotherm II
4 1 Assumptions, Genera] Form, and Limiting Cases 11
5 The Frumkin Isotherm 12
5 1 Free Energy of Adsorption Decreasing with Coverage 12
5 2 Free Energy of Adsorption Increasing with Coverage 14
5 3 Frumkin-Type Adsorption from Solution 14
6 Experimental Tests of the Isotherms 15
7 Conclusions 16
References 17
Chapter 2
Organic Adsorption at Electrodes 19
B J Piersma
1 Introduction 19
2 Comparison of Methods lor Adsorption Studies in the
Gas Phase and at Electrodes in Solution 20
x Contents
3 Energetics of Adsorption 22
4 Trends in Electrosorption 27
5 Modes of Adsorption and Structure of Adsorbed Species 30
6 The Adsorption Characteristics of Some Selected
Compounds 34
6 1 Carbon Monoxide 34
6 2 Formic Acid 35
6 3 Alcohols 38
6 4 Hydrocarbons 40
7 Open-Circuit Adsorption Behavior 46
8 Summary 48
References 49
Chapter 3
Kinetics of Diffusion-Controlled Electrosorption of Neutral
Molecules 53
AKN Reddy
1 Introduction 53
2 The Adsorption Isoiherm and the Mass Transfer Process 55
3 Analysis of the Diffusion Problem 57
4 The Time Variation of the Surface Concentration of
Adsorbed Species 61
5 Mass Transport-Controlled Electrosorption Under
Stirred Conditions 67
References 70
Chapter 4
Oxygen Adsorption and Oxide Formation on Electrodes 73
M A Gens haw
1 Introduction 73
2 Thermodynamics of Oxidation 73
3 Characteristics of Physically Adsorbed Oxygen 74
4 Characteristics of Chemisorbed Oxygen 74
5 The Occurrence of Physical Adsorption 74
6 The Occurrence of Chemisorption 75
7 Mechanism of Oxide Growth 75
7 1 Growth of Nonconducting Oxides 76
7 2 Growth of Semiconducting Oxides 79
Contents xi
7 3 Growth of Conducting Oxides 81
7 4, Growth of Oxides by Diffusion 84
8 Why is Adsorbed Oxygen Important? 85
References 86
Chapter 5
The Potential of Zero Charge 87
S D Argade and E Gileadi
1 Introduction 87
1 1 What is the Potential of Zero Charge ? 87
1 2 The Rational Scale of Potential 88
1 3 Electrode Kinetics and the Potential of Zero Charge 90
131 Primary Effects 90
132 Secondary Effects 92
1 4 Dependence of Adsorption on the Potential of
Zero Charge 93
2 Aspects of the Potential of Zero Charge Dependent on
the Metal 94
2 1 The Relation Between Potential of Zero Charge,
Contact Potential Difference, and
Work Function 94
2 2 Physicochemical Properties of the Metal 95
3 Aspects of the Potential of Zero Charge Related to the
System 99
3 1 Specific Adsorption of Ions 101
3 2 Organic Adsorption 102
3 3 Surface Coverage with Atomic Hydrogen or Oxygen 102
3 4 pH Variation 103
4 Methods of Determination of the Potential of Zero Charge 103
4 1 Surface Tension Methods 103
411 Electrocapillarv Curves 103
412 Contact Angle Method 104
4 2 Change of Surface Area 104
4 3 Capacity Measurements 106
;i44 Adsorption Methods 107
441 Tonic Adsorption 108
442 Dependence of Organic Adsorption on
:i Electrolyte Concentration 108
xii Contents
4 5 Friction Methods 108
451 The Pendulum Method 108
452 The Angle of Inclination Method ; 110
4 6 Ultrasonic Method Ill
4 7 Repulsion of Double Layers on Two Wires Ill
5 Conclusions 113
References 114
Chapter 6
The Role of Solvents at Electrodes 117
K Mtiller
1 Introduction 117
2 Field-Dependent Orientation of the Solvent at the
Metal-Solution Interface 117
3 Dielectric Properties of the Solvent at the Electrode 119
3 1 The Double aver as Parallel Plate Capacitor 119
3 2 Dielectric Properties of Dipolar Substances 120
3 3 Dielectric Relaxation and Rate Theory; Distribution
of Relaxation Times 124
3 4 Experimental Determination of the Dielectric
Properties of Water in the Electric
Double Layer 126
3 5 Theoretical Considerations and Discussions 129
351 Artifacts 129
352 The Value of the Mean Relaxation Time 130
353 Dipole Relaxation and Double-Layer Structure 130
354 The Value of rw and the Mechanism of
Conduction 131
3 6 Conclusions 132
4 Adsorptive Properties of the Solvent at the Electrode 133
4 1 Gibbs Surface Excess and Adsorption of Neutral
Molecules 133
4 2 Model of the Adsorption Process 135
421 Exchange Equilibrium 135
422 The Mechanism of Adsorption 135
423 Model of Adsorbed Molecules 136
424 Molecular Interactions at the Interface 138
4 3 The Electric Variable 140
Contents xiii
4 4 Adsorption Equations 141
4 5 Conclusions 142
5 Final Remarks 143
References 145
Chapter 7
Theoretical Consideration of the Double Layer 147
H D Hurwitz
1 An Electrostatic Model of the Electrochemical Double
Layer 147
1 1 General Features of the Model 147
1 2 Distinction Between the Electrostatic1 Interactions in
the Double Layer 148
13A Closed Solution for the Coulomb Potential of an
Isolated Charge 149
1 4 Determination of the Average Electrostatic Potential
in the Double Layer 153
2 The Local Thermodynamic Formulation for
Inhomogeneous Electrochemical Systems 155
2 1 The Local Balance Theory of Prigogine, Mazur,
and Defay 155
2 2 The Definition of Pressure at the Interphase 157
2 3 The Definition of the Electrochemical Potential 159
2 4 The Distribution Function at Equilibrium 160
3 Theories of the Ionic Double Layer 161
3 1 General Evolution of the Theoretical Concepts of
the Diffuse Layer 161
3 2 Preliminaries on the Statistical Mechanical
Formulation in Fluids 163
321 The Set Notation 163
322 Definition of Probability Density in the
Canonical Ensemble 163
323 The Correlation and Radial Distribution
Function 165
324 Kirkwood s Superposition Approximation 166
325 Distribution in the Grand Ensemble 166
326 Average Electrostatic Potential and Free
Energy 167
xiv Contents
3 3 The Differential Equation Method of Debye and
Hiickel 168
3 4 The Gouy Potential in the Diffuse Layer 170
341 The 1 ntegrability Condition in the Case of
an Inhomogeneous System 171
342 The Solution of Gouy and Chapman 175
343 Determination of the Self-Atmosphere Effect
by Means of the Cluster Expansion
Method 177
344 The Diffuse Layer Version of the Expansion
Method in Terms of a Charging Parameter 179
345 The Evaluation of the Electrostatic Potentials
in the Diffuse Layer by:Means of Stillinger
and Kirkwood s Method : 184
346 Application of the Local Thermodynamic
Method 190
3 5 General Evolution of Ideas on Specific Adsorption
in the Inner Layer 194
3 6 General Expression of the Adsorption Isotherm 196
3 7 The Mobile Monolayer Adsorption 201
371 Description of the Model of Mobile
Adsorption 201
372 The Cavity Field 207
373 The Coordination Field 209
374 The Radial Redistribution Work 210
375 The Final Form of the Adsorption Isotherm
and Its Application 211
3 8 The Discreteness of Charge Model and Lattice
Adsorption 214
References 216
Index 219
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| spelling | Electrosorption Hrsg. von Eliezer Gileadi* New York Plenum Pr. 1967 XIV,221 S.m.Abb. txt rdacontent n rdamedia nc rdacarrier Adsorption Électrochimie Électrodes Electrochemistry Electrodes Elektrosorption (DE-588)4151971-1 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Sorption (DE-588)4181865-9 gnd rswk-swf Adsorption (DE-588)4000536-7 gnd rswk-swf Elektrode (DE-588)4014247-4 gnd rswk-swf Sorption (DE-588)4181865-9 s Elektrochemie (DE-588)4014241-3 s DE-604 Elektrosorption (DE-588)4151971-1 s Adsorption (DE-588)4000536-7 s Elektrode (DE-588)4014247-4 s Gileadi, Eliʿezer 1932- Sonstige (DE-588)124010180 oth HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003629210&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Electrosorption Adsorption Électrochimie Électrodes Electrochemistry Electrodes Elektrosorption (DE-588)4151971-1 gnd Elektrochemie (DE-588)4014241-3 gnd Sorption (DE-588)4181865-9 gnd Adsorption (DE-588)4000536-7 gnd Elektrode (DE-588)4014247-4 gnd |
| subject_GND | (DE-588)4151971-1 (DE-588)4014241-3 (DE-588)4181865-9 (DE-588)4000536-7 (DE-588)4014247-4 |
| title | Electrosorption |
| title_auth | Electrosorption |
| title_exact_search | Electrosorption |
| title_full | Electrosorption Hrsg. von Eliezer Gileadi* |
| title_fullStr | Electrosorption Hrsg. von Eliezer Gileadi* |
| title_full_unstemmed | Electrosorption Hrsg. von Eliezer Gileadi* |
| title_short | Electrosorption |
| title_sort | electrosorption |
| topic | Adsorption Électrochimie Électrodes Electrochemistry Electrodes Elektrosorption (DE-588)4151971-1 gnd Elektrochemie (DE-588)4014241-3 gnd Sorption (DE-588)4181865-9 gnd Adsorption (DE-588)4000536-7 gnd Elektrode (DE-588)4014247-4 gnd |
| topic_facet | Adsorption Électrochimie Électrodes Electrochemistry Electrodes Elektrosorption Elektrochemie Sorption Elektrode |
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