Fourier transform NMR spectroscopy:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam u. a.
Elsevier
1984
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Studies in physical and theoretical chemistry
30. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 344 S. graph. Darst. |
| ISBN: | 0444422854 0444416994 |
Internformat
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Datensatz im Suchindex
| _version_ | 1804119947124670464 |
|---|---|
| adam_text | studies in physical and theoretical chemistry 30
FOURIER TRANSFORM
NMR SPECTROSCOPY
(second edition)
DEREK SHAW
IGE Medical Systems Ltd ,
Slough, Berkshire, United Kingdom
ELSEVIER
Amsterdam — Oxford — New York — Tokyo 1984
CONTENTS
Preface 1X
Acknowledgement X1
Chapter 1 Introduction 1
1 Historical 1
2 Pulsed high resolution nmr3
3 The Fourier transform 4
4 The nmr spectrum 5
References 9
Chapter 2 Principles of magnetic resonance 11
1 The nuclear spin H
2 The nucleus in a magnetic field 12
3 The quantum mechanical description of magnetic resonance 16
4 The population of spin states 19
5 Relaxation effects 21
6 The nmr line shape 25
7 The Bloch equations in the laboratory frame 26
8 The rotating frame of reference 29
9 The Bloch equations in the rotating frame 32
References 35
Chapter 3 The mathematics of Fourier nmr 37
1 Fourier series and Fourier transforms 37
2 Fourier pairs 40
3 The two domains 42
4 Fourier transformations in 2 dimensions 43
5 The representation of physical quantities 44
6 Convolution 45
7 Cross-correlatio n 48
8 Auto-correlatio n 50
9 Linear systems 53
10 Discrete or digital Fourier transforms 58
References 59
Chapter 4 Excitation techniques in nmr 61
1 Introduction 61
2 The nmr spectrum in two domains 62
3 Two basic f t experiments 64
4 Advantages of the time domain 66
5 Pulsed excitation and the impulse response function 68
6 The free induction decay 69
7 Continuous wave excitation 72
8 Stochastic excitation 74
9 Correlation spectroscopy 79
10 Tailored excitation 83
11 The equivalence of swept and Fourier nmr 85
12 Difference spectroscopy 90
References 91
VI
Chapter 5 Pulsed n
1 The Bloch equations for pulsed excitation 93
2 The steady state, phase and intensity anomalies 101
3 The effect of finite pulse power 104
4 The free induction decay 105
5 The gain in sensitivity using pulsed excitation 109
6 Multipulse excitation in liquids 116
7 Multipulse sequences to enhance sensitivity 123
8 Mul tipulse spectrum editing 128
9 Compos i te pulses 130
10 Saturation effects in pulsed nmr 133
References 137
Chapter 6 Ins t rument at ion 139
1 Introduction 139
2 The magnet 139
3 Field/frequency lock 142
4 The probe 145
5 Frequency generation 147
6 Transmitter and power amplifier 148
7 The receiver 149
8 The pulse programmer 153
9 The spin decoupler 153
10 The interface 15,6
11 The computer 161
12 Software 162
13 Factors affecting the signal to noise ratio of a spectrometer 173
References 181
Chapter 7 Experimental techniques 183
I Introductio n 183
2 Sample preparation 183
3 Spectral width and offset 187
4 Acquisition time 189
5 Choice of pulse width 190
6 Spin decoupling 197
7 Number of transients 200
8 Setting the gain 201
9 The use of weighting functions 203
10 Apodi sat ion 211
II Problems encountered in the presence of large solvent peaks 212
12 Spectral presentation 217
References 219
Chapter 8 Multiple resonance 221
1 I nt roduct ion and history 221
2 Double resonance theory 222
3 Bloch-Siegert effects 227
4 The generalised Overhauser effect 228
5 Sp in-tick ling 230
6 INDOR 231
*
VII
7 The nuclear Overhauser effect 233
8 Techniques of spin decoupling 238
9 Gated decoupling experiments 242
10 Applications of double resonance techniques 245
References 24 7
Chapter 9 Relaxation 249
1 Definition of and T2 249
2 Theory of molecular motion 250
3 Relaxation mechanisms , 254
4 Dipole-dipole relaxation 256
5 Spin rotation 260
6 Chemical shift anisotropy 26 1
7 Scalar relaxation 262
8 Quadrupolar relaxation 265
9 Electron-nuclear relaxation 266
10 The relative significance of relaxation mechanisms 268
11 Applications of carbon T^ data 270
12 The measurement of spin lattice relaxation times 274
13 The measurement of spin-spin relaxation times 287
14 Rotating frame resonance effects 289
References 29 1
Chapter 10 Multidimensional nmr 295
1 Two dimensional nmr 295
2 Classical description of 2D nmr 297
3 The phase of 2D spectra 302
4 Data handling in 2D nmr 303
5 2D FT experiments 305
6 Multiple quantum experiments 316
7Nmr imaging 319
8 Factors affecting the gradients used in nmr imaging 321
9 Imaging methods 322
10 Relaxat ion effects in nmr imaging 328
11 The quality of nmr imaging methods 329
12 Future trends 331
References 331
Appendix l Jean Baptiste Joseph Fourier 333
Appendix 2 Building blocks for 2D and multipulse nmr 336
Subject index 339
|
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| discipline | Chemie / Pharmazie Physik |
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| isbn | 0444422854 0444416994 |
| language | English |
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| physical | XI, 344 S. graph. Darst. |
| publishDate | 1984 |
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| series | Studies in physical and theoretical chemistry |
| series2 | Studies in physical and theoretical chemistry |
| spelling | Shaw, Derek Verfasser aut Fourier transform NMR spectroscopy 2. ed. Amsterdam u. a. Elsevier 1984 XI, 344 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Studies in physical and theoretical chemistry 30. Fourier, Spectroscopie par transformée de ram Spectroscopie de la résonance magnétique nucléaire ram Fourier-Spektroskopie (DE-588)4135413-8 gnd rswk-swf Fourier-Transformation (DE-588)4018014-1 gnd rswk-swf Spektroskopie (DE-588)4056138-0 gnd rswk-swf NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf NMR-Spektroskopie (DE-588)4075421-2 s Fourier-Transformation (DE-588)4018014-1 s DE-604 Spektroskopie (DE-588)4056138-0 s 1\p DE-604 Fourier-Spektroskopie (DE-588)4135413-8 s 2\p DE-604 Studies in physical and theoretical chemistry 30. (DE-604)BV000004482 30 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003600056&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Shaw, Derek Fourier transform NMR spectroscopy Studies in physical and theoretical chemistry Fourier, Spectroscopie par transformée de ram Spectroscopie de la résonance magnétique nucléaire ram Fourier-Spektroskopie (DE-588)4135413-8 gnd Fourier-Transformation (DE-588)4018014-1 gnd Spektroskopie (DE-588)4056138-0 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd |
| subject_GND | (DE-588)4135413-8 (DE-588)4018014-1 (DE-588)4056138-0 (DE-588)4075421-2 |
| title | Fourier transform NMR spectroscopy |
| title_auth | Fourier transform NMR spectroscopy |
| title_exact_search | Fourier transform NMR spectroscopy |
| title_full | Fourier transform NMR spectroscopy |
| title_fullStr | Fourier transform NMR spectroscopy |
| title_full_unstemmed | Fourier transform NMR spectroscopy |
| title_short | Fourier transform NMR spectroscopy |
| title_sort | fourier transform nmr spectroscopy |
| topic | Fourier, Spectroscopie par transformée de ram Spectroscopie de la résonance magnétique nucléaire ram Fourier-Spektroskopie (DE-588)4135413-8 gnd Fourier-Transformation (DE-588)4018014-1 gnd Spektroskopie (DE-588)4056138-0 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd |
| topic_facet | Fourier, Spectroscopie par transformée de Spectroscopie de la résonance magnétique nucléaire Fourier-Spektroskopie Fourier-Transformation Spektroskopie NMR-Spektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003600056&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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