Constitution and biosynthesis of lignin:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1968
|
| Schriftenreihe: | Molecular biology, biochemistry and biophysics
2 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | IX, 129 S. |
Internformat
MARC
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| 245 | 1 | 0 | |a Constitution and biosynthesis of lignin |c K. Freudenberg ; A. C. Neish |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1968 | |
| 300 | |a IX, 129 S. | ||
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| 490 | 1 | |a Molecular biology, biochemistry and biophysics |v 2 | |
| 650 | 4 | |a Lignine | |
| 650 | 7 | |a Lignine |2 gtt | |
| 650 | 4 | |a Lignin | |
| 650 | 0 | 7 | |a Lignin |0 (DE-588)4167660-9 |2 gnd |9 rswk-swf |
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| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Lignin |0 (DE-588)4167660-9 |D s |
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| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Lignin |0 (DE-588)4167660-9 |D s |
| 689 | 2 | 1 | |a Struktur |0 (DE-588)4058125-1 |D s |
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| 700 | 1 | |a Freudenberg, Karl |d 1886-1983 |e Sonstige |0 (DE-588)116773758 |4 oth | |
| 700 | 1 | |a Neish, Arthur Charles |e Sonstige |4 oth | |
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Datensatz im Suchindex
| _version_ | 1804119875565649920 |
|---|---|
| adam_text | KJFreudenberg • A C Neish
Constitution and Biosynthesis
of Lignin
With 10 Figures
,j, fr,j*
Cc st J SC-OII©
0
Springer-Verlag Berlin • Heidelberg • New York 1968
Table of Contents
Monomeric Intermediates in the Biosynthesis of Lignin
Arthur C Neish, Halifax, Nova Scotia
I Introduction 3
II Experimental Methods 9
A General Remarks 9
B Tracer Studies 10
1 Feeding of Precursors 10
2 Measurement of 14C-Incorporation into Lignin 12
C Enzyme Studies 13
III Biosynthesis of Aromatic Amino Acids in Plants 15
A Summary of Work with Bacterial Mutants 15
B Studies on Vascular Plants 15
IV Ring-substituted Cinnamic Acids as Intermediates in Lignification 17
A General Remarks ; 17
B Tracer Studies 17
1 Comparison of Precursors 17
2 Comparison of Species 29
C Enzyme Studies 30
V Cinnamyl-Alcohol Derivatives as Intermediates in Lignification 31
VI Compounds Biogenetically-Related to Lignin 32
VII Evolution of Lignification 34
VIII Summary 37
IX References 37
The Constitution and Biosynthesis of Lignin
Karl Freudenberg, Heidelberg
Part I
A The Beginning 47
B Lignin Preparations and Their Isolation 50
VIII
Table of Contents
C Lignin Derivatives and Their Preparation 53
D The Aromatic Nature of Lignin 55
E Other Observations 60
1 Liberation of Formaldehyde; search for C-Methyl 60
2 Oxidation to Vanillin and Allied Materials 61
3 Other Oxidation Products 62
4 Hydrogenation 62
5 Lignin and Alcohols 63
F The Elemental Analysis of Lignin and the Calculation of Its Composition 64
1 Introductory Remarks 64
2 Expression of Lignin Analyses 65
3 Recalculation of Analyses for Acetyllignin 66
4 Recalculation of Analyses for Methyllignin 67
5 Recalculation of Lignothioglycolic Acid 68
G Analytical Data on Lignin 69
1 Elemental Composition 69
2 Hydroxyl Estimation 70
3 Carbonyl Groups 72
4 Ether Oxygen and Oxygen Balance 72
H Early Approaches to the Constitution of Lignin 74
Part II
A Degradation of Lignin to Methoxybenzenecarboxylic Acids and Other
Products 78
1 Compounds of the Catechol (Veratrole) Series 78
2 Compounds of the Anisole Series 80
3 Compounds of the Trimethoxybenzene Series 80
4 Other Oxidation Products 80
B The Dehydrogenation of Coniferyl Alcohol 82
1 Introductory Remarks 82
2 Monolignols 85
3 Dilignols 86
4 Trilignols 91
5 Higher Oligolignols 91
C Linkage of Lignin with Carbohydrates 92
D Quinone Methides: Benzyl Aryl Ethers in Lignin; Hydrolysis Products 93
E Biochemical and Tracer Experiments 97
1 Biochemical Experiments and Other Observations 97
2 Tracer Experiments 99
Table of Contents
IX
mposition
and Other
53
55
60
60
61
62
62
63
64
64
65
66
67
68
69
69
70
72
72
74
F Schematic Model of the Constitution of Spruce Lignin 102
G Appraisal of the Schematic Formula for Spruce Lignin 105
H Other Proposals for Formulae 108
I Beech Lignin, Other Kinds of Lignin and the Concept of Lignin; Lignite
and Humic Acid 110
1 Beech Lignin and Other Kinds of Lignin 110
2 The Concept of Lignin 114
3 Fossilized Wood (Lignite) 115
4 Humic Substances 115
K Concluding Remark 116
L References 116
Subject Index 123
78
78
80
80
80
82
82
85
86
91
91
92
93
is Products
97
97
|
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| institution | BVB |
| language | English |
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| physical | IX, 129 S. |
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| series | Molecular biology, biochemistry and biophysics |
| series2 | Molecular biology, biochemistry and biophysics |
| spelling | Constitution and biosynthesis of lignin K. Freudenberg ; A. C. Neish Berlin [u.a.] Springer 1968 IX, 129 S. txt rdacontent n rdamedia nc rdacarrier Molecular biology, biochemistry and biophysics 2 Lignine Lignine gtt Lignin Lignin (DE-588)4167660-9 gnd rswk-swf Struktur (DE-588)4058125-1 gnd rswk-swf Biosynthese (DE-588)4006902-3 gnd rswk-swf Lignin (DE-588)4167660-9 s DE-604 Biosynthese (DE-588)4006902-3 s Struktur (DE-588)4058125-1 s Freudenberg, Karl 1886-1983 Sonstige (DE-588)116773758 oth Neish, Arthur Charles Sonstige oth Molecular biology, biochemistry and biophysics 2 (DE-604)BV000000294 2 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003552240&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Constitution and biosynthesis of lignin Molecular biology, biochemistry and biophysics Lignine Lignine gtt Lignin Lignin (DE-588)4167660-9 gnd Struktur (DE-588)4058125-1 gnd Biosynthese (DE-588)4006902-3 gnd |
| subject_GND | (DE-588)4167660-9 (DE-588)4058125-1 (DE-588)4006902-3 |
| title | Constitution and biosynthesis of lignin |
| title_auth | Constitution and biosynthesis of lignin |
| title_exact_search | Constitution and biosynthesis of lignin |
| title_full | Constitution and biosynthesis of lignin K. Freudenberg ; A. C. Neish |
| title_fullStr | Constitution and biosynthesis of lignin K. Freudenberg ; A. C. Neish |
| title_full_unstemmed | Constitution and biosynthesis of lignin K. Freudenberg ; A. C. Neish |
| title_short | Constitution and biosynthesis of lignin |
| title_sort | constitution and biosynthesis of lignin |
| topic | Lignine Lignine gtt Lignin Lignin (DE-588)4167660-9 gnd Struktur (DE-588)4058125-1 gnd Biosynthese (DE-588)4006902-3 gnd |
| topic_facet | Lignine Lignin Struktur Biosynthese |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003552240&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000000294 |
| work_keys_str_mv | AT freudenbergkarl constitutionandbiosynthesisoflignin AT neisharthurcharles constitutionandbiosynthesisoflignin |