Radiochemistry and nuclear methods of analysis:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York u.a.
Wiley
1991
|
| Schriftenreihe: | Chemical analysis
116 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII, 531 S. Ill., graph. Darst. |
| ISBN: | 0471600768 |
Internformat
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Datensatz im Suchindex
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| adam_text | RADIOCHEMISTRY AND NUCLEAR METHODS OF ANALYSIS WILLIAM D. EHMANN
PROFESSOR, DEPARTMENT OF CHEMISTRY UNIVERSITY OF KENTUCKY LEXINGTON,
KENTUCKY DIANE E. VANCE STAFF DEVELOPMENT SCIENTIST ANALYTICAL SERVICES
ORGANIZATION OAK RIDGE Y-12 PLANT OAK RIDGE, TENNESSEE A
WILEY-INTERSCIENCE PUBLICATION JOHN WILEY & SONS, INC. NEW YORK /
CHICHESTER / BRISBANE / TORONTO / SINGAPORE *. CONTENTS CHAPTER 1
INTRODUCTION TO RADIOCHEMISTRY 1 1.1. THE DISCOVERY OF RADIOACTIVITY AND
EVOLUTION OF NUCLEAR THEORY 1 1.2. FORCES IN MATTER AND THE SUBATOMIC
PARTICLES 20 1.2.1. FORCES IN NATURE 20 1.2.2. THE SUBATOMIC PARTICLES
21 1.3. NUCLIDES AND NATURAL DECAY CHAINS 22 1.3.1. NUCLIDES AND SYMBOLS
23 1.3.2. CLASSIFICATION OF NUCLIDES 23 1.3.3. CHART OF THE NUCLIDES 25
1.3.4. NATURAL DECAY CHAINS 28 1.3.5. AN EXTINCT NATURAL DECAY CHAIN 31
CHAPTER 2 TYPES OF RADIOACTIVE DECAY 35 2.1. ALPHA-PARTICLE DECAY 36
2.2. BETA DECAY 41 2.2.1. NEGATRON DECAY 41 2.2.2. POSITRON DECAY 43
2.2.3. ELECTRON CAPTURE (EC OR E) 45 2.3. GAMMA DECAY 46 2.3.1. PURE
GAMMA-RAY EMISSION 48 2.3.2. INTERNAL CONVERSION (IC) 48 2.3.3. PAIR
PRODUCTION (PP) 49 2.4. BRANCHING DECAYS AND DECAY SCHEMES 50 2.5. LESS
COMMON DECAY MODES 50 2.5.1. SPONTANEOUS FISSION DECAY 50 2.5.2.
DELAYED-NEUTRON EMISSION 52 2.5.3. DELAYED-PROTON EMISSION 53 2.5.4.
DOUBLE-BETA DECAY - 53 2.5.5. TWO-PROTON DECAY 54 2.5.6. 14 C AND OTHER
CLUSTER EMISSION DECAY 54 XI XLL CONTENTS CHAPTER 3 NUCLEAR CHEMISTRY
AND MASS-ENERGY RELATIONSHIPS 57 3.1. DESCRIPTION OF THE NUCLEUS 57 3.2.
NUCLEAR PROPERTIES 61 3.2.1. ANGULAR MOMENTUM AND NUCLEAR SPIN 61 3.2.2.
MAGNETIC MOMENT (/A) 61 3.2.3. PARITY AND SYMMETRY 62 3.3. MODELS OF
NUCLEAR STRUCTURE 62 3.3.1. SHELL MODEL (SINGLE PARTICLE MODEL) 63
3.3.2. FERMI GAS MODEL 65 3.3.3. LIQUID DROP MODEL 66 3.3.4. OPTICAL
MODEL (CLOUDY CRYSTAL BALL MODEL) 67 3.3.5. COLLECTIVE MODEL 67 3.4.
MASS-ENERGY RELATIONSHIPS 67 3.4.1. MASS-ENERGY EQUIVALENCE 68 3.4.2.
ENERGY CHANGES IN NUCLEAR REACTIONS 69 3.4.3. ENERGY CHANGES IN
RADIOACTIVE DECAY 74 3.4.4. CLOSED-CYCLE DECAY FOR MASS-ENERGY
CALCULATIONS 75 3.4.5. SEMIEMPIRICAL BINDING ENERGY EQUATION 76 3.4.6.
NUCLEAR ENERGY SURFACE DIAGRAMS 78 CHAPTER 4 NUCLEAR REACTIONS 85 4.1.
TYPES OF NUCLEAR REACTIONS 85 4.1.1. SCATTERING REACTIONS 85 4.1.2.
OTHER REACTIONS 86 4.2. ENERGETICS OF NUCLEAR REACTIONS 87 4.2.1.
MOMENTUM CORRECTION 88 4.2.2. COULOMB BARRIER CORRECTION 89 4.3. CROSS
SECTIONS FOR NUCLEAR REACTIONS 90 4.3.1. MEASUREMENT OF CROSS SECTION 92
4.3.2. EXCITATION FUNCTIONS 96 4.4. REACTION MECHANISMS 100 4.4.1.
COMPOUND-NUCLEUS FORMATION 100 4.4.2. DIRECT INTERACTIONS 102 4.5.
SPECIAL NUCLEAR REACTIONS 103 4.5.1. NEUTRON-INDUCED FISSION 103 4.5.2.
FUSION 106 CONTENTS XLLL 4.5.3. HEAVY-ION REACTIONS 107 4.5.4.
PHOTONUCLEAR REACTIONS 107 CHAPTER 5 RATES OF NUCLEAR DECAY 113 5.1.
RATES OF RADIOACTIVE DECAY 113 5.1.1. HALF-LIFE AND AVERAGE LIFE 114
5.2. UNITS OF RADIOACTIVE DECAY 116 5.3. BRANCHING DECAY 118 5.4.
EXPERIMENTAL METHODS FOR DETERMINATION OF HALF-LIFE 119 5.4.1. LONG
HALF-LIVES 119 5.4.2. MEDIUM HALF-LIVES 124 5.4.3. SHORT HALF-LIVES 127
5.4.4. VERY SHORT HALF-LIVES 129 5.5. ESTIMATION OF HALF-LIFE FROM
THEORY AND SYSTEMATICS 131 5.6. GROWTH OF RADIOACTIVE PRODUCTS IN A
DECAY CHAIN 133 5.6.1. PARENT WITH A SINGLE RADIOACTIVE DAUGHTER 134
5.6.2. PARENT WITH MULTIPLE RADIOACTIVE DAUGHTERS 138 5.7. GROWTH OF
PRODUCTS IN A NEUTRON FLUX 140 CHAPTER 6 INTERACTIONS OF RADIATION WITH
MATTER 147 6.1. MODES OF INTERACTION 147 6.2. HEAVY CHARGED-PARTICLE
INTERACTIONS 149 6.2.1. RANGE RELATIONSHIPS FOR HEAVY CHARGED PARTICLES
149 6.2.2. STOPPING POWER 154 6.3. BETA-PARTICLE INTERACTIONS 154 6.3.1.
RANGE RELATIONSHIPS FOR BETA PARTICLES 156 6.3.2. THE FEATHER METHOD 158
6.3.3. BREMSSTRAHLUNG RADIATION 160 6.3.4. CERENKOV RADIATION 161 6.3.5.
BETA BACKSCATTER 161 6.3.6. POSITRON INTERACTIONS 161 6.4. GAMMA-RAY
INTERACTIONS 162 6.4.1. PHOTOELECTRIC EFFECT 162 6.4.2. COMPTON
SCATTERING 164 6.4.3. PAIR PRODUCTION 167 6.4.4. MATHEMATICS OF
GAMMA-RAY ABSORPTION 170 XVI CONTENTS CHAPTER 10 RADIOTRACER METHODS 313
10.1. GENERAL ASPECTS OF RADIOTRACER USE 313 10.1.1. ASSUMPTIONS MADE IN
TRACER STUDIES 313 10.1.2. FACTORS IN THE CHOICE OF A RADIOTRACER 314
10.1.3. PRODUCTION OF RADIOTRACERS 315 10.1.4. ADVANTAGES AND
DISADVANTAGES OF RADIOTRACER USE 316 10.2. ISOTOPE DILUTION ANALYSIS 318
10.2.1. THEORY AND CALCULATIONS FOR DIDA 318 10.2.2. APPLICATIONS OF IDA
319 10.2.3. VARIATIONS OF IDA 321 10.3. TRACERS IN THE STUDY OF CHEMICAL
PROCESSES 323 10.3.1. EQUILIBRIUM PROCESSES 323 10.3.2. ANALYTICAL
APPLICATIONS 325 10.3.3. STUDIES OF REACTION MECHANISMS 327 10.4. OTHER
APPLICATIONS OF RADIOTRACERS AND RADIONUCLIDES 327 10.5. NUCLEAR
MEDICINE AND PHARMACY 331 10.5.1. GENERAL ASPECTS OF RADIOPHARMACEUTICAL
USE 331 10.5.2. NUCLEAR PROPERTIES OF INDICATOR NUCLIDES 332 10.5.3. IN
VIVO DIAGNOSTIC PROCEDURES 338 10.5.4. IN VITRO DIAGNOSTIC TESTING:
RADIOIMMUNOASSAY 340 10.5.5. THERAPEUTIC USES OF RADIATION 342 CHAPTER
11 ION BEAM ANALYSIS AND CHEMICAL APPLICATIONS OF RADIOACTIVITY 347 11.1
PARTICLE-INDUCED X-RAY EMISSION 347 11.1.1. OVERVIEW OF THE PIXE PROCESS
348 11.1.2. PROJECTILE ACCELERATION AND TARGET PREPARATION 348 11.1.3.
IONIZATION AND X-RAY EMISSION 351 11.1.4. DETECTION AND ANALYSIS OF X
RAYS 351 11.1.5. APPLICATIONS OF PIXE 353 11.1.6. PIXE VARIATIONS 354
11.2. RUTHERFORD BACKSCATTERING SPECTROMETRY 355 11.2.1. THE SCATTERING
REACTION 356 11.2.2. SURFACE ANALYSIS USING RBS 357 11.2.3. DEPTH
PROFILING USING RBS 359 11.2.4. CHANNELING EFFECTS 362 11.2.5.
APPLICATIONS OF RBS 363 CONTENTS XVU 11.3. MOESSBAUER SPECTROSCOPY 364
11.4. HOT-ATOM CHEMISTRY 367 11.4.1. PRODUCTION OF HOT ATOMS 369 11.4.2.
ENERGY CALCULATIONS 369 11.4.3. APPLICATIONS OF HOT-ATOM REACTIONS 371
11.5. RADIATION CHEMISTRY 373 CHAPTER 12 NUCLEAR DATING METHODS 379
12.1. GENERAL PRINCIPLES OF NUCLEAR DATING METHODS 379 12.2. RADIOCARBON
DATING 382 12.3. TRITIUM DATING 386 12.4. U-PB AND TH-PB METHODS 387
12.4.1 SIMPLE HE ACCUMULATION METHOD 387 12.4.2. SINGLE-DECAY-CHAIN
METHODS 387 12.4.3.. PB-PB METHOD 389 12.5. RB-SR METHOD 391 12.6. K-AR
METHOD 395 12.6.1. STANDARD METHOD 395 12.6.2. INCREMENTAL HEATING
METHOD 395 12.7. PLEOCHROIC HALOS 397 12.8. FISSION TRACKS 397 12.9.
SPECIAL METHODS 399 12.9.1. COSMIC-RAY EXPOSURE AGES OF METEORITES 399
12.9.2. TERRESTRIAL AGES OF METEORITES 400 12.9.3. EXTINCT NATURAL
RADIONUCLIDES 401 12.9.4. RE-OS METHOD 403 12.9.5. LU-HF METHOD 403
12.9.6. K-CA METHOD 403 CHAPTER 13 THE ORIGIN OF THE CHEMICAL ELEMENTS
407 13.1. COSMOLOGY 407 13.1.1. ELEMENTAL ABUNDANCES 408 13.1.2. COSMIC
ABUNDANCE CURVES 413 13.2. PRIMORDIAL NUCLEOSYNTHESIS 414 13.3. STELLAR
EVOLUTION 417 13.3.1. STAR POPULATIONS 417 13.3.2. EVOLUTION OF A STAR
418 XV111 CONTENTS 13.4. STELLAR NUCLEOSYNTHESIS 420 13.4.1. HYDROGEN
FUSION 420 13.4.2. THE CNO BI-CYCLE 421 13.4.3. HELIUM BURNING 423
13.4.4. HEAVIER ELEMENT BURNING 424 13.4.5. THE S-PROCESS 426 13.4.6.
THE R- AND P-PROCESSES 428 13.4.7. SUPERNOVAE 430 13.5. THE SOLAR
NEUTRINO PROBLEM 431 13.6. SYNTHESIS OF BE, B, AND LI 433 CHAPTER14
PARTICLE GENERATORS 437 14.1. NATURAL PARTICLE SOURCES 437 14.2. NUCLEAR
REACTORS 438 14.2.1. THE FISSION PROCESS 438 14.2.2. MAJOR COMPONENTS OF
REACTORS 444 14.2.3. TYPES OF REACTORS 450 14.2.4. APPLICATIONS OF
REACTORS 452 14.3. ACCELERATORS: BASIC COMPONENTS 458 14.4.
COCKROFT-WALTON ACCELERATORS 461 14.5. VAN DE GRAAFF ACCELERATORS 462
14.6. LINEAR ACCELERATORS 465 14.7. CYCLOTRONS 466 14.8. SYNCHROTRONS
470 14.9. LARGE ACCELERATORS FOR NUCLEAR PHYSICS RESEARCH 472 APPENDIX A
STATISTICS FOR RADIOCHEMISTRY 475 APPENDIX B GENERAL REFERENCES AND DATA
SOURCES 483 APPENDIX C NUCLIDIC PROPERTIES 485 APPENDIX D USEFUL
CONSTANTS AND CONVERSIONS 517 INDEX 519
|
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| id | DE-604.BV005633356 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:32:26Z |
| institution | BVB |
| isbn | 0471600768 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-003520548 |
| oclc_num | 22906590 |
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| owner | DE-12 DE-91G DE-BY-TUM DE-83 DE-11 |
| owner_facet | DE-12 DE-91G DE-BY-TUM DE-83 DE-11 |
| physical | XVIII, 531 S. Ill., graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Wiley |
| record_format | marc |
| series | Chemical analysis |
| series2 | Chemical analysis |
| spelling | Ehmann, William D. Verfasser aut Radiochemistry and nuclear methods of analysis William D. Ehmann ; Diane E. Vance New York u.a. Wiley 1991 XVIII, 531 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemical analysis 116 Radiochemie gtt Nuclear chemistry Radiochemistry Radiochemie (DE-588)4138529-9 gnd rswk-swf Kernchemie (DE-588)4138530-5 gnd rswk-swf Radiochemie (DE-588)4138529-9 s DE-604 Kernchemie (DE-588)4138530-5 s Vance, Diane E. Verfasser aut Chemical analysis 116 (DE-604)BV000008780 116 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003520548&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ehmann, William D. Vance, Diane E. Radiochemistry and nuclear methods of analysis Chemical analysis Radiochemie gtt Nuclear chemistry Radiochemistry Radiochemie (DE-588)4138529-9 gnd Kernchemie (DE-588)4138530-5 gnd |
| subject_GND | (DE-588)4138529-9 (DE-588)4138530-5 |
| title | Radiochemistry and nuclear methods of analysis |
| title_auth | Radiochemistry and nuclear methods of analysis |
| title_exact_search | Radiochemistry and nuclear methods of analysis |
| title_full | Radiochemistry and nuclear methods of analysis William D. Ehmann ; Diane E. Vance |
| title_fullStr | Radiochemistry and nuclear methods of analysis William D. Ehmann ; Diane E. Vance |
| title_full_unstemmed | Radiochemistry and nuclear methods of analysis William D. Ehmann ; Diane E. Vance |
| title_short | Radiochemistry and nuclear methods of analysis |
| title_sort | radiochemistry and nuclear methods of analysis |
| topic | Radiochemie gtt Nuclear chemistry Radiochemistry Radiochemie (DE-588)4138529-9 gnd Kernchemie (DE-588)4138530-5 gnd |
| topic_facet | Radiochemie Nuclear chemistry Radiochemistry Kernchemie |
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