Oxygen chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | Undetermined |
| Veröffentlicht: |
New York [u.a.]
Oxford Univ. Press
1991
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| Schriftenreihe: | The international series of monographs on chemistry
26 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 223 S. |
| ISBN: | 0195057988 |
Internformat
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Datensatz im Suchindex
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| adam_text | OXYGEN CHEMISTRY DONALD T. SAWYER TEXAS A&M UNIVERSITY FOREWORD BY
PROFESSOR R. J. P. WILLIAMS, FRS NEW YORK OXFORD OXFORD UNIVERSITY PRESS
1991 CONTENTS 1. INTRODUCTION: WHY OXYGEN CHEMSTRY?, 3 CHEMISTRY: THE
SCIENCE OF MOLECULES, 3 CENTRAL ROLE OF OXYGEN IN CHEMISTRY, 4 DIOXYGEN,
7 O2, A UNIQUE NATURAL PRODUCT; REVOLUTIONARY TRANSFORMATION OF BIOLOGY
AND CHEMISTRY, 10 PROCESS CHEMISTRY THAT UTILIZES O2, HOOH, AND O3, 17
REFERENCES, 17 2. REDOX THERMODYNAMICS FOR OXYGEN SPECIES (O3,02, HOO-,
02% HOOH, HOO-, O, O--, AND HO ); EFFECTS OF MEDIA AND PH, 19 REDOX
THERMODYNAMICS OF DIOXYGEN SPECIES AND OZONE, 19 REDOX THERMODYNAMICS OF
ATOMIC OXYGEN, 23 NUCLEOPHILIC ATTACK VIA SINGLE-ELECTRON TRANSFER, 26
ELECTROCHEMISTRY OF DIOXYGEN, 27 SUMMARY, 50 REFERENCES, 50 3. NATURE OF
CHEMICAL BONDS FOR OXYGEN IN ITS COMPOUNDS, 52 ELECTRONEGATIVITIES OF
ELEMENTS AND VALENCE-BOND THEORY, 53 COVALENT BONDING IN
OXYGEN-CONTAINING MOLECULES, 58 COVALENT BOND ENERGIES FOR OXYGEN IN
MOLECULES, 64 THE CASE AGAINST 0 2+ -, 78 REFERENCES, 80 4. REACTIVITY
OF HYDROGEN PEROXIDE, ALKYL HYDROPEROXIDES, AND PERACIDS, 82 ELEMENTARY
REACTION CHEMISTRY, 83 FENTON CHEMISTRY, 84 ACTIVATION OF HOOH BY LEWIS
ACIDS, 85 FE(IUE)CL3-INDUCED EPOXIDATION, MONO-OXYGENATION, AND
DEHYDROGENATION, 96 OXYGEN-ATOM TRANSFER CHEMISTRY; FORMATION AND
REACTIVITY OF ATOMIC OXYGEN FROM HYDROPEROXIDES [HOOH, ROOH, R C(0)OOH],
100 ACTIVATION OF HOOH FOR DIOXYGENASE CHEMISTRY, 102 NUCLEOPHILIC
CHARACTER OF HOOH, 112 BIOLOGICAL SYSTEMS, 114 REFERENCES, 117 XU
CONTENTS 5. REACTIVITY OF OXYGEN RADICALS [HO-, RO-, HOO-, ROO-, AND
RC(0)0], 120 REACTIVITY OF HO-, 121 REACTIVITY OF HOO-, 124 REFERENCES,
130 6. REACTIVITY OF DIOXYGEN AND ITS ACTIVATION FOR SELECTIVE DIOXYGEN-
ATION, MONO-OXYGENATION, DEHYDROGENATION, AND AUTO-OXIDATION OF ORGANIC
SUBSTRATES AND METALS (CORROSION), 132 INTRODUCTION, 132 RADICAL-RADICAL
COUPLING AND AUTO-OXIDATION, 134 METAL-INDUCED ACTIVATION OF 3 0 2 FOR
THE INITIATION OF AUTO- OXIDATION, 135 METAL-INDUCED ACTIVATION OF
DIOXYGEN FOR OXYGENASE AND DEHYDROGENASE CHEMISTRY, 138 METAL-INDUCED
REDUCTIVE ACTIVATION OF 0 2 FOR MONO-OXYGENATION, 143
METAL-SURFACE-INDUCED ACTIVATION OF DIOXYGEN FOR OXYGENASE CHEMISTRY,
145 BIOLOGICAL SYSTEMS, 150 SINGLET DIOXYGEN ( 1 02), 156 REFERENCES,
158 7. REACTIVITY OF SUPEROXIDE ION, 160 BRONSTED BASE, 160
NUCLEOPHILICITY, 161 ONE-ELECTRON REDUCTANT, 174 SEQUENTIAL
DEPROTONATION-DEHYDROGENATION OF DIHYDROGROUPS, 176 RADICAL-RADICAL
COUPLING, 181 BIOLOGICAL SYSTEMS, 183 REFERENCES, 185 8. REACTIVITY OF
OXY-ANIONS [HO-, RO , HOO (ROO ), AND 0 2 -] AS NUCLEOPHILES AND
ONE-ELECTRON REDUCING AGENTS, 188 SOLVENT EFFECTS ON THE REDOX CHEMISTRY
OF HO , 188 REACTION CLASSIFICATIONS (SINGLE-ELECTRON SHIFT MECHANISM),
189 RELATIVE REACTIVITY OF HOOVO2VHO- WITH ELECTROPHILIC SUBSTRATES, 206
OXIDATIVE PHOSPHORYLATION, 209 SUMMARY, 210 REFERENCES, 211 INDEX, 215
|
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| id | DE-604.BV005587700 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:31:57Z |
| institution | BVB |
| isbn | 0195057988 |
| language | Undetermined |
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| physical | XII, 223 S. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Oxford Univ. Press |
| record_format | marc |
| series | The international series of monographs on chemistry |
| series2 | The international series of monographs on chemistry |
| spelling | Sawyer, Donald T. Verfasser aut Oxygen chemistry Donald T. Sawyer New York [u.a.] Oxford Univ. Press 1991 XII, 223 S. txt rdacontent n rdamedia nc rdacarrier The international series of monographs on chemistry 26 Sauerstoff (DE-588)4051803-6 gnd rswk-swf Sauerstoff (DE-588)4051803-6 s DE-604 The international series of monographs on chemistry 26 (DE-604)BV000005251 26 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003499500&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sawyer, Donald T. Oxygen chemistry The international series of monographs on chemistry Sauerstoff (DE-588)4051803-6 gnd |
| subject_GND | (DE-588)4051803-6 |
| title | Oxygen chemistry |
| title_auth | Oxygen chemistry |
| title_exact_search | Oxygen chemistry |
| title_full | Oxygen chemistry Donald T. Sawyer |
| title_fullStr | Oxygen chemistry Donald T. Sawyer |
| title_full_unstemmed | Oxygen chemistry Donald T. Sawyer |
| title_short | Oxygen chemistry |
| title_sort | oxygen chemistry |
| topic | Sauerstoff (DE-588)4051803-6 gnd |
| topic_facet | Sauerstoff |
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