Relaxation and thermodynamics in polymers: glass transition
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
Akad.-Verl.
1992
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 355 S. graph. Darst. |
| ISBN: | 3055013921 |
Internformat
MARC
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| 650 | 4 | |a Relaxation, Phénomènes de | |
| 650 | 7 | |a Relaxation, Phénomènes de |2 ram | |
| 650 | 4 | |a Solutions de polymère | |
| 650 | 4 | |a Température de transition vitreuse | |
| 650 | 4 | |a Thermodynamique | |
| 650 | 7 | |a Thermodynamique |2 ram | |
| 650 | 4 | |a Glass transition temperature | |
| 650 | 4 | |a Polymer solutions | |
| 650 | 4 | |a Relaxation phenomena | |
| 650 | 4 | |a Thermodynamics | |
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Datensatz im Suchindex
| _version_ | 1804119787212636160 |
|---|---|
| adam_text | ERNST-JOACHIM DONTH RELAXATION AND THERMODYNAMICS IN POLYMERS GLASS
TRANSITION AKADEMIE VERLAG TABLE OF CONTENTS INTRODUCTION 1 I
FUNDAMENTALS 3 1. THE 10-NM SCALE: STRUCTURE ELEMENTS OF 2 . . . 20 NM
SIZE 9 1.1 THE 1-NM SCALE: P LEVEL 9 1.2 CLASSIFICATION OF LENGTH SCALES
IN POLYMERS 14 1.3 MACROMOLECULAR COILS 14 1.4 POLYMER CONCENTRATION 16
1.5 ENTANGLEMENT 20 1.6 POLYMER NETWORKS 23 1.7 CHAIN FOLDED
CRYSTALLITES 25 1.8 STRUCTURE AND DYNAMICS - AN OUTLINE 28 2. LINEAR
RESPONSE 31 2.1 MECHANICAL MODELS FOR VISCOELASTICITY 34 2.2 DISCUSSION
OF THE MECHANICAL MODELS 38 2.3 GENERAL LINEAR RESPONSE 38 2.4
RELAXATION AND RETARDATION SPECTRA 43 2.5 CORRELATION FUNCTION AND
SPECTRAL DENSITY 45 2.6 FLUCTUATION DISSIPATION THEOREM (FDT) 46 2.7
DIFFERENT ACTIVITIES 50 2.8 GENERAL SCALING PRINCIPLE (GSP). MODE
LENGTHS 53 3. THERMODYNAMICS 59 3.1 NETWORK THERMODYNAMICS 59 3.2
DISCUSSION 60 3.3 FLORY HUGGINS FORMULA 63 3.4 DISCUSSION 65 VIII
CONTENTS 3.5 THERMODYNAMIC SYSTEMS: SPATIAL AND TEMPORAL ASPECTS 3.6
SUBSYSTEMS 3.7 FDT AGAIN: WHAT IS A THERMODYNAMIC EXPERIMENT? 3.8 SMALL
SYSTEMS 3.9 FUNCTIONAL SUBSYSTEMS. THERMOKINETIC STRUCTURE 4.
THEORETICAL PHYSICS CODE 4.1 ANALYTICAL METHODS 1. ORDER PARAMETER AND
MEAN FIELD 2. EFFECTIVE HAMILTONIAN 3. FIELD THEORY METHODS 4.
RENORMALIZATION 5. DIRECT CORRELATION FUNCTION 6. GENERAL LANGEVIN
EQUATION (GLE) 7. RANDOM PHASE APPROXIMATION (RPA) 8. DIRECTORY 4.2
SCALING AND CROSSOVER 1. GENERAL SCALING PRINCIPLE (GSP) AGAIN 2.
ABSENCE OF TYPICAL LENGTH 3. REDUCTION OF VARIABLES 4. REDUCTION AND
DIMENSIONAL ANALYSIS 5. CRITICAL SCALING (WIDOM SCALING) 6. CROSSOVER 7.
CONFINED SCALING 4.3 COMPUTER SIMULATION 68 70 71 76 78 83 84 84 85 87
88 90 90 93 94 95 96 96 96 98 99 100 100 101 II RELAXATION 103 5. THREE
SIMPLE MODELS 5.1 BARRIER MODEL. ARRHENIUS MECHANISM 5.2 DISCUSSION 5.3
ROUSE MODES 5.4 DISCUSSION 5.5 REPTATION: TUBE MODEL 5.6 DISCUSSION 105
105 108 114 118 122 125 CONTENTS IX 6. GLASS TRANSITION. MULTIPLICITY IN
AMORPHOUS POLYMERS 131 6.1 GLASS TRANSITION IN SIMPLE GLASS FORMERS 132
6.2 COMPARISON: PHASE TRANSITION AND DYNAMIC GLASS TRANSITION 135 6.3
WLF SCALING 138 6.4 IDEAL DYNAMIC GLASS TRANSITION 142 6.5 GLASS
TRANSITION MULTIPLICITY 149 6.6 DISPERSION ZONES IN AMORPHOUS POLYMERS
152 1. SECONDARY RELAXATIONS 152 2. GENERAL REMARKS TO MAIN AND FLOW
TRANSITION AND THEIR SEQUENTIAL PREDECESSORS 154 3. MAIN TRANSITION 155
4. FLOW TRANSITION (OR TERMINAL ZONE) 156 6.7 DEVIATIONS FROM WLF
SCALING 157 6.8 MINIMAL COOPERATIVITY, CAGE EFFECTS, AND EXCESS CLUSTER
SCATTERING 160 1. MINIMAL COOPERATIVITY AND SPLITTING POINT 160 2.
NONACTIVATED PROCESS 164 3. EXCESS CLUSTER SCATTERING 166 6.9 ACTIVITY
ARRANGEMENT ACROSS DISPERSION ZONES 168 6.10 RJ ACTIVITY AND D ACTIVITY
171 1. DISPERSION ZONE AND TRANSPORT (OR FLOW) ZONE 171 2. R AND D
ACTIVITY 175 3. MODEL FOR FLOW TRANSITION 178 7. THERMAL GLASS
TRANSITION 181 7.1 FICTIVE TEMPERATURE. MATERIAL TIME 183 1. THE
CONCEPTIONS 183 2. NARAYANASWAMY SCHEME 184 3. DISCUSSION 185 7.2
FREEZING-IN AT THERMAL GLASS TRANSITION 187 7.3 NONLINEARITY,
OVERSHOOTS, AND KOVACS EXPANSION GAP 191 7.4 PHYSICAL AGING 195 7.5
CONVENTIONAL THERMODYNAMICS OF THERMAL GLASS TRANSITION 198 7.6 LOW
TEMPERATURE BEHAVIOR * 200 X CONTENTS 8. EXAMPLES 205 8.1 RELAXATION
CARDS FOR AMORPHOUS POLYMERS 205 8.2 CONTROL OF T % 207 8.3 RELAXATION
IN POLYMER SOLUTIONS 212 8.4 MIXTURES AND STATISTICAL COPOLYMERS 216 8.5
RELAXATION IN SEMICRYSTALLINE POLYMERS 219 8.6 FREE VOLUME AND
CONFIGURATIONAL ENTROPY 222 8.7 IONIC CONDUCTIVITY 226 8.8 GLASS
STRUCTURE 230 8.9 THERMOSTIMULATION 232 III THERMODYNAMICS 235 9.
THERMODYNAMICS OF MIXTURES 237 9.1 9.2 9.3 9.4 9.5 10. 10.1 10.2 10.3
10.4 10.5 10.6 10.7 MIXING AND EXCESS VARIABLES SMALL-MOLECULE MIXTURES
FLORY HUGGINS AGAIN POLYMER-POLYMER MIXTURES AND POLYMER SOLUTIONS
SWELLING EQUILIBRIUM OF POLYMER NETWORKS COMPATIBILITY OF POLYMERS
TERMINOLOGY ORNSTEIN ZERNICKE (OZ) APPROACH TO CRITICAL PHENOMENA 1.
CLASSICAL TREATMENT FOR SMALL-MOLECULE SYSTEMS 2. ADAPTATION FOR
POLYMERS 3. DISCUSSION SPINODAL PHASE DECOMPOSITION 1. CAHN HILLIARD
APPROACH 2. FURTHER INGREDIENTS 3. GENERAL DISCUSSION HOMOGENEOUS
NUCLEATION DIFFUSION INTERFACE MICROPHASE DECOMPOSITION OF BLOCK
COPOLYMERS 239 242 246 249 254 257 257 259 259 261 263 265 265 269 272
273 279 283 285 CONTENTS XI 10.8 GRADIENT TERM AND NATURAL SUBSYSTEM 288
10.9 GRANULATED PHASE DECOMPOSITION 291 11. SEMICRYSTALLINE POLYMERS 295
11.1 TERMINOLOGY AND SALIENT FACTS 296 11.2 PRIMARY AND SECONDARY
NUCLEATION 298 11.3 NUCLEATION-CONTROLLED CRYSTAL GROWTH 302 11.4
CRYSTALLIZATION AND MELTING 305 11.5 WHY LAMELLAS? 309 APPENDICES 311
AL. FOURIER AND FOURIER LAPLACE TRANSFORMS AS USED IN THIS BOOK 311 A2.
MOLECULAR MASS AND CHEMICAL CONFIGURATION OF THE MONOMERIC UNIT FOR
SEVERAL POLYMERS 313 LISTOFTABLES 315 FREQUENTLY USED SYMBOLS, ACRONYMS,
AND SYNONYMS 316 REFERENCES 321 SUBJECT INDEX 339
|
| any_adam_object | 1 |
| author | Donth, Ernst-Joachim 1936-2020 |
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| author_sort | Donth, Ernst-Joachim 1936-2020 |
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| callnumber-subject | QD - Chemistry |
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| dewey-ones | 547 - Organic chemistry |
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| dewey-search | 547.7/04563 |
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| discipline | Chemie / Pharmazie Physik |
| edition | 1. ed. |
| format | Book |
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| id | DE-604.BV005575123 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:31:44Z |
| institution | BVB |
| isbn | 3055013921 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-003491832 |
| oclc_num | 28298962 |
| open_access_boolean | |
| owner | DE-703 DE-384 DE-355 DE-BY-UBR DE-29T DE-91G DE-BY-TUM DE-634 DE-83 DE-188 |
| owner_facet | DE-703 DE-384 DE-355 DE-BY-UBR DE-29T DE-91G DE-BY-TUM DE-634 DE-83 DE-188 |
| physical | XI, 355 S. graph. Darst. |
| publishDate | 1992 |
| publishDateSearch | 1992 |
| publishDateSort | 1992 |
| publisher | Akad.-Verl. |
| record_format | marc |
| spelling | Donth, Ernst-Joachim 1936-2020 Verfasser (DE-588)107210681 aut Relaxation and thermodynamics in polymers glass transition Ernst-Joachim Donth 1. ed. Berlin Akad.-Verl. 1992 XI, 355 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymères ram Relaxation, Phénomènes de Relaxation, Phénomènes de ram Solutions de polymère Température de transition vitreuse Thermodynamique Thermodynamique ram Glass transition temperature Polymer solutions Relaxation phenomena Thermodynamics Glas (DE-588)4021142-3 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf Übergangszustand (DE-588)4186592-3 gnd rswk-swf Relaxation (DE-588)4049365-9 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Relaxation (DE-588)4049365-9 s Polymere (DE-588)4046699-1 s DE-604 Thermodynamik (DE-588)4059827-5 s Glas (DE-588)4021142-3 s 1\p DE-604 Übergangszustand (DE-588)4186592-3 s 2\p DE-604 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003491832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Donth, Ernst-Joachim 1936-2020 Relaxation and thermodynamics in polymers glass transition Polymères ram Relaxation, Phénomènes de Relaxation, Phénomènes de ram Solutions de polymère Température de transition vitreuse Thermodynamique Thermodynamique ram Glass transition temperature Polymer solutions Relaxation phenomena Thermodynamics Glas (DE-588)4021142-3 gnd Thermodynamik (DE-588)4059827-5 gnd Übergangszustand (DE-588)4186592-3 gnd Relaxation (DE-588)4049365-9 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4021142-3 (DE-588)4059827-5 (DE-588)4186592-3 (DE-588)4049365-9 (DE-588)4046699-1 |
| title | Relaxation and thermodynamics in polymers glass transition |
| title_auth | Relaxation and thermodynamics in polymers glass transition |
| title_exact_search | Relaxation and thermodynamics in polymers glass transition |
| title_full | Relaxation and thermodynamics in polymers glass transition Ernst-Joachim Donth |
| title_fullStr | Relaxation and thermodynamics in polymers glass transition Ernst-Joachim Donth |
| title_full_unstemmed | Relaxation and thermodynamics in polymers glass transition Ernst-Joachim Donth |
| title_short | Relaxation and thermodynamics in polymers |
| title_sort | relaxation and thermodynamics in polymers glass transition |
| title_sub | glass transition |
| topic | Polymères ram Relaxation, Phénomènes de Relaxation, Phénomènes de ram Solutions de polymère Température de transition vitreuse Thermodynamique Thermodynamique ram Glass transition temperature Polymer solutions Relaxation phenomena Thermodynamics Glas (DE-588)4021142-3 gnd Thermodynamik (DE-588)4059827-5 gnd Übergangszustand (DE-588)4186592-3 gnd Relaxation (DE-588)4049365-9 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Polymères Relaxation, Phénomènes de Solutions de polymère Température de transition vitreuse Thermodynamique Glass transition temperature Polymer solutions Relaxation phenomena Thermodynamics Glas Thermodynamik Übergangszustand Relaxation Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003491832&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT donthernstjoachim relaxationandthermodynamicsinpolymersglasstransition |