Handbook of chemical equilibria in analytical chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English Czech |
| Veröffentlicht: |
Chichester
Horwood u.a.
1985
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Ellis Horwood series in analytical chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 414 S. graph. Darst. |
| ISBN: | 0853121079 0470274794 |
Internformat
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| 245 | 1 | 0 | |a Handbook of chemical equilibria in analytical chemistry |c Stanislav Kotrlý and Ladislav Šůcha |
| 250 | |a 1. publ. | ||
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Datensatz im Suchindex
| _version_ | 1804119776908279808 |
|---|---|
| adam_text | HANDBOOK OF
CHEMICAL EQUILIBRIA
IN ANALYTICAL
CHEMISTRY
Stanislav Kotrly
and
Ladislav Sucha
ELLIS HORWOOD LBMITED
Publishers • Chichester
Halsted Press: a division of
JOHN WILEY amp; SONS
New York • Brisbane • Chichester • Toronto
Contents
Foreword 9
Chapter 1 - Chemical Reactions and Equilibria in Analytical Chemistry 11
Chapter 2 — Chemical Equilibria and Equilibrium Constants 16
2 1 Definitions of equilibrium constants 16
2 2 The effect of temperature on the equilibrium constant 18
2 3 The effect of ionic strength on the value of the equilibrium
constant 20
231 Activity coefficients of non-electrolytes 20
232 Activity coefficients of electrolytes 22
233 Interconversion of thermodynamic and concentration
constants 29
2 4 Types of chemical equilibria in solution and expressions for
equilibrium constants 30
241 Protonation (acid-base) equilibria 31
242 Complexation equilibria 34
243 Oxidation-reduction equilibria 35
244 Liquid-liquid partition equilibria 38
245 Partition equilibria on ion-exchangers 39
246 Precipitation equilibria 40
Chapter 3 - Chemical Reactions Affected by Side-Equilibria 43
3 1 Formulation of conditional equilibrium constants and side-
reaction coefficients 44
311 Complex-formation equilibria influenced by side-reactions 44
312 Conditional precipitation equilibria 51
313 Conditional oxidation-reduction potentials 53
314 Conditional equilibria in liquid-liquid partition systems 57
6 Contents
315 Conditional equilibria on ion-exchangers 59
3 2 Calculation of complicated equilibria with the aid of a com-
puter 59
321 Program COMICS 61
322 Program HALTAFALL 62
Chapter 4 - Diagrams for Consecutive Equilibrium Systems 67
4 1 Distribution diagrams 67
4 2 Logarithmic diagrams 69
421 Logarithmic concentration diagrams for protonation
equilibria s 70
422 Logarithmic solubility diagram for a complexation reaction
with a common ion 74
423 Logarithmic activity-ratio diagrams 77
4 3 Predominance-area diagrams 79
431 Construction of a predominance-area diagram in the
absence of solid phase 81
432 Construction of a predominance-area diagram in the
presence of a solid compound 84
433 Significance of predominance-area diagrams 86
Chapter 5 — Constants of Protonation Equilibria 87
Chapter 6 — Stability Constants of Complexes with Inorganic
Ligands 109
Chapter 7 - Stability Constants of Complexes with Organic Ligands 142
Chapter 8 - Solubility Products of Sparingly Soluble Sal ts 209
Chapter 9 - Oxidation-Reduction Potentials 221
Chapter 10 - Side-Reaction Coefficients for Protonation Equilibria 251
Chapter 11 — Side-Reaction Coefficients for Complexation Equilibria
of Metal Ions 278
Chapter 12 — Diagrams of Precipitation Equilibria 339
12 1 Graphs of conditional solubility products 339
12 2 Logarithmic concentration diagrams for precipitation equi-
libria 343
Contents 7
12 2 1 pH-Dependence solubility diagram for boric acid 343
12 2 2 Logarithmic solubility diagram for iron(lll) hydroxide,
showing pH-dependence 346
- 12 2 3 Logarithmic solubility diagram of indium(IIl) hydro-
xide, showing dependence on pH and concentration
of chloride 348
12 2 4 Predominance-area diagram for the equilibrium system
of indium(III) hydroxo- and chloro-complexes 351
Chapter 13 - Diagrams for Oxidation-Reduction Equilibria 356
13 1 Logarithmic activity-ratio diagrams of some redox systems 356
13 1 1 Logarithmic activity-ratio diagram of redox forms of
iron in aqueous solution 357
13 1 2 Simplified logarithmic activity-ratio diagram for redox
forms of iron 357
13 1 3 Logarithmic activity-ratio diagram for the redox system
of iron in presence of hydrolysis products 359
13 2 Predominance-area diagrams 370
13 2 1 Diagram of redox, complexation and precipitation
equilibria of indium in aqueous solution, showing
the dependence on pH 370
13 2 2 Diagram for redox equilibria in a system of oxygen,
hydrogen peroxide and water, showing pH-dependence 376
13 2 3 Dependence of redox equilibria of cadmium in aqueous
solution on the concentration of chloride ions 378
Chapter 14 - Examples of Applications of Tables and Graphs 382
14 1 Calculation of the pH in an isopolyacid equilibrium system in
aqueous solution 382
14 2 Treatment of side-reactions in the calculation of masking
efficiency 384
14 3 Consideration of the course of a redox reaction by use of
a predominance-area diagram 386
14 4 Hydrolysis of metal ions in aqueous solution 390
14 4 1 Use of the log aM(0H)-pH relationship for the deter-
mination of the extent of hydrolysis of a metal ion in
aqueous solution 390
14 4 2 Precipitation of sparingly soluble hydroxides 398
14 4 3 Use of plots of pM =/(pH) 399
Index 401
|
| any_adam_object | 1 |
| author | Kotrly, Stanislav Sucha, Ladislav |
| author_facet | Kotrly, Stanislav Sucha, Ladislav |
| author_role | aut aut |
| author_sort | Kotrly, Stanislav |
| author_variant | s k sk l s ls |
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| dewey-full | 541.3/92 543/.00212 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry 543 - Analytical chemistry |
| dewey-raw | 541.3/92 543/.00212 |
| dewey-search | 541.3/92 543/.00212 |
| dewey-sort | 3541.3 292 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 1. publ. |
| format | Book |
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| id | DE-604.BV005557642 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:31:34Z |
| institution | BVB |
| isbn | 0853121079 0470274794 |
| language | English Czech |
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| physical | 414 S. graph. Darst. |
| publishDate | 1985 |
| publishDateSearch | 1985 |
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| publisher | Horwood u.a. |
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| series2 | Ellis Horwood series in analytical chemistry |
| spelling | Kotrly, Stanislav Verfasser aut Handbook of chemical equilibria in analytical chemistry Stanislav Kotrlý and Ladislav Šůcha 1. publ. Chichester Horwood u.a. 1985 414 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Ellis Horwood series in analytical chemistry Chimie analytique Chimie analytique ram Ionenwisselaars gtt Organometaalcomplexen gtt Redoxreacties gtt Zuur-base-evenwicht gtt Équilibre chimique Équilibre chimique ram Chemical equilibrium Chemistry, Analytic Konstante (DE-588)4202467-5 gnd rswk-swf Analytische Chemie (DE-588)4129906-1 gnd rswk-swf Chemisches Gleichgewicht (DE-588)4147642-6 gnd rswk-swf Tabelle (DE-588)4184303-4 gnd rswk-swf Chemisches Gleichgewicht (DE-588)4147642-6 s Konstante (DE-588)4202467-5 s DE-604 Analytische Chemie (DE-588)4129906-1 s Tabelle (DE-588)4184303-4 s Sucha, Ladislav Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003484627&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kotrly, Stanislav Sucha, Ladislav Handbook of chemical equilibria in analytical chemistry Chimie analytique Chimie analytique ram Ionenwisselaars gtt Organometaalcomplexen gtt Redoxreacties gtt Zuur-base-evenwicht gtt Équilibre chimique Équilibre chimique ram Chemical equilibrium Chemistry, Analytic Konstante (DE-588)4202467-5 gnd Analytische Chemie (DE-588)4129906-1 gnd Chemisches Gleichgewicht (DE-588)4147642-6 gnd Tabelle (DE-588)4184303-4 gnd |
| subject_GND | (DE-588)4202467-5 (DE-588)4129906-1 (DE-588)4147642-6 (DE-588)4184303-4 |
| title | Handbook of chemical equilibria in analytical chemistry |
| title_auth | Handbook of chemical equilibria in analytical chemistry |
| title_exact_search | Handbook of chemical equilibria in analytical chemistry |
| title_full | Handbook of chemical equilibria in analytical chemistry Stanislav Kotrlý and Ladislav Šůcha |
| title_fullStr | Handbook of chemical equilibria in analytical chemistry Stanislav Kotrlý and Ladislav Šůcha |
| title_full_unstemmed | Handbook of chemical equilibria in analytical chemistry Stanislav Kotrlý and Ladislav Šůcha |
| title_short | Handbook of chemical equilibria in analytical chemistry |
| title_sort | handbook of chemical equilibria in analytical chemistry |
| topic | Chimie analytique Chimie analytique ram Ionenwisselaars gtt Organometaalcomplexen gtt Redoxreacties gtt Zuur-base-evenwicht gtt Équilibre chimique Équilibre chimique ram Chemical equilibrium Chemistry, Analytic Konstante (DE-588)4202467-5 gnd Analytische Chemie (DE-588)4129906-1 gnd Chemisches Gleichgewicht (DE-588)4147642-6 gnd Tabelle (DE-588)4184303-4 gnd |
| topic_facet | Chimie analytique Ionenwisselaars Organometaalcomplexen Redoxreacties Zuur-base-evenwicht Équilibre chimique Chemical equilibrium Chemistry, Analytic Konstante Analytische Chemie Chemisches Gleichgewicht Tabelle |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003484627&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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