Atomic spectra and radiative transitions:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin u.a.
Springer
1992
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Springer series on atoms + plasmas
12 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Transl. from Russ. |
| Beschreibung: | XIV, 356 S. . graph. Darst. |
| ISBN: | 3540545182 0387545182 |
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| 245 | 1 | 0 | |a Atomic spectra and radiative transitions |c Igor I. Sobelman |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Berlin u.a. |b Springer |c 1992 | |
| 300 | |a XIV, 356 S. . graph. Darst. | ||
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| 490 | 1 | |a Springer series on atoms + plasmas |v 12 | |
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| 650 | 4 | |a Radiative transitions | |
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Datensatz im Suchindex
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| adam_text | IGOR I. SOBELMAN ATOMIC SPECTRA AND RADIATIVE TRANSITIONS SECOND EDITION
WITH 26 FIGURES SPRINGER-VERLAG BERLIN HEIDELBERG NEW YORK LONDON PARIS
TOKYO HONG KONG BARCELONA BUDAPEST CONTENTS PART I ELEMENTARY
INFORMATION ON ATOMIC SPECTRA CHAPTER 1 THE HYDROGEN SPECTRUM 1.1
SCHRODINGER S EQUATION FOR THE HYDROGEN ATOM 3 1.1.1 ENERGY LEVELS 3
1.1.2 WAVE FUNCTIONS 5 1.2 SERIES REGULARITIES 7 1.2.1 RADIATIVE
TRANSITION SELECTION RULES Y 7 1.2.2 SPECTRAL SERIES OF THE HYDROGEN
ATOM .,.- . 8 1.2.3 HYDROGENLIKE IONS S . 9 1.3 FINE STRUCTURE 10 1.3.1
VELOCITY DEPENDENCE OF ELECTRON MASS 10 1.3.2 SPIN-ORBIT INTERACTION 11
1.3.3 FINE STRUCTURE. SELECTION RULES 12 1.3.4 LAMB SHIFT 15 CHAPTER 2
SYSTEMATICS OF THE SPECTRA OF MULTIELECTRON ATOMS 2.1 CENTRAL FIELD 16
2.1.1 CENTRAL FIELD APPROXIMATION 16 2.1.2 PARITY OF STATES 18 2.1.3
SYSTEMATICS OF ELECTRON STATES IN A CENTRAL FIELD 19 2.2 ELECTROSTATIC
AND SPIN-ORBIT SPLITTING IN THE LS COUPLING APPROXIMATION 20 2.2.1
SPECTRAL TERMS. LS QUANTUM NUMBERS 20 2.2.2 FINE STRUCTURE OF TERMS 21
2.2.3 FINDING THE TERMS OF MULTIELECTRON CONFIGURATIONS 23 2.2.4
RADIATIVE TRANSITIONS 26 2.3 JJ COUPLING APPROXIMATION 27 2.3.1 VARIOUS
COUPLING SCHEMES 27 2.3.2 SYSTEMATICS OF ELECTRON STATES WITH JJ
COUPLING 29 X CONTENTS CHAPTER 3 SPECTRA OF MULTIELECTRON ATOMS 3.1
PERIODIC SYSTEM OF ELEMENTS 32 3.2 SPECTRA OF THE ALKALI ELEMENTS 34
3.2.1 TERM SCHEME 34 3.2.2 SERIES REGULARITIES 37 3.2.3 FINE STRUCTURE
37 3.2.4 COPPER, SILVER, AND GOLD SPECTRA 38 3.3 SPECTRA OF THE ALKALINE
EARTH ELEMENTS 39 3.3.1 HE SPECTRUM : 39 3.3.2 SPECTRA OF THE ALKALINE
EARTH ELEMENTS 40 3.3.3 ZINC, CADMIUM, AND MERCURY SPECTRA 42 3.4
SPECTRA OF ELEMENTS WITH P VALENCE ELECTRONS 42 3.4.1 ONE P ELECTRON
OUTSIDE FILLED SHELLS 42 3.4.2 CONFIGURATION P 2 43 3.4.3 CONFIGURATION
/J 3 44 3.4.4 CONFIGURATION P 4 45 3.4.5 CONFIGURATION P 5 46 3.4.6
CONFIGURATION P 6 , 46 3.5 SPECTRA OF ELEMENTS WITH UNFILLED D AND /
SHELH..^ 48 3.5.1 ELEMENTS WITH UNFILLED D SHELLS 48 3.5.2 ELEMENTS
WITH UNFILLED / SHELLS 49 PART II THEORY OF ATOMIC SPECTRA CHAPTER 4
ANGULAR MOMENTA 4.1 ANGULAR MOMENTUM OPERATOR. ADDITION OF ANGULAR
MOMENTA 53 4.1.1 ANGULAR MOMENTUM OPERATOR 53 4.1.2 ORBITAL ANGULAR
MOMENTUM 54 4.1.3 ELECTRON SPIN 54 4.1.4 ADDITION OF TWO ANGULAR MOMENTA
55 4.1.5 ADDITION OF THREE OR MORE ANGULAR MOMENTA 57 4.2 ANGULAR
MOMENTUM VECTOR ADDITION COEFFICIENTS 60 4.2.1 CLEBSCH-GORDAN AND
ASSOCIATED COEFFICIENTS 60 4.2.2 SUMMARY OF FORMULAS FOR 3J SYMBOLS 62
4.2.3 RACAH W COEFFICIENTS AND 6Y SYMBOLS 66 4.2.4 SUMMARY OF FORMULAS
FOR 6J SYMBOLS 70 4.2.5 9Y SYMBOLS 72 4.3 IRREDUCIBLE TENSOR OPERATORS
74 CONTENTS XI 4.3.1 SPHERICAL TENSORS 74 4.3.2 MATRIX ELEMENTS 76 4.3.3
SOME EXAMPLES OF CALCULATION OF REDUCED MATRIX ELEMENTS .... 78 4.3.4
TENSOR PRODUCT OF OPERATORS 80 4.3.5 MATRIX ELEMENTS WITH COUPLED
ANGULAR MOMENTA 84 4.3.6 DIRECT PRODUCT OF OPERATORS 86 CHAPTER 5
SYSTEMATICS OF THE STATES OF MULTIELECTRON ATOMS 5.1 WAVE FUNCTIONS 89
5.1.1 CENTRAL FIELD APPROXIMATION 89 5.1.2 TWO-ELECTRON WAVE FUNCTIONS
IN LSM L M S REPRESENTATION 90 5.1.3 TWO-ELECTRON WAVE FUNCTIONS IN
MM SM$ REPRESENTATION 93 5.1.4 MULTIELECTRON WAVE FUNCTIONS IN A
PARENTAGE SCHEME APPROXIMATION 96 5.1.5 FRACTIONAL PARENTAGE
COEFFICIENTS 96 5.1.6 CLASSIFICATION OF IDENTICAL TERMS OF /
CONFIGURATION ACCORDING TO SENIORITY (SENIORITY NUMBER) 98 5.2 MATRIX
ELEMENTS OF SYMMETRIC OPERATORS .- 106 5.2.1 STATEMENT OF THE PROBLEM
;/. . 106 5.2.2 F MATRIX ELEMENTS. PARENTAGE SCHEME APPROXIMATION 108
5.2.3 F MATRIX ELEMENTS. EQUIVALENT ELECTRONS 109 5.2.4 Q MATRIX
ELEMENTS. PARENTAGE SCHEME APPROXIMATION ILL 5.2.5 Q MATRIX ELEMENTS.
EQUIVALENT ELECTRONS 113 5.2.6 SUMMARY OF RESULTS 115 5.3 ELECTROSTATIC
INTERACTION IN LS COUPLING. TWO-ELECTRON CONFIGURATION . 115 5.3.1
COULOMB AND EXCHANGE INTEGRALS 115 5.3.2 CONFIGURATION MIXING 118 5.4
ELECTROSTATIC INTERACTION IN LS COUPLING. MULTIELECTRON CONFIGURATION .
120 5.4.1 CONFIGURATIONS / AND / / 120 5.4.2 MORE THAN HALF FILLED
SHELLS 123 5.4.3 FILLED (CLOSED) SHELLS 123 5.4.4 APPLICABILITY OF THE
SINGLE-CONFIGURATION APPROXIMATION 124 5.5 MULTIPLET SPLITTING IN LS
COUPLING 126 5.5.1 PRELIMINARY REMARKS 126 5.5.2 LANDE INTERVAL RULE 126
5.5.3 ONE ELECTRON OUTSIDE CLOSED SHELLS 128 5.5.4 CONFIGURATION / 130
5.5.5 PARENTAGE SCHEME APPROXIMATION 132 5.5.6 FINE-STRUCTURE SPLITTING
OF LEVELS OF HE 133 5.5.7 SPIN-SPIN AND SPIN-OTHER ORBIT INTERACTIONS
139 5.6 JJ COUPLING 141 5.6.1 WAVE FUNCTIONS 141 5.6.2 SPIN-ORBIT AND
ELECTROSTATIC INTERACTIONS 143 XII CONTENTS 5.7 INTERMEDIATE COUPLING
AND OTHER TYPES OF COUPLING 144 5.7.1 TRANSFORMATIONS BETWEEN LS AND JJ
COUPLING SCHEMES 144 5.7.2 INTERMEDIATE COUPLING 147 5.7.3 JL COUPLING
152 5.7.4 EXPERIMENTAL DATE 153 5.7.5 OTHER TYPES OF COUPLING 154
CHAPTER 6 HYPERFINE STRUCTURE OF SPECTRAL LINES 6.1 NUCLEAR MAGNETIC
DIPOLE AND ELECTRIC QUADRUPOLE MOMENTS 156 6.1.1 MAGNETIC MOMENTS 156
6.1.2 QUADRUPOLE MOMENTS 157 6.2 HYPERFINE SPLITTING 159 6.2.1 GENERAL
CHARACTER OF THE SPLITTING 159 6.2.2 CALCULATION OF THE HYPERFINE
SPLITTING CONSTANT A 162 6.2.3 CALCULATION OF THE HYPERFINE SPLITTING
CONSTANT B 168 6.2.4 RADIATIVE TRANSITIONS BETWEEN HYPERFINE-STRUCTURE
COMPONENTS. 170 6.2.5 ISOTOPE SHIFT OF THE ATOMIC LEVELS 170 CHAPTER 7
THE ATOM IN AN EXTERNAL ELECTRIC FIELD 7.1 QUADRATIC STARK EFFECT .-R
173 7.2 HYDROGENLIKE LEVELS. LINEAR STARK EFFECT 177 7.3 INHOMOGENEOUS
FIELD. QUADRUPOLE SPLITTING 181 7.4 TIME-DEPENDENT FIELD 183 7.4.1
AMPLITUDE MODULATION 183 7.4.2 THE HYDROGEN ATOM IN A ROTATING ELECTRIC
FIELD 187 CHAPTER 8 THE ATOM IN AN EXTERNAL MAGNETIC FIELD 8.1 ZEEMAN
EFFECT 189 8.2 PASCHEN-BACK EFFECT 194 8.2.1 STRONG FIELD 194 8.2.2
SPLITTING OF HYPERFINE STRUCTURE COMPONENTS IN A MAGNETIC FIELD 198
CHAPTER 9 RADIATIVE TRANSITIONS 9.1 ELECTROMAGNETIC RADIATION 200 9.1.1
QUANTIZATION OF THE RADIATION FIELD 200 9.1.2 RADIATIVE TRANSITION
PROBABILITIES 201 9.1.3 CORRESPONDENCE PRINCIPLE FOR SPONTANEOUS
EMISSION 202 9.1.4 DIPOLE RADIATION 203 CONTENTS XIII 9.1.5 STIMULATED
EMISSION AND ABSORPTION 203 9.1.6 EFFECTIVE CROSS SECTIONS OF ABSORPTION
AND STIMULATED EMISSION 205 9.2 ELECTRIC DIPOLE RADIATION 205 9.2.1
SELECTION RULES, POLARIZATION AND ANGULAR DISTRIBUTION 205 9.2.2
OSCILLATOR STRENGTHS AND LINE STRENGTHS 208 9.2.3 LS COUPLING
APPROXIMATION. RELATIVE INTENSITIES OF MULTIPLET COMPONENTS 211 9.2.4
ONE ELECTRON OUTSIDE CLOSED SHELL 213 9.2.5 MULTIELECTRON
CONFIGURATIONS. DIFFERENT COUPLING SCHEMES 214 9.2.6 RELATIVE
INTENSITIES OF ZEEMAN AND STARK COMPONENTS OF LINES.. 215 9.3 MULTIPOLE
RADIATION 216 9.3.1 FIELDS OF ELECTRIC AND MAGNETIC MULTIPOLE MOMENTS
216 9.3.2 INTENSITY OF MULTIPOLE RADIATION 220 9.3.3 SELECTION RULES 222
9.3.4 ELECTRIC MULTIPOLE RADIATION 223 9.3.5 MAGNETIC DIPOLE RADIATION
225 9.3.6 TRANSITIONS BETWEEN HYPERFINE STRUCTURE COMPONENTS. RADIO
EMISSION FROM HYDROGEN 227 9.4 CALCULATION OF RADIATIVE TRANSITION
PROBABILITIES 229 9.4.1 APPROXIMATE METHODS .--: . 229 9.4.2 THREE WAYS
OF WRITING FORMULAS FOR TRANSITION*PROBABILITIES... 230 9.4.3 THEOREMS
FOR SUMS OF OSCILLATOR STRENGTHS .. *?. 232 9.4.4 SEMIEMPIRICAL METHODS
OF CALCULATING OSCILLATOR STRENGTHS 235 9.4.5 ELECTRIC DIPOLE TRANSITION
PROBABILITIES IN THE COULOMB APPROXIMATION 236 9.4.6 INTERCOMBINATION
TRANSITIONS 237 9.5 CONTINUOUS SPECTRUM 239 9.5.1 CLASSIFICATION OF
PROCESSES 239 9.5.2 PHOTORECOMBINATION AND PHOTOIONIZATION: GENERAL
EXPRESSIONS FOR EFFECTIVE CROSS SECTIONS 239 9.5.3 BREMSSTRAHLUNG:
GENERAL EXPRESSIONS FOR EFFECTIVE CROSS SECTIONS 245 9.5.4 RADIATION AND
ABSORPTION COEFFICIENTS 248 9.5.5 PHOTORECOMBINATION AND
PHOTOIONIZATION: HYDROGENLIKE ATOMS. 251 9.5.6 PHOTORECOMBINATION AND
PHOTOIONIZATION: NONHYDROGENLIKE ATOMS 255 9.5.7 BREMSSTRAHLUNG IN A
COULOMB FIELD 257 9.6 FORMULAS FOR Q FACTORS 274 9.6.1 SYMMETRY AND SUM
RULES 274 9.6.2 LS COUPLING. ALLOWED TRANSITIONS 275 9.6.3 JL COUPLING
279 9.7 TABLES OF OSCILLATOR STRENGTHS AND RADIATIVE TRANSITION
PROBABILITIES.. 281 9.7.1 TRANSITION PROBABILITIES FOR THE HYDROGEN ATOM
281 9.7.2 RADIATIVE TRANSITION PROBABILITIES IN THE BATES-DAMGAARD
APPROXIMATION 283 XIV CONTENTS 9.7.3 OSCILLATOR STRENGTHS AND
PROBABILITIES OF SOME SELECTED TRANSITIONS 284 9.7.4 EFFECTIVE CROSS
SECTIONS AND RATES OF PHOTORECOMBINATION ... 284 CHAPTER 10 RELATIVISTIC
CORRECTIONS IN THE SPECTROSCOPY OF MULTICHARGED IONS 10.1 DIRAC
EQUATION. PAULI EQUATION 303 10.1.1 DIRAC EQUATION 303 10.1.2 ELECTRON
SPIN 305 10.1.3 NON-RELATIVISTIC APPROXIMATION. PAULI EQUATION 308 10.2
CENTRAL FIELD 310 10.2.1 NON-RELATIVISTIC APPROXIMATION 310 10.2.2
SECOND APPROXIMATION WITH RESPECT TO V/C. FINE SPLITTING.... 313 10.2.3
DIRAC EQUATION FOR A CENTRAL FIELD 316 10.2.4 COULOMB FIELD. ENERGY
LEVELS, FINE SPLITTING 319 10.2.5 COULOMB FIELD. RADIAL FUNCTIONS 322
10.3 RELATIVISTIC CORRECTIONS 325 10.3.1 CALCULATION OF SOME RADIAL
INTEGRALS 325 10.3.2 HYPERFINE SPLITTING CONSTANT A 326 10.3.3 HYPERFINE
SPLITTING CONSTANT B .YF. 330 10.3.4 NUCLEUS FINITE-SIZE CORRECTION .
331 10.3.5 RADIATIVE CORRECTIONS. LAMB SHIFT 333 CHAPTER 11 SPECTRA OF
MULTICHARGED IONS 11.1 ENERGY LEVELS 339 11.2 FORBIDDEN TRANSITIONS 341
11.2.1 H-LIKE IONS 342 11.2.2 HE-LIKE IONS 342 11.3 SATELLITE STRUCTURE
346 REFERENCES 351 LIST OF SYMBOLS 353 SUBJECT INDEX 355
|
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| id | DE-604.BV004711024 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:16:31Z |
| institution | BVB |
| isbn | 3540545182 0387545182 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002895771 |
| oclc_num | 24701900 |
| open_access_boolean | |
| owner | DE-384 DE-20 DE-19 DE-BY-UBM DE-83 DE-11 DE-188 |
| owner_facet | DE-384 DE-20 DE-19 DE-BY-UBM DE-83 DE-11 DE-188 |
| physical | XIV, 356 S. . graph. Darst. |
| publishDate | 1992 |
| publishDateSearch | 1992 |
| publishDateSort | 1992 |
| publisher | Springer |
| record_format | marc |
| series | Springer series on atoms + plasmas |
| series2 | Springer series on atoms + plasmas |
| spelling | Sobel'man, Igor' I. 1927- Verfasser (DE-588)104311924 aut Vvedenie v teoriju atomnych spektrov Atomic spectra and radiative transitions Igor I. Sobelman 2. ed. Berlin u.a. Springer 1992 XIV, 356 S. . graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series on atoms + plasmas 12 Transl. from Russ. Atomic spectroscopy Radiative transitions Atomspektrum (DE-588)4143334-8 gnd rswk-swf Atomspektroskopie (DE-588)4143333-6 gnd rswk-swf Strahlungsübergang (DE-588)4183547-5 gnd rswk-swf Atomspektrum (DE-588)4143334-8 s Strahlungsübergang (DE-588)4183547-5 s DE-604 Atomspektroskopie (DE-588)4143333-6 s Springer series on atoms + plasmas 12 (DE-604)BV000903784 12 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002895771&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sobel'man, Igor' I. 1927- Atomic spectra and radiative transitions Springer series on atoms + plasmas Atomic spectroscopy Radiative transitions Atomspektrum (DE-588)4143334-8 gnd Atomspektroskopie (DE-588)4143333-6 gnd Strahlungsübergang (DE-588)4183547-5 gnd |
| subject_GND | (DE-588)4143334-8 (DE-588)4143333-6 (DE-588)4183547-5 |
| title | Atomic spectra and radiative transitions |
| title_alt | Vvedenie v teoriju atomnych spektrov |
| title_auth | Atomic spectra and radiative transitions |
| title_exact_search | Atomic spectra and radiative transitions |
| title_full | Atomic spectra and radiative transitions Igor I. Sobelman |
| title_fullStr | Atomic spectra and radiative transitions Igor I. Sobelman |
| title_full_unstemmed | Atomic spectra and radiative transitions Igor I. Sobelman |
| title_short | Atomic spectra and radiative transitions |
| title_sort | atomic spectra and radiative transitions |
| topic | Atomic spectroscopy Radiative transitions Atomspektrum (DE-588)4143334-8 gnd Atomspektroskopie (DE-588)4143333-6 gnd Strahlungsübergang (DE-588)4183547-5 gnd |
| topic_facet | Atomic spectroscopy Radiative transitions Atomspektrum Atomspektroskopie Strahlungsübergang |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002895771&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000903784 |
| work_keys_str_mv | AT sobelmanigori vvedenievteorijuatomnychspektrov AT sobelmanigori atomicspectraandradiativetransitions |