Properties of polymers: their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1990
|
| Ausgabe: | 3., completely rev. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XXII, 875 S. graph. Darst. |
| ISBN: | 0444881603 |
Internformat
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| 250 | |a 3., completely rev. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1990 | |
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Datensatz im Suchindex
| _version_ | 1804118800046489600 |
|---|---|
| adam_text | Titel: Properties of polymers
Autor: Krevelen, Dirk W. van
Jahr: 1990
CONTENTS
From the preface to the first edition (1972) vii
From the preface to the second edition (1976) ix
Preface to the third edition xi
Acknowledgements xv
Part I. General introduction: A bird s-eye view of polymer science and engineering
Chapter 1. Polymer properties 3
Approach and Objective 3
Bibliography 5
Chapter 2. Typology of polymers 7
A. Polymer structure 8
B. Molecular mass and molecular mass distribution 16
C. Phase transitions in polymers 22
D. Morphology of solid polymers 29
E. Polymeric liquid crystals 34
F. Multiple component polymer systems 36
G. Relaxation phenomena 38
Appendix I. Milestones in the history of polymer science 40
Appendix II. Chronological development of commercial polymers 43
Bibliography 45
Chapter 3. Typology of properties 49
A. The concept Polymer properties 49
B. Physical quantities and their units 52
C. Categories of physical quantities 53
D. Dimensionless groups of quantities 54
E. Types of molar properties 57
F. Additive molar functions 60
Bibliography 66
Part II. Thermophysical properties of polymers
Chapter 4. Volumetric properties 71
XVII
XVIII
A. Fundamental quantities of mass and volume 72
B. Standard molar volumes at room temperature (298 K) 76
C. Thermal expansion 88
D. Isothermal compression - Equations of state 101
Bibliography 106
Chapter 5. Calorimetric properties 109
A. Heat capacity 109
B. Latent heat of crystallization and fusion (melting) 118
C. Enthalpy and entropy 123
Bibliography 127
Chapter 6. Transition temperatures 129
A. The glass transition temperature 130
B. The crystalline melting point 151
C. Relationship between glass transition temperature and melting point of
polymers 166
D. Relationship between Tg, Tm and other transition temperatures 169
E. Transitions in thermotropic liquid crystal polymers 172
Appendix I. Rules of thumb for substituting a H-atom by a group X 180
Appendix II. Similarities and differences between Yg and Ym 182
Bibliography 186
Chapter 7. Cohesive properties and solubility 189
A. Cohesive energy 190
B. Solubility 200
C. Internal pressure 220
Bibliography 224
Chapter 8. Interfacial energy properties 227
A. Surface energy of liquids and melts 228
B. Surface energy of solid polymers 231
C. General expression for the interfacial tension 236
D. Polymer adhesion 239
Bibliography 240
Chapter 9. Limiting viscosity number (intrinsic viscosity) and related properties of
very dilute solutions 243
A. Molecular dimensions of the conformational state 244
B. The limiting viscosity number (intrinsic viscosity) 247
C. Interrelationships of limiting diffusive transport quantities 278
Bibliography 282
XIX
Part III. Properties of polymers in fields of force
Chapter 10. Optical properties 287
A. Optical properties in general 287
B. Light refraction 290
C. Reflection 297
D. Birefringence (and optical rotation) 298
E. Light scattering 307
F. Absorption 313
G. Optical appearance properties 313
Bibliography 318
Chapter 11. Electrical properties 321
A. Dielectric polarization 321
B. Static electrification and conductivity 329
C. Ultimate electrical properties 339
Bibliography 340
Chapter 12. Magnetic properties 343
A. Magnetic susceptibility (Magnetic inductive capacity) 343
B. Magnetic resonance 347
Bibliography 363
Chapter 13. Mechanical properties of solid polymers 367
A. Elastic parameters 367
B. Rubber elasticity 384
C. Viscoelasticity 388
D. Ultimate mechanical properties 412
E. Mechanical properties of uniaxially oriented polymers (fibers) 423
Bibliography 435
Chapter 14. Acoustic properties 439
A. Sound propagation and absorption 440
B. Additive molar functions for sound propagation 442
C. Sonic absorption 449
Bibliography 453
Part IV. Transport properties of polymers
Chapter 15. Rheological properties of polymer melts 457
A. Modes of deformation and definition of viscosity 458
B. Newtonian shear viscosity of polymer melts 462
C. Non-Newtonian shear viscosity of polymer melts 474
D. Extensional viscosity of polymer melts 486
XX
E. Elastic effects in polymer melts 487
F. Rheological properties of liquid crystal polymer melts 491
Appendix I. Flow of polymer melts through narrow tubes and capillaries 493
Appendix II. Analysis of flow in processing operations 494
Bibliography 497
Chapter 16. Rheological properties of polymer solutions 499
A. Dilute polymer solutions 500
B. Concentrated polymer solutions 505
C. Extensional deformation of polymer solutions 520
D. Solutions of lyotropic liquid crystal polymers 521
Bibliography 522
Chapter 17. Transport of thermal energy 525
Thermal conductivity 525
Bibliography 532
Appendix 533
Chapter 18. Properties determining mass transfer in polymeric systems 535
A. Permeation of simple gases 535
B. Permeations of a more complex nature 561
C. Dissolution of polymers as a case of permeation 577
D. Bibliography 582
Chapter 19. Crystallization and recrystallization 585
A. Crystallinity, nucleation and growth 585
B. Spherulitic crystallization of polymers from the melt 588
C. Induced crystallization of flexible polymeric molecules by pressure and stress 603
D. Extended chain crystallization of flexible polymer chains 609
E. Extended chain crystallization of rigid macromolecules 618
Bibliography 620
Part V. Properties determining the chemical stability and breakdown of polymers
Chapter 20. Thermochemical properties 627
A. Thermodynamics and kinetics 627
B. Calculation of the free enthalpy of reaction from group contributions 629
C. Thermodynamics of free radicals 635
Bibliography 638
Chapter 21. Thermal decomposition 641
A. Thermal degradation 641
B. Char formation 649
C. Kinetics of thermal degradation 652
XXI
Bibliography 653
Chapter 22. Chemical degradation 655
Bibliography 660
Part VI. Polymer properties as an integral concept
Chapter 23. Intrinsic properties in retrospect 663
A. Reference values of intrinsic properties expressed as a function of additive
quantities 664
B. Effect of structural groups on properties 666
C. Dependence of intrinsic properties on process variables 668
D. Outlook 671
Chapter 24. Processing properties 673
A. Classification of processes 673
B. Some important processing properties 674
C. Implementation of processing research 691
Bibliography 692
Chapter 25. Product properties (I): Mechanical behaviour and failure 695
A. Failure mechanisms in polymers 696
B. Deformation properties 698
C. Toughness and endurance 705
D. Hardness 713
E. Friction and wear 716
F. The mechanical shortcomings of homogeneous materials and the need for
composites 719
Bibliography 723
Chapter 26. Product properties (II): Environmental behaviour and failure 725
A. Thermal end use properties 725
B. Flammability of polymers 727
C. Environmental decay of polymers in liquids 736
Bibliography 743
Chapter 27. An illustrative example of end use properties: Article properties of
textile products 745
A. Aesthetic properties 745
B. Use or performance properties 747
C. Maintenance or care properties 753
D. Integral evaluation of fibre polymers, fibres and yarns by the criteria men¬
tioned (profile method) 754
Bibliography 756
XXII
Part VII. Comprehensive tables
I. International system of units (SI) 761
II. Survey of conversion factors 763
III. Values of some fundamental constants 773
IV. Physical constants of the most important solvents 774
V. Physical properties of the most important polymers 790
VI. Published data on high performance polymers 804
VII. Code symbols for the most important polymers 808
VIII. Trade names and generic names 811
IX. Survey of group contributions in additive molar quantities 816
Indexation
Symbol index 827
Author index 847
Subject index 861
|
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| discipline | Physik Chemie Werkstoffwissenschaften |
| edition | 3., completely rev. ed. |
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| language | English |
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| spelling | Krevelen, Dirk W. van 1914-2001 Verfasser (DE-588)136511147 aut Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions by D. W. van Krevelen 3., completely rev. ed. Amsterdam [u.a.] Elsevier 1990 XXII, 875 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Materiaalkunde gtt Polimeros (Quimica) larpcal Polymeren gtt Polymères - Propriétés mécaniques Polymers Mechanical properties Chemische Struktur (DE-588)4009857-6 gnd rswk-swf Physikalische Eigenschaft (DE-588)4134738-9 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Eigenschaft (DE-588)4151179-7 gnd rswk-swf Polymere (DE-588)4046699-1 s Chemische Struktur (DE-588)4009857-6 s Physikalische Eigenschaft (DE-588)4134738-9 s DE-604 Eigenschaft (DE-588)4151179-7 s 1\p DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002876158&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Krevelen, Dirk W. van 1914-2001 Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions Materiaalkunde gtt Polimeros (Quimica) larpcal Polymeren gtt Polymères - Propriétés mécaniques Polymers Mechanical properties Chemische Struktur (DE-588)4009857-6 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Polymere (DE-588)4046699-1 gnd Eigenschaft (DE-588)4151179-7 gnd |
| subject_GND | (DE-588)4009857-6 (DE-588)4134738-9 (DE-588)4046699-1 (DE-588)4151179-7 |
| title | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_auth | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_exact_search | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_full | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions by D. W. van Krevelen |
| title_fullStr | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions by D. W. van Krevelen |
| title_full_unstemmed | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions by D. W. van Krevelen |
| title_short | Properties of polymers |
| title_sort | properties of polymers their correlation with chemical structure their numerical estimation and prediction from additive group contributions |
| title_sub | their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| topic | Materiaalkunde gtt Polimeros (Quimica) larpcal Polymeren gtt Polymères - Propriétés mécaniques Polymers Mechanical properties Chemische Struktur (DE-588)4009857-6 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Polymere (DE-588)4046699-1 gnd Eigenschaft (DE-588)4151179-7 gnd |
| topic_facet | Materiaalkunde Polimeros (Quimica) Polymeren Polymères - Propriétés mécaniques Polymers Mechanical properties Chemische Struktur Physikalische Eigenschaft Polymere Eigenschaft |
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