Complex chemistry:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin u.a.
Springer
1991
|
| Schriftenreihe: | Structure and bonding
76 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 197 S. graph. Darst. |
| ISBN: | 3540534997 0387534997 |
Internformat
MARC
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| 245 | 1 | 0 | |a Complex chemistry |c with contributions by G. Blasse ... |
| 264 | 1 | |a Berlin u.a. |b Springer |c 1991 | |
| 300 | |a 197 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
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TABLE OF CONTENTS
STRUCTURAL AND PHYSICAL CORRELATIONS IN THE BIOLOGICAL
PROPERTIES OF TRANSITION METAL HETEROCYCLIC
THIOSEMICARBAZONE AND S-ALKYLDITHIOCARBAZATE COMPLEXES
D. X. WEST, S.B. PADHYE, P.B. SONAWANE. 1
NATURE AND DYNAMICS OF THE SPIN-STATE INTERCONVERSION
IN METAL COMPLEXES
E. KONIG. 51
OPTICAL ELECTRON TRANSFER BETWEEN METAL IONS
AND ITS CONSEQUENCES
G. BLASSE. 153
AUTHOR INDEX VOLUMES 1-76. 189
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/943287782
STRUCTURAL AND PHYSICAL CORRELATIONS IN THE
BIOLOGICAL PROPERTIES OF TRANSITION METAL
HETEROCYCLIC THIOSEMICARBAZONE AND
IS-ALKYLDITHIOCARBAZATE COMPLEXES
1 INTRODUCTION.
4
2 BIOLOGICAL ACTIVITY OF THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
5
2.1 ANTITUBERCULAR ACTIVITY.
5
2.2 ANTILEPROTIC ACTIVITY. 6
2.3 ANTIFUNGAL ACTIVITY.
7
2.4 ANTIVIRAL ACTIVITY.
7
2.5 ANTIMALARIAL ACTIVITY. 9
2.6 ANTITUMOR ACTIVITY.
9
3 CHEMICAL NATURE OF THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES. 10
3.1 PREPARATIVE METHODS. 10
3.2 BONDING AND STEREOCHEMISTRY.
11
4 TRANSITION METAL COMPLEXES. 14
4.1 IRON(LII).
14
4.1.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 14
4.1.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
15
4.1.3 2-PICOLYIKETONE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES. 17
4.1.4 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 18
4.1.5 2,6-DIACETYLPYRIDINE BIS(THIOSEMICARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 19
4.1.6 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 20
4.1.7 2-FORMYL-AND 2-ACETYLTHIOPHENE THIOSEMICARBAZONES. 20
STRUCTURE AND BONDING 76
R SPRINGER-VERLAG BERLIN HEIDELBERG 1991
2
DOUGLAS X. WEST ET AL.
4.2 IRON(II). 20
4.2.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 20
4.2.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
21
4.2.3 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 21
4.2.4 2,6-DIACETYLPYRIDINE BIS(THIOSEMFCARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 21
4.2.5 2-FORMYL- AND 2-ACETYLTHIOPHENE THIOSEMICARBAZONES. 21
4.3 COPPER(II). 22
4.3.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 22
4.3.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
24
4.3.3 2-PIEOLYIKETONE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES. 27
4.3.4 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 27
4.3.5 2,6-DIACETYLPYRIDINE BISFTHIOSEMICARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 28
4.3.6 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES 28
4.3.7 2-FORMYLPYRAZOLE THIOSEMICARBAZONES. 29
4.3.8 2-FORMYL- AND 2-ACETYLFURAN THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 29
4.3.9 OTHER POLYDENTATE THIOSEMICARBAZONES. 30
4.4 COBALT(III). 31
4.4.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES .
. 31
4.4.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
31
4.4.3 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES
AND S-ALKYLDITHIOCARBAZATES. 32
4.4.4 2,6-DIACETYLPYRIDINE BIS(THIOSEMICARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 33
4.4.5 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 33
4.4.6 2-FORMYLPYRAZOLE THIOSEMICARBAZONES. 33
4.4.7 2-FORMYL- AND 2-ACETYLFURAN THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 33
4.4.8 2-FORMYL- AND 2-ACETYLTHIOPHENE THIOSEMICARBAZONES. 34
4.5 COBALTLLLL. 34
4.5.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 34
4.5.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES.
34
4.5.3 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 35
4.5.4 2,6-DIACETYLPYRIDINE BIS(THIOSEMICARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 35
4.5.5 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 36
4.5.6 2-FORMYL- AND 2-ACETYLFURAN THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 36
4.5.7 OTHER POLYDENTATE THIOSEMICARBAZONES. 37
4.6 NICKEL(II). 37
4.6.1 2-FORMYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 37
4.6.2 2-ACETYLPYRIDINE THIOSEMICARBAZONES AND S-ALKYLDITHIOCARBAZATES
. 38
4.6.3 2-PICOLYIKETONE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 39
4.6.4 2-FORMYLQUINOLINE AND 1-FORMYLISOQUINOLINE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 40
4.6.5 2,6-DIACETYLPYRIDINE BIS(THIOSEMICARBAZONES) AND
BIS(S-ALKYLDITHIOCARBAZATES). 41
4.6.6 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONES AND
S-ALKYLDITHIOCARBAZATES. 41
4.6.7 2-FORMYLPYRAZOLE THIOSEMICARBAZONES. 42
4.6.8 2-FORMYL- AND 2-ACETYLFURAN THIOSEMICARBAZONES AND S-ALKYLDITHIO
CARBAZATES. 42
STRUCTURAL AND PHYSICAL CORRELATIONS
3
4.6.9 2-FORMYL- AND 2-ACETYLTHIOPHENE THIOSEMICARBAZONES. 43
4.6.10 OTHER POLYDENTAT THIOSEMICARBAZONES. 43
4.7 OTHER METAL ION COMPLEXES. 44
5 CONCLUSIONS AND SUGGESTIONS FOR FURTHER STUDIES. 44
6 REFERENCES. 44
7 APPENDIX-SYMBOLS FOR ORGANIC MOLECULES. 49
NATURE AND DYNAMICS OF THE SPIN-STATE
INTERCONVERSION IN METAL COMPLEXES
1 INTRODUCTION. 53
2 THE VARIATION OF MOLECULAR VOLUME AND SOME THEORETICAL IMPLICATIONS.
59
3 METHODS AND BASIC RELATIONS FOR RELAXATION MEASUREMENTS OF SPIN-STATE
EQUILIBRIA. 68
4 RELAXATION OF SPIN-STATE EQUILIBRIA OF METAL COMPLEXES IN SOLUTION. 74
4.1 COMPLEXES OF IRON(II). 74
4.2 COMPLEXES OF IRON(III). 79
4.3 COMPLEXES OF COBALT(II). 82
5 CONSEQUENCES WITH RESPECT TO THE ENERGETIC AND MOLECULAR PROPERTIES OF
THE ACTIVATED
COMPLEX FROM ABSOLUTE REACTION RATE THEORY. 83
6 DESCRIPTION IN TERMS OF A RADIATIONLESS NONADIABATIC MULTIPHONON
PROCESS. 93
6.1 OUTLINE OF THE METHOD. 94
6.2 CALCULATION OF ELECTRONIC MATRIX ELEMENTS. 97
6.3 CALCULATION OF RATE CONSTANTS . 99
7 RELAXATION OF THERMALLY QUENCHED OR OPTICALLY EXCITED HIGH-SPIN STATES
RESULTING
FROM THE SPIN-STATE TRANSITION IN SOLID METAL COMPLEXES. 101
7.1 SURVEY OF THE AVAILABLE RESULTS. 101
7.2 STUDIES ON INDIVIDUAL SYSTEMS. 103
8 RATES OF SPIN-STATE TRANSITION FOR SOLID METAL COMPLEXES BASED ON THE
LINE SHAPE
ANALYSIS OF MOSSBAUER SPECTRA. 107
8.1 LIFETIME LIMITS AND THE RATE OF SPIN-STATE CONVERSION. 107
8.2 THE RELAXATION THEORY OF BLUME AND TJON. 109
STRUCTURE AND BONDING 76
(C
SPRINGER-VERLAG BERLIN HEIDELBERG 1991
52
EDGAR KONIG
8.3 A SIMPLE EXAMPLE OF LINE SHAPE ANALYSIS: SPIN-STATE RELAXATION IN
THE NITROSYL
COMPLEX FE(J-MPH)NO.
115
8.4 INDIVIDUAL SPIN-STATE INTERCONVERSION RATE STUDIES.
119
9 THE MOLECULAR REORGANIZATION ASSOCIATED WITH SPIN-STATE EQUILIBRIA IN
SOLUTION
AND THE STRUCTURAL CHANGES ACCOMPANYING SPIN-STATE TRANSITIONS IN SOLID
METAL COMPLEXES.
134
10 CONCLUSIONS.
145
11 REFERENCES.
14
G
OPTICAL ELECTRON TRANSFER BETWEEN METAL IONS
AND ITS CONSEQUENCES
1 INTRODUCTION.154
2 METAL-TO-METAI CHARGE TRANSFER (MMCT) INVOLVING ONE CLOSED-SHELL
TRANSITION-METAL ION.156
2.1 GENERAL.156
2.2 SURVEY OF OTHER CASES.158
3 OTHER EXAMPLES OF OPTICAL MMCT TRANSITIONS.167
3.1 MOLECULAR COMPLEXES.167
3.2 M(D")M(DM)CT IN SOLIDS. 168
3.3 OTHER EXAMPLES IN SOLIDS. 170
4 THE NATURE OF MMCT TRANSITIONS. 172
5 MIXED-VALENCE COMPOUNDS. 175
6 THE ROLE OF MMCT IN THE FIELD OF SEMICONDUCTORS. 177
7 THE ROLE OF CT STATES IN OTHER PHENOMENA. 180
8 CONCLUSION. 184
9 REFERENCES. 185
STRUCTURE AND BONDING 76
C SPRINGER-VERLAG BERLIN HEIDELBERG 1991 |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV004669672 |
| illustrated | Illustrated |
| indexdate | 2024-10-09T16:25:03Z |
| institution | BVB |
| isbn | 3540534997 0387534997 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002868768 |
| oclc_num | 24080608 |
| open_access_boolean | |
| owner | DE-12 DE-355 DE-BY-UBR DE-703 DE-29T DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-83 DE-11 DE-188 |
| owner_facet | DE-12 DE-355 DE-BY-UBR DE-703 DE-29T DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-83 DE-11 DE-188 |
| physical | 197 S. graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Springer |
| record_format | marc |
| series | Structure and bonding |
| series2 | Structure and bonding |
| spelling | Complex chemistry with contributions by G. Blasse ... Berlin u.a. Springer 1991 197 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Structure and bonding 76 Complexes métalliques ram Composés complexes ram Ions métalliques ram Complex compounds Low-Spin-Komplexe (DE-588)4342326-7 gnd rswk-swf High-Spin-Komplexe (DE-588)4342325-5 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 gnd rswk-swf Übergang Physik (DE-588)4140022-7 gnd rswk-swf Biologische Aktivität (DE-588)4291566-1 gnd rswk-swf Übergangsmetallion (DE-588)4186579-0 gnd rswk-swf Komplexe (DE-588)4133953-8 gnd rswk-swf Thiosemicarbazidderivate (DE-588)4185303-9 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Metallkomplexe (DE-588)4038898-0 s DE-604 Übergangsmetallkomplexe (DE-588)4131837-7 s Komplexe (DE-588)4133953-8 s Thiosemicarbazidderivate (DE-588)4185303-9 s Biologische Aktivität (DE-588)4291566-1 s Low-Spin-Komplexe (DE-588)4342326-7 s High-Spin-Komplexe (DE-588)4342325-5 s Übergang Physik (DE-588)4140022-7 s Übergangsmetallion (DE-588)4186579-0 s Elektronentransfer (DE-588)4151907-3 s Blasse, G. Sonstige oth Structure and bonding 76 (DE-604)BV002531227 76 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002868768&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Complex chemistry Structure and bonding Complexes métalliques ram Composés complexes ram Ions métalliques ram Complex compounds Low-Spin-Komplexe (DE-588)4342326-7 gnd High-Spin-Komplexe (DE-588)4342325-5 gnd Metallkomplexe (DE-588)4038898-0 gnd Übergang Physik (DE-588)4140022-7 gnd Biologische Aktivität (DE-588)4291566-1 gnd Übergangsmetallion (DE-588)4186579-0 gnd Komplexe (DE-588)4133953-8 gnd Thiosemicarbazidderivate (DE-588)4185303-9 gnd Elektronentransfer (DE-588)4151907-3 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4342326-7 (DE-588)4342325-5 (DE-588)4038898-0 (DE-588)4140022-7 (DE-588)4291566-1 (DE-588)4186579-0 (DE-588)4133953-8 (DE-588)4185303-9 (DE-588)4151907-3 (DE-588)4131837-7 (DE-588)4143413-4 |
| title | Complex chemistry |
| title_auth | Complex chemistry |
| title_exact_search | Complex chemistry |
| title_full | Complex chemistry with contributions by G. Blasse ... |
| title_fullStr | Complex chemistry with contributions by G. Blasse ... |
| title_full_unstemmed | Complex chemistry with contributions by G. Blasse ... |
| title_short | Complex chemistry |
| title_sort | complex chemistry |
| topic | Complexes métalliques ram Composés complexes ram Ions métalliques ram Complex compounds Low-Spin-Komplexe (DE-588)4342326-7 gnd High-Spin-Komplexe (DE-588)4342325-5 gnd Metallkomplexe (DE-588)4038898-0 gnd Übergang Physik (DE-588)4140022-7 gnd Biologische Aktivität (DE-588)4291566-1 gnd Übergangsmetallion (DE-588)4186579-0 gnd Komplexe (DE-588)4133953-8 gnd Thiosemicarbazidderivate (DE-588)4185303-9 gnd Elektronentransfer (DE-588)4151907-3 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Complexes métalliques Composés complexes Ions métalliques Complex compounds Low-Spin-Komplexe High-Spin-Komplexe Metallkomplexe Übergang Physik Biologische Aktivität Übergangsmetallion Komplexe Thiosemicarbazidderivate Elektronentransfer Übergangsmetallkomplexe Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002868768&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV002531227 |
| work_keys_str_mv | AT blasseg complexchemistry |