The chemical physics of atomic and molecular clusters: Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Amsterdam u.a.
North-Holland
1990
|
| Schriftenreihe: | Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi
107 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Parallelt.: La fisica chimica degli aggregati atomici e molecolari |
| Beschreibung: | XVIII, 814 S. |
| ISBN: | 0444883312 |
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| 245 | 1 | 0 | |a The chemical physics of atomic and molecular clusters |b Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 |c ed. by G. Scoles |
| 246 | 1 | 3 | |a La fisica chimica degli aggregati atomici e molecolari |
| 264 | 1 | |a Amsterdam u.a. |b North-Holland |c 1990 | |
| 300 | |a XVIII, 814 S. | ||
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| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi |v 107 | |
| 500 | |a Parallelt.: La fisica chimica degli aggregati atomici e molecolari | ||
| 650 | 4 | |a Agrégat | |
| 650 | 4 | |a Atome | |
| 650 | 7 | |a Atomes |2 ram | |
| 650 | 4 | |a Molécule | |
| 650 | 7 | |a Molécules |2 ram | |
| 650 | 4 | |a Théorie atomique | |
| 650 | 4 | |a Théorie moléculaire | |
| 650 | 4 | |a Atomic theory | |
| 650 | 4 | |a Microclusters | |
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| 710 | 2 | |a Società italiana di fisica |e Sonstige |0 (DE-588)1011890-1 |4 oth | |
| 830 | 0 | |a Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi |v 107 |w (DE-604)BV000002984 |9 107 | |
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Datensatz im Suchindex
| _version_ | 1804118641960026112 |
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| adam_text | ITALIAN PHYSICAL SOCIETY PROCEEDINGS OF THE INTERNATIONAL SCHOOL OF
PHYSICS ENRICO FERMI» COURSE CVII EDITED BY G. SCOLES DIRECTOR OF THE
COURSE VARENNA ON LAKE COMO VILLA MONASTERO 28 JUNE - 7 JULY 1988 THE
CHEMICAL PHYSICS OF ATOMIC AND MOLECULAR CLUSTERS 1990 NORTH-HOLLAND
AMSTERDAM - OXFORD - NEW YORK - TOKYO I N D I C E G. SCOLES AND S.
STRINGARI - PREFACE PAG. XVN GRUPPO FOTOGRAFICO DEI PARTECIPANTI AL
CORSO FUORI TESTO PART I. - THEORY R. S. BERRY - STRUCTURE AND DYNAMICS
OF CLUSTERS: AN INTRODUCTION. 1. WHAT ARE CLUSTERS? PAG. 3 2.
SIMULATIONS AND DIAGNOSTICS » 8 21 » 8 2*2 T... » 15 R. S. BERRY -
STRUCTURE AND DYNAMICS OF CLUSTERS: PHASE EQUILIBRIUM AND PHASE CHANGE.
1. SOLID AND LIQUID CLUSTERS: THEIR EQUILIBRIUM » 23 RI » 25 1*2 » 27 2.
SIMULATIONS » 32 2*1 » 32 2*2 » 37 3. THE FUTURE » 39 J. JORTNER, D.
SCHARF, N. BEN-HORIN, U. EVEN AND U. LANDMAN - SIZE EFFECTS IN CLUSTERS.
PROLOGUE » 43 1. ENERGETIC AND THERMODYNAMIC SIZE EFFECTS » 44 1 1.
ENERGETIC SIZE EFFECTS » 44 1*1.1. FROM MOLECULES TO CLUSTERS » 44
1*1.2. FROM CLUSTER TO BULK CONDENSED MATTER » 45 1*2. ISOMERIZATION AND
MELTING OF CLUSTERS » 50 1*3. EXPERIMENTAL INTERROGATION OF CLUSTER
ISOMERIZATION » 58 V VI INDICE 2. DYNAMIC SIZE EFFECTS IN ELECTRONICALLY
EXCITED RARE-GAS CLUSTERS PAG. 64 2 1. REACTIVE AND NONREACTIVE
RELAXATION » 64 2 2. APPLICATION OF CLASSICAL MOLECULAR-DYNAMICS METHOD
» 67 2 3. ANALYSIS OF THE MOLECULAR-DYNAMICS DATA » 71 2 3.1. SIZE
ANALYSIS » 71 2 3.2. ENERGETICS » 72 2 3.3. CONFIGURATIONAL RELAXATION »
72 2 3.4. MASS TRANSPORT OF ELECTRONIC EXCITATIONS » 73 2 4.
COMPUTATIONAL RESULTS » 73 2 4.1. ATOMIC-IMPURITY EXCITATIONS IN XE*AR
12 AND XE*AR 54 CLUSTERS » 73 2 4.2. EXCIMER EXCITATIONS IN XE|AR N AND
XEFAR 53 CLUSTERS ... » 81 2 5. DISCUSSION » 91 2 5.1. DYNAMICS OF
ATOMIC-IMPURITY EXCITATIONS » 91 2 5.2. DYNAMICS OF EXCIMER EXCITATIONS
» 92 F. G. AMAR - A STRUCTURAL APPROACH TO THE ANALYSIS OF CLUSTER
DYNAMICS. PART I - INTRODUCTION » 99 PART II - MELTING AND ISOMERIZATION
OF ARGON CLUSTERS » 100 1. BACKGROUND » 100 2. MELTING LOOPS » 101 3.
ISOMERS OF AR 7 » 103 4. MOLECULAR DYNAMICS AND QUENCHING » 104 5.
RESIDENCE TIMES » 107 6. LIFETIME DISTRIBUTIONS » 111 7. AR 7 MELTING:
SUMMARY » 113 PART III - COOLING AND DYNAMIC QUENCHING OF AR 13 » 113 1.
INTRODUCTION » 113 2. BROWNIAN DYNAMICS » 114 3. OTHER QUENCHING
TECHNIQUES » 115 4. RESULTS » 115 5. CONCLUSIONS » 119 PART IV -
PHOTODISSOCIATION DYNAMICS OF BR^ IN (C0 2 ) TC AND AR* CLUSTERS » 119
1. BACKGROUND » 119 2. A MODEL FOR NEGATIVE-ION PHOTODISSOCIATION » 120
3. VARIABLE-CHARGE CALCULATION » 123 4. MINIMUM-ENERGY STRUCTURES » 124
5. PHOTOEXCITATION DYNAMICS OF MINIMUM-ENERGY STRUCTURES » 125 6.
THERMAL AVERAGES » 129 7. CAGING FRACTION » 130 8. DISCUSSION » 131 PART
V - SUMMARY » 132 INDICE VII R. J. LE ROY - SPECTRA, PHASE TRANSITIONS
AND DYNAMICAL ISOMERIZA- TIONS» OF MIXED VAN DER WAALS CLUSTERS. 1.
INTRODUCTION PAG. 137 2. METHODOLOGY, POTENTIAL-ENERGY SURFACE AND
EQUILIBRIUM STRUCTURES .... » 138 3. SIMULATING THE CLUSTER SPECTRA »
141 4. DYNAMICAL SIMULATIONS AND PHASE CHANGE BEHAVIOUR » 146 5.
SPONTANEOUSLY REVERSING ISOMERIZATION OF AN ISOLATED SF 6 -(AR) 9
CLUSTER » 150 6. DISCUSSION AND SPECULATIONS » 154 W. ANDREONI - THE
CAR-PARRINELLO METHOD AND ITS APPLICATION TO MICROCLUSTERS. 1.
INTRODUCTION » 159 2. THE CAR-PARRINELLO METHOD » 159 3. COMPUTATIONAL
PROCEDURE » 162 4. SOME TEST EXAMPLES » 164 5. SOME RESULTS: STRUCTURAL
AND FINITE-7 PROPERTIES » 167 6. FINAL REMARKS » 173 R. KAWAI, I. L.
GARZOEN, X. P. LONG AND J. H. WEARE - SIMULATION OF METALLIC AND IMPURE
VAN DER WAALS CLUSTERS. INTRODUCTION » 177 1. STRUCTURAL AND DYNAMICAL
PROPERTIES OF IMPURE VAN DER WAALS SYS- TEMS » 178 1 1. LOW-TEMPERATURE
STRUCTURES » 180 11.1. THE A 1S B SYSTEM » 180 1*1.2. THE A 55 B SYSTEM
» 181 1*1.3. THE A 13 B 13 SYSTEM » 182 1*2. THE FINITE-TEMPERATURE
BEHAVIOR » 182 1*2.1. HEATING IN THE A 12 B, A 1S B AND A 55 SS SYSTEMS »
182 1*2.2. HEATING IN THE A 1S B 13 SYSTEM » 186 2. CAR AND PARRINELLO
METHODS FOR METALLIC CLUSTERS » 187 S. STRINGARI - CLUSTERS OF QUANTUM
LIQUIDS. 1. INTRODUCTION » 199 2. BULK AND SURFACE PROPERTIES OF 4 HE
AND 3 HE » 200 2*1. BULK PROPERTIES » 200 2*2. SURFACE PROPERTIES » 203
3. GROUND-STATE PROPERTIES OF HELIUM CLUSTERS » 205 3 1. THE DENSITY
FUNCTIONAL APPROACH » 205 3*2. GROUND-STATE PROPERTIES OF 4 HE CLUSTERS
» 208 VIII INDICE 3 3. GROUND-STATE PROPERTIES OF 3 HE CLUSTERS PAG. 212
3 4. 3 HE IMPURITIES ON 4 HE CLUSTERS » 219 4. COLLECTIVE EXCITATIONS IN
HELIUM CLUSTERS » 223 4 1. COLLECTIVE MODES IN 4 HE CLUSTERS » 223 4
1.1. COMPRESSION MODES » 225 4 1.2. SURFACE EXCITATIONS » 227 4 2.
COLLECTIVE MODES IN 3 HE CLUSTERS » 227 4*2.1. DENSITY EXCITATIONS » 228
4 2.2. MAGNETIC EXCITATIONS » 229 5. CONCLUSIONS » 233 X. CAMPI -
FRAGMENTATION OF CLUSTERS. 1. INTRODUCTION » 237 2. SURVEY OF
EXPERIMENTAL DATA » 237 2 1. FRAGMENTATION OF NUCLEI » 237 2 2.
FRAGMENTATION OF ATOMIC CLUSTERS » 244 3. ELEMENTS OF CLUSTER
FRAGMENTATION THEORY » 248 31. PARTITIONS » 248 3 2. GEOMETRICAL MODEIS
» 250 3 3. STATISTICAL EQUILIBRIUM » 256 3 4. RATE EQUATION THEORY » 257
4. SIGNALS OF SCALING IN CLUSTER FRAGMENTATION » 258 4 1. CRITICAL
BEHAVIOUR AND CRITICAL EXPONENTS » 259 4 2. FINITE-SIZE SCALING » 265
SUMMARY » 266 PART IL - SPECTROSCOPY AND PHOTODISSOCIATION R. 0. WATTS -
INFRARED SPECTROSCOPY OF LARGE CLUSTERS. 1. INTRODUCTION » 271 2.
EXPERIMENTAL METHODS » 272 3. EXPERIMENTAL RESULTS » 276 4.
VIBRATIONAL-SPECTROSCOPY THEORY » 287 5. SEMI-CLASSICAL CALCULATIONS OF
BAND SHAPES » 299 6. QUANTUM SIMULATION » 311 7. SUMMARY » 326 D. J.
LEVANDIER, M. MENGEL, J. MCCOMBIE AND G. SCOLES - INFRARED SPECTROSCOPY
IN AND ON ARGON CLUSTERS: MATRIX AND SURFACE SPECTROSCOPY IN THE GAS
PHASE. 1. INTRODUCTION » 331 2. EXPERIMENTAL BACKGROUND » 332 INDICE IX
3. CLUSTERS AS MICROREACTORS: COMPLEX FORMATION BETWEEN CH 3 F AND HCL
IN ARGON PAG. 334 4. THE SURFACE OF CLUSTERS: A UNIQUE ENVIRONMENT FOR
SPECTROSCOPY AND CHEMICAL DYNAMICS » 338 5. CLUSTERS AND GLASSES » 345
6. PHASE COEXISTENCE IN CLUSTERS: HOT SOLIDS AND COLD LIQUIDS » 351 7.
CLUSTERS AS MICROSOLUTIONS: WILL THE WOULD-BE SOLUTE BE ADMITTED IN OR
LEFT ON THE SURFACE? » 352 G. DELACRETAZ, P. FAYET, J. P. WOLF AND L.
WOESTE - SPECTROSCOPY, REACTIVITY AND PHOTODYNAMICS OF SIZE-SELECTED
METAL CLUSTERS. 1. INTRODUCTION » 359 2. SPECTROSCOPIC APPROACHES TO
METAL CLUSTERS » 359 2 1. CLUSTER BEAM SOURCES FOR PERFORMING
SPECTROSCOPY » 359 2 2. EESONANT TWO-PHOTON IONIZATION AND DEPLETION
SPECTROSCOPY » 363 2 3. AS AN EXAMPLE: SPECTROSCOPY OF NA 3 » 372 2*3.1.
THE GROUND STATE OF NA 3 » 372 2 3.2. THE 675 NM SYSTEM (A-STATE) » 372
2 3.3. THE510NMSYSTEM(SS-STATE) » 373 2 3.4. THE560NMSYSTEM(SS -STATE) »
374 2 3.5. THE 475NM SYSTEM (C-STATE) » 375 2 3.6. THE PREDISSOCIATED
420 NM SYSTEM (D-AT&TE) » 376 3. CHEMICAL REACTIONS OF METAL CLUSTERS »
378 3 1. PRODUCTION OF SIZE-SELECTED METAL CLUSTER IONS » 378 3 2.
EXPERIMENTAL SET-UP » 381 3 3. CLUSTER-MOLECULE REACTIONS » 384 4.
PHOTODYNAMICS OF METAL CLUSTERS » 389 M. MOSKOVITS - SIZE-DEPENDENT
PROPERTIES IN SMALL METAL AND SEMICONDUCTOR CLUSTERS » 397 W. D. KNIGHT
- STRUCTURES OF METAL CLUSTERS. 1. INTRODUCTION » 413 2. SHELL STRUCTURE
» 414 3. EXPERIMENTAL PROPERTIES » 419 3 1. ABUNDANCE AND STABILITY »
419 3 2. IONIZATION POTENTIAL » 420 3 3. STATIC ELECTRIC POLARIZABILITY
» 422 3 4. GIANT DIPOLE RESONANCE » 422 4. CONCLUSIONS AND FUTURE
DIRECTIONS » 424 1. X INDICE T. D. MARK, A. STAMATOVIC, F. HOWORKA, P.
SCHEIER AND G. WALDER - INTERACTION BETWEEN VISIBLE LASER LIGHT AND
EXPANDING VAN DER WAALS CLUSTER BEAMS. 1. INTRODUCTION PAG. 427 2.
EXPERIMENTAL TECHNIQUE » 428 3. RESULTS » 429 4. EXPERIMENTAL TESTS »
440 4 1. LASER POWER DEPENDENCE » 440 4 2. LASER WAVELENGTH DEPENDENCE
» 443 4 3. LASER FOCUS DEPENDENCE » 443 4 4. DEPENDENCE ON IRRADIATION
GEOMETRY » 444 4 5. VARIOUS FURTHER TESTS AND OBSERVATIONS » 444 5.
ANALYSIS (CROSS-SECTION) AND INTERPRETATION (DISSOCIATION MECHANISM) ..
» 445 D. RAY, N. E. LEVINGER AND W. C. LINEBERGER - SPECTROSCOPY AND
DYNAMICS OF VAN DER WAALS» CLUSTER IONS. 1. INTRODUCTION » 451 2.
DISCUSSION » 452 2 1. EXPERIMENTAL METHOD » 452 2 2. OPTICAL ABSORPTION
IN VAN DER WAALS» CLUSTER IONS » 454 2 3. PHOTODISSOCIATION DYNAMICS OF
VAN DER WAALS» CLUSTER IONS ..... » 457 2 4. PHOTOCHEMISTRY IN CLUSTER
IONS » 461 3. CONCLUSION » 463 S. T. ARNOLD, J. V. COE, J. G. EATON, C.
B. FREIDHOFF, L. KIDDER, G. H. LEE, M. R. MANAA, K. M. MCHUGH, D. PATEL-
MISRA, H. W. SARKAS, J. T. SNODGRASS AND K. H. BOWEN - PHOTODETACHMENT
SPECTROSCOPY OF NEGATIVE CLUSTER IONS. 1. INTRODUCTION » 467 2.
EXPERIMENTAL » 469 3. RESULTS AND DISCUSSION » 470 3*1. ION-MOLECULE
COMPLEXES: CLUSTER ANIONS WITH LOCALIZED EXCESS NEGATIVE CHARGES » 470
3 2. MORE COMPLICATED CASES: CLUSTER ANIONS WITH EXCESS CHARGE DISPERSAL
» 479 3 3. ALKALI METAL CLUSTER ANIONS » 484 3 4. WATER CLUSTER ANIONS »
486 C. BRECHIGNAC AND PH. CAHUZAC - EXCITATION OF FREE METAL CLUSTERS.
1. INTRODUCTION » 491 2. PHOTOEXCITATION OF ALKALI CLUSTER IONS » 491
INDICE KI 2*1. UNIMOLECULAR DISSOEIATION FOLLOWING ELECTRONIC EXCITATION
PAG. 491 2 1.1. EXPERIMENTAL PROCEDURE » 493 2 1.2. ENERGETIC OF THE
UNIMOLECULAR DISSOEIATION » 494 2 1.3. DYNAMICS OFTHE UNIMOLECULAR
DISSOEIATION » 496 2 2. PHOTOINDUCED DISSOEIATION: A PROBE TO FOLLOW
ELECTRONIC EXCITATION » 500 3. PHOTOIONIZATION OF METAL CLUSTERS » 502
3 1. DIRECT IONIZATION » 503 3 1.1. CHARGE EXCHANGE BETWEEN NA^ CLUSTER
AND CS ATOMS: GENERATION OF NEUTRAL MASS-SELECTED CLUSTER BEAM » 503 3
1.2. PHOTOIONIZATION OF MASS-SELECTED NEUTRAL CLUSTERS » 506 3 2.
AUTOIONIZATION PROCESS » 507 PART III. - MASS SPECTROSCOPY SCATTERING
AND CHEMICAL PROP- ERTIES G. TORCHET, J. FARGES, M. F. DE FERAUDY AND B.
RAOULT - ELECTRON DIFFRACTION STUDIES OF CLUSTERS PRODUCED IN A FREE JET
EXPANSION. 1. INTRODUCTION » 513 2. EXPERIMENTAL METHODS » 514 2 1.
CLUSTER BEAM » 514 2 2. ELECTRON DIFFRACTION » 515 2 3. APPARATUS » 518
3. DIFFRACTION PATTERN ANALYSIS » 520 3 1. ONSET OF CONDENSATION » 520
3 2. CRYSTALLOGRAPHIC METHODS » 521 3 2.1. CLUSTER STRUETURE » 522
3 2.2. CLUSTER SIZE » 522 3 2.3. LATTICE PARAMETER » 523 3 2.4. LATTICE
DYNAMICS » 524 3 3. CALCULATED DIFFRACTION FUNETIONS » 526 3 3.1.
HOMOGENEOUS MODEIS » 526 3 3.2. SIMULATION OF CLUSTER DYNAMICS » 527
3 3.3. MOLECULAR DYNAMICS » 531 4. SIZE EFFECTS IN AR CLUSTER STRUETURE
» 532 4 1. DIFFRACTION PATTERNS » 532 4 2. POLYICOSAHEDRAL STRUETURE »
532 4 3. MULTILAYER ICOSAHEDRAL STRUETURE » 533 4 4. CRYSTALLINE
STRUETURE » 536 5. TEMPERATURE EFFECTS IN SF 6 CLUSTERS » 537 5 1.
CLUSTER TEMPERATURE » 537 5 2. TEMPERATURE EFFECTS IN SF 6 EXPERIMENTS »
539 5 3. MD SIMULATION OFTHE PHASE TRANSITION » 540 U. BUCK - CLUSTER
PROPERTIES FROM SCATTERING EXPERIMENTS WITH ATOMS. 1. INTRODUCTION » 543
2. SCATTERING ANALYSIS AND SIZE SELECTION » 545 XII INDICE 21. THE
METHOD PAG. 545 2 2. EXPERIMENTAL RESULTS » 547 3. COLLISIONAL ENERGY
TRANSFER » 550 4. CLUSTER FORMATION IN SUPERSONIC EXPANSIONS » 552 5.
FRAGMENTATION BY ELECTRON IMPACT IONIZATION » 555 6. INFRARED
PHOTODISSOCIATION OF SIZE-SELECTED CLUSTERS » 565 6 1. EXPERIMENTAL
METHOD » 565 6 2. RESULTS FOR ETHYLENE » 567 6 3. RESULTS FOR METHANOL »
571 7. CONCLUSIONS » 573 L. BENEVENTI, P. CASAVECCHIA, L. YU. RUSIN AND
G. G. VOLPI - CROSSED-MOLECULAR-BEAM EXPERIMENTS ON NITRIC OXIDE
CLUSTERS. 1. INTRODUCTION » 579 2. EXPERIMENTAL » 581 3. SCATTERING
ANALYSIS » 583 4. RESULTS » 585 4 1. ELECTRON ENERGY DEPENDENCE OF
DINIER FRAGMENTATION » 591 4 2. BEAM TEMPERATURE DEPENDENCE OF (NO) TC
CLUSTERS » 591 5. DISCUSSION » 593 J. P. TOENNIES - HELIUM CLUSTERS. 1.
INTRODUCTION » 597 2. MASS SPECTROMETER AND TIME-OF-FLIGHT EXPERIMENTS »
600 3. SCATTERING OF MONOENERGETIC ELECTRONS » 605 4. SCATTERING OF
ATOMS AND MOLECULES » 611 5. SUMMARY » 615 H. HABERLAND -
SOLVATED-ELECTRON CLUSTERS. INTRODUCTION » 619 1. EXPERIMENT » 621 L L.
THE EXPERIMENTAL PROBLEM AND ITS SOLUTION » 621 2. MASS SPECTRA » 623 3.
FIELD DETACHMENT » 629 4. PHOTODETACHMENT » 631 M. L. MANDICH -
CHEMISTRY OF CARBON AND SILICON CLUSTERS. 1. INTRODUCTION » 635 2.
EXPERIMENTAL TECHNIQUES » 636 INDICE XIII 2 1. ION CYCLOTRON RESONANCE
MASS SPECTROMETRY PAG. 636 21.1. BASIC PRINCIPLES OF ICK » 637 2 1.2.
APPLICATION OF FTICR TO STUDIES OF CLUSTER CHEMISTRY .... » 643 2
1.2.1. GETTING CLUSTERS INTO THE ION CELL » 643 2 1.2.2. CLUSTER ARE
TRAPPED TO ALLOW FOR REACTIONS » 649 2 1.2.3. OBTAINING REACTION RATES
AND PRODUCT DISTRIBU- TIONS » 651 2 1.2.4. DISTINGUISHING GROUND-STATE
REACTIONS » 654 2 2. SELECTED ION FLOW TUBE TECHNIQUES » 655 2 - 2.1.
BASIC PRINCIPLES OF SIFT » 655 2 2.2. DETERMINATION OF RATE CONSTANTS
AND PRODUCT DISTRIBU- TIONS USING SIFT » 657 3. CARBON CLUSTER CHEMISTRY
» 658 3 1. REACTIONS OF POSITIVE CARBON CLUSTER IONS » 659 3 1.1.
REACTIVITY WITH SMALLMOLECULES: 0 2 , D 2 AND CO » 659 3 1.1.1. PRIMARY
REACTIONS » 659 3 1.1.2. SECONDARY REACTIONS » 664 3 1.1.3. CORRELATIONS
OF QN REACTIVITY WITH CARBENE CHEMISTRY » 666 3 1.1.4. COMPARISON OF C*
REACTIVITY WITH THEORETICAL ELECTRONIC-STRUCTURE CALCULATIONS » 669
3 1.1.5. THE SPECIAL REACTIVITY OF C7 : EVIDENCE FOR MULTI- PLE ISOMERS
» 674 3 2.1. REACTIVITY WITH SMALL HYDROCARBONS: CH 4 , C 2 H 2 AND C 2
H 4 » 677 3 2.1.1. REACTIONS WITH CH 4 » 677 3 2.1.2. REACTIONS OF CS +9
WITH C 2 H 2 » 679 3 2.1.3. REACTIONS OF CF 0+ 2O WITH C 2 H 2 » 681
3 2.1.4. REACTIONS OF C + WITH C 2 H 4 » 682 4. SILICON CLUSTER
CHEMISTRY » 684 4 1. REACTIONS OF SMALL POSITIVE AND NEGATIVE SILICON
CLUSTER IONS » 685 4 1.1. SYSTEMATIC TRENDS IN THE REACTIONS OF SILICON
CLUSTER IONS .. » 685 4 1.2. SILICON CLUSTER STRUCTURE AND THE NATURE OF
POSSIBLE REACTIVE SITES » 689 4 1.3. CHEMISTRY OF REACTIVE SILICON
CENTERS; LESSONS FROM ORGANOSILICON CHEMISTRY » 692 4*1.3.1. SILYLENES »
693 4 1.3.2. RADICAL SILICON CENTERS (SILYLS) » 695 4 1.4. REACTIONS OF
SMALL SILICON CLUSTERS WITH N0 2 , XEF 2 AND 0 2 » 696 4 1.4.1. N0 2 »
696 4 1.4.2. XEF 2 » 703 4 - 1.4.3. 0 2 » 707 4 1.5. REACTIONS OF SMALL
SILICON CLUSTERS WITH CH 3 SIH 3 AND SID 4 » 710 4-1.5.1. CH 3 SIH 3 »
710 4 1.6. REACTIONS OF SMALL SILICON CLUSTERS WITH D 2 , C 2 H 2 , NH 3
, H 2 OANDN 2 0 » 714 4 1.7. DEPENDENCE OF OBSERVED REACTIVITY ON
CLUSTER SIZE » 717 4 2. REACTIONS OF LARGE POSITIVE SILICON CLUSTER IONS
» 719 5. SEQUENTIAL CLUSTERING REACTIONS OF SILICON IONS WITH SID 4 »
720 5 1. OBSERVED REACTION SEQUENCE STARTING WITH SI + » 721 XIV INDICE
5 2. THEORETICALLY DERIVED REACTION MECHANISMS OF CLUSTERING SE- QUENCE
PAG. 723 5 2.1. SI + + SID 4 » 724 5 2.2. SI 2 D 2+ + SID 4 » 727 5 -
2.3. SI 3 D 4F + SID 4 » 729 5 2.4. SI 4 D 6+ + SID 4 » 731 5 3. PHASE
SPACE MODEL CALCULATIONS OF TRANSITION STATE ENERGIES » 732 5 3.1.
APPLICATION OF PHASE SPACE THEORY TO THE REACTION OF SI + WITH SID 4 »
733 53.1.1. OVERVIEW » 733 5*3.1.2. DERIVATION OF VARIOUS REACTION
PROBABILITIES (;) FOR *SI + + SID 4 REACTIONS » 733 5 3.1.3.
CALCULATION OF EXPERIMENTAL OBSERVABLES FOR *SI + + SID 4 REACTIONS »
735 5 3.1.4. CALCULATION OF EXPERIMENTAL OBSERVABLES FOR *SI 2 D 2+ AND
*SI 3 D 4F + SID 4 REACTIONS » 738 5 4. PHASE SPACE MODEL CALCULATIONS
OF SI 5 DTO COMPLEX ENERGY » 742 5 4.1. KINETICS MECHANISM » 742 5 4.2.
PHASE SPACE CALCULATION OF THE UNIMOLECULAR DISSOCIATION RATE, FC D »
743 5 4.3. CALCULATION OF EXPERIMENTALLY OBSERVED FORMATION RATE FOR SI
5 DTO » 744 5 5. COMPARISON OF THEORY AND EXPERIMENT » 746 5 6.
SEQUENTIAL CLUSTERING REACTIONS OF SI 2+7 WITH SID 4 » 747 5 7.
IMPLICATIONS FOR PRENUCLEATION OF HYDROGENATED SILICON PARTICLES » 751
E. K. PARKS AND S. J. RILEY - EXPERIMENTAL STUDIES OF THE CHEMISTRY OF
METAL CLUSTERS. 1. INTRODUCTION » 761 2. EXPERIMENTAL . » 762 3.
EXAMPLE OF MEASUREMENTS OF CLUSTER CHEMICAL PROPERTIES » 767 4.
CONCLUSION » 776 A. J. ST ACE - THE UNIMOLECULAR FRAGMENTATION OF ION
CLUSTERS. 1. INTRODUCTION » 779 2. EXPERIMENTAL CONSIDERATIONS » 781 3.
ION CLUSTER FRAGMENTATION PROCESSES » 784 3 1. THE UNIMOLECULAR DECAY OF
X^ CLUSTERS » 784 3 2. INTERMOLECULAR ION-MOLECULE REACTIONS IN X
CLUSTERS » 786 3 3. UNIMOLECULAR FRAGMENTATION OF MOLECULAR IONS IN
ASSOCIATION WITH INERT-GAS CLUSTERS » 788 3 3.1. EXCITATION » 788 3 3.2.
FRAGMENTATION » 790 3 3.3. POSITION OF THE MOLECULAR IONS WITH RESPECT
TO THE INERT- GAS COMPONENT » 791 4. CONCLUSION » 794 INDICE XV N. NISHL
AND K. YAMAMOTO - MOLECULAR CLUSTERS ISOLATED FROM AQUEOUS SOLUTIONS BY
ADIABATIC EXPANSION OF LIQUID JETS: A NEW APPROACH FOR MOLECULAR
ASSOCIATION IN SOLUTIONS. 1. INTRODUCTION PAG. 797 2. APPARATUS » 798
3. NOZZLE TO SKIMMER DISTANCE » 800 4. STOCHASTIC SOLUTE CONCENTRATION
IN CLUSTERS » 801 5. DISSOCIATION AND EVAPORATION OF MOLECULES ON
ELECTRON IMPACT IONIZATION » 802 6. ASSOCIATION-DISSOCIATION
EQUILIBRIUMOFHYDRATE CLUSTERS IN SOLUTION .... » 803 7. ETHANOL CHAIN
FORMATION ASSISTED BY WATER » 806 8. HYDROPHOBIE HYDRATION AND
HYDROPHILIC HYDRATION » 810 9. SUMMARY » 813
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| dewey-raw | 539/.6 |
| dewey-search | 539/.6 |
| dewey-sort | 3539 16 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
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| genre | (DE-588)1071861417 Konferenzschrift 1988 Varenna gnd-content |
| genre_facet | Konferenzschrift 1988 Varenna |
| id | DE-604.BV004476480 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:13:32Z |
| institution | BVB |
| institution_GND | (DE-588)1011890-1 |
| isbn | 0444883312 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002773862 |
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| owner_facet | DE-12 DE-355 DE-BY-UBR DE-83 |
| physical | XVIII, 814 S. |
| publishDate | 1990 |
| publishDateSearch | 1990 |
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| publisher | North-Holland |
| record_format | marc |
| series | Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi |
| series2 | Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi |
| spelling | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 ed. by G. Scoles La fisica chimica degli aggregati atomici e molecolari Amsterdam u.a. North-Holland 1990 XVIII, 814 S. txt rdacontent n rdamedia nc rdacarrier Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi 107 Parallelt.: La fisica chimica degli aggregati atomici e molecolari Agrégat Atome Atomes ram Molécule Molécules ram Théorie atomique Théorie moléculaire Atomic theory Microclusters Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Cluster (DE-588)4010318-3 gnd rswk-swf (DE-588)1071861417 Konferenzschrift 1988 Varenna gnd-content Cluster (DE-588)4010318-3 s Physikalische Chemie (DE-588)4045959-7 s 1\p DE-604 Scoles, Giacinto Sonstige oth Società italiana di fisica Sonstige (DE-588)1011890-1 oth Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi 107 (DE-604)BV000002984 107 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002773862&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 Scuola Internazionale di Fisica Enrico Fermi: Proceedings of the International School of Physics Enrico Fermi Agrégat Atome Atomes ram Molécule Molécules ram Théorie atomique Théorie moléculaire Atomic theory Microclusters Physikalische Chemie (DE-588)4045959-7 gnd Cluster (DE-588)4010318-3 gnd |
| subject_GND | (DE-588)4045959-7 (DE-588)4010318-3 (DE-588)1071861417 |
| title | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 |
| title_alt | La fisica chimica degli aggregati atomici e molecolari |
| title_auth | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 |
| title_exact_search | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 |
| title_full | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 ed. by G. Scoles |
| title_fullStr | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 ed. by G. Scoles |
| title_full_unstemmed | The chemical physics of atomic and molecular clusters Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 ed. by G. Scoles |
| title_short | The chemical physics of atomic and molecular clusters |
| title_sort | the chemical physics of atomic and molecular clusters varenna on lake como villa monastero 28 june 7 july 1988 |
| title_sub | Varenna on Lake Como, Villa Monastero, 28 June - 7 July 1988 |
| topic | Agrégat Atome Atomes ram Molécule Molécules ram Théorie atomique Théorie moléculaire Atomic theory Microclusters Physikalische Chemie (DE-588)4045959-7 gnd Cluster (DE-588)4010318-3 gnd |
| topic_facet | Agrégat Atome Atomes Molécule Molécules Théorie atomique Théorie moléculaire Atomic theory Microclusters Physikalische Chemie Cluster Konferenzschrift 1988 Varenna |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002773862&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000002984 |
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