Chromatography : concepts and contrasts:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
New York u.a.
Wiley
1988
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Schriftenreihe: | A Wiley-Interscience publication
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XII, 297 S. graph. Darst. |
ISBN: | 0471848212 |
Internformat
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Datensatz im Suchindex
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adam_text | CHROMATOGRAPHY:
CONCEPTS
AND CONTRASTS
James M Miller
Drew University
Madison, New Jersey
A Wiley-lnterscience Publication
JOHN WILEY amp; SONS
New York / Cliichester / Brisbane / Ibronto / Singapore
CONTENTS
1 INTRODUCTION TO CHROMATOGRAPHY 1
A Brief History 1
Definitions and Classifications 4
Separation 4
Chromatography 4
Chromatographic Symbols 7
The Normal Distribution 12
Other Terms 14
Summary 23
References 23
2 KINETIC PROCESSES IN CHROMATOGRAPY 25
Configurations of the Stationary Phase 25
The Rate Theory 28
The Original Van Deemter Theory 28
A Modern View of the Rate Theory 29
A Redefinition of H 35
Practical Consequences of the Rate Theory 35
References 38
3 PHYSICAL FORCES AND MOLECULAR INTERACTIONS 40
Intermodular and Interionic Forces 40
Introduction 40
Ionic Interactions 42
Van der Waals Forces 43
Hydrogen Bonding 45
Charge Transfer 45
Size Exclusion—Sieving 45
Some Models 47
vii
viii Contents
Hildebrand s Solubility Parameter 49
Snyder s Solvent Parameter 49
References 51
4 OPTIMIZATION AND THE ACHIEVEMENT OF
SEPARATION 53
Kinetics and Zone Broadening 53
Thermodynamics and Zone Migration 54
The Achievement of Separation 55
The Optimization of Separations 56
References 59
5 COMPARISONS BETWEEN CHROMATOGRAPHIC
MODES 60
Gas Chromatography Compared to Liquid Chromatography 60
Gases Compared to Liquids 60
Supercritical Fluids 64
Efficiency and Speed 65
Reduced Parameters 66
Column and Planar Configurations 69
Peaks Compared to Bands 69
Retention Ratio and Retardation Factor 71
Special Techniques 74
References 74
6 QUALITATIVE ANALYSIS 75
Retention Parameters 75
Relative Retention Parameters • 77
Two Column Plots 80
Other Methods of Qualitative Analysis 81
Chemical Methods 81
Instrumental Methods 82
References 87
Contents ix
7 QUANTITATIVE ANALYSIS 88
Detectors 88
Classification of Detectors 88
Detector Characteristics 92
Detector Specifications 95
Statistics of Quantitative Calculations 98
Quantitative Methods 101
Considerations in Setting Up a Method 101
Methods of Quantitative Analysis 103
References 107
8 GAS CHROMATOGRAPHY 109
Instrumentation 111
The Mobile Phase 111
Injection Ports and Valves 112
Columns 114
Detectors 121
Instrumentation Summary 131
The Stationary Phase 131
Typical Liquids 132
Rohrschneider/McReynolds Constants 137
Methods for Selecting Stationary Phases 141
Temperature Effects 144
Programmed Temperature GC (PTGC) 146
Special Topics 150
Inorganic GC 150
Inverse GC 150
Flow Programming 150
Preparative Scale GC 150
Other Special Techniques 150
Evaluation 151
References 151
9 LIQUID CHROMATOGRAPHY IN COLUMNS 154
Classification of LC Methods 154
Contents
Liquid-Solid Chromatography (LSC) 158
Liquid-Liquid Chromatography (LLC) 163
Bonded Phase Chromatography (BPC) 166
Ion Exchange Chromatography (IEC) 171
Size Exclusion Chromatography (SEC) 186
Instrumentation 193
Pumping Systems and the Mobile Phase 194
Sampling 197
Columns 199
Detectors 204
Mobile Phases and Their Selection 209
Classification of Solvent Properties 209
Overlapping Resolution Mapping 213
Phase Selection Diagrams 218
Sample Clean-Up and Preparative Isolation 219
Sample Clean-Up 220
Low Pressure Prep LC 220
High Performance Prep LC 222
Special Topics 224
Pseudophase or Micellar LC 224
Affinity Chromatography 224
Internal Surface Reverse Phase Supports 225
Instrumental Topics 226
Evaluation 227
References 228
10 LIQUID CHROMATOGRAPHY ON PLANE SURFACES 232
Theory 232
The Nature of Mobile Phase Flow 232
Other Comparisons with Column Methods 234
The Stationary Phase 236
Thin Layers 236
Paper 239
The Mobile Phase 241
Apparatus and Procedures 242
Contents xi
Sampling
Development
Visualization and Detection
Quantitative Analysis
Evaluation
References
Selected Bibliography
OTHER TOPICS
Supercritical Fluid Chromatography (SFC)
Principles of Operation
Instrumentation
Applications
Chromatography and On-line Mass Spec and Infrared
Requirements for Interfacing
GC/MS and GC/FTIR
LC/MS and LC/FTIR
SFC/MS and SFC/FTIR
Chiral Separations
Diastereomer Separations
Chiral Mobile Phases
Chiral Stationary Phases
Derivatization
Reasons for Derivatization
Methods
Examples
References
SELECTION OF A METHOD
Methods of Attack
Literature Searching
The Experimental Approach
Summary
References
Contents
APPENDIX 286
Typical Chromatographic Calculations 286
Calculations: Gas Chromatogram of Toluene 289
List of Symbols and Acronyms 290
INDEX 295
|
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id | DE-604.BV004124027 |
illustrated | Illustrated |
indexdate | 2024-07-09T16:08:45Z |
institution | BVB |
isbn | 0471848212 |
language | English |
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physical | XII, 297 S. graph. Darst. |
publishDate | 1988 |
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publisher | Wiley |
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series2 | A Wiley-Interscience publication |
spelling | Miller, James M. Verfasser aut Chromatography : concepts and contrasts James M. Miller New York u.a. Wiley 1988 XII, 297 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-Interscience publication Chromatographie (DE-588)4010153-8 gnd rswk-swf Flüssigkeitschromatographie (DE-588)4017622-8 gnd rswk-swf Gaschromatographie (DE-588)4019330-5 gnd rswk-swf Dünnschichtchromatographie (DE-588)4013227-4 gnd rswk-swf Dünnschichtchromatographie (DE-588)4013227-4 s DE-604 Flüssigkeitschromatographie (DE-588)4017622-8 s Gaschromatographie (DE-588)4019330-5 s Chromatographie (DE-588)4010153-8 s HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002573919&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Miller, James M. Chromatography : concepts and contrasts Chromatographie (DE-588)4010153-8 gnd Flüssigkeitschromatographie (DE-588)4017622-8 gnd Gaschromatographie (DE-588)4019330-5 gnd Dünnschichtchromatographie (DE-588)4013227-4 gnd |
subject_GND | (DE-588)4010153-8 (DE-588)4017622-8 (DE-588)4019330-5 (DE-588)4013227-4 |
title | Chromatography : concepts and contrasts |
title_auth | Chromatography : concepts and contrasts |
title_exact_search | Chromatography : concepts and contrasts |
title_full | Chromatography : concepts and contrasts James M. Miller |
title_fullStr | Chromatography : concepts and contrasts James M. Miller |
title_full_unstemmed | Chromatography : concepts and contrasts James M. Miller |
title_short | Chromatography : concepts and contrasts |
title_sort | chromatography concepts and contrasts |
topic | Chromatographie (DE-588)4010153-8 gnd Flüssigkeitschromatographie (DE-588)4017622-8 gnd Gaschromatographie (DE-588)4019330-5 gnd Dünnschichtchromatographie (DE-588)4013227-4 gnd |
topic_facet | Chromatographie Flüssigkeitschromatographie Gaschromatographie Dünnschichtchromatographie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002573919&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT millerjamesm chromatographyconceptsandcontrasts |