Modern supercritical fluid chromatography:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Heidelberg u.a.
Hüthig
1988
|
| Schriftenreihe: | Chromatographic methods
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XII, 239 S. Ill., graph. Darst. |
| ISBN: | 3778515691 |
Internformat
MARC
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| 245 | 1 | 0 | |a Modern supercritical fluid chromatography |c ed. by C. M. White |
| 264 | 1 | |a Heidelberg u.a. |b Hüthig |c 1988 | |
| 300 | |a XII, 239 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Chromatographic methods | |
| 500 | |a Literaturangaben | ||
| 650 | 4 | |a Chromatographie en phase supercritique | |
| 650 | 4 | |a Supercritical fluid chromatography | |
| 650 | 0 | 7 | |a Flüssigkeitschromatographie |0 (DE-588)4017622-8 |2 gnd |9 rswk-swf |
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| 700 | 1 | |a White, Curt M. |e Sonstige |4 oth | |
| 856 | 4 | 2 | |m HEBIS Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001604338&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-001604338 | ||
Datensatz im Suchindex
| _version_ | 1804116896887341056 |
|---|---|
| adam_text | IMAGE 1
MODERN SUPERCRITICAL
FLUID CHROMATOGRAPHY
EDITED BY C. M. WHITE WITH CONTRIBUTIONS BY M. ASHRAF-KHORASSANI, D. S.
BOYER, S. J. DELUCA, R. B. DENYSZYN, P. R. GRIFFITHS, J. P. GUZOWSKI, H.
H. HILL, JR., R. K. HOUCK, R. P. KHOSAH, E. KLESPER, J. M. LEVY,
K. L. MAGUIRE, M. MORRISSEY, F. PACHOLEC, G. L. PARIENTE, A. C.
ROSSELLI, F. P. SCHMITZ, H. E. SCHWARTZ, R. D. SMITH, L. T. TAYLOR, K.
J. VOORHEES, H. M. WIDMER, B. W. WRIGHT, AND S. D. ZAUGG
SFC-87 WAS SUPPORTED BY
DR. ALFRED HUTHIG VERLAG HEIDELBERG BASEL NEW YORK
IMAGE 2
IX
CONTENTS
1 INTRODUCTION TO COMPOSITION GRADIENTS IN SUPERCRITICAL FLUID CHRO-
MATOGRAPHY E. KLESPER AND F. P. SCHMITZ 1
1.1 INTRODUCTION 2
1.2 COMPOSITION GRADIENTS 4
1.3 MULTIPLE GRADIENTS CONTAINING COMPOSITION GRADIENTS 13
2 RECENT ADVANCES IN PACKED COLUMN SFC F. PACHOLEC, D. S. BOYER, R. K.
HOUCK, AND A. C. ROSSELLI 17
2.1 INTRODUCTION 19
2.2 PHYSICAL CHARACTERISTICS AND DIMENSIONS OF MODERN PACKED SFC COLUMNS
21
2.2.1 GENERAL 21
2.2.2 PARTICLE DIAMETER AND COLUMN LENGTH 22
2.2.3 COLUMN INTERNAL DIAMETER 24
2.3 MOBILE PHASES AND MODIFIERS 26
2.4 INERTNESS 29
2.5 REPRODUCIBILITY 31
2.6 SENSITIVITY 33
2.7 RESOLUTION 37
2.8 CONCLUSIONS 40
3 SOLUBILITY OF VARIOUS ORGANIC MODIFIERS IN LIQUID CARBON DIOXIDE K. L.
MAGUIRE AND R. B. DENYSZYN 45
3.1 INTRODUCTION 47
3.1.1 REVIEW OF PAST SOLUBILITY RESEARCH 47
3.1.2 THE PURPOSE OF USING POLAR MODIFIERS IN LIQUID CARBON DIOXIDE 49
3.2 DETERMINATION OF MODIFIER SOLUBILITY 50
3.2.1 EXPERIMENTAL SYSTEIN 50
3.2.2 EXPERIMENTAL MEASUREMENTS 52
3.3 RESULTS AND DISCUSSION 53
IMAGE 3
CONTENTS
3.3.1 METHANOL/CARBON DIOXIDE MIXTURE 53
3.3.2 ACETONITRILE/CARBON DIOXIDE MIXTURE 55
3.3.3 CHLOROFORM/CARBON DIOXIDE MIXTURE 55
3.3.4 COMPARISON OF RESULTS TO LITERATURE 56
3.4 CONCLUSION 57
4 SUPERCRITICAL FLUID CHROMATOGRAPHY/MASS SPECTROMETRY K. J. VOORHEES,
S. D. ZAUGG, AND S. J. DELUCA 59
4.1 INTRODUCTION 60
4.2 DIRECT FLUID INJECTION CHEMICAL IONIZATION MASS SPECTROMETRY .. 62
4.3 OTHER TYPES OF INTERFACES USED WITH CHEMICAL IONIZATION 64
4.4 DIRECT FLUID INJECTION ELECTRON IONIZATION MASS SPECTROMETRY . .. 69
4.5 COMMERCIAL INTERFACES V 76
4.6 SUMMARY 77
5 CAPILLARY SFC AND SFC/FT-IR WITH POLAR MOBILE PHASES G. L. PARIENTE
AND P. R. GRIFFITHS 81
5.1 INTRODUCTION 83
5.2 FUNDAMENTAL REQUIREMENTS WITH CC1 2 F 2 86
5.3 RETENTION BEHAVIOR WITH CC1 2 F 2 AS THE MOBILE PHASE 87
5.4 FT-IR IDENTIFICATION OF ELUITES WITH A POLAR MOBILE PHASE 90
6 ION MOBILITY SPECTROMETRY AS A DETECTION METHOD FOR SUPERCRITICAL
FLUID CHROMATOGRAPHY H. H. HILL, JR. AND M. MORRISSEY 95
6.1 INTRODUCTION 97
6.2 ION MOBILITY SPECTROMETRY 98
6.3 THE ION MOBILITY DRIFT GAS 98
. 6.4 MOBILITY VALUES 101
6.5 DETECTION OF COMPOUNDS WITHOUT CHROMOPHORES 104
6.6 MOLECULAR WEIGHT RANGE 107
6.7 SELECTIVE DETECTION 108
6.8 MOBILE PHASE COMPATIBILITY 109
IMAGE 4
CONTENTS XI
7 ELUTION BEHAVIOR OF NITROGEN-CONTAINING COMPOUNDS OF DIFFERENT
BASICITY FROM VARIOUS STATIONARY PHASES EMPLOYING A SUPERCRITICAL MOBILE
PHASE M. ASHRAF-KHORASSANI AND L. T. TAYLOR 115
7.1 INTRODUCTION 117
7.2 EXPERIMENTAL 118
7.3 RESULTS AND DISCUSSION 119
7.3.1 PRP-1 COLUMN 119
7.3.2 SILICA COLUMN 122
7.3.3 OCTADECYL COLUMN 124
7.3.4 PROPYLAMINO COLUMN 125
8 APPLICATIONS OF SFC IN THE PETROLEUM INDUSTRY H. E. SCHWARTZ, J. M.
LEVY, AND J. P. GUZOWSKI 135
8.1 INTRODUCTION 138
8.2 HYDROCARBON GROUP SEPARATIONS 139
8.3 ANALYSIS OF POLYNUCLEAR AROMATIC HYDROCARBONS 145
8.4 SIMULATED DISTILLATION (SIMDIS) 149
9 ANALYTICAL AND APPLIED SEPARATIONS WITH SUPERCRITICAL FLUIDS AND
ALUMINA R. P. KHOSAH 155
9.1 INTRODUCTION 157
9.2 EXPERIMENTAL PROCEDURE 159
9.2.1 APPARATUS 159
9.2.2 ANALYTICAL WORK 160
9.2.2.1 CAPILLARY COLUMN TECHNIQUES 160
9.2.2.2 PACKED COLUMN TECHNIQUES 160
9.2.3 ADSORPTION/DESORPTION AND PURIFICATION STUDIES 160
9.3 RESULTS AND DISCUSSION: ANALYTICAL WORK 160
9.3.1 CAPILLARY COLUMNS 160
9.3.1.1 SAMPLE INTRODUCTION 161
9.3.1.2 FILM THICKNESS AN DIAMETER 162
9.3.1.3 LENGTH 162
9.3.1.4 OPERATING PARAMETERS 162
9.3.1.5 SAMPLE ANALYSIS 163
IMAGE 5
XII CONTENTS
9.3.1.5.1 POLYPROPYLENE GLYCOL (PPG-425) 163
9.3.1.5.2 POLYETHYLENE GLYCOLS (PEG) 166
9.3.1.5.3 TRITON X-100 168
9.3.1.5.4 LUBRICANT MATERIALS 169
9.3.1.5.5 POLY(A-OLEFINS) 172
9.3.1.5.6 FISH OILS 174
9.3.2 PACKED COLUMN SFC 174
9.3.3 APPLIED SEPARATIONS 179
9.4 CONCLUSIONS 183
10 RESTRICTOR PERFORMANCE CHARACTERISTICS FOR SFC B. W. WRIGHT AND R. D.
SMITH 189
10.1 INTRODUCTION 191
10.2 * THERMODYNAMICS 192
10.2.1 ESTIMATION OF FLOW RATES THROUGH SFC RESTRICTORS 194
10.3 TRANSPORT OF NONVOLATILE COMPOUNDS THROUGH RESTRICTORS 198 10.3.1
CLUSTER FORMATION DURING EXPANSION 201
10.4 PRACTICAL RESTRICTORS FOR SFC 202
10.5 QUALITATIVE RESTRICTOR EVALUATION 204
10.6 CONCLUSIONS 208
11 INDUSTRIAL SIGNIFICANCE OF SUPERCRITICAL FLUID CHROMATOGRAPHY H. M.
WIDMER 211
11.1 INTRODUCTION 212
11.2 SUPERCRITICAL FLUIDS IN THE CONTEXT OF THE OPPORTUNITIES AND NEEDS
OF MODERN ANALYTICAL CHEMISTRY 213
11.3 CAPILLARY SFC 214
11.4 SFC WITH PACKED COLUMNS 216
11.5 HYPENATED SFC TECHNIQUES 218
SUBJECT INDEX 233
|
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| genre | (DE-588)1071861417 Konferenzschrift 1987 Pittsburgh Pa. gnd-content |
| genre_facet | Konferenzschrift 1987 Pittsburgh Pa. |
| id | DE-604.BV002489033 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:45:48Z |
| institution | BVB |
| isbn | 3778515691 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001604338 |
| oclc_num | 18955142 |
| open_access_boolean | |
| owner | DE-384 DE-355 DE-BY-UBR DE-29T DE-11 DE-188 |
| owner_facet | DE-384 DE-355 DE-BY-UBR DE-29T DE-11 DE-188 |
| physical | XII, 239 S. Ill., graph. Darst. |
| publishDate | 1988 |
| publishDateSearch | 1988 |
| publishDateSort | 1988 |
| publisher | Hüthig |
| record_format | marc |
| series2 | Chromatographic methods |
| spelling | Modern supercritical fluid chromatography ed. by C. M. White Heidelberg u.a. Hüthig 1988 XII, 239 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chromatographic methods Literaturangaben Chromatographie en phase supercritique Supercritical fluid chromatography Flüssigkeitschromatographie (DE-588)4017622-8 gnd rswk-swf SFC (DE-588)4184106-2 gnd rswk-swf (DE-588)1071861417 Konferenzschrift 1987 Pittsburgh Pa. gnd-content SFC (DE-588)4184106-2 s DE-604 Flüssigkeitschromatographie (DE-588)4017622-8 s White, Curt M. Sonstige oth HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001604338&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Modern supercritical fluid chromatography Chromatographie en phase supercritique Supercritical fluid chromatography Flüssigkeitschromatographie (DE-588)4017622-8 gnd SFC (DE-588)4184106-2 gnd |
| subject_GND | (DE-588)4017622-8 (DE-588)4184106-2 (DE-588)1071861417 |
| title | Modern supercritical fluid chromatography |
| title_auth | Modern supercritical fluid chromatography |
| title_exact_search | Modern supercritical fluid chromatography |
| title_full | Modern supercritical fluid chromatography ed. by C. M. White |
| title_fullStr | Modern supercritical fluid chromatography ed. by C. M. White |
| title_full_unstemmed | Modern supercritical fluid chromatography ed. by C. M. White |
| title_short | Modern supercritical fluid chromatography |
| title_sort | modern supercritical fluid chromatography |
| topic | Chromatographie en phase supercritique Supercritical fluid chromatography Flüssigkeitschromatographie (DE-588)4017622-8 gnd SFC (DE-588)4184106-2 gnd |
| topic_facet | Chromatographie en phase supercritique Supercritical fluid chromatography Flüssigkeitschromatographie SFC Konferenzschrift 1987 Pittsburgh Pa. |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001604338&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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