Inorganic reactions and methods: 15 Electron-transfer and electrochemical reactions ; photochemical and other energized reactions
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Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Weinheim [u.a.]
VCH Verlagsges.
1986
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XXIII, 399 S. graph. Darst. |
ISBN: | 0895732653 3527262733 |
Internformat
MARC
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245 | 1 | 0 | |a Inorganic reactions and methods |n 15 |p Electron-transfer and electrochemical reactions ; photochemical and other energized reactions |c ed. J. J. Zuckerman |
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adam_text | INORGANIC REACTIONS AND METHODS VOLUME 15 ELECTRON-TRANSFER AND
ELECTROCHEMICAL REACTIONS; PHOTOCHEMICAL AND OTHER ENERGIZED REACTIONS
EDITOR J.J. ZUCKERMAN SUBJECT INDEX EDITOR A.P. HAGEN CONTENTS OF VOLUME
15 HOW TO USE THIS BOOK XI PREFACE TO THE SERIES XVII EDITORIAL
CONSULTANTS TO THE SERIES XXI CONTRIBUTORS TO VOLUME 15 XXIII 12.
ELECTRON-TRANSFER AND ELECTROCHEMICAL REACTIONS 1 12.1. INTRODUCTION 2
12.2. ELECTRON TRANSFER 3 12.2.1. INTRODUCTION 3 12.2.2. CLASSIFICATION
OF ELECTRON-TRANSFER REACTIONS 3 12.2.2.1. OUTER-SPHERE REACTIONS 5
12.2.2.1.1. EXAMPLES OF OUTER-SPHERE REACTIONS 6 12.2.2.1.2.
OUTER-SPHERE TRANSITION STATES 7 12.2.2.2. INNER-SPHERE REACTIONS 9
12.2.2.2.1. INNER-SPHERE REACTIONS: SCHEME I 11 12.2.2.2.2. INNER-SPHERE
REACTIONS: SCHEME II 11 12.2.2.2.3. INNER-SPHERE REACTIONS: SCHEME III
12 12.2.2.2.4. DOUBLE-LIGAND BRIDGING 14 12.2.2.3. OTHER REACTION
CLASSES 14 12.2.2.3.1. MIXED OUTER-AND INNER-SPHERE REACTIONS 14
12.2.2.3.2. INTRAMOLECULAR ELECTRON TRANSFER 14 12.2.2.3.3. TWO-ELECTRON
TRANSFERS 16 12.2.3. THEORY OF ELECTRON-TRANSFER REACTIONS 16 12.2.3.1.
THE STABILITY OF THE PRECURSOR COMPLEX 17 12.2.3.2. POTENTIAL-ENERGY
SURFACES 20 12.2.3.2.1. OFZERO ORDER. 20 12.2.3.2.2. OF FIRST ORDER. 22
12.2.3.2.3. _ THE ELECTRONIC FACTOR 23 12.2.3.3. ELECTRON-EXCHANGE
REACTIONS 24 12.2.3.3.1. THE REORGANIZATION ENERGY 26 12.2.3.3.2.
NUCLEAR TUNNELING IN ELECTRON EXCHANGE 29 12.2.3.3.3. QUANTUM-MECHANICAL
TREATMENT 30 12.2.3.3.4. COMPARISON OF OBSERVED AND CAICULATED
PARAMETERS FOR ELECTRON EXCHANGE 32 CONTENTS OF VOLUME 15 ELECTRON
TRANSFER THEORY OF ELECTRON-TRANSFER REACTIONS 12.2.3.4. ELECTRON
TRANSFER ACCOMPANIED BY A NET CHEMICAL CHANGE 37 12.2.3.4.1.
SEMICLASSICAL TREATMENT 39 12.2.3.4.2. CROSS REACTIONS AND
ELECTRON-EXCHANGE RATES 41 12.2.3.4.3. QUANTUM-MECHANICAL TREATMENT 45
12.2.3.5. CONCLUSIONS 46 12.2.4. GENERAL REACTIVITY PATTERNS IN ELECTRON
TRANSFER 47 12.2.4.1. THE INNER-SHELL REORGANIZATION ENERGY: EXCHANGE
RATES OF AQUO IONS 49 12.2.4.2. VARIATIONS WITH LIGAND: THE OUTER-SHELL
REORGANIZATION ENERGY 53 12.2.4.3. ELECTRONIC FACTORS: NONADIABATICITY
58 12.2.4.4. FREE-ENERGY RELATIONS 59 12.2.4.5. INNER-SPHERE VERSUS
OUTER-SPHERE ELECTRON TRANSFER 64 12.2.4.6. RATE SATURATION IN ELECTRON
TRANSFER 65 12.2.5. SPECIFIC REACTIVITY PATTERNS IN ELECTRON-TRANSFER
REACTIONS 68 12.2.5.1. VARIATION WITH THE REDUCTANT 68 12.2.5.1.1.
ONE-ELECTRON REDUCTANTS 68 12.2.5.1.2. TWO-ELECTRON REDUCTANTS 78
12.2.5.2. VARIATION WITH THE OXIDANT 78 12.2.5.2.1. ONE-ELECTRON
OXIDANTS 78 12.2.5.2.2. MULTIPLE-ELECTRON OXIDANTS 81 12.2.5.3.
OXIDATION AND REDUCTION OF COORDINATED LIGANDS 82 12.2.5.4. CATALYSIS IN
ELECTRON-TRANSFER REACTIONS 83 12.2.5.4.1. CATALYZED ELECTRON TRANSFER
83 12.2.5.4.2. CATALYZED LIGAND SUBSTITUTION 84 12.2.5.5. INDUCED
ELECTRON-TRANSFER REACTIONS 85 12.2.5.6. PHOTOINDUCED ELECTRON-TRANSFER
REACTIONS 86 12.3. ELECTROCHEMICAL REACTIONS 88 12.3.1. INTRODUCTION 88
12.3.1.1. THE ELECTRODE PROCESS 88 12.3.1.2. REVERSIBILITY 89
12.3.1.2.1. ELECTROCHEMICAL REVERSIBILITY 89 12.3.1.2.2. CHEMICAL
REVERSIBILITY 90 12.3.1.3. COMPLEX ELECTRODE MECHANISMS 91 12.3.2.
DIAGNOSTIC ELECTROCHEMICAL MEASUREMENTS 91 12.3.2.1. VOLTAMMETRIC
METHODS 91 12.3.2.1.1. DIRECT-CURRENT POLAROGRAPHY 91 12.3.2.1.2.
PULSE-POLAROGRAPHIC METHODS 100 CONTENTS OF VOLUME 15 VII 12.3.2.1.3.
ALTERNATING-CURRENT POLAROGRAPHY 107 12.3.2.1.4. CYCLIC VOLTAMMETRY 110
12.3.3. EVALUATION OF FORMAL POTENTIALS 116 12.3.3.1. INVOLVING STABLE
REACTANTS AND PRODUCTS. 116 12.3.3.2. INVOLVING UNSTABLE ELECTRODE
PRODUCTS. 118 12.3.3.3. INVOLVING REACTANTS UNDERGOING MULTIPLE-
ELECTRODE REACTIONS. 123 12.3.4. CHEMICAL REACTIONS ACCOMPANYING
ELECTRODE REACTIONS 128 12.3.4.1. REACTIONS PRECEDING ELECTRON TRANSFER
(CE) 128 12.3.4.1.1. SLOW-REACTION (1 12.3.4.1.2. FAST-REACTION (1
A) LIMIT 130 12.3.4.1.3. INTERMEDIATE-REACTION KINETICS 130 12.3.4.2.
REACTIONS FOLLOWING ELECTRON TRANSFER (EC) 133 12.3.4.2.1. GIVING
ELECTROINACTIVE PRODUCTS. 133 12.3.4.2.2. GIVING ELECTROACTIVE PRODUCTS
(ECE). 135 12.3.4.3. OTHER COUPLED CHEMICAL REACTIONS 141 12.3.5.
ELECTROCHEMICAL SYNTHESIS 142 12.3.5.1. BY CONTROLLED-POTENTIAL
ELECTROLYSIS. 142 12.3.5.2. INVOLVING BULK PREPARATIONS. 145 12.3.5.3.
CONCLUSIONS 147 12.3.6. THERMODYNAMICS OF SIMPLE ELECTROCHEMICAL
REACTIONS 147 12.3.7. KINETICS OF ELECTROCHEMICAL REACTIONS 150
12.3.7.1. BASIC CHARACTERISTICS 151 12.3.7.2. THEORY OF HETEROGENEOUS
ELECTRON-TRANSFER REACTIONS 153 12.3.7.3. DOUBLE-LAYER EFFECTS IN
ELECTROCHEMICAL KINETICS 164 12.3.7.4. ELECTRODE-REACTION MECHANISMS 165
12.3.7.5. INFLUENCE OF THE ELECTRODE MATERIAL 168 12.3.7.6.
ELECTROCHEMICAL REACTIVITY PATTERNS* COMPARISONS WITH HOMOGENEOUS
REACTIVITIES 171 13. PHOTOCHEMICAL AND OTHER ENERGIZED REACTIONS 175
13.1. INTRODUCTION 176 13.2. PHOTOSUBSTITUTION AND PHOTOISOMERIZATION
177 13.2.1. WITH GROUP VIA COMPLEXES 179 13.2.1.1. OF CHROMIUM(LLL). 179
13.2.1.2. OF MOLYBDENUM AND TUNGSTEN. 183 VIII CONTENTS OF VOLUME 15
13.2.2. 13.2.3. 13.2.3.1. 13.2.3.2. 13.2.3.3. 13.2.3.4. 13.2.3.5.
13.2.3.6. 13.2.3.7. 13.2.3.8. 13.2.4. 13.2.4.1. 13.2.4.1.1. 13.2.4.1.2.
13.2.4.1.3. 13.2.4.1.4. 13.2.4.1.5. 13.2.4.1.6. 13.2.4.1.7. 13.2.4.2.
13.2.4.3. 13.2.5. 13.2.5.1. 13.2.5.2. 13.2.5.3. 13.2.5.4. 13.2.5.5.
PHOTOSUBSTITUTION AND PHOTOISOMERIZATION WITH GROUP VIIA COMPLEXES. WITH
GROUP VIII COMPLEXES OF IRON. OF RUTHENIUM. OF OSMIUM. OF COBALT. OF
RHODIUM(LLL) AND IRIDIUM(LLL). OF NICKEL(LL) AND PALLADIUM(LL). OF
PLATINUM(LL). OF PLATINUM(IV). WITH METAL CARBONYLS INVOLVING
MONONUCLEAR COMPLEXES OF TITANIUM, ZIRCONIUM AND HAFNIUM. OF VANADIUM,
NIOBIUM AND TANTALUM. OF CHROMIUM, MOLYBDENUM AND TUNGSTEN. OF MANGANESE
AND RHENIUM. OF IRON, RUTHENIUM AND OSMIUM. OF COBALT, RHODIUM AND
IRIDIUM. OF NICKEL. INVOLVING DINUCLEAR COMPLEXES. INVOLVING POLYNUCLEAR
COMPLEXES. WITH OTHER ORGANOMETALLIC COMPLEXES CONTAINING METAL
HYDRIDES. CONTAINING ISOCYANIDES. CONTAINING OLEFINS. CONTAINING ARENES
AND CYCLOPENTADIENYLS. CONTAINING ALKYLS. 184 184 185 186 190 190 195
198 199 202 204 204 205 206 209 217 221 225 226 226 229 230 230 235 236
240 242 13.3. PHOTOINDUCED CLEAVAGE OF METAL-METAL BONDS 246 13.3.1.
13.3.1.1. 13.3.1.1.1. 13.3.1.1.2. 13.3.1.1.3. 13.3.1.1.4. 13.3.1.1.5.
13.3.1.2. 13.3.2. IN DINUCLEAR COMPLEXES 246 THAT ARE HOMONUCLEAR 246
AND CONTAIN CHROMIUM, MOLYBDENUM AND TUNGSTEN. 246 AND CONTAIN
MANGANESE, TECHNETIUM AND RHENIUM. 248 AND CONTAIN IRON AND RUTHENIUM.
252 AND CONTAIN COBALT. 254 AND CONTAIN NICKEL, PALLADIUM AND PLATINUM.
255 THAT ARE HETERONUCLEAR. 256 IN POLYNUCLEAR COMPLEXES. 257 CONTENTS
OF VOLUME 15 IX 13.4. PHOTOINDUCED ELECTRON-TRANSFER REACTIONS 260
13.4.1. EXCITED-STATE ASSIGNMENTS 260 13.4.2. EXCITED-STATE ELECTRON
EXCHANGE 262 13.4.3. QUENCHING AND BACK REACTIONS 265 13.4.4.
FREE-ENERGY RELATIONS 269 13.5. 13.5.1. 13.5.2. 13.5.3. 13.5.4.
13.5.4.1. 13.5.4.2. 13.5.4.3. 13.5.4.4. 13.5.5. 13.5.5.1. 13.5.5.2.
13.5.5.3. 13.5.5.4. 13.5.5.5. 13.5.5.5.1. 13.5.5.5.2. 13.5.5.6.
13.5.5.6.1. 13.5.5.6.2. 13.5.5.7. 13.5.5.7.1. 13.5.5.7.2. 13.5.5.7.3.
13.5.5.7.4. 13.5.5.7.5. 13.5.5.7.6. 13.5.5.7.7. 13.5.5.7.8. 13.5.5.8.
13.5.5.8.1. 13.5.5.8.2. 13.5.5.8.3. 13.5.5.9. 13.5.5.9.1. 13.5.5.9.2.
13.5.5.9.3. PULSE RADIOLYSIS INTRODUCTION PRINCIPLES TECHNIQUES BY
RADIATION GENERATION OF HYDRATED ELECTRONS. OF HYDROXYL RADICALS. OF
HYDROGEN ATOMS. OF SECONDARY RADICALS. OF METAL COMPLEXES INVOLVING
GROUPS IA AND IIA. INVOLVING GROUP IIIA. INVOLVING GROUP IVA. INVOLVING
GROUP VA. INVOLVING GROUP VIA WITH CHROMIUM. WITH MOLYBDENUM AND
TUNGSTEN. INVOLVING GROUP VIIA WITH MANGANESE. WITH TECHNETIUM.
INVOLVING GROUP VIIIA WITH IRON. WITH RUTHENIUM. WITH OSMIUM. WITH
COBALT. WITH RHODIUM. WITH IRIDIUM. WITH NICKEL. WITH PALLADIUM AND
PLATINUM. INVOLVING GROUP IB WITH COPPER. WITH SILVER. WITH GOLD.
INVOLVING GROUP IIB WITH ZINC. WITH CADMIUM. WITH MERCURY. 272 272 272
273 274 274 274 275 275 276 277 277 277 277 278 278 279 280 280 280 281
281 282 284 284 288 289 289 290 291 291 292 293 293 293 294 294 CONTENTS
OF VOLUME 15 PULSE RADIOLYSIS OF METAL COMPLEXES 13.5.5.10. INVOLVING
GROUP HIB 13.5.5.10.1. WITH GALLIUM. 13.5.5.10.2. WITH INDIUM.
13.5.5.10.3. WITH THALLIUM. 13.5.5.11. INVOLVING GROUP IVB 13.5.5.11.1.
WITHTIN. 13.5.5.11.2. WITH LEAD. 13.5.5.12. INVOLVING LANTHANIDES.
13.5.5.13. INVOLVING ACTINIDES. 295 295 295 295 296 296 296 296 297 LIST
OF ABBREVIATIONS AUTHOR INDEX COMPOUND INDEX SUBJECT INDEX 299 305 333
395
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id | DE-604.BV002395312 |
illustrated | Illustrated |
indexdate | 2024-07-09T15:44:38Z |
institution | BVB |
isbn | 0895732653 3527262733 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001557006 |
oclc_num | 473043658 |
open_access_boolean | |
owner | DE-12 DE-703 DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-384 DE-19 DE-BY-UBM DE-634 DE-11 |
owner_facet | DE-12 DE-703 DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-384 DE-19 DE-BY-UBM DE-634 DE-11 |
physical | XXIII, 399 S. graph. Darst. |
publishDate | 1986 |
publishDateSearch | 1986 |
publishDateSort | 1986 |
publisher | VCH Verlagsges. |
record_format | marc |
spelling | Inorganic reactions and methods 15 Electron-transfer and electrochemical reactions ; photochemical and other energized reactions ed. J. J. Zuckerman Weinheim [u.a.] VCH Verlagsges. 1986 XXIII, 399 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Fotochemische Reaktion (DE-588)4138378-3 gnd rswk-swf Elektrochemische Reaktion (DE-588)4151764-7 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Elektrochemische Reaktion (DE-588)4151764-7 s DE-604 Fotochemische Reaktion (DE-588)4138378-3 s Elektronentransfer (DE-588)4151907-3 s Zuckerman, Jerry J. Sonstige oth (DE-604)BV002395307 15 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001557006&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Inorganic reactions and methods Fotochemische Reaktion (DE-588)4138378-3 gnd Elektrochemische Reaktion (DE-588)4151764-7 gnd Elektronentransfer (DE-588)4151907-3 gnd |
subject_GND | (DE-588)4138378-3 (DE-588)4151764-7 (DE-588)4151907-3 |
title | Inorganic reactions and methods |
title_auth | Inorganic reactions and methods |
title_exact_search | Inorganic reactions and methods |
title_full | Inorganic reactions and methods 15 Electron-transfer and electrochemical reactions ; photochemical and other energized reactions ed. J. J. Zuckerman |
title_fullStr | Inorganic reactions and methods 15 Electron-transfer and electrochemical reactions ; photochemical and other energized reactions ed. J. J. Zuckerman |
title_full_unstemmed | Inorganic reactions and methods 15 Electron-transfer and electrochemical reactions ; photochemical and other energized reactions ed. J. J. Zuckerman |
title_short | Inorganic reactions and methods |
title_sort | inorganic reactions and methods electron transfer and electrochemical reactions photochemical and other energized reactions |
topic | Fotochemische Reaktion (DE-588)4138378-3 gnd Elektrochemische Reaktion (DE-588)4151764-7 gnd Elektronentransfer (DE-588)4151907-3 gnd |
topic_facet | Fotochemische Reaktion Elektrochemische Reaktion Elektronentransfer |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001557006&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV002395307 |
work_keys_str_mv | AT zuckermanjerryj inorganicreactionsandmethods15 |