Optical circular dichroism: principles, measurements and applications ; [with ... 10 tables]
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim, Bergstr.
Verl. Chemie
1965
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 247 S. graph. Darst. |
Internformat
MARC
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| 245 | 1 | 0 | |a Optical circular dichroism |b principles, measurements and applications ; [with ... 10 tables] |c by Léon Velluz ; Maurice Legrand and Marc Grosjean |
| 264 | 1 | |a Weinheim, Bergstr. |b Verl. Chemie |c 1965 | |
| 300 | |a XII, 247 S. |b graph. Darst. | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | OPTICAL CIRCULAR DICHROISM
PRINCIPLES,MEASUREMENTS,ANDAPPLICATIONS
by
r
LEONVELLUZ
Member of the Acad, des Sc , Paris
MAURICELEGRANDandMARCGROSJEAN
Docteur - Ingenieur, Paris Docteur - Ingenieur, Nancy
Translated from the French manuscript by
DR JOHN MACCORDICK
Heidelberg
VERLAGCHEMIE • G M B
ACADEMICPRESSINC •
/
H • WEINHEIM/BERGSTR
NEWYORKANDLONDON
Table of Contents
Introduction VII
I From Rotatory Power to Circular Dichroism 1
A Rotatory Power 1
B Rotatory Dispersion 3
C Circular Dichroism : 5
D Molecular Interpretation 6
II Relationships between Rotatory Dispersion and Circular Dichroism 9
A Definitions of Phenomena 9
B Origin of Phenomena 12
1 The Role of Valence Electrons 12
2 Concept of an Optically Active Chromophore 14
C Relationship with Absorption in Natural Light • • • 6
D Scope of Application 17
III The Measurement of Optical Circular Dichroism 21
A The Action of a Dichroic Material upon Light 21
1 Circularly Polarized Light 21
2 Plane-Polarized Light 22
3 Elliptical Light 24
4 Natural Light 24
5 Measurement of Absorption 25
6 Materials Exhibiting Circular Dichroism 26
B Measurement of Circular Dichroism in the Visible and Ultraviolet Spectral
Regions 26
1 Difficulties of Measurement 26
2 Circular and Elliptical Polarizers 27
3 Circular and Elliptical Analyzers 29
C Polarizers for Use in the Visible and Ultraviolet Spectral Regions 31
1 Total Reflection Polarizers 31
a The Classical Glazebrook Prism 31
b The Glan Prism 32
2 Double-Image Polarizers 33
a The Birefringent Prism 33
b Rochon and Wollaston Prisms 34
c The Total Reflection Separating Prism 35
3 Dichroic Polarizers 36
X _ Table of Contents
D Quarter-Wave Systems 37
1 Thin Crystalline Plates 37
2 The Fresnel Rhomb ! 38
3 Systems Utilizing the Electro-Optic Effect of Crystals (Pockels Effect) 40
a Uniaxial Crystals Ammonium Dihydrogen Phosphate 40
b Cubic Crystals 46
E Measuring Devices 46
1 Visual Measurement (Bruhat s Device) 46
2 Photographic Measurement (ICuhn and Braun s Device) 49
3 Photoelectric Measurement , 51
a The First Device of Badoz, Billardon, and Mathieu 51
b The Second Device of Badoz, Billardon, and Mathieu 52
c Mitchell s Device 52
d Spectrophotometric Devices 53
e Rosenheck and Doty s Device 55
4 Conclusions 56
F Our Measuring Equipment 57
1 Principles 57
2 Description of the Optics 57
3 Description of the Electronics 60
4 Factors Affecting the Precision of Measurement 63
a Rotation of Materials 63
b Stray Birefringences of the Optical Elements 64
c Imperfections in the Circular Polarizer System 66
d Background Noise 67
e Optical Bandwidth Stray Light 69
f Supplementary Absorption Fluorescence Suspensions 72
G Nomenclature 73
1 The Choice of Variable 73
2 Description of Graphs 75
3 Abbreviated Notation for Publications 76
IV Optically Active Structures Containing Carbonyl Functions 79
A The Carbonyl Chromophore 79
1 Transitions 79
2 Solvent Effects 81
3 Conjugation Effects 81
4 The Concept of Normalized Curves 82
B Studies of the Steroid Cyclohexanones 83
1 Discussion of Results 83
2 The Octant Rule 88
3 Examples of Applications 90
a Configuration at the Junction of Two Rings 90
b Location of a Carbonyl Group •; 93
c Orientation of Substituents in the a Position 95
d Special Case of 11-Keto Steroids 97
I! !: !;!! || •«; ;;
Table of Contents XI
C Studies of Steroid Cyclopentanones 99
117-and16-Ketones99
2 The Influence of Asymmetric Centers 101
D Studies of the Steroid Alkyl Ketones 103
1 Discussion of Results 103
2 Application of the Octant Rule 106
a The Case of Simple 20-0xopregnanes 106
b The Case of 17a-Hydroxy Derivatives 107
c The Case of 17a,21-Dihydroxy Derivatives 108
3 Example of Application 108
E Studies of Steroid Diketones 110
F Studies of Steroid Ketones with 4- or 7-Membered Rings 114
1 Steroids with a 4-Membered Ring D 114
2 Steroids with a 7-Membered Ring C 116
G Studies of a-Bromo, a-Epoxy, and Conjugated Steroid Ketones 120
1 a-Bromo Ketones 120
2 a-Epoxy Ketones 123
3 Conjugated Ketones 126
H Conformational Analysis in the Terpene Series * 134
I Studies of Conjugated Carboxylic Acids 139
O
V Studies of Several Groups with No Absorption between 2200 A and
the Visible Region 143
A The Hydroxyl Group 145
1 Xanthates 145
2 Nitrous Esters 149
B The Amino Group 154
1 Alkyl Dithiocarbamates 154
2 /V-Salicyiidenes 156
3 Nitrosamines 159
4 Thiohydantoins and N-Thionocarbethoxy Derivatives 162
C The Carboxyl Group 164
VI Studies of Several Natural Products with Complex Chromophores 167
A Cobalamins 167
1 Cyanocobalamin 167
2 Dicyano Derivatives 169
3 Influence of the Medium 171
4 Aquocobalamin 173
5 Conformational Studies of the Cobalticotrin Nucleus 174
6 Discussion of the Aquocobalamin Structure 175
B Natural Hydro xyanthraquinone Pigments 178
1 Measurements and Results 179
2 Choice of Configuration 180
XU Table of Contents
C Polypeptides, Proteins, and Nucleic Acids 182
1 Polypeptides and Proteins 182
2 Polynucleotides and Nucleic Acids 184
VII Effects of Various Physical Factors 189
• A Concentration 189
B Temperature 193
C Solvents 195
VIII Molecular Theories of Optical Activity 201
Appendix Optical Circular Dichroism of Some Products 211
A Saturated Monoketones 211
B Unsaturated Monoketones 217
C Diketones 224
D Triketones 233
£ Derivatives of Alcohols (Nitrites) 238
F Derivatives of Amines (N-Dithiocarbomethoxy and TV-Salicylidene) 240
G Derivatives of Amides (Nitroso Compounds) 241
Author Index 243
Subject Index 245
|
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| discipline | Chemie / Pharmazie Physik Chemie |
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| indexdate | 2024-07-09T15:43:18Z |
| institution | BVB |
| language | English |
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| physical | XII, 247 S. graph. Darst. |
| publishDate | 1965 |
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| spelling | Velluz, Léon Verfasser aut Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] by Léon Velluz ; Maurice Legrand and Marc Grosjean Weinheim, Bergstr. Verl. Chemie 1965 XII, 247 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zirkulardichroismus (DE-588)4010215-4 gnd rswk-swf Zirkulardichroismus (DE-588)4010215-4 s DE-604 Legrand, Maurice Verfasser aut Grosjean, Marc Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001498888&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Velluz, Léon Legrand, Maurice Grosjean, Marc Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] Zirkulardichroismus (DE-588)4010215-4 gnd |
| subject_GND | (DE-588)4010215-4 |
| title | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] |
| title_auth | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] |
| title_exact_search | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] |
| title_full | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] by Léon Velluz ; Maurice Legrand and Marc Grosjean |
| title_fullStr | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] by Léon Velluz ; Maurice Legrand and Marc Grosjean |
| title_full_unstemmed | Optical circular dichroism principles, measurements and applications ; [with ... 10 tables] by Léon Velluz ; Maurice Legrand and Marc Grosjean |
| title_short | Optical circular dichroism |
| title_sort | optical circular dichroism principles measurements and applications with 10 tables |
| title_sub | principles, measurements and applications ; [with ... 10 tables] |
| topic | Zirkulardichroismus (DE-588)4010215-4 gnd |
| topic_facet | Zirkulardichroismus |
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