The chemistry of niobium and tantalum:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
1967
|
| Series: | Topics in inorganic and general chemistry
10 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | VIII, 243 S. |
Staff View
MARC
| LEADER | 00000nam a2200000 cb4500 | ||
|---|---|---|---|
| 001 | BV002278925 | ||
| 003 | DE-604 | ||
| 005 | 20130616 | ||
| 007 | t | ||
| 008 | 890928s1967 |||| 00||| eng d | ||
| 035 | |a (OCoLC)687086 | ||
| 035 | |a (DE-599)BVBBV002278925 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-355 |a DE-19 |a DE-83 |a DE-11 |a DE-188 |a DE-210 | ||
| 050 | 0 | |a QD181.N3 | |
| 082 | 0 | |a 546/.524 | |
| 084 | |a VH 8072 |0 (DE-625)147349: |2 rvk | ||
| 084 | |a WER 372f |2 stub | ||
| 084 | |a WER 368f |2 stub | ||
| 084 | |a CHE 373f |2 stub | ||
| 100 | 1 | |a Fairbrother, Fred |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The chemistry of niobium and tantalum |c F. Fairbrother |
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1967 | |
| 300 | |a VIII, 243 S. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Topics in inorganic and general chemistry |v 10 | |
| 650 | 7 | |a Chemie |2 gtt | |
| 650 | 7 | |a Metais E Seus Compostos (Quimica) |2 larpcal | |
| 650 | 7 | |a Niobium |2 gtt | |
| 650 | 7 | |a Quimica Inorganica |2 larpcal | |
| 650 | 7 | |a Tantalium |2 gtt | |
| 650 | 4 | |a Niobium | |
| 650 | 4 | |a Tantalum | |
| 650 | 0 | 7 | |a Niobverbindungen |0 (DE-588)4280031-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Tantalverbindungen |0 (DE-588)4184437-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Tantal |0 (DE-588)4059023-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Niob |0 (DE-588)4042362-1 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Tantalverbindungen |0 (DE-588)4184437-3 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Tantal |0 (DE-588)4059023-9 |D s |
| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Niobverbindungen |0 (DE-588)4280031-6 |D s |
| 689 | 2 | |5 DE-604 | |
| 689 | 3 | 0 | |a Niob |0 (DE-588)4042362-1 |D s |
| 689 | 3 | |5 DE-604 | |
| 830 | 0 | |a Topics in inorganic and general chemistry |v 10 |w (DE-604)BV001888756 |9 10 | |
| 856 | 4 | 2 | |m HEBIS Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497407&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 940 | 1 | |q HUB-ZB011200803 | |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-001497407 | ||
Record in the Search Index
| _version_ | 1804116737306656768 |
|---|---|
| adam_text | THE CHEMISTRY OF
NIOBIUM AND TANTALUM
BY
F FAIRBROTHER, D Sc ,FRIC
Professor Emeritus,
University of Manchester (Great Britain)
ELSEVIER PUBLISHING COMPANY
AMSTERDAM/LONDON/NEWYORK
Contents
Preface , v
Introduction 1
Chapter ] Separation and Extraction Metallurgy 7
a Separation of the metals 7
b Extraction of the metals 10
References 14
Chapter 2 Physical Properties of the Metals 16
References 18
Chapter 3 Oxygen Compounds 20
a Anhydrous oxides 20
b Hydrous oxides 33
c Niobates and tantalates 36
(i) Water-soluble niobates, 36 - (ii) Water-soluble tantalates, 40 - (iii) An
hydrous niobates and tantalates (mixed oxides), 41 - (iv) Niobium and
tantalum bronzes, 47
d Hydrous oxide complexes 47
(i) a-Hydroxy-acid complexes, 47 - (ii) Di-ol complexes, 51 - (iii) Inorganic-
acid complexes, 53 - (iv) Amine complexes, 54 - (v j Water-insoluble com
plexes, 56
e Tropolone complexes 56
f Alkoxides and related compounds 58
g Nitrato and phosphato compounds 62
(i) Nitrates, 62 - (ii) Phosphates, 63
h Antimony-oxygen compounds 65
i Sulphato complexes 65
j Peroxo compounds 67
References 68
Chapter 4 Halogen Compounds 74
A Pentahalides and Their Derivatives
1 Pentafluorides 74
a Preparation 74
b Physical properties 76
c Chemical properties 78
(i) Reactions with non-ionic ligands, 78 - (ii) Reactions with ionic ligands,
80 - (iii) Niobium (V) and tantalum (V) oxide fluorides, 85
2 Pentachlorides 86
a Preparation 86
(i) From the metals, 86 - (ii) From the anhydrous or liydrous pentoxides, 86
b Physical properties 88
c Chemical properties 94
(i) Simple adducts, 94 - (ii) Chlorine-elimination reactions, 98 - (iii) Reduc
tion reactions, 100 - (iv) Reactions with anionic ligands, 100 - (v) Niobium
(V) and tantalum (V) oxide chlorides, 101
CONTENTS VII
3 Pentabromides 108
a Preparation 108
(i) From the anhydrous pentoxides, 108 - (ii) From the metals, 109
b Physical properties 110
c Chemical properties Ill
(i) Simple adducts, 111 - (ii) Bromine-elimination reactions, 112 - (iii)
Reduction reactions,~113 - (iv) Niobium (V) and tantalum (V) oxide bro
mides, 113
4 Pentaiodides 115
a Preparation 115
b Physical properties 116
c Chemical properties 117
(i) Niobium (V) and tantalum (V) iodides, 117 - (ii) Niubium (V) and
tantalum (V) oxide iodides, 118
B Sub-Halides and Their Derivatives
1 Tetrahalide s - 120
a Tetrafluorides 120
b Tetrachlorides 122
M(IV) oxide chlorides, 128
c Tetrabromides 129
d Tetraiodides 130
M(IV) oxide iodides, 132
2 Trihalide phases 133
a Trifluorides 133
(i) Niobium trifluoride, 133 - (ii) Tantalum trifluoride, 134
b Trichlorides 134
(i) Niobium trichloride, 134- (ii) Nb-;C18 136 - (iii) Tantalum trichlo
ride, 137
c Tribromides 138
(i) Niobium tribromide, 138 - (ii)Nb3Brg, 138 - (iii) Tantalum tribromide,
d Triiodides 140
(i) Niobium triiodide, 140 - (ii) Nb3I8, 141 - (iii) Tantalum triiodide, 141
3 Polynuclear halides containing M, clusters 142
a Fluorides 142
b Chlorides 144
(i) Anhydrous phases, 144 - (ii) Hydrated salts, 145
c Bromides 148
(i) Anhydrous phases, 148 - (ii) Hydrated salts, 149
d Iodides 150
References 152
Chapter 5 Hydrogen Systems 159
a General 159
b Niobium dihydride 164
c Molecular hydrides 165
References 166
Chapter 6 Carbon, Silicon and Boron Systems 167
a Carbon systems 167
(i) Carbides, 167 - (ii) Organometallic compounds, 171 - (iii) Cyanogen
compounds, 174
b Silicon systems 174
c Boron systems 179
References 184
VIII CONTENTS
Chapter 7 Nitrogen, Phosphorus, Arsenic, Antimony and Bismuth Systems 187
a Nitrogen systems 187
(i) The niobium-nitrogen system, 187 - (ii) Carbonitrides, 192 - (iii) Oxo-
nitrides, 192 - (iv) The tantalum-nitrogen system, 192 - (v) Tantalum oxide
nitride, 196- (vi) Molecular metal-nitrogen compounds, 196
b Phosphorus systems 197
c Arsenic systems 200
d Antimony systems 202
e Bismuth systems 205
References 205
Chapter 8 Sulphur, Selenium and Tellurium Systems 207
a Sulphur systems 207
(i) The niobium-sulphur system, 207 - (ii) The tantalum-sulphur system,
208 - (iii) Molecular metal-sulphur systems, 211
b Selenium and tellurium systems 212
(i) The niobium-selenium system, 213 - (ii) The niobium-tellurium system,
216 - (iii) The tantalum-selenium system, 217 - (iv) The tantalum-tellurium
system, 219
References 220
Chapter 9 Analytical Chemistry 222
a General 222
b Dissolution of the sample 224
c Separation from other metals 226
d Gravimetric methods 227
e Chromatographic separation 228
f Solvent extraction 229
g Colorimetric methods 229
h Radiochemical methods 231
References 232
Subject Index
a Niobium 235
b Tantalum 239
|
| any_adam_object | 1 |
| author | Fairbrother, Fred |
| author_facet | Fairbrother, Fred |
| author_role | aut |
| author_sort | Fairbrother, Fred |
| author_variant | f f ff |
| building | Verbundindex |
| bvnumber | BV002278925 |
| callnumber-first | Q - Science |
| callnumber-label | QD181 |
| callnumber-raw | QD181.N3 |
| callnumber-search | QD181.N3 |
| callnumber-sort | QD 3181 N3 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VH 8072 |
| classification_tum | WER 372f WER 368f CHE 373f |
| ctrlnum | (OCoLC)687086 (DE-599)BVBBV002278925 |
| dewey-full | 546/.524 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546/.524 |
| dewey-search | 546/.524 |
| dewey-sort | 3546 3524 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Werkstoffwissenschaften Chemie |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>02093nam a2200589 cb4500</leader><controlfield tag="001">BV002278925</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20130616 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">890928s1967 |||| 00||| eng d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)687086</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV002278925</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-355</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-188</subfield><subfield code="a">DE-210</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD181.N3</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">546/.524</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VH 8072</subfield><subfield code="0">(DE-625)147349:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 372f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 368f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 373f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Fairbrother, Fred</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The chemistry of niobium and tantalum</subfield><subfield code="c">F. Fairbrother</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Amsterdam [u.a.]</subfield><subfield code="b">Elsevier</subfield><subfield code="c">1967</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">VIII, 243 S.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="1" ind2=" "><subfield code="a">Topics in inorganic and general chemistry</subfield><subfield code="v">10</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Chemie</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Metais E Seus Compostos (Quimica)</subfield><subfield code="2">larpcal</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Niobium</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Quimica Inorganica</subfield><subfield code="2">larpcal</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Tantalium</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Niobium</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Tantalum</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Niobverbindungen</subfield><subfield code="0">(DE-588)4280031-6</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Tantalverbindungen</subfield><subfield code="0">(DE-588)4184437-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Tantal</subfield><subfield code="0">(DE-588)4059023-9</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Niob</subfield><subfield code="0">(DE-588)4042362-1</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Tantalverbindungen</subfield><subfield code="0">(DE-588)4184437-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="1" ind2="0"><subfield code="a">Tantal</subfield><subfield code="0">(DE-588)4059023-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="2" ind2="0"><subfield code="a">Niobverbindungen</subfield><subfield code="0">(DE-588)4280031-6</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="2" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="3" ind2="0"><subfield code="a">Niob</subfield><subfield code="0">(DE-588)4042362-1</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="3" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="830" ind1=" " ind2="0"><subfield code="a">Topics in inorganic and general chemistry</subfield><subfield code="v">10</subfield><subfield code="w">(DE-604)BV001888756</subfield><subfield code="9">10</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HEBIS Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497407&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="940" ind1="1" ind2=" "><subfield code="q">HUB-ZB011200803</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-001497407</subfield></datafield></record></collection> |
| id | DE-604.BV002278925 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:43:16Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001497407 |
| oclc_num | 687086 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-83 DE-11 DE-188 DE-210 |
| owner_facet | DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-83 DE-11 DE-188 DE-210 |
| physical | VIII, 243 S. |
| psigel | HUB-ZB011200803 |
| publishDate | 1967 |
| publishDateSearch | 1967 |
| publishDateSort | 1967 |
| publisher | Elsevier |
| record_format | marc |
| series | Topics in inorganic and general chemistry |
| series2 | Topics in inorganic and general chemistry |
| spelling | Fairbrother, Fred Verfasser aut The chemistry of niobium and tantalum F. Fairbrother Amsterdam [u.a.] Elsevier 1967 VIII, 243 S. txt rdacontent n rdamedia nc rdacarrier Topics in inorganic and general chemistry 10 Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd rswk-swf Tantalverbindungen (DE-588)4184437-3 gnd rswk-swf Tantal (DE-588)4059023-9 gnd rswk-swf Niob (DE-588)4042362-1 gnd rswk-swf Tantalverbindungen (DE-588)4184437-3 s DE-604 Tantal (DE-588)4059023-9 s Niobverbindungen (DE-588)4280031-6 s Niob (DE-588)4042362-1 s Topics in inorganic and general chemistry 10 (DE-604)BV001888756 10 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497407&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fairbrother, Fred The chemistry of niobium and tantalum Topics in inorganic and general chemistry Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd Tantalverbindungen (DE-588)4184437-3 gnd Tantal (DE-588)4059023-9 gnd Niob (DE-588)4042362-1 gnd |
| subject_GND | (DE-588)4280031-6 (DE-588)4184437-3 (DE-588)4059023-9 (DE-588)4042362-1 |
| title | The chemistry of niobium and tantalum |
| title_auth | The chemistry of niobium and tantalum |
| title_exact_search | The chemistry of niobium and tantalum |
| title_full | The chemistry of niobium and tantalum F. Fairbrother |
| title_fullStr | The chemistry of niobium and tantalum F. Fairbrother |
| title_full_unstemmed | The chemistry of niobium and tantalum F. Fairbrother |
| title_short | The chemistry of niobium and tantalum |
| title_sort | the chemistry of niobium and tantalum |
| topic | Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd Tantalverbindungen (DE-588)4184437-3 gnd Tantal (DE-588)4059023-9 gnd Niob (DE-588)4042362-1 gnd |
| topic_facet | Chemie Metais E Seus Compostos (Quimica) Niobium Quimica Inorganica Tantalium Tantalum Niobverbindungen Tantalverbindungen Tantal Niob |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497407&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV001888756 |
| work_keys_str_mv | AT fairbrotherfred thechemistryofniobiumandtantalum |